Materials Data on Ti(NO3)4 by Materials Project
Ti(NO3)4 is beta Sn-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Ti(NO3)4 clusters. Ti4+ is bonded in a distorted hexagonal bipyramidal geometry to eight O2- atoms. There are a spread of Ti–O bond distances ranging from 2.09–2.12 Å. There are four inequivalent N5+ sites. In the first N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.20–1.32 Å. In the second N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.20–1.32 Å. In the third N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.20–1.32 Å. In the fourth N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.20–1.31 Å. There are twelve inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the second O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the third O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the fifth O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the sixth O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the eighth O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the ninth O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the tenth O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom. In the eleventh O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the twelfth O2- site, O2- is bonded in an L-shaped geometry to one Ti4+ and one N5+ atom.