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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

Observing Ocean Ecosystem Responses to Volcanic Ash

Volcanic eruptions can be catastrophic events, particularly when they occur in inhabited coastal environments. They also play important roles in climate and biogeochemical cycles, including through nutrient deposition in the ocean. Volcanic ash studies in the ocean have focused on the phytoplankton response, generally quantifying changes in chlorophyll-a concentration. Many gaps remain in addressing fundamental questions regarding why volcanic ash deposition may enhance or limit both phytoplankton growth and/or drive community composition shifts. Here we outline a wide, multidisciplinary vision for monitoring volcanic eruptions near ocean ecosystems from satellites, including considerations for characteristics of airborne volcanic ash and ash geochemistry in seawater. Ultimately, observations beyond chlorophyll-a are needed to quantify phytoplankton communities (including harmful algal blooms) and possible impacts across higher trophic levels. We synthesize relevant research from volcanic studies as well as atmospheric and ocean sciences to identify the ‘known unknowns’ in ash-ecosystem studies. Our goal is to move toward an improved understanding of how real-time and near-real-time monitoring of volcanic eruptions can help address societally relevant questions.

volcano↗
NASA NTRS1974

An atlas of volcanic ash

Volcanic ash samples collected from a variety of recent eruptions were studied, using petrography, chemical analyses, and scanning electron microscopy to characterize each ash type and to relate ash morphology to magma composition and eruption type. The ashes are best placed into two broad genetic categories: magnetic and hydrovolcanic (phreatomagmatic). Ashes from magmatic eruptions are formed when expanding gases in the magma form a froth that loses its coherence as it approaches the ground surface. During hydrovolcanic eruptions, the magma is chilled on contact with ground or surface waters, resulting in violent steam eruptions. Within these two genetic categories, ashes from different magma types can be characterized. The pigeon hole classification used here is for convenience; there are eruptions which are driven by both phreatic and magmatic gases.

Heiken, G.↗
NASA NTRS1998

Effect of Particle Non-Sphericity on Satellite Monitoring of Drifting Volcanic Ash Clouds

Volcanic eruptions loft gases and ash particles into the atmosphere and produce effects that are both short term (aircraft hazards, interference with satellite measurements) and long term (atmospheric chemistry, climate). Large (greater than 0.5mm) ash particles fall out in minutes [Rose et al, 1995], but fine ash particles can remain in the atmosphere for many days. This fine volcanic ash is a hazard to modem jet aircraft because the operating temperatures of jet engines are above the solidus temperature of volcanic ash, and because ash causes abrasion of windows and airframe, and disruption of avionics. At large distances(10(exp 2)-10(exp 4) km or more) from their source, drifting ash clouds are increasingly difficult to distinguish from meteorological clouds, both visually and on radar [Rose et al., 1995]. Satellites above the atmosphere are unique platforms for viewing volcanic clouds on a global basis and measuring their constituents and total mass. Until recently, only polar AVHRR and geostationary GOES instruments could be used to determine characteristics of drifting volcanic ash clouds using the 10-12 micron window [Prata 1989; Wen and Rose 1994; Rose and Schneider 1996]. The NASA Total Ozone Mapping Spectrometer (TOMS) instruments aboard the Nimbus-7, Meteor3, ADEOS, and Earth Probe satellites have produced a unique data set of global SO2 volcanic emissions since 1978 (Krueger et al., 1995). Besides SO2, a new technique has been developed which uses the measured spectral contrast of the backscattered radiances in the 330-380nm spectral region (where gaseous absorption is negligible) in conjunction with radiative transfer models to retrieve properties of volcanic ash (Krotkov et al., 1997) and other types of absorbing aerosols (Torres et al., 1998).

Krotkov, Nicholay A.↗
DOE OSTI2018

Volcanic ash from Puyehue-Cordón Caulle Volcanic Complex and Calbuco promote a differential response of pro-inflammatory and oxidative stress mediators on human conjunctival epithelial cells

Highlights: • Volcanic ash induces a redox imbalance on conjunctival epithelial cells. • Volcanic ash triggers a pro-inflammatory response mediated by IL-6 and IL-8. • MUC1 expression decreased on conjunctival cells exposed to volcanic ash. Volcanic ash could pose a hazard to the ocular surface as it is constantly exposed to environmental particles. We exposed conjunctival cells to Puyehue-Cordón Caulle volcanic complex (PCCVC) or Calbuco ash particles and evaluated proliferation, viability, apoptosis, MUC1 expression, pro-inflammatory cytokines, and oxidative stress markers. Ash particles from these volcanoes vary in size, composition, and morphology. Our results demonstrate that PCCVC but not Calbuco ash particles induce cytotoxicity on human conjunctival epithelial cells viewed as a decrease in cell proliferation and the transmembrane mucin MUC1 expression; a pro-inflammatory response mediated by IL-6 and IL-8; and an imbalance of the redox environment leading to protein oxidative damage. This is the first in vitro study that assesses the biological effect of volcanic ash particles on human conjunctival epithelial cells and the involvement of inflammatory mediators and oxidative stress as the mechanisms of damage. Our results could provide a better understanding of the ocular symptoms manifested by people living near volcanic areas.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2024

Inverse Modeling of the Initial Stage of the 1991 Pinatubo Volcanic Cloud Accounting for Radiative Feedback of Volcanic Ash

The way volcanic clouds evolve is very sensitive to the initial spatial 3D distributions of volcanic materials, which are often unknown. In this study, we conducted inverse modeling of the Mt. Pinatubo cloud using TOMS 2D mapping of Aerosol Index and SO 2 loading during the first three post-eruption days to estimate the time-dependent emissions profiles and initial 3D spatial distributions of volcanic ash and SO 2 . We account for aerosol radiative feedback and dynamic lofting of volcanic ash in the inversion calculations for the first time. This resulted in a lower ash injection height (by 1.5 km for ash) than without ash radiative feedback. The Pinatubo eruption ejected ≈77% of fine ash at 12 to 23 km, ≈65% of SO 2 at 18–25 km. In contrast with previous studies, which suggested that all volcanic materials were emitted above the tropopause, a significant fraction of SO 2 (5.1 of 15.5 Mt) and fine ash (37.2 of 66.5 Mt) were ejected in the troposphere, where SO 2 quickly oxidized into sulfate aerosol that is short-lived in the troposphere. This explains the early presence of sulfate aerosols in the plume and why the models can reproduce the observed volcanic aerosols' optical depth (AOD), assuming lower-than-observed SO 2 emission in the stratosphere. Despite the quicker than in observations build-up of sulfate AOD, in a month after the eruption, the evolution of the Pinatubo AOD simulated using the obtained ash and SO 2 initial distributions converges with the available stratospheric aerosol and gas experiment (SAGE) observations.

Pinatubo volcanic ash and SO2 emissions↗
DOE OSTI2014

Computation of probabilistic hazard maps and source parameter estimation for volcanic ash transport and dispersion

Volcanic ash advisory centers are charged with forecasting the movement of volcanic ash plumes, for aviation, health and safety preparation. Deterministic mathematical equations model the advection and dispersion of these plumes. However initial plume conditions – height, profile of particle location, volcanic vent parameters – are known only approximately at best, and other features of the governing system such as the windfield are stochastic. These uncertainties make forecasting plume motion difficult. As a result of these uncertainties, ash advisories based on a deterministic approach tend to be conservative, and many times over/under estimate the extent of a plume. This paper presents an end-to-end framework for generating a probabilistic approach to ash plume forecasting. This framework uses an ensemble of solutions, guided by Conjugate Unscented Transform (CUT) method for evaluating expectation integrals. This ensemble is used to construct a polynomial chaos expansion that can be sampled cheaply, to provide a probabilistic model forecast. The CUT method is then combined with a minimum variance condition, to provide a full posterior pdf of the uncertain source parameters, based on observed satellite imagery. The April 2010 eruption of the Eyjafjallajökull volcano in Iceland is employed as a test example. The puff advection/dispersion model is used to hindcast the motion of the ash plume through time, concentrating on the period 14–16 April 2010. Variability in the height and particle loading of that eruption is introduced through a volcano column model called bent. Output uncertainty due to the assumed uncertain input parameter probability distributions, and a probabilistic spatial-temporal estimate of ash presence are computed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1972

Morphology and petrography of volcanic ashes.

Study of volcanic ash samples collected from a variety of recent eruptions using petrography, chemical analyses, and scanning electron microscopy to characterize each type and to relate ash morphology to magma composition and the type of eruption. The ashes are placed in the broad genetic categories of magmatic and phreatomagmatic. The morphology of ash particles from magmatic eruptions of high viscosity magma is governed primarily by vesicle density and shape. Ash particles from eruptions of low viscosity magmas are mostly droplets. The morphology of ash particles from phreatomagmatic eruptions is controlled by stresses within the chilled magma which result in fragmentation of the glass to form small blocky or pyramidal glass ash particles.

Heiken, G.↗
NASA NTRS2016

Ultraviolet Satellite Measurements of Volcanic Ash

Ultraviolet (UV) remote sensing of volcanic ash and other absorbing aerosols from space began with the launch of the first Total Ozone Mapping Spectrometer (TOMS) instrument in 1978. Subsequent UV satellite missions (TOMS, GOME, SCIAMACHY, OMI, GOME-2, OMPS) have extended UV ash measurements to the present, generating a unique multidecadal record. A UV Aerosol Index (UVAI) based on two near-UV wavelengths, equally applicable to multispectral (TOMS, DSCOVR) or hyperspectral (GOME, SCIAMACHY, OMI, GOME-2, OMPS) instruments, has been used to derive a unique absorbing aerosol climatology across multiple UV satellite missions. Advantages of UV ash measurements relative to infrared (IR) techniques include the ability to detect ash at any altitude (assuming no clouds), above clouds, and over bright surfaces, where visible and IR techniques may fail. Disadvantages include the daytime-only restriction and nonspecificity to silicate ash, since UV measurements are sensitive to any UV-absorbing aerosol, including smoke, desert dust, and pollution. However, simultaneous retrieval of sulfur dioxide (SO2) abundance and UVAI provides robust discrimination of volcanic clouds. Although the UVAI is only semiquantitative, it has proved successful at detecting and tracking volcanic ash clouds from many volcanic eruptions since 1978. NASA A-Train measurements since 2006 (eg, CALIOP) have provided much improved constraints on volcanic ash altitude, and also permit identification of aerosol type through sensor synergy. Quantitative UV retrievals of ash optical depth, effective particle size, and ash column mass are possible and require assumptions of ash refractive index, particle size distribution, and ash layer altitude. The lack of extensive ash refractive index data in the UV-visible and the effects of ash particle shape on retrievals introduce significant uncertainty in the retrieved parameters, although limited validation against IR ash retrievals has been successful. In this contribution, we review UV ash detection and retrieval techniques and provide examples of volcanic eruptions detected in the approx. 37 year data record.

Multidecadal record↗
DOE OSTI2016

Water dynamics in cement paste at early age prepared with pozzolanic volcanic ash and Ordinary Portland Cement using quasielastic neutron scattering

Early age hydration kinetics of Portland cement with pozzolanic volcanic ash was examined using quasielastic neutron scattering. Volcanic ash consisting of two different particle sizes was used to prepare cement pastes with different ratios of Portland cement to volcanic ash. The concentration of the volcanic ash played a major role in the bound water index and self-diffusion coefficients of hydration water confined in the cement paste. An increase in the particle size of the volcanic ash affected the degree of hydration by allowing more free and mobile water in the gel pores, suggesting that volcanic ash may not have completely reacted during the experimental time frame. This study shows that the particle size along with variation in volcanic ash composition governs the early age hydration process in volcanic ash cements.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Hydration kinetics and morphology of cement pastes with pozzolanic volcanic ash studied via synchrotron-based techniques

Here, this study investigates the early ages of hydration behavior when basaltic volcanic ash was used as a partial substitute to ordinary Portland cement using ultra-small-angle X-ray scattering and wide-angle X-ray scattering (WAXS). The mix design consisted of 10, 30 and 50% substitution of Portland cement with two different-sized volcanic ashes. The data showed that substitution of volcanic ash above 30% results in excess unreacted volcanic ash, rather than additional pozzolanic reactions along longer length scales. WAXS studies revealed that addition of finely ground volcanic ash facilitated calcium-silicate-hydrate related phases, whereas inclusion of coarser volcanic ash caused domination by calcium-aluminum-silicate-hydrate and unreacted MgO phases, suggesting some volcanic ash remained unreacted throughout the hydration process. Addition of more than 30% volcanic ash leads to coarser morphology along with decreased surface area and higher intensity of scattering at early-age hydration. This suggests an abrupt dissolution indicated by changes in surface area due to the retarding gel formation that can have implication on early-age setting influencing the mechanical properties of the resulting cementitious matrix. The findings from this work show that the concentration of volcanic ash influences the specific surface area and morphology of hydration products during the early age of hydration. Therefore, natural pozzolanic volcanic ashes can be a viable substitute to Portland cement by providing environmental benefits in terms of lower-carbon footprint along with long-term durability.

36 MATERIALS SCIENCE↗
NASA NTRS2013

Filling the Gaps: The Synergistic Application of Satellite Data for the Volcanic Ash Threat to Aviation

Although significant progress has been made in recent years, estimating volcanic ash concentration for the full extent of the airspace affected by volcanic ash remains a challenge. No single satellite, airborne or ground observing system currently exists which can sufficiently inform dispersion models to provide the degree of accuracy required to use them with a high degree of confidence for routing aircraft in and near volcanic ash. Toward this end, the detection and characterization of volcanic ash in the atmosphere may be substantially improved by integrating a wider array of observing systems and advancements in trajectory and dispersion modeling to help solve this problem. The qualitative aspect of this effort has advanced significantly in the past decade due to the increase of highly complementary observational and model data currently available. Satellite observations, especially when coupled with trajectory and dispersion models can provide a very accurate picture of the 3-dimensional location of ash clouds. The accurate estimate of the mass loading at various locations throughout the entire plume, however improving, remains elusive. This paper examines the capabilities of various satellite observation systems and postulates that model-based volcanic ash concentration maps and forecasts might be significantly improved if the various extant satellite capabilities are used together with independent, accurate mass loading data from other observing systems available to calibrate (tune) ash concentration retrievals from the satellite systems.

Murray, John↗
DOE OSTI2022

Occurrences of REE and CM in volcanic ash beds associated with coals in SW Wyoming & NW Colorado

Rare earth elements (REEs) and critical minerals (CMs) are vital components in the nation’s economy, national security, and the further strengthening of our renewable energy capabilities and infrastructure. Recent work has revealed more insight into previously unknown modes of occurrence for REEs, particularly in coal seams and adjacent noncoal sediments, but many data gaps persist. Temporal relationships between coal beds and adjacent tonstiens, ash beds, or other partings are widely recognized but not fully understood. Variations in REE concentration and their direct or indirect association with coal beds are not predictable. This study presents findings from examining lateral and potentially stratigraphic variation of REE and CM occurrences in coals of late Cretaceous and Paleocene age. In this study we collected and examined samples of differing ages both core and coal mine exposures for qualitative x-ray fluorescence (XRF), and multi-element geochemistry. Preliminary XRF data indicates variable levels of light REEs in a core from the Yampa coalfield of Moffat County in northwest Colorado. An absence of similar enrichments in slightly older coals in the Adaville Formation of the Fold and Thrust belt in southwest Wyoming is described from XRF and ICP-MS evaluation. Previous work has shown an association with the Yampa Bed and REE enrichment in coals of the Upper Cretaceous Williams Fork Formation. While not common and widespread, this association suggests that leaching or reworking of the ash bed could lead to elevated REEs in the adjacent coal. We investigate differences between the two data occurringas geologic compositions and post-depositional histories. In-depth petrography and precise geochemistry should reveal data that at the very least will help improve some aspects of the geologic models of coal basins and the effect of an influx of non-coal sediments.

REE, CM, ash, volcanic ash, coal↗
DOE OSTI2015

Effects Of Crystallographic Properties On The Ice Nucleation Properties Of Volcanic Ash Particles

Specific chemical and physical properties of volcanic ash particles that could affect their ability to induce ice formation are poorly understood. In this study, the ice nucleating properties of size-selected volcanic ash and mineral dust particles in relation to their surface chemistry and crystalline structure at temperatures ranging from –30 to –38 °C were investigated in deposition mode. Ice nucleation efficiency of dust particles was higher compared to ash particles at all temperature and relative humidity conditions. Particle characterization analysis shows that surface elemental composition of ash and dust particles was similar; however, the structural properties of ash samples were different.

Environmental Molecular Sciences Laboratory↗
NASA NTRS2017

The Hazard of Volcanic Ash Ingestion

A research team of U.S. Government agencies and engine manufacturers conducted an experiment to test volcanic-ash ingestion by a NASA owned engine in the same family as the PW 2000 that was donated by the U.S. Air Force. The experiment, called Vehicle Integrated Propulsions Research (VIPR) test, was conducted under the auspices of NASAs Convergent Aeronautics Solutions (CAS) Program and took place in summer of 2015 at Edwards AFB in California as an on-ground, on-wing test. The primary objectives of the volcanic ash test were to determine the effect on the engine of several hours of exposure to low to moderate ash concentrations and to evaluate the capability of engine health management technologies for detecting these effects. The target concentrations of volcanic ash tested were at 1 and 10 mgm3. A natural volcanic ash was used that is representative of distal ash clouds many 100s to 1000 km from a volcanic source. The glassy ash particles were expected to soften and become less viscous when exposed to the high temperatures of the combustion chamber, then stick to the nozzle guide vanes of the high-pressure turbine and this was observed. Numerous observations and measurements of the engines performance and degradation were made during the course of the experiment, including borescope inspections after each test run. The engine has been disassembled so that detailed inspections of the engine effects have been made. A summary of the test methodology and execution will be made along with results from the test. While not intended to be sufficient for rigorous certification of engine performance when ash is ingested, the experiment should provide useful information to aircraft manufacturers, airline operators, and military and civil regulators in their efforts to evaluate the range of risks that ash hazards pose to aviation.

Lekki, John↗
DOE OSTI2024

Godzilla mineral dust and La Soufrière volcanic ash fallout immediately stimulate marine microbial phosphate uptake

During the “Godzilla” dust storm of June 2020, unusually high fluxes of mineral dust traveled across the Atlantic from the Sahara Desert, reaching the Caribbean Basin, Gulf Coast, and southeastern United States. Additionally, an eruption of the La Soufrière volcano on St. Vincent in April 2021 generated substantial ashfall in the southeastern Caribbean. While many studies have analyzed mineral dust’s ability to relieve nutrient limitation of phosphorus (P) in the P-stressed North Atlantic, less is known about the impact of extreme events and other natural aerosols on fluxes of P into seawater and from seawater into marine microbial cells. We quantified P and iron (Fe) content in mineral dust from the Godzilla dust storm and volcanic ash from the La Soufrière eruption collected at Ragged Point, Barbados. We also performed seawater incubations to assess the marine microbial response to aerosol deposition. Using environmentally-relevant concentrations of atmospheric particles for within the ocean’s mixed layer allowed us to draw realistic conclusions about how these deposition events impacted P cycling in situ. Volcanic ash has lower P content than mineral dust, and P in volcanic ash is far less soluble (~1%) than assumed in current atmospheric deposition models. Adding mineral dust and the volcanic ash leachate in concentrations representing different deposition scenarios increased soluble reactive phosphorus (SRP) concentrations in coastal seawater by ~7-32 nM. Phosphate uptake rate was stimulated in coastal seawater after either mineral dust or volcanic ash deposition at aerosol concentrations relevant to the Godzilla dust event, with ash eliciting the fastest uptake rate. Furthermore, high concentrations of both the mineral dust and volcanic ash led to slightly elevated alkaline phosphatase activity (APA) compared to the relevant controls, indicating higher potential for use of dissolved organic phosphorus (DOP) as a P source. Quantifying these aerosols’ impacts on P cycling is a significant step towards achieving a better understanding of their potential roles in relieving nutrient limitation and fueling the biological carbon pump.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Gaussian Process Emulators for Volcanic Ash Dispersion Model Tephra2

It is necessary to predict volcanic ash deposition since falling ash is harmful to human activities. Because simulators built for this purpose are computationally expensive, it is popular to use statistical emulators for geophysical hazard analyses, where a large number of simulations are required. Gaussian stochastic process emulators are able to approximate expensive simulations in an accurate and efficient way. Using a relatively small number of simulation runs, a well-trained emulator can accurately predict simulation outputs at massive new input points in a few seconds. Under different explosive eruption conditions, we constructed Gaussian stochastic process emulators for Tephra2, a simulation tool for estimating the accumulation of volcanic ash over a region. Historical wind records are used as input wind data, without assuming a Gaussian wind speed profile or common wind direction among elevations. While there are several inputs for Tephra2, we use no more than three physically motivated variables as emulator inputs to reduce the computational cost of emulations. The emulator outputs predict the mass of tephra per unit area at 50281 grid points around a predetermined vent location.

58 GEOSCIENCES↗
DOE OSTI2020

Persisting volcanic ash particles impact stratospheric SO 2 lifetime and aerosol optical properties

Volcanic ash is often neglected in climate simulations because ash particles are assumed to have a short atmospheric lifetime, and to not participate in sulfur chemistry. After the Mt. Kelut eruption in 2014, stratospheric ash-rich aerosols were observed for months. Here we show that the persistence of super-micron ash is consistent with a density near 0.5 g cm -3 , close to pumice. Ash-rich particles dominate the volcanic cloud optical properties for the first 60 days. We also find that the initial SO 2 lifetime is determined by SO 2 uptake on ash, rather than by reaction with OH as commonly assumed. About 43% more volcanic sulfur is removed from the stratosphere in 2 months with the SO 2 heterogeneous chemistry on ash particles than without. This research suggests the need for re-evaluation of factors controlling SO 2 lifetime in climate model simulations, and of the impact of volcanic ash on stratospheric chemistry and radiation.

54 ENVIRONMENTAL SCIENCES↗