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V3Au is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. V is bonded in a distorted square co-planar geometry to four equivalent Au atoms. All V–Au bond lengths are 2.74 Å. Au is bonded to twelve equivalent V atoms to form a mixture of face and corner-sharing AuV12 cuboctahedra.
V3Au crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. V is bonded in a 6-coordinate geometry to two equivalent V and four equivalent Au atoms. Both V–V bond lengths are 2.44 Å. All V–Au bond lengths are 2.73 Å. Au is bonded to twelve equivalent V atoms to form a mixture of edge and face-sharing AuV12 cuboctahedra.
(V3Au)2N2 is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional and consists of one ammonia molecule and one V3Au framework. In the V3Au framework, V is bonded in a linear geometry to two equivalent Au atoms. Both V–Au bond lengths are 2.44 Å. Au is bonded to six equivalent V atoms to form corner-sharing AuV6 octahedra. The corner-sharing octahedral tilt angles are 0°.