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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Empirical Study of the Multiaxial, Thermomechanical Behavior of NiTiHf Shape Memory Alloys

An empirical study was conducted to characterize the multiaxial, thermomechanical responses of new high temperature NiTiHf alloys. The experimentation included loading thin walled tube Ni(sub 50.3)Ti(sub 29.7)Hf(sub 20) alloy samples along both proportional and nonproportional axial-torsion paths at different temperatures while measuring surface strains using stereo digital image correlation. A Ni(sub 50.3)Ti(sub 33.7)Hf(sub 16) alloy was also studied in tension and compression to document the effect of slightly depleting the Hf content on the constitutive responses of NiTiHf alloys. Samples of both alloys were made from nearly texture free polycrystalline material processed by hot extrusion. Analysis of the data shows that very small changes in composition significantly alter NiTiHf alloy properties, as the austenite finish (Af) temperature of the 16-at Hf alloy was found to be approximately 60 C less than the 20-at Hf alloy (approximately 120 C vs. 180 C). In addition, the 16-at Hf alloy exhibited smaller compressive transformation strains (2 vs. 2.5 percent). Multi-axial characterization of the 20-at % Hf alloy showed that while the random polycrystal transformation strains in tension (4 percent) and compression (2.5 percent) are modest in comparison with binary NiTi (6 percent, 4 percent), the torsion performance is superior (7 vs. 4 shear strain width to the pseudoelastic plateau).

tensile deformation↗

Thermomechanical behavior of a polynorbornadiene

A high-temperature linear amorphous hydrocarbon polymer synthesized cationically from 2,5-norbornadiene was studied thermomechanically with respect to physical transitions and stability in nitrogen. The glass transition temperature was determined to be 320 C (at less than 1 cps), which is probably the highest known for a linear hydrocarbon addition polymer. The thermomechanical technique of torsional braid analysis, together with thermogravimetric analysis, differential thermal analysis, infrared analysis, and solubility studies, was used to investigate the sequential events of the glass transition and degradation. The polymer is of particular interest since it is a high-temperature plastic which in the bulk form would probably need to be processed at high speeds in the vicinity of the glass transition temperature in an inert atmosphere. The presence of tertiary hydrogen atoms should render it amenable to degradation by the earth's environment.

Roller, M. B.↗

Thermomechanical behavior of plasma-sprayed ZrO2-Y2O3 coatings influenced by plasticity, creep and oxidation

Thermocycling of ceramic-coated turbomachine components produces high thermomechanical stresses that are mitigated by plasticity and creep but aggravated by oxidation, with residual stresses exacerbated by all three. These residual stresses, coupled with the thermocyclic loading, lead to high compressive stresses that cause the coating to spall. A ceramic-coated gas path seal is modeled with consideration given to creep, plasticity, and oxidation. The resulting stresses and possible failure modes are discussed.

Padovan, J.↗

Thermomechanical behavior of plasma-sprayed ZrO2-Y2O3 coatings influenced by plasticity, creep, and oxidation

Thermocycling of ceramic-coated turbomachine components produces high thermomechanical stresses that are mitigated by plasticity and creep but aggravated by oxidation, with residual stresses exacerbated by all three. These residual stresses, coupled with the thermocyclic loading, lead to high compressive stresses that cause the coating to spall. A ceramic-coated gas path seal is modeled with consideration given to creep, plasticity, and oxidation. The resulting stresses and possible failure modes are discussed.

Padovan, J.↗

Thermomechanical behavior.

Ductility in polycrystalline single phase ceramics, noting behavior at room and high temperature of single crystal structure, dislocation, etc

DUCTILITY↗

Thermomechanical behavior of amorphous tactic methacrylate polymers

Dynamic mechanical spectra of amorphous stereoregular poly(methyl methacrylate)s and poly(t-butyl methacrylate)s with assigned microtacticities are presented and discussed. An intermolecular argument is invoked to account for the higher glass transition temperature of syndiotactic vis a vis isotactic PMMA, in spite of the higher density of the latter at 30 C. An argument is presented to show that the ratio of glassy-region relaxation temperature to glass transition temperature is not only a measure of the degree of coupling of the beta and glass transition processes, but also of the degree to which intermolecular factors influence these processes. The greater extent of the low-temperature irreversibilities observed in the thermomechanical spectra of poly(t-butyl methacrylate)s is attributed to the brittle character induced by the bulky side groups which presumably weaken cohesive forces.

Kiran, E.↗

Analysis and Development of Finite Element Methods for the Study of Nonlinear Thermomechanical Behavior of Structural Components

Underintegrated methods are investigated with respect to their stability and convergence properties. The focus was on identifying regions where they work and regions where techniques such as hourglass viscosity and hourglass control can be used. Results obtained show that underintegrated methods typically lead to finite element stiffness with spurious modes in the solution. However, problems exist (scalar elliptic boundary value problems) where underintegrated with hourglass control yield convergent solutions. Also, stress averaging in underintegrated stiffness calculations does not necessarily lead to stable or convergent stress states.

Oden, J. Tinsley↗

Thermomechanical Behavior of Advanced SiC Fiber Multifilament Tows

In order to relate single fiber behavior to multiple fiber behavior in composites, fast-fracture tensile strength, creep, and stress-rupture studies were conducted on advanced SiC fiber multifilament tows in the temperature range from 20 to 1400 C in air as well as in inert environments. For conditions of small fiber creep (short times and low temperatures), the tow results of this study confirm the ability of limited single fiber data to model the strength behavior of multiple fibers in a bundle. For conditions of high creep (long times and high temperatures), further studies are needed to explain tow rupture behavior being better than average single fiber behavior.

Yun, Hee Mann↗

Thermomechanical Fatigue Behavior of Three Cfcc's

The thermomechanical fatigue (TMF) behavior of three continuous-fiber ceramic composites (CFCC's) was examined. The three matrices consisted of two different glass-ceramics and silicon carbide, respectively. The matrices of some of the specimens with the silicon carbide matrix were enhanced to improve oxidation resistance. All three were reinforced with Nicalon fibers with various fiber architectures. The thermoelastic properties of the matrix relative to the fibers, the elastic moduli and coefficients of thermal expansion (CTE), were different in each composite, providing a comparison of the effects of these critical properties. The specimens were tested under in-phase (IP) and out-of-phase (OP) cyclic loadings with respect to thermal cycling between 600 C and 1100 C. One of the glass-ceramic composites had greatly increased TMF lives compared to the other glass-ceramic matrix composites. This was probably caused by the reversal of the CTE mismatch between the fibers and the matrices and caused by the different oxidation resistances of the composites. For the same TMF lives a cross-ply reinforced composite had a maximum cyclic stress half as great, as that of unidirectionally reinforced composite. This indicated that the (0 deg) ply fibers had a strong influence of TMF life. Both the glass ceramic matrix composites had shallow-slope stress-life plots that indicated sensitivity to damage and therefore low damage tolerance. The composites with an unenhanced silicon carbide matrix experienced the shortest TMF lives of all the CFCC's tested. However, the enhanced composite had the longest. Also, the enhanced composite demonstrated the best damage tolerance as evidenced by a stress-life curve that curves sharply upward to the left. In all the composites, out-of-phase cyclic loading was worse than in-phase cyclic loadings despite the CTE mismatch between fiber and matrix. A damage investigation and a preliminary analysis of the stresses in the fibers and matrices taking into account their respective thermoelastic properties provided insight into the relative behavior of the glass-ceramic matrix composites under IP and OP TMF.

Worthem, Dennis W.↗

Thermomechanical deformation behavior of a dynamic strain aging alloy, Hastelloy X

An experimental study was performed to identify the effects of dynamic strain aging (solute drag) and metallurgical instabilities under thermomechanical loading conditions. The study involved a series of closely controlled thermomechanical deformation tests on the solid-solution-strenghened nickel-base superalloy, Hastelloy X. This alloy exhibits a strong isothermal strain aging peak at approximately 600 C, promoted by the effects of solute drag and precipitation hardening. Macroscopic thermomechanical hardening trends are correlated with microstructural characteristics through the use of transmission electron microscopy. These observations are compared and contrasted with isothermal conditions. Thermomechanical behavior unique to the isothermal database is identified and discussed. The microstructural characteristics were shown to be dominated by effects associated with the highest temperature of the thermomechanical cycle. Results indicate that the deformation behavior of Hastelloy X is thermomechanically path dependent. In addition, guidance is given pertaining to deformation modeling in the context of macroscopic unified theory. An internal state variable is formulated to qualitatively reflect the isotropic hardening trends identified in the TMD experiments.

Castelli, Michael G.↗

Thermomechanical Fatigue Behavior of Coated and Uncoated Enhanced SiC/SiC Studied

Thermomechanical fatigue (TMF) testing provides a method of evaluating candidate continuous-fiber-reinforced ceramic composites under thermal and mechanical loading conditions. Although these tests are complicated, they provide a reasonable approximation of the combined thermal and mechanical loads that will be experienced by the material in service. The resulting data will be used to develop life-prediction models as well as to aid materials development.

Source record↗

Ability of the total strain version of strainrange partitioning to characterize thermomechanical fatigue behavior

Strainrange partitioning (SRP) was originally developed on an inelastic strain basis for isothermal fatigue in the high-strain regime where the inelastic strainrange could be determined accurately. However, most power-generating equipment operates in the regime where the inelastic strains are small and difficult to determine with any degree of accuracy. This shortcoming led to the development of the total strain version of SRP (TS-SRP). Power-generating equipment seldom operates under isothermal conditions, and isothermal life prediction methods cannot be depended on to predict the lives of anisothermal cycles. To overcome this shortcoming, a method was proposed for extending TS-SRP to characterize anisothermal fatigue behavior and to predict the lives of thermomechanical fatigue (TMF) cycles using apppropriate anisothermal data. The viability of this method, referred to as TMF/TS-SRP, was demonstrated using TMF data for two high-temperature aerospace alloys. In this report, data from the literature are used to examine the ability of TMF/TS-SRP to characterize the failure and flow behavior of three low-strength, high-ductility alloys widely used for ground-based power-generating equipment. The three alloys are type 304 stainless steel, 1Cr-1Mo-0.25V steel, and 2.25Cr-1Mo steel. Because of the limited nature of the data, it was possible to evaluate the characterization, but not the predictive capability of TMF/TS-SRP.

Saltsman, James F.↗

Thermomechanical fatigue behavior of SiC/Ti-24Al-11Nb in air and argon environments

A series of tension-tension, load-controlled thermomechanical fatigue (TMF) tests were conducted on a titanium aluminide composite in both laboratory air and a flowing argon environment. Results from these tests show that the environment plays an increasingly important role as applied stress levels are decreased. Differences in damage mechanisms between the two environments were observed which corresponds to observed variations in TMF lives.

Bartolotta, Paul A.↗