Materials Data on VAsRh by Materials Project
RhVAs crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. V is bonded in a 3-coordinate geometry to six equivalent Rh and five equivalent As atoms. There are a spread of V–Rh bond distances ranging from 2.90–2.96 Å. There are a spread of V–As bond distances ranging from 2.53–2.82 Å. Rh is bonded in a 12-coordinate geometry to six equivalent V, two equivalent Rh, and four equivalent As atoms. Both Rh–Rh bond lengths are 2.81 Å. There are a spread of Rh–As bond distances ranging from 2.40–2.52 Å. As is bonded in a 9-coordinate geometry to five equivalent V and four equivalent Rh atoms.
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