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AmeriFlux FLUXNET-1F US-UC2 LTAR UCB (Upper Chesapeake Bay) EC2

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-UC2 LTAR UCB (Upper Chesapeake Bay) EC2. This is the FLUXNET version of the carbon flux data for the site US-UC2 LTAR UCB (Upper Chesapeake Bay) EC2 produced by applying the standard ONEFlux (1F) software. Site Description - Upper Chesapeake Bay farm is privately owned. The farming that took place was performed by the Farm Owner. The ground is rolling terrain, next to wooded areas, private resdiences and other large fields maintained by private land owners. At the time of this collection period, the site housed another Eddy Covariance System and a two Phenocams. Crop has been continuous corn with plans to rotate to alfalfa grass mixture.

Goslee, Sarah↗

Materials Data on UC2 by Materials Project

UC2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. U6+ is bonded in a 10-coordinate geometry to ten equivalent C3- atoms. There are two shorter (2.29 Å) and eight longer (2.58 Å) U–C bond lengths. C3- is bonded in a 2-coordinate geometry to five equivalent U6+ and one C3- atom. The C–C bond length is 1.38 Å.

36 MATERIALS SCIENCE↗

Materials Data on UC2 by Materials Project

UC2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. U6+ is bonded in a body-centered cubic geometry to eight equivalent C3- atoms. All U–C bond lengths are 2.33 Å. C3- is bonded to four equivalent U6+ atoms to form a mixture of edge and corner-sharing CU4 tetrahedra.

36 MATERIALS SCIENCE↗

Materials Data on UC2 by Materials Project

UC2 is Pyrite structured and crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. U6+ is bonded to six equivalent C3- atoms to form UC6 octahedra that share corners with twelve equivalent UC6 octahedra and corners with six equivalent CU3C tetrahedra. The corner-sharing octahedral tilt angles are 72°. All U–C bond lengths are 2.36 Å. C3- is bonded to three equivalent U6+ and one C3- atom to form CU3C tetrahedra that share corners with three equivalent UC6 octahedra and corners with fifteen equivalent CU3C tetrahedra. The corner-sharing octahedral tilt angles are 69°. The C–C bond length is 1.43 Å.

36 MATERIALS SCIENCE↗

AmeriFlux US-UC2 LTAR UCB (Upper Chesapeake Bay) EC2

This is the AmeriFlux version of the carbon flux data for the site US-UC2 LTAR UCB (Upper Chesapeake Bay) EC2. Site Description - Upper Chesapeake Bay farm is privately owned. The farming that took place was performed by the Farm Owner. The ground is rolling terrain, next to wooded areas, private resdiences and other large fields maintained by private land owners. At the time of this collection period, the site housed another Eddy Covariance System and a two Phenocams. Crop has been continuous corn with plans to rotate to alfalfa grass mixture.

Goslee, Sarah↗

Irradiation of UC1+x kernels using the MiniFuel vehicle: Microstructure, phase analysis, and initial post-irradiation examination

Uranium carbide is a candidate fuel form for a wide range of advanced reactors, including larger Generation IV reactors as well as small modular reactors and microreactors. However, its commercial deployment timeline faces challenges via traditional qualification approaches. To address this issue, an accelerated fission rate irradiation test was performed to collect basic fuel performance data to inform fuel performance models and potential future integral tests. Hyperstoichiometric UC (UC1+x) kernels were irradiated in the High Flux Isotope Reactor using the MiniFuel irradiation vehicle. The test matrix spanned two temperature regimes (700 °C and 800 °C) and burnup levels (1.8 % FIMA and 2.8 % FIMA). Between 21 and 63 kernels were tested at each unique temperature and burnup condition. As-fabricated microstructural analysis revealed a multiphase composition with UC, UC2, UC2−y, and U-C-O bearing phases for the irradiated kernels. Following irradiation, fission gas release, swelling, and microstructures were analyzed. Measured fission gas release was below 5 % for all irradiation conditions, reaching a maximum at the highest temperature and burnup condition. A binary swelling response was observed; the lower burnup and temperature conditions resulted in negligible swelling, but the higher burnup and temperature conditions produced significant anisotropic swelling and densification in a subset of kernels. The basic microstructural exams of kernels following irradiation were not capable of showing a correlation between kernels that exhibited excessive swelling and those that did not. Characterization of a subset of samples using the Advanced Photon Source and more detailed microstructural examination of unirradiated kernels revealed that a subset of kernels contained very high UC2 phase fractions. The anomalous swelling response is hypothesized to have been driven by this chemical variation. The results of this irradiation highlight the potential of accelerated fission rate irradiation testing to explore such behaviors and inform the development of fuel specifications.

Adorno Lopes, Denise [ORNL] (ORCID:000900023705987↗

A Data Quality-Aware Framework to Reliably Forecast Photovoltaic Generation and Consumer Load for an Improved Resilience of Microgrids

Photovoltaic (PV) power and consumer load forecasting plays a critical role to ensure operational resilience of the electric grid. Most data-driven forecasting algorithms rely heavily on the continuous availability of good quality data for periodic training and validation. When deployed at the grid’s edge, prolonged disruptions to communications during extreme events degrade data quality. Factors such as missing observations, epistemic uncertainties, data drift, and concept drift are manifestations of data quality that impact the generalization of such field-deployed forecasting models. Currently, there exists no mechanism in the literature to dynamically switch between models under varying degrees of data quality as quantified by certain metrics for each factor highlighted above. This paper addresses this shortcoming by conceptually introducing a data qualityaware framework for reliable PV generation and consumer load forecasting. The framework’s design incorporates components of missing values, divergence tests, and continuous monitoring of generalization performance to detect changes in data quality caused by communications disruptions and trigger specific classes of forecasting models grouped under three use cases (UC1- UC3). As a first step towards validating this framework, real data collected from an actual field microgrid system is used to demonstrate the viability of the three use cases. Results show that the performance is the best in UC1 with an unadjusted R-square value of 0.954, followed by 0.939 for UC2 and 0.757 for UC3.

Sundararajan, Aditya↗