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Results for “Thermionic Energy Conversion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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9 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

System and method for work function reduction and thermionic energy conversion

A thermionic energy converter, preferably including an anode and a cathode. An anode of a thermionic energy converter, preferably including an n-type semiconductor, one or more supplemental layers, and an electrical contact. A method for work function reduction and/or thermionic energy conversion, preferably including inputting thermal energy to a thermionic energy converter, illuminating an anode of the thermionic energy converter, thereby preferably reducing a work function of the anode, and extracting electrical power from the system.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2023

System and method for work function reduction and thermionic energy conversion

A thermionic energy converter, preferably including an anode and a cathode. An anode of a thermionic energy converter, preferably including an n-type semiconductor, one or more supplemental layers, and an electrical contact. A method for work function reduction and/or thermionic energy conversion, preferably including inputting thermal energy to a thermionic energy converter, illuminating an anode of the thermionic energy converter, thereby preferably reducing a work function of the anode, and extracting electrical power from the system.

Schwede, Jared William↗
DOE OSTI2020

Thermionic emission and energy conversion

This project worked on development of a transformative heat-to-electricity conversion device based on thermionic energy conversion. The research provided a unique opportunity to transform the thermionics technology of the 1950-1990s by applying modern materials and 21st century wafer-scale fabrication methods. Research was conducted to further development of a thermionic energy converter based on modern microfabrication and new low work function anode materials that can surpass all other forms of direct heat-to-electricity conversion. This project completed the following goals: (1) Developed components for use in thermionic energy converters and electron emission devices, including electrode materials for electron emission and electron absorption with ultimate work functions below 5 eV; (2) Designed and fabricated thermionic devices for energy conversion and electron emission based on the components developed in (1); (3) Engineered test systems to characterize electronic, thermal, and mechanical properties of thermionic devices and electron emitters and their components, and test devices and components designed and fabricated in (1) and (2); and (4) Developed theoretical modeling capabilities in support of these technical objectives.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Discovery of Stable Surfaces with Extreme Work Functions by High‐Throughput Density Functional Theory and Machine Learning

Abstract The work function is the key surface property that determines the energy required to extract an electron from the surface of a material. This property is crucial for thermionic energy conversion, band alignment in heterostructures, and electron emission devices. This work presents a high‐throughput workflow using density functional theory (DFT) to calculate the work function and cleavage energy of 33,631 slabs (58,332 work functions) that are created from 3,716 bulk materials. The number of calculated surface properties surpasses the previously largest database by a factor of ≈27. Several surfaces with an ultra‐low (<2 eV) and ultra‐high (>7 eV) work function are identified. Specifically, the (100)‐Ba‐O surface of BaMoO 3 and the (001)‐F surface of Ag 2 F have record‐low (1.25 eV) and record‐high (9.06 eV) steady‐state work functions. Based on this database a physics‐based approach to featurize surfaces is utilized to predict the work function. The random forest model achieves a test mean absolute error (MAE) of 0.09 eV, comparable to the accuracy of DFT. This surrogate model enables rapid predictions of the work function (≈ 10 5 faster than DFT) across a vast chemical space and facilitates the discovery of material surfaces with extreme work functions for energy conversion and electronic device applications.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2023

Kinetic simulations of ignited mode cesium vapor thermionic converters

Cesium vapor thermionic converters are an attractive method of converting high-temperature heat directly to electricity, but theoretical descriptions of the systems have been difficult due to the multi-step ionization of Cs through inelastic electron–neutral collisions. This work presents particle-in-cell simulations of these converters, using a direct simulation Monte Carlo collision model to track 52 excited states of Cs. Here, these simulations show the dominant role of multi-step ionization, which also varies significantly based on both the applied voltage bias and pressure. The electron energy distribution functions are shown to be highly non-Maxwellian in the cases analyzed here. A comparison with previous approaches is presented, and large differences are found in ionization rates due especially to the fact that previous approaches have assumed Maxwellian electron distributions. Finally, an open question regarding the nature of the plasma sheaths in the obstructed regime is discussed. The one-dimensional simulations did not produce stable obstructed regime operation and thereby do not support the double-sheath hypothesis.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2025

Efficiency and Physical Limitations of Adiabatic Direct Energy Conversion in Axisymmetric Fields

We describe and analyze a new class of direct energy conversion schemes based on the adiabatic magnetic drift of charged particles in axisymmetric magnetic fields. The efficiency of conversion as well as the geometrical and dynamical limitations of the recoverable power are calculated. The geometries of these axisymmetric field configurations are suited for direct energy conversion in radiating advanced aneutronic reactors and in advanced divertors of deuterium-tritium tokamak reactors. The E × B configurations considered here do not suffer from the classical drawbacks and limitations of thermionic and magnetohydrodynamic high-temperature direct energy conversion devices.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2021

Comprehensive energy balance analysis of photon-enhanced thermionic power generation considering concentrated solar absorption distribution

The present article reports a comprehensive energy balance analysis of a photon-enhanced thermionic emission (PETE) device when it is used for concentrated solar power (CSP) generation. To this end, we consider a realistic PETE device composed of a boron-doped silicon emitter on glass and a phosphorus-doped diamond collector on tungsten separated by the interelectrode vacuum gap. Here, depth-dependent spectral solar absorption and its photovoltaic and photothermal energy conversion processes are rigorously calculated to predict the PETE power output and energy conversion efficiency. Our calculation predicts that when optimized, the power output of the considered PETE device can reach 1.6 W/cm 2 with the energy conversion efficiency of ~ 18% for 100× solar concentration, which is substantially lower than those predicted in previous works under ideal conditions. In addition, the photon-enhancement ratio is lower than 10 and decreases with the increasing solar concentration due to the photothermal heating of the emitter assembly, suggesting that PETE should be more suitable for lowto- medium CSP below ~ 100× concentration. These observations signify the importance of a rigorous energy balance analysis based on spectral and spatial solar absorption distribution for the accurate prediction of PETE power generation.

14 SOLAR ENERGY↗
DOE OSTI2020

Simulation of Nanoscale High-Efficiency Thermionic Converters

LBNL provided development and feedback for Warp's mesh refinement solver and cutcell capabilities, authoring adjusted implementations for use with the dielectric solver in 3D. This work has been documented in a separate branch of the RadiaSoft Warp fork, and is currently under review. LBNL has also provided feedback on the new tests developed to study dielectric charging and shaped emitters. The LBNL contributions enabled the Radiasoft team to progress steadily and meet the goal of the projects for the duration of the collaboration. Results have been reported in one refereed paper, three proceeding papers, four oral and six poster presentions.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2023

Alternative Power and Propulsion for Space Systems

What are the main sources of power and propulsion for space systems and what are their advantages, disadvantages, how do they work, and what are the politics behind them? The following topics will be analyzed solar panels, batteries, radioisotope thermoelectric generator (RTG), advanced Stirling radioscopic generator (ASRG), reactors, nuclear thermal rockets (NTP), thermionic experiment with conversion (TOPAZ), electrothermal plasma thruster (VASIMR), ion propulsion, and finally nuclear pulse propulsion. The production of Pu-238 is extremely controversial but a vital source of fuel for many of these space systems. Soral and Batteries are the most common and the least controversial forms of power used in space systems today. However, is ineffective for deep space exploration as they only function for up to four years without needing to be recharged. This is where nuclear systems come into play. Nuclear systems such as an RTG will “live” up to 88 years. For example, Voyager 1 is powered by an RTG It has been traveling since 1977 and has left out solar system in 2012 and has yet to run out of power. However, this type of technology (nuclear) has many hurtles it needs to jump through before advancements in can go much further.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗