Materials Data on Ti4P3 by Materials Project
Ti4P3 crystallizes in the cubic I-43d space group. The structure is three-dimensional. Ti+2.25+ is bonded to six equivalent P3- atoms to form a mixture of distorted face, edge, and corner-sharing TiP6 octahedra. The corner-sharing octahedra tilt angles range from 19–48°. There are three shorter (2.46 Å) and three longer (2.68 Å) Ti–P bond lengths. P3- is bonded in a 8-coordinate geometry to eight equivalent Ti+2.25+ atoms.
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