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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Combined infrared and ultraviolet-visible spectroscopy matrix-isolated carbon vapor

Infrared and UV-visible absorption spectra have been measured on the same sample of matrix-isolated carbon vapor in order to establish correlations between absorption intensities of vibrational and electronic transitions as a function of sample annealing. A high degree of correlation has been found between the IR feature at 1998/cm recently assigned to C8 and a UV absorption feature at about 3100 A. Thus, for the first time, direct evidence is given for the assignment of one of the unknown UV-visible features of the long-studied matrix-isolated carbon vapor spectrum.

Kurtz, Joe↗
NASA NTRS1991

High-resolution UV-visible spectroscopy of lunar red spots

A spectral reflectance study of selected lunar 'red spots', highland areas characterized by an absorption in the ultraviolet relative to the visible was conducted. Some red spots were suggested to be the sites of ancient highland volcanism. High-resolution spectral data of eight red spots on the western portion of the moon over the wavelength region 0.39-0.82 micron were obtained. Much spectral variation among these red spots in the magnitude as well as the wavelength position of the ultraviolet absorption were found. Spectral structure at visible and near-infrared wavelength were also identified. These spectral differences indicate that red spots do not have a single mineralogical composition, which in turn suggests that red spots may have multiple origins. Additional imaging spectroscopic observations were taken of the Herigonius red spot, a morphologically complex region northeast of Mare Humorum. These data reveal significant spectral differences among the various morphological units within the Herigonius red spot. Although some of these are likely due to the effects of the maturation process, others appear to reflect differences in mineral abundances and composition.

Bruno, B. C.↗
NASA NTRS1985

The eclipse of Epsilon Aurigae visible spectroscopy and ultraviolet activity

The preliminary results of the study of several high resolution spectrograms (lambda 3500 - lambda 7000 A), obtained at the Haute Provence Observatory (OHP) in France, at different epochs before, during and after the eclipse are reported. Some of these spectrograms are compared with corresponding IUE high resolution observations, in order to study the effects of the intrinsic UV activity, towards the longer wavelengths.

Ferluga, S.↗
NASA NTRS1993

On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

Perliski, Lori M.↗
NASA NTRS1980

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Several techniques were used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visible spectroscopy. Each pretreatment type gave a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments were identified readily. Results indicate that reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity were observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods.

Beck, B.↗
NASA NTRS1982

IUE spectroscopy, visible-band polarimetry, and radiometry of V641 Mon

This hot, double line, ellipsoidal variable member of NGC 2264 has been shown previously to be either a semi-detached or contact close binary. Low-resolution IUE spectra are best fitted to a Kurucz model atmosphere for very small (approximately 0.08 mag) E(B-V). The familiar interstellar absorption dip near lambda 2200 is apparently absent. A suitable model atmosphere can be fitted to the IUE fluxes, but flux excesses (compared to the model) appear for all the published U through L magnitudes. The spectrum of the B through L excess appears to follow a .0001 lambda dependence. It is shown that this cannot be interpreted as arising from another star fortuitously observed in the visible band or IR. Ground based polarization measures indicate V641 Mon to be a polarization variable. Previous and new V light curves show the amplitude of light variability itself to be variable by about a factor of 2. It is suggested that all these observed characteristics are best explained by postulating "third light" and identifying part of it with Rayleigh scattered starlight very near to the stars. From this same region there arise circumstellar absorptions which give rise to nontheoretical strengths for Si II and Si III lines.

Koch, R. H.↗
NASA NTRS1985

IUE spectroscopy, visible-band photometry, and polarimetry of HD 47732 (V641 Monocerotis)

Several high- and low-dispersion IUE spectra are described for the hot, massive close binary HD 47732. The stellar silicon lines do not show theoretically expected strength, the weakness being attributed to incipicent emission. A weak stellar wind is measurable with an expansion velocity of about 500 km/s. There is difficulty in fitting a model atmosphere to all of the IUE continuum and visible band and IR measures. These difficulties are resolved by appealing to a 22,500 K model atmosphere and a distinctive interstellar extinction law. Numerous V band measures show the polarization to be variable, but not strongly in a phased-locked way. This suggests sporadic outbursts of gas feeding the shell. Several seasonal V band light curves are discussed, and the seasonal variations among them are attributed to variable developments of a systemic shell which scatters the photospheric light and dilutes to a variable degree the light variation due to ellipticity of figure of the component stars.

Koch, R. H.↗
NASA NTRS2000

Visible Wavelength Spectroscopy of Ferric Minerals: A Key Tool for Identification of Ancient Martian Aqueous Environments

The mineralogic signatures of past aqueous alteration of a basaltic Martian crust may include iron oxides and oxyhydroxides, zeolites, carbonates, phyllosilicates, and silica. The identities, relative abundances, and crystallinities of the phases formed in a particular environment depend on physicochemical conditions. At one extreme, hot spring environments may be characterized by smectite-chlorite to talc-kaolinite silicate assemblages, plus crystalline ferric oxides dominated by hematite. However, most environments, including cold springs, pedogenic layers, and ponded surface water, are expected to deposit iron oxides and oxyhydroxides, carbonates, and smectite-dominated phyllosilicates. A substantial fraction of the ferric iron is expected to occur in nanophase form, with the exact mineralogy strongly influenced by Eh-pH conditions. Detection of these phases has been an objective of a large body of terrestrial telescopic, Mars orbital, and landed spectral investigations and in situ compositional measurements. However, clear identifications of many of these phases is lacking. Neither carbonate nor silica has been unequivocally detected by any method. Although phyllosilicates may occur near the limit of detection by remote sensing, in general they appear to occur in only poorly crystalline form. In contrast, compelling evidence for ferric iron minerals has been gathered by recent telescopic investigations, the Imager for Mars Pathfinder (IMP), and the Thermal Emission Spectrometer (TES) on the Mars Global Surveyor (MGS). These data yield two crucial findings: (1) In the global, high spatial resolution TES data set, highly crystalline ferric iron (as coarse-grained 'gray' hematite) has been recognized but with only very limited spatial occurrence and (2) Low-resolution telescopic reflectance spectroscopy, very limited orbital reflectance spectroscopy, and landed multispectral imaging provide strong indications that at least two broad classes of ferric iron minerals are commonplace in non-dust covered regions.

Murchie, Scott L.↗
NASA NTRS2003

Planet detection and spectroscopy in visible light with a single aperture telescope and a nulling coronagraph

This talk describes a new concept for visible direct detection of Earth like extra solar planets using a nulling coronagraph instrument behind a 4m telescope in space. In the baseline design, a 4 beam nulling interferometer is synthesized from the telescope pupil, producing a very deep theta^4null which is then filtered by a coherent array of single mode fibers to suppress the residual scattered light. With perfect optics, the stellar leakage is less than 1e-11 of the starlight at the location of the planet. With diffraction limited telescope optics (lambda/20), suppression of the starlight to ~1e-10 is possible. The concept is described along with the key advantages over more traditional approaches such as apodized aperture telescopes and Lyot type coronagraphs.

coronagraph↗
NASA NTRS2012

Visible Light Spectroscopy of GEO Debris

Our goal is to understand the physical characteristics of debris at geosynchronous orbit (GEO). Our approach is to compare the observed reflectance as a function of wavelength with laboratory measurements of typical spacecraft surfaces to understand what the materials are likely to be. Because debris could be irregular in shape and tumbling at an unknown rate, rapid simultaneous measurements over a range of wavelengths are required. Acquiring spectra of optically faint objects with short exposure times to minimize these effects requires a large telescope. We describe optical spectroscopy obtained during 12-14 March 2012 with the IMACS imaging spectrograph on the 6.5-m 'Walter Baade' Magellan telescope at Las Campanas Observatory in Chile. When used in f/2 imaging mode for acquisition, this instrument has a field of view of 30 arc-minutes in diameter. After acquisition and centering of a GEO object, a 2.5 arc-second wide slit and a grism are moved into the beam for spectroscopy. We used a 200 l/mm grism blazed at 660 nm for wavelength coverage in the 500-900 nm region. Typical exposure times for spectra were 15-30 seconds. Spectra were obtained for five objects in the GEO regime listed as debris in the US Space Command public catalog, and one high area to mass ratio GEO object. In addition spectra were obtained of three cataloged IDCSP (Initial Defense Communications Satellite Program) satellites with known initial properties just below the GEO regime. All spectra were calibrated using white dwarf flux standards and solar analog stars. We will describe our experiences using Magellan, a telescope never used previously for orbital debris spectroscopy, and our initial results.

Seitzer, Patrick↗
NASA NTRS2017

Smectite Formation in the Presence of Sulfuric Acid: Implications for Acidic Smectite Formation on Early Mars

The excess of orbital detection of smectite deposits compared to carbonate deposits on the martian surface presents an enigma because smectite and carbonate formations are both favored alteration products of basalt under neutral to alkaline conditions. We propose that Mars experienced acidic events caused by sulfuric acid (H2SO4) that permitted phyllosilicate, but inhibited carbonate, formation. To experimentally verify this hypothesis, we report the first synthesis of smectite from Mars-analogue glass-rich basalt simulant (66 wt% glass, 32 wt% olivine, 2 wt% chromite) in the presence of H2SO4 under hydrothermal conditions (approximately 200 degC). Smectites were analyzed by X-ray diffraction, Mossbauer spectroscopy, visible and near-infrared reflectance spectroscopy and electron microprobe to characterize mineralogy and chemical composition. Solution chemistry was determined by Inductively Coupled Plasma Mass Spectrometry. Basalt simulant suspensions in 11-42 mM H2SO4 were acidic with pH less than or equal to 2 at the beginning of incubation and varied from acidic (pH 1.8) to mildly alkaline (pH 8.4) at the end of incubation. Alteration of glass phase during reaction of the basalt simulant with H2SO4 led to formation of the dioctahedral smectite at final pH approximately 3 and trioctahedral smectite saponite at final pH approximately 4 and higher. Anhydrite and hematite formed in the final pH range from 1.8 to 8.4 while natroalunite was detected at pH 1.8. Hematite was precipitated as a result of oxidative dissolution of olivine present in Adirondack basalt simulant. Formation of secondary phases, including smectite, resulted in release of variable amounts of Si, Mg, Na and Ca while solubilization of Al and Fe was low. Comparison of mineralogical and solution chemistry data indicated that the type of smectite (i.e., dioctahedral vs trioctahedral) was likely controlled by Mg leaching from altering basalt and substantial Mg loss created favorable conditions for formation of dioctahedral smectite. We present a model for global-scale smectite formation on Mars via acid-sulfate conditions created by the volcanic outgassing of SO2 in the Noachian and early Hesperian.

Smectite↗
NASA NTRS2014

Perkinelmer Lamda 950 Measurements in Support of Nasa's Hubble Space Telescope

We present visible spectroscopy measurements using the PerkinElmer Lambda 950 grating monochromator in support of two projects at NASA Goddard Space Flight Center. The first and primary project to be discussed is the Wide Field Planetary Camera 2 as an upgrade to the Hubble Space Telescope. Numerous optical filters were measured in the visible and near-infrared regions to experimentally vet the theoretical prediction upon which the filters were engineered. The second topic of our presentation will cover the measurement of SNAP prototype filters from three venders (ASAHI, BARR and JDSU) with applications towards NASAs the Joint Dark Energy Mission (JDEM).

Perkin Elmer Lambda 950↗
NASA NTRS2017

Coloring Jupiter's Clouds: Radiolysis of Ammonium Hydrosulfide (NH4SH)

Here we present our recent studies on the color and spectral reflectance changes induced by approximately 0.9 megaelectronvolts proton irradiation of ammonium hydrosulfide, NH4SH, a compound predicted to be an important tropospheric cloud component of Jupiter and other giant planets. Ultraviolet-visible spectroscopy was used to observe and identify reaction products in the ice sample and digital photography was used to document the corresponding color changes at 10-160 degrees Kelvin. Our experiments clearly show that the resulting color of the sample depends not only on the irradiation dose but also the irradiation temperature. Furthermore, unlike in our most recent studies of irradiation of NH4SH at 120 degrees Kelvin, which showed that higher irradiation doses caused the sample to appear green, the lower temperature studies now show that the sample becomes red after irradiation. However, comparison of these lower temperature spectra over the entire spectral range observed by HST (Hubble Space Telescope) shows that even though the color and spectrum resemble the color and spectrum of the GRS (Jupiter’s Great Red Spot), there is still enough difference to suggest that another component may be needed to adequately fit spectra of the GRS and other red regions of Jupiter's clouds. Regardless, the presence of NH4SH in the atmosphere of Jupiter and other gas giants, combined with this compound's clear alteration via radiolysis, suggests that its contribution to the ultraviolet-visible spectra of any of these object's clouds is significant.

ultraviolet-visible spectroscopy↗
NASA NTRS1991

Lunar and Planetary Science Conference, 21st, Houston, TX, Mar. 12-16, 1990, Proceedings

The present conference on lunar and planetary science discusses the geology and geophysics of Venus; the lunar highlands and regolith; magmatic processes of the moon and meteorites; remote sensing of the moon and Mars; chondrites, cosmic dust, and comets; ammonia-water mixtures; and the evolution of volcanism, tectonics, and volatiles on Mars. Attention is given to volcanism on Venus, pristine moon rocks, the search for Crisium Basin ejecta, Apollo 14 glasses, lunar anorthosites, the sources of mineral fragments in impact melts 15445 and 15455, and argon adsorption in the lunar atmosphere. Also discussed are high-pressure experiments on magnesian eucrite compositions, the early results of thermal diffusion in metal-sulfide liquids, preliminary results of imaging spectroscopy of the Humorum Basin region of the moon, high-resolution UV-visible spectroscopy of lunar red spots, and a radar-echo model for Mars. Other topics addressed include nitrogen isotopic signatures in the Acapulco Meteorite, tridymite and maghemite formation in an Fe-SiO smoke, and the enigma of mottled terrain on Mars.

Ryder, Graham↗
NASA NTRS1980

Spectroscopic characterization of titanium 6-4 surfaces after chemical pretreatments

Several techniques have been used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visibile spectroscopy. Each pretreatment type gives a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments are identified readily. Reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity have been observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods.

Chen, W.↗