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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Spacecraft Lighting to Mitigate Microbial Growth

In this innovation project, we investigated the usage of narrow band violet light (408 nm) to attenuate the growth of bacteria typically found on ISS. Violet light is less hazardous than UV light and it can transmit through plastics, such as clear acrylics, making it possible to incorporate into large surface lamps and acrylic or polycarbonate based optical light guides. This study built a custom LED surface panel that was edge lit by an array of 408 nm violet LEDS. The optical light guide technology used in the lamp and the 408 nm violet LEDs are available on the market from multiple vendors. The application of the concept of using violet light driven LED panels and optical light guides is to integrate the paneling into spacecraft architectural surfaces for the automation of a light based microbial countermeasure that could enhance current cleaning methods used in areas on spacecraft prone to microbial growth.

Clark, Toni A.↗
DOE OSTI2020

Complete Inactivation of Blood Borne Pathogen Trypanosoma cruzi in Stored Human Platelet Concentrates and Plasma Treated With 405 nm Violet-Blue Light

The introduction of pathogen reduction technologies (PRTs) to inactivate bacteria, viruses and parasites in donated blood components stored for transfusion adds to the existing arsenal toward reducing the risk of transfusion-transmitted infectious diseases (TTIDs). We have previously demonstrated that 405 nm violet-blue light effectively reduces blood-borne bacteria in stored human plasma and platelet concentrates. In this report, we investigated the microbicidal effect of 405 nm light on one important bloodborne parasite Trypanosoma cruzi that causes Chagas disease in humans. Our results demonstrated that a light irradiance at 15 mWcm -2 for 5 h, equivalent to 270 Jcm -2 , effectively inactivated T. cruzi by over 9.0 Log 10 , in plasma and platelets that were evaluated by a MK2 cell infectivity assay. Giemsa stained T. cruzi infected MK2 cells showed that the light-treated parasites in plasma and platelets were deficient in infecting MK2 cells and did not differentiate further into intracellular amastigotes unlike the untreated parasites. The light-treated and untreated parasite samples were then evaluated for any residual infectivity by injecting the treated parasites into Swiss Webster mice, which did not develop infection even after the animals were immunosuppressed, further demonstrating that the light treatment was completely effective for inactivation of the parasite; the light-treated platelets had similar in vitro metabolic and biochemical indices to that of untreated platelets. Overall, these results provide a proof of concept toward developing 405 nm light treatment as a pathogen reduction technology (PRT) to enhance the safety of stored human plasma and platelet concentrates from bloodborne T. cruzi, which causes Chagas disease.

405 nm light↗
DOE OSTI2024

405 nm violet-blue light inactivates hepatitis C cell culture virus (HCVcc) in ex vivo human platelet concentrates and plasma

Abstract Added safety measures coupled with the development and use of pathogen reduction technologies (PRT) significantly reduces the risk of transfusion-transmitted infections (TTIs) from blood products. Current approved PRTs utilize chemical and/or UV-light based inactivation methods. While the effectiveness of these PRTs in reducing pathogens are well documented, these can cause tolerable yet unintended consequences on the quality and efficacy of the transfusion products. As an alternative to UV-based approaches, we have previously demonstrated that 405 nm violet-blue light exposure successfully inactivates a variety of pathogens, including bacteria, parasites, and viruses, in both platelet concentrates (PCs) and plasma. Herein, we show that 405 nm light treatment effectively inactivates hepatitis C cell culture virus (HCVcc) by up to ~ 3.8 log10 in small volumes of a variety of matrices, such as cell culture media, PBS, plasma, and PCs with 27 J/cm 2 of light exposure, and total inactivation of HCVcc after 162 J/cm 2 light exposure. Furthermore, we demonstrate that carry-over of media supplemented with fetal bovine serum enhances the production of reactive oxygen species (ROS), providing mechanistic insights to 405 nm light-mediated viral inactivation. Overall, 405 nm light successfully inactivates HCVcc, further strengthening this method as a novel PRT for platelets and plasma.

Science & Technology - Other Topics↗
DOE OSTI2018

How does Cerenkov radiation work?

The behavior of matter can constantly amaze people, especially when extreme conditions are involved. In this video, Fermilab’s Dr. Don Lincoln describes what happens when a charged particle travels through a transparent material faster than light travels through that same material. When that happens, blue and violet light is emitted. This light is called Cerenkov light. This video tells you everything you need to know.

43 PARTICLE ACCELERATORS↗
DOE OSTI2026

Understanding spectral dependance of laser-induced damage precursors in dielectric materials (Abbreviated report_23-ERD-006)

High peak and average power laser systems are typically limited by the handling fluence of the optical components. In particular, the multilayer dielectric coatings are known to be much lower operational fluence than the more ideal bulk materials. In this project we proposed and succeeded in probing different established classes of damage prone precursors at different wavelengths to understand their fundamental laser damage response as a function of wavelength. This study helped to shed light on the fundamental physics of the non-linear precursors that govern laser damage phenomena for ns-regime pulsed laser damage. In this study, we utilized the onsite coating capabilities (VPL, IBS coating lab) to purposefully generate laser damage-prone precursors in hafnia-based coatings (both single and multi-layer coatings). Specifically, we engineered coatings with craze lines initiated by nodules, generated coatings with our xenon-based coating process to suppress nanobubble formation and generated hafnia coatings under controlled oxygen flow conditions to study hafnia sub-oxides and oxygen flow dependance. In these studies we found that craze lines are rife with precursors that are sensitive to ultra-violet light but not to infrared light; we found that the removal of nanobubbles helps with all wavelengths tested, but is most impactful for ultra-violet light; we also found that ultra-violet laser damage performance of hafnia is closely matched to oxygen flow rate, while the infrared performance may be slightly better at lower flow rates. During this LDRD we also successfully stood up a new laser damage testing capability, namely a wavelength agile damage test station to study the spectral response of known laser-induced damage precursors. This is a unique and important capability for Lawrence Livermore National Lab, allowing us to understand the spectral response of materials under high intensity irradiation and damage. This is a vital tool to understand non-linear optical response at wavelengths that we have previously been unable to test at.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Brief history of the Martian 'violet haze' problem.

A brief but thorough survey of the literature on the Martian 'violet haze' problem is presented. It is evident that both the normal lack of contrast of the surface features in violet light and their occasional appearance are phenomena intrinsic to Mars. Models involving simple uniform layers of scattering or absorbing materials are inadequate to account for the observations. We suggest that the role of haze has historically been misinterpreted. The blank disk of Mars in violet light occurs when the atmosphere is relatively free of haze. The formation of optically thin white hazes over the bright areas increases the contrast and produces 'blue clearing.'

Thompson, D. T.↗
NASA NTRS2015

NASA Ames UV-LED Poster Overview

UV-LED is a small satellite technology demonstration payload being flown on the Saudisat-4 spacecraft that is demonstrating non-contacting charge control of an isolated or floating mass using new solid-state ultra-violet light emitting diodes (UV-LEDs). Integrated to the rest of the spacecraft and launched on a Dnepr in June 19, 2014, the project is a collaboration between the NASA Ames Research Center (ARC), Stanford University, and King Abdulaziz City for Science and Technology (KACST). Beginning with its commissioning in December, 2015, the data collected by UV-LED have validated a novel method of charge control that will improve the performance of drag-free spacecraft allowing for concurrent science collection during charge management operations as well as reduce the mass, power and volume required while increasing lifetime and reliability of a charge management subsystem. UV-LED continues to operate, exploring new concepts in non-contacting charge control and collecting data crucial to understanding the lifetime of ultra-violet light emitting diodes in space. These improvements are crucial to the success of ground breaking missions such as LISA and BBO, and demonstrates the ability of low cost small satellite missions to provide technological advances that far exceed mission costs.

KACST↗
NASA NTRS1973

Identification, definition and mapping of terrestrial ecosystems in interior Alaska

The author has identified the following significant results. A reconstituted, simulated color-infrared print, enlarged to a scale of 1:250,000, was used to make a vegetation map of a 3,110 sq km area just west of Fairbanks, Alaska. Information was traced from the print which comprised the southeastern part of ERTS-1 scene 1033-21011. A 1:1,000,000 scale color-infrared transparency of this scene, obtained from NASA, was used along side the print as an aid in recognizing colors, color intensities and blends, and mosaics of different colors. Color units on the transparency and print were identified according to vegetation types using NASA air photos, U.S. Forest Service air photos, and experience of the investigator. Five more or less pure colors were identified and associated with vegetation types. These colors were designated according to their appearances on the print: (1) orange for forest vegetation dominated by broad-leaved trees: (2) gray for forest vegetation dominated by needle-leaved trees; (3) violet for scrub vegetation; (4) light violet denoting herbaceous tundra vegetation; and (5) dull violet for muskeg vegetation. This study has shown, through close examinations of the NASA transparency, that much more detailed vegetation landscape, or ecosystem maps could be produced, if only spectral signatures could be consistently and reliably recognized and transferred to a map of suitable scale.

Anderson, J. H.↗
NASA NTRS1993

Micro-precision control/structure interaction technology for large optical space systems

The CSI program at JPL is chartered to develop the structures and control technology needed for sub-micron level stabilization of future optical space systems. The extreme dimensional stability required for such systems derives from the need to maintain the alignment and figure of critical optical elements to a small fraction (typically 1/20th to 1/50th) of the wavelength of detected radiation. The wavelength is about 0.5 micron for visible light and 0.1 micron for ultra-violet light. This lambda/50 requirement is common to a broad class of optical systems including filled aperture telescopes (with monolithic or segmented primary mirrors), sparse aperture telescopes, and optical interferometers. The challenge for CSI arises when such systems become large, with spatially distributed optical elements mounted on a lightweight, flexible structure. In order to better understand the requirements for micro-precision CSI technology, a representative future optical system was identified and developed as an analytical testbed for CSI concepts and approaches. An optical interferometer was selected as a stressing example of the relevant mission class. The system that emerged was termed the Focus Mission Interferometer (FMI). This paper will describe the multi-layer control architecture used to address the FMI's nanometer level stabilization requirements. In addition the paper will discuss on-going and planned experimental work aimed at demonstrating that multi-layer CSI can work in practice in the relevant performance regime.

Sirlin, Samuel W.↗
NASA NTRS1993

Impact contribution of prebiotic reactants to Earth

A study was performed to explore the effectiveness of comets for chemical evolution. The concentration of amino acids in various terrestrial environments was mathematically explored as there is evidence that amino acids formed as a result of cometary impact. First, the initial concentration of amino acids in surface environment after cometary impact was estimated. The effect of hydrothermal vents, ultra-violet rays, and clays was taken into consideration. Next, the absorption of amino acids by clay particles before degradation by ultra-violet light was analyzed. Finally, the effectiveness of clays, ultra-violet, and hydrothermal vents as sinks for cometary amino acids was compared. A mathematical model was then developed for the production of impact deposits on Earth for the past 2 Ga, and the relative thickness distribution was computed for impact deposits produced in 2 Ga. The reported relative thickness distribution of tillites and diamicites of all ages agrees with the thickness calculated from this impact model. This suggests that many of the ancient tillites and diamicites could be of impact origin. The effectiveness of comets was explored on the chemical evolution of amino acids. The effect of sinks such as clays, submarine vents, and UV light on amino acid concentration was considered. Sites favorable to chemical evolution of amino acids were examined, and it was concluded that chemical evolution could have occurred at or above the surface even during periods of intense bombardment of the Earth more than 3.8 billion years ago.

Aggarwal, Hans R.↗
NASA NTRS2019

Spacecraft Lighting to Mitigate Microbial Growth

ISS crew health research indicate risk for immune system degradation for long duration missions, necessitating the need to maximize countermeasures on microbial growth (1). This project will investigate applications using violet (400nm) LEDs to mitigate growth of bacteria on architectural surfaces. The application is primarily for architectures and surfaces where a higher amount of bacterial growth is expected. The project will build two different types of violet light sources that represent lamp types that could be installed in spacecraft applications. Under a controlled setting, using violet LEDs, the evaluation will test the effectiveness of a glowing work surface using LED Panel verses an LED array overhead lamp. The effectiveness of the lighting systems to attenuate bacterial growth will be compared to a control. The results of this study can be used to inform spacecraft system architects on novel ways to improve habitat health, and reduce reliance on manual cleaning methods.

Clark, Toni A.↗
DOE OSTI2025

Hybrid epoxy–acrylate resins for wavelength-selective multimaterial 3D printing

Structures in nature have evolved to combine hard and soft materials in precise 3D arrangements, which imbues bulk properties and functionality that remain elusive to mimic synthetically. However, the potential for biomimetic analogs to seamlessly interface hard materials with soft surfaces for applications ranging from robotics and sealants to medical devices (e.g., prosthetics and wearable health monitors) has driven the demand for innovative chemistries and manufacturing approaches. Herein, we unveil a liquid resin for rapid, high resolution digital light processing (DLP) 3D printing of multimaterial objects with an unprecedented combination of strength, elasticity, and resistance to aging. Two enabling discoveries are the use of a covalently bound (hybrid) epoxy-acrylate monomer that precludes plasticization of soft domains and a wavelength-selective photosensitizer that accelerates cationic curing for hard domains. Using dual projection for multicolor DLP 3D printing (UV and violet light), several bioinspired metamaterial structures are fabricated, including one with hard springs embedded in a soft cylinder to adjust compressive behavior and a detailed knee joint featuring “bones” and “ligaments” for smooth motion. Lastly, the application of this system to facilitate selective stretching for electronic devices is demonstrated with a proof-of-concept device.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Achieving spin-triplet exciton transfer between silicon and molecular acceptors for photon upconversion

Inorganic semiconductor nanocrystals interfaced with spin-triplet exciton-accepting organic molecules have emerged as promising materials for converting incoherent long-wavelength light into the visible range. However, these materials to date have made exclusive use of nanocrystals containing toxic elements, precluding their use in biological or environmentally sensitive applications. In this paper, we address this challenge by chemically functionalizing non-toxic silicon nanocrystals with triplet-accepting anthracene ligands. Photoexciting these structures drives spin-triplet exciton transfer from silicon to anthracene through a single 15 ns Dexter energy transfer step with a nearly 50% yield. When paired with 9,10-diphenylanthracene emitters, these particles readily upconvert 488–640 nm photons to 425 nm violet light with efficiencies as high as 7 ± 0.9% and can be readily incorporated into aqueous micelles for biological use. Our demonstration of spin-triplet exciton transfer from silicon to molecular triplet acceptors can critically enable new technologies for solar energy conversion, quantum information and near-infrared driven photocatalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Effects of Natural and Artificial Weathering on the Physical Properties of Recycled Poly(ethylene terephthalate)

In accelerated weathering tests, specimens are exposed to higher radiation intensity, temperature and humidity than is likely under natural weathering in order to achieve rapid degradation of the polymer in a convenient short time. In the current work, a correlation between the two environments is attempted so that a prediction of lifetimes in the natural environment can be achieved. During aging, surface flaws are created due to the chain scission process. This is initiated by the absorption of ultra-violet light and directly affects visual appearance and impact strength. After natural weathering, the material shows only plastic deformation in an impact test. However, after artificial weathering to 5000 h of UV exposure, there is a decrease of 85% in impact strength. Colour change occurs at a high rate in the early stages of UV exposure. Beyond 2000 h of exposure, the colour change approaches a steady state and a correlation between the changes under natural and artificial weathering becomes apparent for a potential prediction of lifetimes. From the analysis including the specular component (SCI), taking surface roughening into account, 1 year under natural weathering was found to be equivalent to 25 days under accelerated weathering.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effects of size reduction on microstructural, optical, vibrational, magnetic and photocatalytic properties of ZnO nanocrystals

Highlights: • ZnO nanocrystals of different sizes 4–19 nm, thus different S/V ratios synthesized. • Lattice strain and lattice volume increase with size reduction. • Raman spectra show enhanced surface effects with phonon mode disappearance. • ESR shows exchange interaction; VSM shows surface originated ferromagnetism. • Photocatalysis is less affected with size reduction and surface enhancement. - Abstract: ZnO nanocrystals were synthesized in the size range 4 nm–19 nm by chemical co-precipitation method and extensively characterized by various techniques. Size control was achieved by changing the concentration of ME that acted as the capping agent. Lattice strain and lattice volume were found to increase with the decrease in crystallite size that could be attributed to an enhanced influence of surface atoms. Raman spectroscopy provided evidence of enhancement of surface influence and reduction of crystallinity with the observation of decrease in E{sub 2}{sup high} phonon mode intensity with a decrease in crystallite size. Electron spin resonance spectra revealed the presence of exchange interaction as well as presence of lattice disorder. Vibrating sample magnetometry results showed that M-H curves exhibit hysteresis loops which confirmed the ferromagnetic nature of the nanocrystals and it could be attributed to the interaction between localized electron spins resulting from oxygen vacancies at the surface. Blue shift of the UV–Visible absorption spectra was observed with decrease in crystallite size, which could be attributed to quantum confinement effect. Room temperature photoluminescence spectra were recorded under UV light excitation, which showed emission of different colours (light violet, violet, blue and green) in the visible region, attributable to the presence of various types of defects such as zinc interstitial, zinc vacancy and oxygen vacancy in the ZnO nanocrystals. Photodegradation of aqueous methylene blue by the ZnO nanocrystals was performed under simulated sunlight irradiation. There was a very small increase in efficiency of photodegradation with size reduction, which showed that there was no significant change in surface defects with size reduction in the nanocrystals despite the surface enhancement. A mechanism for photocatalysis involving defect states has been proposed.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2022

Fluorescence strobo-stereoscopy for specular reflection-suppressed full field of view imaging

This report introduces fluorescence strobo-stereoscopy (FSS) to suppress strong specular reflection and enable the full field of view (FFOV) 3D surface imaging while the part is rotating. Specular reflection off the target surface significantly degrades the image quality and becomes critical for highly reflective surface measurements. In FSS, the fluorescent dye-doped fluid applied on the machined surface is excited upon incident ultra-violet light and becomes a new light source by Stokes' Law. Thus, specular reflection off of smooth surface can be suppressed by separating the fluorescent light from the excitation light. The developed FSS comprises a pair of imaging cameras, spatial filters, and an excitation light source. As a result, FSS effectively rejected the specular reflection and improved the FFOV 3D surface image quality of the machined part by enhancing contrast in the rotating target surface. Such enhancements in 3D imaging allowed to identify manufacturing tolerance of the part and to detect the surface features. The axial and lateral accuracy errors of FSS were 2.3% and 1.4% with the target size of 4.07 mm and 0.215 mm, respectively. A whole view reconstruction of the cylindrical target sample was performed, and the corresponding cylindricity and diameter deviation were assessed. The fluid media effect and the target surface quality effect were discussed.

3D surface imaging↗
DOE OSTI2018

Large regional shortwave forcing by anthropogenic methane informed by Jovian observations

Recently, it was recognized that widely used calculations of methane radiative forcing systematically underestimated its global value by 15% by omitting its shortwave effects. We show that shortwave forcing by methane can be accurately calculated despite considerable uncertainty and large gaps in its shortwave spectroscopy. We demonstrate that the forcing is insensitive, even when confronted with much more complete methane absorption spectra extending to violet light wavelengths derived from observations of methane-rich Jovian planets. We undertake the first spatially resolved global calculations of this forcing and find that it is dependent on bright surface features and clouds. Localized annual mean forcing from preindustrial to present-day methane increases approaches +0.25 W/m 2 , 10 times the global annualized shortwave forcing and 43% of the total direct CH 4 forcing. Shortwave forcing by anthropogenic methane is sufficiently large and accurate to warrant its inclusion in historical analyses, projections, and mitigation strategies for climate change.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Fused Filament Fabrication of Polycarbonate in a Reactive Atmosphere

Fused Filament Fabrication (FFF) has become extremely useful in various industries, particularly when complex parts are needed in low volumes. However, the material properties available in FFF polymers are limited in scope. The properties of a FFF part can be changed in multiple ways. This study explores changing the bulk properties of a part by affecting each layer as it prints. Prior work has demonstrated the feasibility of altering polymer properties by layerwise exposure to a liquid chemical, but properties have never been modified in situ using a reactive gas. Here, FFF is done in the presence of a reactive gas. Specifically, the part is printed with polycarbonate in a reactive atmosphere of ozone and ultra-violet light. It was found that as each layer is exposed to a reactive gas, the bulk properties of the part change. A visual chemical change was seen, as well as confirmation of the reaction through Fourier transform infrared spectroscopy attenuated total reflectance. The change in mechanical properties was measured through Dynamic Mechanical Analysis shear tests, showing a bulk change can be efficiently produced through FFF in a reactive atmosphere.

36 MATERIALS SCIENCE↗