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At least 19 records

Supersonic transport vis-a-vis energy savings

The energy and economic saving modifications in supersonic transportation are studied. Modifications in the propulsion systems and in the aerodynamic configurations of the Concorde aircraft to reduce noise generation and increase fuel efficiency are discussed. The conversion of supersonic aircraft from fuel oils to synthetic fuels is examined.

Cormery, G.↗

Mega-geomorphology: Mars vis a vis Earth

The areas of chaotic terrain, the giant chasma of the Valles Marineris region, the complex linear and circular depressions of Labyrinthus Noctis on Mars all suggest the possibility of large scale collapse of parts of the martian crust within equatorial and sub equatorial latitudes. It seems generally accepted that the above features are fossil, being perhaps, more than a billion years old. It is possible that parts of Earth's crust experienced similar episodes of large scale collapse sometime early in the evolution of the planet.

Sharp, R. P.↗

Global Ultraviolet Imaging Processing for the GGS Polar Visible Imaging System (VIS)

The Visible Imaging System (VIS) on Polar spacecraft of the NASA Goddard Space Flight Center was launched into orbit about Earth on February 24, 1996. Since shortly after launch, the Earth Camera subsystem of the VIS has been operated nearly continuously to acquire far ultraviolet, global images of Earth and its northern and southern auroral ovals. The only exceptions to this continuous imaging occurred for approximately 10 days at the times of the Polar spacecraft re-orientation maneuvers in October, 1996 and April, 1997. Since launch, approximately 525,000 images have been acquired with the VIS Earth Camera. The VIS instrument operational health continues to be excellent. Since launch, all systems have operated nominally with all voltages, currents, and temperatures remaining at nominal values. In addition, the sensitivity of the Earth Camera to ultraviolet light has remained constant throughout the operation period. Revised flight software was uploaded to the VIS in order to compensate for the spacecraft wobble. This is accomplished by electronic shuttering of the sensor in synchronization with the 6-second period of the wobble, thus recovering the original spatial resolution obtainable with the VIS Earth Camera. In addition, software patches were uploaded to make the VIS immune to signal dropouts that occur in the sliprings of the despun platform mechanism. These changes have worked very well. The VIS and in particular the VIS Earth Camera is fully operational and will continue to acquire global auroral images as the sun progresses toward solar maximum conditions after the turn of the century.

Frank, L. A.↗

Human Stability While Exercising on a VIS Device in Zero Gravity

BACKGROUND: A Vibration Isolation and Stabilization (VIS) system is being designed for use with the European Enhanced Exploration Exercise Device (E4D) [1]. The exercise bar is attached to cables that extend and retract through openings in the E4D platform, which the subject stands on while exercising. Since the E4D is mounted on a moving VIS device, the whole system moves under the subject’s feet. While tension in the cables does help stabilize a crew member in 0g by bracing him or her against the moving platform, flexible cables do not offer full support against falling. This raises the question of whether various exercises that are successfully performed in 1g on a stationary device can be performed without losing balance in 0g on a moving device. Quantifying stability conditions and establishing stability requirements for exercise countermeasure systems is a long-standing challenge and this work helped to inform this specific need for integrated E4D/VIS flight project development. METHODS AND RESULTS: A simplified stability analysis can be attempted based on platform accelerations generated by the VIS device simulation. In this type of analysis, the subject is conceived as standing on the platform in 0g while being held down to it by the tension in the cables. If the sideways acceleration of the platform is such that the cables cannot generate a sufficient moment relative to, e.g., the heels or the toes of the subject to overcome the tipping moment from the inertial forces on the accelerated subject’s body, the subject becomes unstable. This approach, which we refer to as the ‘static’ approximation, indicated failure of all the exercises that were considered in the comprehensive VIS analysis of the E4D. It was realized, however, that platform accelerations are not externally imposed but are themselves induced by the motion of the subject’s body during exercise, and a model calculation confirmed that this drastically altered the tipping moment on the subject, with the potential to even switch the direction in which the body would tip over. This made it imperative to consider in a coupled manner both the motion of the exercising subject’s body and the induced VIS platform motion while considering stability. The coupled dynamics requirement was met by the VIS simulation incorporating time-dependent human mass properties atop the platform and driven by the inertial forces from the prescribed subject motion relative to the platform based on motion-capture recorded human trajectories in 1g on a stationary E4D [2]. To analyze simulation results, a stability criterion was also needed. We do not know how to account for the human ‘control system’ that would take visual and vestibular cues as inputs as the platform moves in 0g. We thus chose to follow an approach we had previously used to analyze the dynamic feasibility of performing a task in lunar gravity along the human body trajectory recorded in 1g [3]. In this approach, one analyzes the center of pressure (COP) between the shoes and the ground (or platform) and checks if the COP remains within the convex hull of the footprints on the ground (or platform), commonly referred to as base of support (BOS). Since pressure is vertical and, in the absence of foot restraints, positive, the COP going outside the BOS indicates that the trajectory recorded in 1g is not dynamically feasible in microgravity and/or on the moving platform of the device. The outcome of the COP-based analysis was that some of the key exercises, especially the deadlift and the back squat exercises, were found to be dynamically feasible for at least some number of the exercise cycles, this number increasing with the cable tension. While this type of stability analysis does not account for the likely alteration of the exercise trajectory from its 1g form in space, it does show that there exist at least some realistic trajectories that pass the dynamic feasibility criterion. This adds confidence that, with further adjustment by the subject of the exercise form in 0g on a moving device, a number of exercises can be performed without losing balance.

D Frenkel↗

Electron Precipitation Parameters and Ionospheric Conductances Inferred from Auroral Images Acquired by the Visible Imaging Systems (VIS) on the Polar Spacecraft

The Visible Imaging System (VIS) on the polar spacecraft provided time sequences of auroral images at multiple wavelengths that yield information of auroral dynamics on a global scale with a spatial resolution of - 20 km and temporal resolution of approx. 1 minute. Time sequences of VIS images in which the aurora was highly dynamic are used to infer global maps for the electron precipitation parameters, energy flux and characteristic energies, and ionospheric conductances. The maps are inferred from the corresponding VIS images using an auroral model (Lumerzheim et al., 1987). The temporal and spatial resolution of the VIS inferred patterns are unprecedented. The inferred patterns are highly structured and vary significantly on a time scale of less than 5 minutes. These patterns can be very beneficial for global physics-based numerical models for the high-latitude ionosphere which previously had to rely on statistical models for the electron precipitation and ionospheric conductance.

Sigwarth, John B.↗

Near-Real-Time Material Tracking: Combining Vis–NIR Spectroscopy with Flow Sensing for Accurate Nd(III) Quantification

A fiber-optic visible–near-infrared (vis–NIR) absorption spectroscopy and flow sensor system has been developed for near-real-time tracking of Nd mass in the effluent stream from a column in a fume hood. The approach leverages two unique data streams and a partial least-squares regression (PLSR) model trained on vis–NIR absorption spectra of Nd(III) (0–1.5 M) in 1 M HNO 3 . In-line volumetric flow rate and vis–NIR spectra are measured in sequence after a chromatography column. The time stamps from each data stream are then synchronized, which allows integrated volumes to be combined with Nd(III) molarities predicted by a PLSR model to accurately calculate the Nd mass flowing through the column. This integrated measurement provides instantaneous mass flow and accumulates these data over time to obtain the total mass processed. The methodology developed in this study contributes critical technical infrastructure to improve monitoring capabilities to support chemical separations and the production of strategic materials and isotopes.

Irvine, Sawyer B. [Oak Ridge National Laboratory (↗

Comparison of Terra and Aqua MODIS VIS Bands On-Orbit Response

The Moderate Resolution Imaging Spectroradiometer (MODIS) has 36 spectral bands with a total of 490 detectors, covering spectral regions in the visible (VIS), near-infrared (NIR), short-wave infrared (SWIR), mid-wave infrared (MWIR), and long-wave infrared (LWIR). MODIS is a cross-track scanning radiometer which collects data using a rotating scan mirror (both sides) over a wide range of scan angles. The VIS, NIR, and SWIR bands (bands 1-19 and 26) make measurements of daytime surface reflected radiances, thus are referred to as the reflective solar bands (RSB). MODIS was built with a complete set of on-board calibrators, capable of providing radiometric, spatial, and spectral calibration and characterization during its entire mission. The RSB on-orbit calibration is primarily provided using a solar diffuser (SD) and a solar diffuser stability monitor (SDSM). The SD and SDSM calibration system is operated on a regular (weekly to bi-weekly) basis. The spectro-radiometric calibration assembly (SRCA) is another on-hoard calibrator that also provides RSB radiometric calibration support. For this purpose, the SRCA is operated in a radiometric mode on a monthly basis. A complete SRCA radiometric calibration is performed using different lamp configurations, or different radiance levels, to cover the range of RSB gain. Two additional SRCA modes with slightly different configurations are designed and operated for sensor on-orbit spectral and spatial characterization. In addition to its on-hoard calibrators, each MODIS makes monthly lunar observations to monitor RSB radiometric calibration stability. The MODIS lunar observations are made through its space view (SV) port at nearly the same lunar phase angles via spacecraft roll maneuvers. The SD, SRCA, and lunar measurements are made at different scan angles and data samples are collected for all spectral bands and detectors using both sides of the scan minor. Since launch, Terra and Aqua MODIS have operated successfully for more than 8 years and 6 years, respectively. Many SD/SDSM, SRCA, and lunar observations have been made by each instrument and used to derive RSB on-orbit calibration parameters, enabling corrections for sensor response changes and changes of the response versus scan angle (RVS). In general, the RSB calibration parameters are updated regularly into the MODIS Level 1B (LIB) code in support of continuous data processing for all MODIS science data products. This paper provides a brief description of MODIS RSB calibration methodologies and approaches, and summarizes on-orbit changes of their responses (gains), particularly for the VIS spectral bands.

Xiong, Xiaoxiong↗

Assessment of SNPP VIIRS VIS NIR Radiometric Calibration Stability Using Aqua MODIS and Invariant Surface Targets

The first Visible Infrared Imaging Radiometer Suite (VIIRS) is onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite. As a primary sensor, it collects imagery and radiometric measurements of the land, atmosphere, cryosphere, and oceans in the spectral regions from visible (VIS) to long-wave infrared. NASA's National Polar-orbiting Partnership (NPP) VIIRS Characterization Support Team has been actively involved in the VIIRS radiometric and geometric calibration to support its Science Team Principal Investigators for their independent quality assessment of VIIRS Environmental Data Records. This paper presents the performance assessment of the radiometric calibration stability of the VIIRS VIS and NIR spectral bands using measurements from SNPP VIIRS and Aqua MODIS simultaneous nadir overpasses and over the invariant surface targets at the Libya-4 desert and Antarctic Dome Concordia snow sites. The VIIRS sensor data records (SDRs) used in this paper are reprocessed by the NASA SNPP Land Product Evaluation and Analysis Tool Element. This paper shows that the reprocessed VIIRS SDRs have been consistently calibrated from the beginning of the mission, and the calibration stability is similar to or better than MODIS. Results from different approaches indicate that the calibrations of the VIIRS VIS and NIR spectral bands are maintained to be stable to within 1% over the first three-year mission. The absolute calibration differences between VIIRS and MODIS are within 2%, with an exception for the 0.865-m band, after correction of their spectral response differences.

Wu, Aisheng↗

Enhanced UV–Vis Rejection Ratio in Metal/BaTiO 3 /β–Ga 2 O 3 Solar–Blind Photodetectors

The fabrication and characterization of metal/BaTiO 3 /β-Ga 2 O 3 solar-blind photodetectors are reported. β-Ga 2 O 3 is a promising material for solar-blind photodetectors due to its large bandgap and the availability of low defect-density melt-grown substrates. In this work, structures are introduced that employ high-permittivity dielectric/semiconductor heterojunctions to enhance the performance of a Schottky photodetector. It is shown that integrating the high-k dielectric BaTiO 3 reduces the dark current by ≈10 4 , all but eliminates illumination induced Schottky barrier lowering, and increases the UV–vis rejection ratio by a factor greater than 9 × 10 3 compared to a Schottky photodetector. It is hypothesized that the high permittivity of the dielectric overcomes the influence of self-trapped holes in Ga 2 O 3 to reduce the peak electric field at the dielectric/metal interface, thereby eliminating the effects of Schottky barrier lowering on illuminated β-Ga 2 O 3 photodetectors. Additionally, it is hypothesized that the increase in the UV–vis rejection ratio is caused by the “dead layer” that forms at the BaTiO 3 /Pt interface.

36 MATERIALS SCIENCE↗

UV-Vis spectrophotometric determination of rare earth elements (REE) speciation at near-neutral to alkaline pH. Part II: hydrolysis of Er from 25 to 75 °C

Aqueous speciation of rare earth elements (REE) controls their mobilization, fractionation, and enrichment in the natural waters. Geochemical modeling of their speciation is key to improve our understanding of the formation of economic mineral deposits, for developing mineral separation and mine tailing recovery technologies, and for characterizing the geochemistry of thermal water. However, our ability to predict the fate of REE in a wide pH and temperature range is limited by the scarcity of thermodynamic data for the REE hydroxyl complexes. In part I of this study (H. J. Han and A. P. Gysi, Dalton Trans., 2024, 53, 13129–13141), the optical properties of m-cresol purple (mCP) were determined using UV-Vis spectrophotometry between 25 and 75 °C in order to develop a method for deriving the hydrolysis constants of erbium (Er). Here, UV-Vis spectrophotometry experiments were conducted as a function of temperature between 35 and 75 °C to determine the hydrolysis of Er in near-neutral to alkaline solutions using mCP as an in situ pH color indicator. Here, the experiments were conducted with Er concentrations from 0 to ~0.253 mmol kg –1 in low ionic strength solutions (≤0.001 mol kg –1 ).

58 GEOSCIENCES↗

Mars Odyssey THEMIS-VIS: Surface-Atmosphere Separation and Derivation of Aerosol Properties

Scattering by atmospheric aerosols can contribute a substantial fraction of the visible-light radiance observed in any remote sensing of Mars. Our objective is to develop techniques to separate this aerosol component from the surface-reflectance component in Mars Odyssey's THEMIS Visible Imaging Subsystem (THEMIS-VIS) dataset. The primary purpose of this study is the production of accurate surface reflectance data in order to allow for reliable color and mineralogical unit mapping. The second principal goal is to study the feasibility of using VIS measurements to derive quantitative information about ice and dust aerosol properties such as particle size and optical depth.

T H McConnochie↗

Challenging Issues for On-orbit Calibration in the VIS and NIR

On-orbit calibration of Earth-observing sensors in the VIS and NIR spectral regions is usually performed using the sensors on-board devices such as internal lamp(s) or solar diffuser plate(s) to provide calibration parameters. For sensors with no (or with less reliable) on-board calibrators, lunar calibration or ground validation approaches are often used. Each of these has its own set of problems that need to be fully addressed in order to support high quality on-orbit calibration and characterization. Some science products, such as Ocean color, may impose more stringent requirements that demand greater calibration precision. This paper uses MODIS as an example to illustrate challenging issues involved in VIS and NIR on-orbit calibration. It focuses on the solar diffuser (SD) calibration approach, including the effects due to SD BRF, SD attenuation screen(s), and earthshine. The impact of optics (solar diffuser and scan mirror) on-orbit degradation, including changes in the sensor s response versus scan angle (RVS), on the calibration and subsequent data quality is also discussed.

Xiong, X.↗

The Refractive Index of Amorphous and Crystalline Water Ice in the UV-vis

Amorphous solid water (ASW) is found on icy dust grains in the interstellar medium (ISM), as well as on comets and other icy objects in the outer solar system. The optical properties of ASW are thus relevant for many astrophysical environments, but in the ultraviolet–visible (UV–vis), its refractive index is not well constrained. Here, we introduce a new method based on UV–vis broadband interferometry to measure the wavelength dependent refractive index n(λ) of amorphous water ice from 10 to 130 K, i.e., for different porosities, in the wavelength range of 210–757 nm. We also present n(λ) for crystalline water ice at 150 K, which allows us to compare our new method with literature data. Based on this, a method to calculate n(λ, ρ) as a function of wavelength and porosity is reported. This new approach carries much potential and is generally applicable to pure and mixed ice, both amorphous and crystalline. The astronomical and physical–chemical relevance and future potential of this work are discussed.

Kofman, Vincent↗

PACE UV-VIS Polarimetric Remote Sensing of Atmosphere-Ocean Systems: Sensitivity to Variations in Brown Carbon

The NASA Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) mission, scheduled for launch in 2024, will carry two instruments that measure ultraviolet (UV) radiance emerging from the top of the atmosphere: the Ocean Color Instrument (OCI) and the Spectro-Polarimeter for Planetary Exploration (SPEXone) instrument. OCI will provide single-view, hyperspectral radiometric data, whereas SPEXone will provide multi-angle, multispectral polarimetric data. Together, these instruments will be the most advanced in NASA’s history for the combined observation of ocean color and atmospheric aerosols in the UV, and they will therefore provide unprecedented research opportunities for the ocean color and atmospheric aerosol communities. In particular, UV observations are best suited to retrieve properties of Colored Dissolved Organic Matter (CDOM) in the ocean, and of Brown Carbon (BrC) aerosols in the atmosphere. However, both CDOM and BrC exhibit very similar absorption spectra in the UV and the visible (VIS) spectrum; hence, care must be taken in accurately modeling these spectra for analyses of OCI and SPEXone measurements. In this presentation, we summarize a simple but highly accurate three-parameter model for complex refractive index spectra of BrC in the UV and VIS. We apply this model to simulations of PACE-like total and polarized multiangle radiance in the UV, and demonstrate that the impact of BrC and CDOM variations can be similar in total radiance, but is easy to distinguish in polarized radiance.

PACE↗

UV-Vis spectrophotometric determination of rare earth elements (REE) speciation at near-neutral to alkaline pH. Part I: m-cresol purple properties from 25-75 °C and Er hydrolysis

The speciation and mobility of rare earth elements (REE) strongly depends on pH which controls the formation of charged aqueous hydroxyl species. The latter potentially play an important role in controlling heavy REE adsorption on clay minerals in near-neutral to alkaline waters such as in regolith-hosted REE mineral deposits. However, accurate REE hydrolysis constants are needed for developing geochemical models that can predict the role of these charged species in natural systems. Here, we develop a robust experimental UV-Vis spectrophotometric method using m-cresol purple to determine in situ pH from 25 to 75 °C. This method is used to derive the average ligand number and hydrolysis constants of erbium (Er) at 25 °C in aqueous solutions with low ionic strength (≤ 0.001 mol/L) at pH from ~7 to 9.5 and in the presence of Er concentrations from 0 to 0.057 mM. The average ligand number ranges between 1 and 3 indicating that Er(OH) 2+ , Er(OH) 2 + and Er(OH) 3 0 control speciation in the experiments. The logarithm of the Er hydrolysis constants (log*β n ° , n= 1 to 3) derived at infinite dilution for the reaction Er 3+ + nH 2 O = Er(OH) n 3-n + nH + are: *β 1 ° = –7.22 ± 0.10, *β 2 ° = –14.52 ± 0.08, *β 3 ° = –23.24 ± 0.04. Implementation of these experimental data into a geochemical model indicates that the Er(OH) 2 + and Er(OH) 3 0 species are both stable in a much wider pH range than previously predicted. Consequently, the positively charged REE hydroxyl complexes can potentially control the fractionation of light vs. heavy REE via adsorption as observed in the formation of certain regolith-hosted REE deposits.

58 GEOSCIENCES↗