Materials Data on V2BiO2 by Materials Project
V2BiO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. V is bonded in a 1-coordinate geometry to three equivalent O atoms. There are one shorter (2.00 Å) and two longer (2.21 Å) V–O bond lengths. Bi is bonded in a distorted linear geometry to two equivalent O atoms. Both Bi–O bond lengths are 2.43 Å. O is bonded in a 4-coordinate geometry to three equivalent V and one Bi atom.
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