Materials Data on V3P by Materials Project
V3P crystallizes in the tetragonal P4_2/n space group. The structure is three-dimensional. there are three inequivalent V sites. In the first V site, V is bonded in a 4-coordinate geometry to four equivalent P atoms. There are a spread of V–P bond distances ranging from 2.37–2.45 Å. In the second V site, V is bonded in a 2-coordinate geometry to three equivalent P atoms. There are a spread of V–P bond distances ranging from 2.37–2.68 Å. In the third V site, V is bonded in a 2-coordinate geometry to two equivalent P atoms. There are one shorter (2.38 Å) and one longer (2.41 Å) V–P bond lengths. P is bonded in a 9-coordinate geometry to nine V atoms.
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