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At least 19 records

Constraining Mornings and Evenings on Distant Worlds: A new Semianalytical Approach and Prospects with Transmission Spectroscopy

The technique of transmission spectroscopy—the variation of a planetary radius with wavelength due to opacity sources in the planet’s terminator region—has been one of the most successful in the characterization of exoplanet atmospheres to date, providing key insights into the composition and structure of these distant worlds. A common assumption made when using this technique, however, is that the variations are the same in the entire terminator region. In reality, the morning and evening terminators might have distinct temperature, pressure, and thus compositional profiles due to the inherent 3D nature of the planet, which would, in turn, give rise to different spectra on each side of it. Constraining those might be fundamental for our understanding of not only the weather patterns in these distant worlds but also the planetary formation signatures that might only be possible to extract once these features are well understood. Motivated by this physical picture, in this work, we perform a detailed study of the observational prospects of detecting this effect. We present an open-source semianalytical framework with which this information can be extracted directly from transit light curves and perform a detailed study of the prospects of detecting the effect with current missions, such as TESS, and upcoming ones, such as JWST. Our results show that these missions show great promise for the detection of this effect. Transmission spectroscopy studies with JWST, in particular, could provide spectra of each of the limbs, allowing us to convey 3D information previously accessible only via phase curves.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Passive Confirmation of the Presence Of High-Explosive Material Via Neutron Transmission Spectroscopy

The goal of this project was to explore a novel approach for identifying presence and potential types of high explosives (HE) in treaty-controlled items with passive neutron sources by using passive neutron transmission spectroscopy. We predominantly look to measure relative elemental abundance of Carbon, Hydrogen, Oxygen, and Nitrogen (CHON) since most relevant materials are certain mix of these elements, as shown in Table 1. Previously, most studies exploring potential identification of CHON elemental content of targets in the vicinity of passive neutron source were focused solely on gamma spectroscopy using high resolution gamma detectors. Using neutron transmission spectroscopy with pulse-shape discrimination (PSD) capable organic scintillators is not only a novel idea in of itself, but arguably necessary for accurate identification of the CHON elemental content of an interrogated target. While high resolution gamma spectroscopy in principle can determine a presence of hydrogen and nitrogen, it is effectively blind to a quantitatively measuring areal densities of C, O. The initially proposed approach, described in detail in the project proposal, was to leverage previous Monte Carlo study on neutron transmission spectroscopy using slab shaped target interrogated with well-collimated (“pencil”) neutron beam. In this study, a simulated test CO 2 target was interrogated by a pencil neutron beam and transmitted neutron spectra were measured using PSD capable organic scintillator using MLEM based unfolding technique. To establish relative elemental content of carbon and oxygen, the unfolded neutron spectrum was fit with a parametrized combination of their respective elemental spectral templates. The individual spectral template was calculated by convoluting ENDF neutron crosssection with the known resolution of the PSD detector used in the study. This approach in the studied configuration successfully quantitatively established relative elemental composition of carbon and oxygen.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Transmission spectroscopy of CF 4 molecules in intense x-ray fields

The nonlinear interaction of x rays with matter is at the heart of understanding and controlling ultrafast molecular dynamics from an atom-specific viewpoint, providing new scientific and analytical opportunities to explore the structure and dynamics of small quantum systems. At increasingly high x-ray intensity, the sensitivity of ultrashort x-ray pulses to specific electronic states and emerging short-lived transient intermediates is of particular relevance for our understanding of fundamental multiphoton absorption processes. In this work, intense x-ray free-electron laser (XFEL) pulses at the European XFEL are combined with a gas cell and grating spectrometer for a high-intensity transmission spectroscopy study of multiphoton-induced ultrafast molecular fragmentation dynamics in CF 4 . This approach unlocks the direct intrapulse observation of transient fragments, including neutral atoms, by their characteristic absorption lines in the transmitted broadband x-ray spectrum. The dynamics with and without initially producing fluorine 𝐾-shell holes are studied by tuning the central photon energy. The absorption spectra are measured at different FEL intensities to observe nonlinear effects. Transient isolated fluorine atoms and ions are spectroscopically recorded within the ultrashort pulse duration of a few tens of femtoseconds. An isosbestic point that signifies the correlated transition between intact neutral CF 4 molecules and charged atomic fragments is observed near the fluorine 𝐾 edge. The dissociation dynamics and the multiphoton absorption-induced dynamics encoded in the spectra are theoretically interpreted. Overall, this study demonstrates the potential of high-intensity x-ray transmission spectroscopy to study ultrafast molecular dynamics with sensitivity to specific intermediate species and their electronic structure.

74 ATOMIC AND MOLECULAR PHYSICS↗

Combining Spectroscopic Ellipsometry with Transmission Spectroscopy to Derive Accurate Optical Constants for Organic Materials

A method for deriving the optical constants of organic powdered materials in the mid-infrared spectral range is introduced using variable angle spectroscopic ellipsometry and transmission spectroscopy. The approach uses pressed pellets of the powder and is applied to organic solids, which have both strong and weak infrared absorption features. Many powders have significant voids and do not press into smooth, homogenous pellets. To account for pellet non-idealities and to accurately measure both n and k, three different forms of pellets were pressed and measured: A pure analyte pellet, a mixed analyte/KBr pellet with a large analyte percentage, and a KBr transmission pellet with only a small analyte percentage. Using all three pellets in a multi-sample analysis involving both ellipsometric and transmission data, the complex refractive index (n/k) values can be derived for many organic compounds. This method is illustrated to calculate the optical constants for anhydrous lactose from 6000-400 cm-1. The transmission measurements improve the spectral fitting of weak absorption features, and the multi-sample analysis enables a better determination of the significant void space that is present in the pure pellet, leading to lower values for both n and k if not properly accounted for in the multi-oscillator model used to fit the ellipsometric data.

Optical constants, refractive index, extinction co↗

Ground-based Transmission Spectroscopy with VLT FORS2: Evidence for Faculae and Clouds in the Optical Spectrum of the Warm Saturn WASP-110b

We present a ground-based optical transmission spectrum for the warm Saturn-mass exoplanet WASP-110b from two transit observations made with the FOcal Reducer and Spectrograph on the Very Large Telescope. The spectrum covers the wavelength range from 4000–8333 Å, which is binned in 46 transit depths measured to an averaged precision of 220 parts per million (ppm) over an averaged 80 Å bin for a Vmag = 12.8 star. The measured transit depths are unaffected by a dilution from a close A-type field dwarf, which was fully resolved. The overall main characteristic of the transmission spectrum is an increasing radius with wavelength and a lack of the theoretically predicted pressure-broadened sodium and potassium absorption features for a cloud-free atmosphere. We analyze archival high-resolution optical spectroscopy and find evidence for low to moderate activity of the host star, which we take into account in the atmospheric retrieval analysis. Using the AURA retrieval code, we find that the observed transmission spectrum can be best explained by a combination of unocculted stellar faculae and a cloud deck. Transmission spectra of cloud-free and hazy atmospheres are rejected at a high confidence. With a possible cloud deck at its terminator, WASP-110b joins the increasing population of irradiated hot-Jupiter exoplanets with cloudy atmospheres observed in transmission.

47 OTHER INSTRUMENTATION↗

Transmission Spectroscopy for the Warm Sub-Neptune HD 3167c: Evidence for Molecular Absorption and a Possible High-metallicity Atmosphere

We present a transmission spectrum for the warm (500−600 K) sub-Neptune HD 3167c obtained using the Hubble Space Telescope Wide Field Camera 3 infrared spectrograph. We combine these data, which span the 1.125–1.643 μm wavelength range, with broadband transit measurements made using Kepler/K2 (0.6–0.9 μm) and Spitzer/IRAC (4–5 μm). We find evidence for absorption by at least one of H{sub 2}O, HCN, CO{sub 2}, and CH{sub 4} (Bayes factor 7.4; 2.5σ significance), although the data precision does not allow us to unambiguously discriminate between these molecules. The transmission spectrum rules out cloud-free hydrogen-dominated atmospheres with metallicities ≤100× solar at >5.8σ confidence. In contrast, good agreement with the data is obtained for cloud-free models assuming metallicities >700× solar. However, for retrieval analyses that include the effect of clouds, a much broader range of metallicities (including subsolar) is consistent with the data, due to the degeneracy with cloud-top pressure. Self-consistent chemistry models that account for photochemistry and vertical mixing are presented for the atmosphere of HD 3167c. The predictions of these models are broadly consistent with our abundance constraints, although this is primarily due to the large uncertainties on the latter. Interior structure models suggest that the core mass fraction is >40%, independent of a rock or water core composition, and independent of atmospheric envelope metallicity up to 1000× solar. We also report abundance measurements for 15 elements in the host star, showing that it has a very nearly solar composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Gemini/GMOS Transmission Spectroscopy of the Grazing Planet Candidate WD 1856+534 b

WD 1856+534 b is a Jupiter-sized, cool giant planet candidate transiting the white dwarf WD 1856+534. Here, we report an optical transmission spectrum of WD 1856+534 b obtained from ten transits using the Gemini Multi Object Spectrograph. This system is challenging to observe due to the faintness of the host star and the short transit duration. Nevertheless, our phase-folded white light curve reached a precision of 0.12%. WD 1856+534 b provides a unique transit configuration compared to other known exoplanets: the planet is 8x larger than its star and occults over half of the stellar disk during mid-transit. Consequently, many standard modeling assumptions do not hold. We introduce the concept of a “limb darkening corrected, time-averaged transmission spectrum” and propose that this is more suitable than (R pλ /R s ) 2 for comparisons to atmospheric models for planets with grazing transits. We also present a modified radiative transfer prescription. Though the transmission spectrum shows no prominent absorption features, it is sufficiently precise to constrain the mass of WD 1856+534 b to be >0.84 M J (to 2σ confidence), assuming a clear atmosphere and a Jovian composition. High-altitude cloud decks can allow lower masses. WD 1856+534 b could have formed either as a result of common envelope evolution or migration under the Kozai–Lidov mechanism. Further studies of WD 1856+534 b, alongside new dedicated searches for substellar objects around white dwarfs, will shed further light on the mysteries of post-main-sequence planetary systems.

79 ASTRONOMY AND ASTROPHYSICS↗

Atmospheric Transmission Spectroscopy of Hot Jupiter KELT-10b using Synthetic Telluric Correction Software

High-resolution spectroscopic visible data were obtained with the Ultraviolet and Visible Echelle Spectrograph on the Very Large Telescope. Our goal was to analyze the data in an effort to detect the presence of sodium in the atmosphere of hot Jupiter exoplanet KELT-10b, as well as characterize the orbit of the planet via the Rossiter-McLaughlin effect. Eighty spectra were collected during a single transit of KELT-10b. After standard spectroscopic calibration using ESO-Reflex, the synthetic telluric modeling software molecfit was applied to remove terrestrial atmospheric effects, and to refine the wavelength calibration. Sodium is recognized by its characteristic absorption doublet located at 5895.924 and 5889.951 Å, which can be seen in the planet atmosphere transmission spectrum and through excess absorption during the transit. The radial velocity of the host star was analyzed by measuring the average shift of absorption features from spectrum to spectrum. Our results indicate a sodium detection in the planet transmission spectrum with a line contrast of 0.66% and 0.43% ± 0.09% for the sodium DII and DI lines, respectively. Excess absorption measurements agree to within one half combined standard deviation between the planet transmission spectrum (0.143% ± 0.020%, a 7σ detection) and during the time series (0.124% ± 0.034%, a 3.6σ detection) in a band 1.25 Å wide. The wavelength grid corrections provided by molecfit were insufficient to determine radial velocities and measure the Rossiter-McLaughlin effect.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Simultaneous Optical Transmission Spectroscopy of a Terrestrial, Habitable-zone Exoplanet with Two Ground-based Multiobject Spectrographs

Investigating the atmospheres of rocky exoplanets is key to performing comparative planetology between these worlds and the terrestrial planets that reside in the inner solar system. Terrestrial exoplanet atmospheres exhibit weak signals, and attempting to detect them pushes at the boundaries of what is possible for current instrumentation. We focus on the habitable-zone terrestrial exoplanet LHS 1140b. Given its 25-day orbital period and 2 hr transit duration, capturing transits of LHS 1140b is challenging. We observed two transits of this object, approximately 1 yr apart, which yielded four data sets thanks to our simultaneous use of the IMACS and LDSS3C multiobject spectrographs mounted on the twin Magellan telescopes at Las Campanas Observatory. We present a jointly fit white light curve, as well as jointly fit 20 nm wavelength-binned light curves from which we construct a transmission spectrum. Binning the joint white light-curve residuals to 3-minute time bins gives an rms of 145 ppm; binning down to 10-minute time bins gives an rms of 77 ppm. Our median uncertainty in R{sub p}{sup 2}/R{sub s}{sup 2} in the 20 nm wavelength bins is 260 ppm, and we achieve an average precision of 1.3× the photon noise when fitting the wavelength-binned light curves with a Gaussian process regression. Our precision on R{sub p}{sup 2}/R{sub s}{sup 2} is a factor of four larger than the feature amplitudes of a clear, hydrogen-dominated atmosphere, meaning that we are not able to test realistic models of LHS 1140b’s atmosphere. The techniques and caveats presented here are applicable to the growing sample of terrestrial worlds in the Transiting Exoplanet Survey Satellite era, as well as to the upcoming generation of ground-based giant segmented mirror telescopes.

79 ASTRONOMY AND ASTROPHYSICS↗

Optical Transmission Spectroscopy of the Terrestrial Exoplanet LHS 3844b from 13 Ground-based Transit Observations

Atmospheric studies of spectroscopically accessible terrestrial exoplanets lay the groundwork for comparative planetology between these worlds and the solar system terrestrial planets. LHS 3844b is a highly irradiated terrestrial exoplanet (R = 1.303 ± 0.022R {sub ⊕}) orbiting a mid-M dwarf 15 parsecs away. Work based on near-infrared Spitzer phase curves ruled out atmospheres with surface pressures ≥10 bars on this planet. We present 13 transit observations of LHS 3844b taken with the Magellan Clay telescope and the LDSS3C multi-object spectrograph covering 620–1020 nm. We analyze each of the 13 data sets individually using a Gaussian process regression, and present both white and spectroscopic light curves. In the combined white light curve we achieve an rms precision of 65 ppm when binning to 10 minutes. The mean white light-curve value of (R {sub p}/R {sub s}){sup 2} is 0.4170 ± 0.0046%. To construct the transmission spectrum, we split the white light curves into 20 spectrophotometric bands, each spanning 20 nm, and compute the mean values of (R {sub p}/R {sub s}){sup 2} in each band. We compare the transmission spectrum to two sets of atmospheric models. We disfavor a clear, solar composition atmosphere (μ = 2.34) with surface pressures ≥0.1 bar to 5.2σ confidence. We disfavor a clear, H{sub 2}O steam atmosphere (μ = 18) with surface pressures ≥0.1 bar to low confidence (2.9σ). Our observed transmission spectrum favors a flat line. For solar composition atmospheres with surface pressures ≥1 bar we rule out clouds with cloud-top pressures of 0.1 bar (5.3σ), but we cannot address high-altitude clouds at lower pressures. Our results add further evidence that LHS 3844b is devoid of an atmosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

Open-source electrochemical cell for in situ X-ray absorption spectroscopy in transmission and fluorescence modes

X-ray spectroscopy is a valuable technique for the study of many materials systems. Characterizing reactions in situ and operando can reveal complex reaction kinetics, which is crucial to understanding active site composition and reaction mechanisms. In this project, the design, fabrication and testing of an open-source and easy-to-fabricate electrochemical cell for in situ electrochemistry compatible with X-ray absorption spectroscopy in both transmission and fluorescence modes are accomplished via windows with large opening angles on both the upstream and downstream sides of the cell. Using a hobbyist computer numerical control machine and free 3D CAD software, anyone can make a reliable electrochemical cell using this design. Onion-like carbon nanoparticles, with a 1:3 iron-to-cobalt ratio, were drop-coated onto carbon paper for testing in situ X-ray absorption spectroscopy. Cyclic voltammetry of the carbon paper showed the expected behavior, with no increased ohmic drop, even in sandwiched cells. Chronoamperometry was used to apply 0.4 V versus reversible hydrogen electrode, with and without 15 min of oxygen purging to ensure that the electrochemical cell does not provide any artefacts due to gas purging. The XANES and EXAFS spectra showed no differences with and without oxygen, as expected at 0.4 V, without any artefacts due to gas purging. The development of this open-source electrochemical cell design allows for improved collection of in situ X-ray absorption spectroscopy data and enables researchers to perform both transmission and fluorescence simultaneously. It additionally addresses key practical considerations including gas purging, reduced ionic resistance and leak prevention.

08 HYDROGEN↗

A Digital Imaging Method for Evaluating the Kinetics of Vapochromic Response

This work describes the use of a cell phone camera and the L*a*b method (color space specified by the International Commission on Illumination) to characterize the color change in different vapochromic systems. In this study we have developed a semi-automatic color change analysis software that digitally analyzes images (e.g., video frames) collected while a vapochromic material is absorbing vapor. The advantages of using this method, as compared to reflectance spectroscopy or transmission spectroscopy through a thin film, include low cost, convenience, portability, ease of sample preparation, the absence of need for specialized equipment, and the ease of simultaneously collecting data on different samples under identical conditions. In addition, this method arguably provides direct insight into what a human would observe when monitoring these color changes by eye. Limitations of the method also are discussed in this paper.

cell phone camera, colorimetric sensing, vapor det↗

Ga speciation in Ga/H-ZSM-5 by in-situ transmission FTIR spectroscopy

H-ZSM-5 supported Ga (Ga/H-ZSM-5) has long been recognized as a promising catalyst for nonoxidative dehydrogenation and dehydroaromatization of alkanes. However, Ga speciation under reaction conditions remains controversial. In this work, in-situ transmission Fourier Transform infrared (FTIR) spectroscopy is employed to systematically investigate Ga speciation in Ga/H-ZSM-5 with three Si/Al ratios (15, 28 and 39) and a wide range of Ga/Al ratios (0–1.7). Quantitative FTIR spectroscopy with pyridine reveals that one Ga atom roughly replaces one Brønsted acid site (BAS) at Ga/BAS ratio up to 0.7, however, only up to ~80% of the BAS on the H-ZSM-5 can be exchanged even with excess amounts of Ga. At a low Si/Al ratio of 15, the intensity of GaH x bands on reduced Ga/H-ZSM-5 at 550 °C increases almost linearly at low Ga loadings (Ga/Al < 0.13), and then levels off. In contrast, no detectable GaH x bands are observed on Ga/H-ZSM-5 with a high Si/Al ratio of 39, with Ga/Al ratios up to 1.3. The dependence of GaH x bands on both the Si/Al ratios and the Ga/Al ratios shows that Ga speciation varies with BAS density in the zeolite. We hypothesize that paired BAS sites are preferentially exchanged with Ga + , leading to the formation of Ga + –H + pair sites, while the exchange of isolated BAS form isolated Ga+ species. Using water as a probe molecule, we show that isolated Ga + and Ga + –H + pair sites have distinct properties, i.e., the former can be easily oxidized by water at 150 °C to form GaOOH species, while the latter is inactive under the same conditions. Furthermore, these results provide direct experimental evidence for the existence of two types of Ga species on reduced Ga/H-ZSM-5, highlighting the possibility that they have different catalytic activities in alkane dehydrogenation reactions.

03 NATURAL GAS↗

NASA’s Pandora SmallSat Mission: Simulating the Impact of Stellar Photospheric Heterogeneity and Its Correction

Stellar photospheric heterogeneity is a dominant astrophysical systematic impacting exoplanet transmission spectroscopy. NASA’s Pandora SmallSat Mission is designed to address this challenge through contemporaneous visible-band photometry and near-infrared spectroscopy of exoplanet host stars. Here, we present an end-to-end simulation study quantifying Pandora’s ability to infer stellar photospheric properties and correct stellar contamination using out-of-transit observations. We construct eight representative stellar activity scenarios and generate 160 simulated Pandora datasets, incorporating time-dependent stellar spectra, instrument response, and noise. Given accurate models, Bayesian retrievals of joint visible photometry (0.4–0.7 μm) and near-infrared spectroscopy (0.9–1.6 μm, R ≈ 120) recover photospheric temperatures with typical uncertainties of ≈30 K, with no significant bias. Models with two spectral components (i.e., a quiescent photosphere and spots) are strongly favored in 95% of cases; one-component models are preferred when true spot filling factors fall below a detection threshold of ≈0.3%. We propagate the true and inferred stellar parameters to compute true, inferred, and residual contamination signals under physically motivated spot geometries. For simple spot distributions, contamination signals of 10 2 –10 3 ppm are reduced to ≲10 ppm—well below Pandora’s expected transmission spectroscopy precision (30–100 ppm). For more complex spot distributions, geometric degeneracies limit deterministic corrections, leaving residual contamination at the 10 3 ppm level that must be mitigated using additional constraints, such as spot-crossing events and joint stellar–planetary retrievals of transmission spectra. These results define regimes in which stellar contamination can be corrected from stellar observations alone and show how Pandora stellar observations can identify cases where additional information is required.

Astronomy and AstroPhysics↗

Interpreting Ionic Conductivity for Polymer Electrolyte Fuel Cell Catalyst Layers with Electrochemical Impedance Spectroscopy and Transmission Line Modeling

A cathode catalyst layer containing optimally distributed ionomer is critical to reduce the platinum loading and increase its utilization in polymer electrolyte fuel cells. Here, electrochemical impedance spectroscopy (EIS) was used to measure effective ionic conductivity of pseudo catalyst layers (PCLs) at a relative humidity (RH) range of 50%-120%. These results are compared to previous work using the hydrogen pump (HP) method. EIS effective ionic conductivity results reported here are higher than those from the HP because in the HP set-up ionic pathways must be effectively connected through the PCL to be counted, whereas in the EIS measurement, ionomer segments that are in contact with the membrane but are not effectively connected all the way through the PCL can be detected. Double layer capacitances and effective ionic conductivities of Pt/C catalyst layers with various supports and ionomer to carbon (I/C) ratios were studied. High surface area carbon support resulted in a lower effective ionic conductivity compared to the graphitized carbon support due to worse ionomer dispersion. Effective ionic conductivities of Pt/C layers were compared to that of PCLs. On average, effective ionic conductivities of Pt/C layers were higher than PCLs because of possible carbon agglomeratio n within the PCLs.

25 ENERGY STORAGE↗

Physical Parameters of the Multiplanet Systems HD 106315 and GJ 9827

HD 106315 and GJ 9827 are two bright, nearby stars that host multiple super-Earths and sub-Neptunes discovered by K2 that are well suited for atmospheric characterization. We refined the planets’ ephemerides through Spitzer transits, enabling accurate transit prediction required for future atmospheric characterization through transmission spectroscopy. Through a multiyear high-cadence observing campaign with Keck/High Resolution Echelle Spectrometer and Magellan/Planet Finder Spectrograph, we improved the planets’ mass measurements in anticipation of Hubble Space Telescope transmission spectroscopy. For GJ 9827, we modeled activity-induced radial velocity signals with a Gaussian process informed by the Calcium II H&K lines in order to more accurately model the effect of stellar noise on our data. We measured planet masses of M {sub b} = 4.87 ± 0.37 M {sub ⊕}, M {sub c} = 1.92 ± 0.49 M {sub ⊕}, and M {sub d} = 3.42 ± 0.62 M {sub ⊕}. For HD 106315, we found that such activity radial velocity decorrelation was not effective due to the reduced presence of spots and speculate that this may extend to other hot stars as well (T {sub eff} > 6200 K). We measured planet masses of M {sub b} = 10.5 ± 3.1 M {sub ⊕} and M {sub c} = 12.0 ± 3.8 M {sub ⊕}. We investigated all of the planets’ compositions through comparison of their masses and radii to a range of interior models. GJ 9827 b and GJ 9827 c are both consistent with a 50/50 rock-iron composition, GJ 9827 d and HD 106315 b both require additional volatiles and are consistent with moderate amounts of water or hydrogen/helium, and HD 106315 c is consistent with a ∼10% hydrogen/helium envelope surrounding an Earth-like rock and iron core.

47 OTHER INSTRUMENTATION↗