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At least 19 records

Development of a tritium recovery system from CANDU tritium removal facility

The main purpose of the Tritium Recovery System (TRS) is to reduce to a maximum possible extent the release of tritium from the facility following a tritium release in confinement boundaries and also to have provisions to recover both elemental and vapors tritium from the purging gases during maintenance and components replacement from various systems processing tritium. This work/paper proposes a configuration of Tritium Recovery System wherein elemental tritium and water vapors are recovered in a separated, parallel manner. The proposed TRS configuration is a combination of permeators, a platinum microreactor (MR) and a trickle bed reactor (TBR) and consists of two branches: one branch for elemental tritium recovery from tritiated deuterium gas and the second one for tritium recovery from streams containing a significant amount of water vapours but a low amount, below 5%, of tritiated gas. The two branches shall work in a complementary manner in such a way that the bleed stream from the permeators shall be further processed in the MR and TBR in view of achieving the required decontamination level. A preliminary evaluation of the proposed TRS in comparison with state of the art tritium recovery system from tritium processing facilities is also discussed. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Seismic Testing of Glovebox Feedthrough Connectors and Vacuum Pumps

In the design of tritium processing systems, the glovebox stripper system processes the glovebox atmosphere to recover tritium released inside the glovebox confinement. The glovebox stripper system must also be capable of processing the additional in-leakage caused by a Design Basis Accident (DBA) earthquake, in order to maintain the glovebox pressure negative relative to the room. However, it is unknown how much additional leakage occurs from electrical bulkhead feedthrough connectors after a DBA event. As there are dozens of these connectors on a tritium glovebox system, the potential increase in in-leakage can be significant. One vital part of the glovebox stripper system are the vacuum pumps that maintain the negative atmosphere of the glovebox following a DBA earthquake. The pumps must be able to operate following an earthquake. One candidate pump is the Senior Aerospace MB-602 Metal Bellows (Met-Bel) pump. A second alternative is the hermetically sealed Edwards Vacuum nXDS15iC Scroll Pump. The Edwards scroll pump is potentially a less expensive alternative to the Met-Bel pumps, but it is unknown if this scroll pumps will survive a DBA accident and remain operational. In order to determine the electrical feedthrough in-leakage and the candidate pumps’ survivability, a seismic test was performed to simulate a DBA earthquake. This report summarizes the results of seismic test, including helium leak rates and functionality tests for the electrical feedthroughs and vacuum pumps. All components had pre- and post-test leak rates less than the threshold valve of 1x10 -6 scc per sec.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Pre-Conceptual Design for Northstar ⁹⁹Mo Process Tritium Removal System

In this report we describe a preliminary concept for a Tritium Removal System (TRS) to remove tritium that is generated in the ⁹⁹Mo production process. Preliminary calculations have been performed to evaluate an approximate size for the system. The concept described utilizes well-established detritiation technology based on catalytic oxidation of tritium and tritiated hydrocarbons to water in a high temperature (400 °C) reactor and capture of water in a molecular sieve bed. The TRS concept involves use of a single system that would cycle through each of the seven online target systems and remove tritium that has been accumulated after one week’s run time. The TRS would perform cleanup operations on each target system for a period of approximately 24 hours. This would occur while the system is still online and just prior to target replacement, so tritium levels would at their minimum values for target replacement. In the concept, during normal operation a small fraction (1%) of the helium recirculating in the system would be diverted through the TRS and returned to the flow loop. With this approach sufficient levels of detritiation can be accomplished in a 24 hour period. In the study it was found that because of the need to maintain low oxygen levels in the system (<100 ppm) this increases the size of the catalytic reactor. As a result of this finding, consideration should be given to other methods for removing tritium from the system. Other methods such as catalytic exchange of tritium with an unsaturated organic compound and subsequent trapping on activated carbon or molecular sieve could offer advantages of reducing reactor size and operation at lower reactor temperature. However the most significant advantage of such an approach would be the ability to operate in very low oxygen environments, which would eliminate any concerns for oxidation of the target.

07 ISOTOPE AND RADIATION SOURCES↗

Physics and technology considerations for the deuterium–tritium fuel cycle and conditions for tritium fuel self sufficiency

The tritium aspects of the DT fuel cycle embody some of the most challenging feasibility and attractiveness issues in the development of fusion systems. The review and analyses in this paper provide important information to understand and quantify these challenges and to define the phase space of plasma physics and fusion technology parameters and features that must guide a serious R&D in the world fusion program. We focus in particular on components, issues and R&D necessary to satisfy three 'principal requirements': (1) achieving tritium self-sufficiency within the fusion system, (2) providing a tritium inventory for the initial start-up of a fusion facility, and (3) managing the safety and biological hazards of tritium. A primary conclusion is that the physics and technology state-of-the-art will not enable DEMO and future power plants to satisfy these principal requirements. We quantify goals and define specific areas and ideas for physics and technology R&D to meet these requirements. A powerful fuel cycle dynamics model was developed to calculate time-dependent tritium inventories and flow rates in all parts and components of the fuel cycle for different ranges of parameters and physics and technology conditions. Dynamics modeling analyses show that the key parameters affecting tritium inventories, tritium start-up inventory, and tritium self-sufficiency are the tritium burn fraction in the plasma (f b ), fueling efficiency (η f ), processing time of plasma exhaust in the inner fuel cycle (t p ), reactor availability factor (AF), reserve time (tr) which determines the reserve tritium inventory needed in the storage system in order to keep the plant operational for time t r in case of any malfunction of any part of the tritium processing system, and the doubling time (t d ). Results show that η f f b > 2% and processing time of 1–4 h are required to achieve tritium self-sufficiency with reasonable confidence. For η f f b = 2% and processing time of 4 h, the tritium start-up inventory required for a 3 GW fusion reactor is ~11 kg, while it is <5 kg if η f f b = 5% and the processing time is 1 h. To achieve these stringent requirements, a serious R&D program in physics and technology is necessary. The EU-DEMO direct internal recycling concept that carries fuel directly from the plasma exhaust gas to the fueling systems without going through the isotope separation system reduces the overall processing time and tritium inventories and has positive effects on the required tritium breeding ratio (TBR R ). A significant finding is the strong dependence of tritium self-sufficiency on the reactor availability factor. Simulations show that tritium self-sufficiency is: impossible if AF < 10% for any η f f b , possible if AF > 30% and 1% ≤ η f f b ≤ 2%, and achievable with reasonable confidence if AF > 50% and η f f b > 2%. These results are of particular concern in light of the low availability factor predicted for the near-term plasma-based experimental facilities (e.g. FNSF, VNS, CTF), and can have repercussions on tritium economy in DEMO reactors as well, unless significant advancements in RAMI are made. There is a linear dependency between the tritium start-up inventory and the fusion power. The required tritium start-up inventory for a fusion facility of 100 MW fusion power is as small as 1 kg. Since fusion power plants will have large powers for better economics, it is important to maintain a 'reserve' tritium inventory in the tritium storage system to continue to fuel the plasma and avoid plant shutdown in case of malfunctions of some parts of the tritium processing lines. But our results show that a reserve time as short as 24 h leads to unacceptable reserve and start-up inventory requirements. Therefore, high reliability and fast maintainability of all components in the fuel cycle are necessary in order to avoid the need for storing reserve tritium inventory sufficient for continued fusion facility operation for more than a few hours. The physics aspects of plasma fueling, tritium burn fraction, and particle and power exhaust are highly interrelated and complex, and predictions for DEMO and power reactors are highly uncertain because of lack of experiments with burning plasma. Fueling by pellet injection on the high field side of tokamak has evolved to be the preferred method to fuel a burning plasma. Extrapolation from the DIII-D penetration scaling shows fueling efficiency expected in DEMO to be <25%, but such extrapolations are highly uncertain. The fueling efficiency of gas in a reactor relevant regime is expected to be extremely poor and not very useful for getting tritium into the core plasma efficiently. Gas fueling will nonetheless be useful for feedback control of the divertor operating parameters. Extensive modeling has been carried out to predict burn fraction, fueling requirements, and fueling efficiency for ITER, DEMO, and beyond. The fueling rate required to operate Q = 10 ITER plasmas in order to provide the required core fueling, helium exhaust and radiative divertor plasma conditions for acceptable divertor power loads was calculated. If this fueling is performed with a 50–50 DT mix, the tritium burn fraction in ITER would be ~0.36%, which is too low to satisfy the self-sufficiency conditions derived from the dynamics modeling for fusion reactors. Extrapolation to DEMO using this approach would also yield similarly low burn fraction. Extensive analysis presented shows that specific features of edge neutral dynamics in ITER and fusion reactors, which are different from present experiments, open possibilities for optimization of tritium fueling and thus to improve the burn fraction. Using only tritium in pellet fueling of the plasma core, and only deuterium for edge density, divertor power load and ELM control results in significant increase of the burn fraction to 1.8–3.6%. These estimates are performed with physics models whose results cannot be fully validated for ITER and DEMO plasma conditions since these cannot be achieved in present tokamak experiments. Thus, several uncertainties remain regarding particle transport and scenario requirements in ITER and DEMO. The safety standard requirements for protection of the public and release guidelines for tritium have been reviewed. General safety approaches including minimizing tritium inventories, reducing tritium permeation through materials, and decontaminating material for waste disposal have been suggested.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Development of Alternative Vacuum Pumps for Tritium Service

In tritium process systems, vacuum pumps are typically used to evacuate volumes and piping, as well as transfer gas to other parts of the process. This was done using the combination of an all-metal scroll pump with a metal bellows backing pump. The all-metal scroll pump, manufactured by Normetex, has been unavailable since 2012, and efforts continue to find a suitable replacement. The main obstacle is finding a pump that has no oils or polymer components, which degrade when exposed to tritium and introduce corrosive and/or hazardous impurities into the process. Since turbomolecular pumps are used in tritium processing, it is thought that pumps similar to the turbomolecular pumps would be of interest. The pumps would need to operate at lower rotational speeds to handle higher pressures and flow rates, which is best suited for Molecular Drag Pumps (MDP). To determine this, the vacuum pump characteristics must be determined for the MDP. This report details pump characteristics using an MDP backed by a Metal Bellows (Met-Bel) pump under static and flow conditions for various gases.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SHINE Vacuum Pump Test Verification

Normetex pumps used world-wide for tritium service are no longer available. DOE and other researchers worldwide have spent significant funds characterizing this pump. Identification of alternate pumps is required for performance and compatibility with tritium gas. Many of the pumps that could be used to meet the functional performance requirements (e.g. pressure and flow conditions) of the Normetex pump have features that include the use of polymers or oils and greases that are not directly compatible with tritium service. This study assembles a test system to determine the flow characteristics for candidate alternate pumps. These tests are critical to the movement of tritium through the SHINE Tritium Purification System (TPS).

07 ISOTOPE AND RADIATION SOURCES↗

Use of system code to estimate equilibrium tritium inventory in fusion DT machines, such as ARIES-AT and components testing facilities

ITER is under construction and will begin operation in 2020. This is the first 500 MWfusion class DT device, and since it is not going to breed tritium, it will consume most of the limited supply of tritium resources in the world. Yet, in parallel, DT fusion nuclear component testing machines will be needed to provide technical data for the design of DEMO. It becomes necessary to estimate the tritium burn-up fraction and corresponding initial tritium inventory and the doubling time of these machines for the planning of future supply and utilization of tritium. With the use of a system code, tritium burn-up fraction and initial tritium inventory for steady state DT machines can be estimated. Estimated tritium burn-up fractions of FNSF-AT, CFETR-R and ARIES-AT are in the range of 1–2.8%. Corresponding total equilibrium tritium inventories of the plasma flow and tritium processing system, and with the DCLL blanket option are 7.6 kg, 6.1 kg, and 5.2 kg for ARIES-AT, CFETR-R and FNSF-AT, respectively.

99 GENERAL AND MISCELLANEOUS↗

Radiolytic Gas Production Rates of Polymers Exposed to Tritium Gas

Data from previous reports on studies of polymers exposed to tritium gas is further analyzed to estimate rates of radiolytic gas production. Also, graphs of gas release during tritium exposure from ultrahigh molecular weight polyethylene (UHMW-PE), polytetrafluoroethylene (PTFE, a trade name is Teflon®), and Vespel® polyimide are re-plotted as moles of gas as a function of time, which is consistent with a later study of tritium effects on various formulations of the elastomer ethylene-propylene-diene monomer (EPDM). These gas production rate estimates may be useful while considering using these polymers in tritium processing systems. These rates are valid at least for the longest exposure times for each material, two years for UHMW-PE, PTFE, and Vespel®, and fourteen months for filled and unfilled EPDM. Note that the production “rate” for Vespel® is a quantity of H 2 produced during a single exposure to tritium, independent of length of time. The larger production rate per unit mass for unfilled EPDM results from the lack of filler- the carbon black in filled EPDM does not produce H 2 or HT. This is one aspect of how inert fillers reduce the effects of ionizing radiation on polymers.

36 MATERIALS SCIENCE↗

Evaluation of High Vacuum Pump for Tritium Service

In tritium process systems, vacuum pumps are typically used to evacuate volumes and piping, as well as transfer gas to other parts of the process. This was done using the combination of an all-metal scroll pump with a metal bellows backing pump. The all-metal scroll pump, manufactured by Normetex, has been unavailable since 2012, and efforts continue to find a suitable replacement. The main obstacle is finding a pump that has no oils or polymer components, which degrade when exposed to tritium and introduce corrosive and/or hazardous impurities into the process. Since turbomolecular pumps are used in tritium processing, it is thought that pumps similar to the turbomolecular pumps would be of interest. A newer model turbomolecular pump with a variable rotation speed has been identified for use in tritium processing. The turbomolecular pump, backed by a Metal Bellows MB-601 pump with the pump heads in series, was characterized for static and gas flow conditions to determine the suction pressure at various discharge pressures or flow rates for various gases.

42 ENGINEERING↗

Alternative All-Metal Scroll Pump Design

In tritium process systems, vacuum pumps are typically used to evacuate volumes and piping, as well as transfer gas to other parts of the process. This was done using the combination of an all-metal scroll pump with a metal bellows backing pump. The all-metal scroll pump, manufactured by Normetex, has been unavailable since 2012, and efforts continue to find a suitable replacement. The main obstacle is finding a pump that has no oils or polymer components, which degrade when exposed to tritium and introduce corrosive and/or hazardous impurities into the process. There have been development efforts to design an all-metal scroll pump design alternative to the Normetex style. The first generation was fabricated out of machined stainless steel, but the thermal management and increased weight were not ideal. To mitigate the weight, an aluminum version was designed. The tritium holdup on untreated aluminum surfaces can be greater than stainless steel, so the wetted aluminum surfaces were electroless plated in nickel and then electroplated in gold. The development effort outlined in this report details the design of an improved version of the stainless steel version.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comparison of Fuel Cycles for Lead-Lithium and Pure Lithium Liquid Metal Walls in a Magnetized Target Fusion Power Plant

General Fusion (GF) is developing an adaptable, commercial fusion power plant based on magnetized target fusion (MTF). The GF approach involves forming a spherical torus of deuterium-tritium plasma in a large (~4 m diameter) cavity formed in liquid metal, and then collapsing that cavity with an array of pneumatic piston drivers. The liquid metal is constantly flowing through the fusion chamber and out to processing systems where tritium and heat will be extracted using tritium extraction technologies and heat exchangers, respectively. Here, this study focuses on two candidate designs for the liquid metal blanket and first wall material for the General Fusion Magnetized Target Fusion (GF MTF) power plant and assesses their impact on the tritium fuel cycle. The first candidate is the lead lithium eutectic (LLE) and the second candidate is pure lithium (Li). It was found that the main differences between LLE and Li designs are the extraction technologies required to remove tritium from the blanket and the amount of tritium and its distribution within the facility. More than 80% of the in-process tritium inventory for the LLE design is contained in the isotope separation system, while for the Li design, over 60% of the in-process tritium inventory is contained within the blanket material. This is due to significant tritium retention by Li. For the Li blanket, the burden of tritium processing rests on the blanket extraction technology rather than the traditional exhaust processing route. Thus, the blanket extraction technology is a main driver of tritium inventory in the Li system and determines the subsequent interface with the tritium processing plant.

General Fusion↗

Tritium processing for the European test blanket systems: current status of the design and development strategy

Tritium processing technologies of the two European Test Blanket Systems (TBS), HCLL (Helium Cooled Lithium Lead) and HCPB (Helium Cooled Pebble Bed), play an essential role in meeting the main objectives of the TBS experimental campaign in ITER. The compliancy with the ITER interface requirements, in terms of space availability, service fluids, limits on tritium release, constraints on maintenance, is driving the design of the TBS tritium processing systems. Other requirements come from the characteristics of the relevant test blanket module and the scientific programme that has to be developed and implemented. This paper identifies the main requirements for the design of the TBS tritium systems and equipment and, at the same time, provides an updated overview on the current design status, mainly focusing onto the tritium extractor from Pb-16Li and TBS tritium accountancy. Considerations are also given on the possible extrapolation to DEMO breeding blanket. (authors)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Continuing the Evaluation of All-Metal Values for Use in a Tritium Environment

It is desired in tritium gas processing systems to minimize the use of polymer components due to their degradation from tritium exposure (beta decay). One source of polymers in tritium processes are valve components. An all-metal diaphragm valve with no plastic wetting components could be used in certain tritium applications to reduce organic materials in the tritium process.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Evaluating All-Metal Valves for Use in a Tritium Environment

In the tritium gas processing system, it is desired to minimize polymer components due to their degradation from tritium exposure (beta decay). One source of polymers in the tritium process is valve components. A vendor has been identified that manufactures a valve that is marketed as being made from all-metal construction. This manufacturer, Ham-Let Group, manufactures a diaphragm valve (3LE series) that claims to be made entirely of metal. SRNL procured twelve (12) Ham-Let diaphragm valves for characterization and evaluation. The characterization tests include identification of the maximum pressure of these valves by performing pressure and burst tests. Leak tests were performed to ensure the valves do not exceed the acceptable leak rate for tritium service. These valves were then cycled in a nitrogen gas and/or vacuum environment to ensure they would be durable in a process environment. They were subsequently leak tested per ASTM protocol to ensure that the valves maintained their leak tight integrity. A detailed material analysis was also conducted to determine hydrogen and tritium compatibility.

36 MATERIALS SCIENCE↗

Component Testing Supporting SHINE Medical Technologies

SHINE is going to be implementing a tritium gas processing system to support their Mo-99 work. They have requested that the Hydrogen Process Group of SRNL does some required testing on the system components before startup. The lab plans on conducting both seismic and valve testing. Test Plan: - Testing 10 1C valves 750,000 cycles or until failure; - Testing intervals will be every couple thousand; - 1C valves will have metal stem tips instead of Polymer due to being in a tritium prone area; - Hope that the valves will still have enough force to create a sufficient seal with metal stem tips; - Goal is for a more cost and space efficient alternative to the 5C valves. Status: - Received half the parts, waiting on the other half due to long procurement times; - Waiting on the LabVIEW program which will perform the testing. Path Forward: - R and DE to change out the stem tips (July 2018); - Assemble Manifold (July 2018); - Perform Testing (August 2018); - Report (September 2018). Since SRNL does not own a shaker table, the test will be conducted at a facility like the NTS Facility in Huntsville, Alabama. Test Plans: - Leak Testing; - Use LabVIEW to monitor for leaks before, during and after seismic testing with an Electronic Pressure Transducer; - If leak is detected, sniff for location using Helium Leak Detector; - Connector Testing; - Use LabVIEW to test for electrical continuity before, during and after seismic testing; - If a connectors continuity is interrupted, further testing will be performed; - Each Pin in faulty connector will be testing to determine specific location of disruption. Path Forward: - Pick a Qualified Vender for testing (July 2018); - Procure the connector plugs (July 2018); - Send components and test plan to facility for testing (August 2018); - Perform Testing (August-September 2018); - Report Results (September 2018)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Testing of an Iodine and Tritium Capture System for an NO₂-Based Tritium Pretreatment Process

The reprocessing of used nuclear fuel would release volatile radionuclides into the off-gas streams of a processing plant, including ³H, ¹⁴C, ⁸⁵Kr, and ¹²⁹I. One potential simplification to the management of the off-gas streams could be achieved through an efficient tritium pretreatment (TPT) step in which the UO₂ fuel is oxidized by either air or NO₂ before dissolution. The oxidation of the UO₂ fuel matrix will result in the release of tritium from the fuel. Upfront release of tritium from the fuel in a pretreatment step with subsequent tritium abatement can minimize or eliminate the distribution of tritium throughout a plant. This can decrease or eliminate the need for tritium capture on multiple off-gas streams and prevent distribution to the aqueous inventory. The use of NO₂ as the oxidant in an advanced tritium pretreatment (ATPT) allows for the oxidation to be performed at lower temperatures and may also result in the quantitative release of iodine from the fuel. The ATPT off-gas will contain up to 75 vol% NO₂ gas. Spencer et al. identified the most promising iodine sorbent as silver nitrate-impregnated alumina (AgA) and the most promising tritium sorbents as 3Å molecular sieve (3Å MS) and silica gel for radionuclide capture from ATPT off-gas streams. An initial series of tests were conducted in fiscal years 2017–2018 with the intent of demonstrating the recovery of iodine and tritium using these sorbents from a recirculating gas stream that simulated the NO₂ recycle loop envisioned for the ATPT system. These initial tests showed low tritium recoveries and significant variations in the iodine recovery on the AgA. Ultimately it was concluded, following disassembly of the system, that corrosion within the system was partially the cause of the poor recovery of both species. All components of that system were disposed of at the end of the analysis. One of the conclusions drawn from the initial tests pointed to the reconsideration of the materials of construction. Based on that recommendation a new test bed for the advanced TPT off-gas system, that addresses the issues identified in the fiscal years 2017 and 2018 scoping tests, was designed and constructed. The test bed used high nickel alloys wherever possible to address the previously observed corrosion issues, a redesigned surge tank to permit ease of purging, an improved feed injection system and a more modular system design that allowed testing of incremental increases in system complexity to allow the isolation of any element that results in changes to recovery of target species. Accompanying that design, a multifaceted test plan was completed. The overarching goals of this test series were two-fold. The first goal was to demonstrate the ability to recover both the iodine and tritium that would be released during TPT in a manner that the releases from the fuel can be quantified. The second goal was to demonstrate that the combined recovery system could operate in any of the three proposed TPT modes (once-through air or O₂, recirculating air or O₂, or recirculating NO x ). A total of 22 tests were completed. Ten tests examined tritium behavior under varying operating parameters, 8 tests examined iodine behavior under varying operating parameters, and 4 tests examined both tritium and iodine behavior. Silica gel was used for the tritium sorbent, and AgA or Ag-mordenite (AgZ) was used as the iodine sorbent. The following conclusions were drawn: Full recovery is achieved for both sorbates when no sorbent is in place indicating no accumulation within the test system. In even the simplest of the configurations (i.e., no sorbents in the columns), iodine is more difficult to transport and recover from the system than tritium. Analysis of the AgA iodine sorbent beds from the integrated tritium and iodine tests indicate quantitative iodine recovery can be achieved (within anticipated experimental errors). This system may provide a means for the quantification of the iodine released by the ATPT process within the experimental uncertainties. This would support 0.33 to 1.00 kg demonstrations of the ATPT process with actual used nuclear fuel. Iodine penetrated further into AgZ than into AgA when operated in gas recirculation mode. Tritium adsorbs to and cannot be fully recovered from the 10-cm column of silica gel at regeneration temperatures up to 140 °C.; Tritium adsorbs to and cannot be recovered from the 10-cm column of AgA at desorption temperatures up to 200 °C. Co-adsorbed tritium was recovered to a greater extent from AgZ than from AgA, but recovery was not complete. No visible corrosion was observed in the test system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Microwave-assisted regeneration of synthetic zeolite used in tritium removal systems

The regeneration process using synthetic honeycomb type 5A zeolite under microwave irradiation was experimentally investigated using a single-mode cavity at 2.46 GHz. In order to investigate the effect of electromagnetic fields, inductive heating by a magnetic field was applied to synthetic zeolite containing water. Because the microwave energy absorbed in the sample was less than 15 W, the zeolite sample was only heated to a temperature of 71 C. degrees. Water desorption was observed based on the increased temperature of the zeolite sample and the thermogravimetric curve that indicated a single step phenomenon. As a result, the regeneration process of zeolite was not complete over a period of 6000 s. A comparison of dielectric heating by an electric field with inductive heating by a magnetic field showed that the regeneration process by microwave irradiation was particularly beneficial in dielectric heating. (authors)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗