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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

A Technical Assessment of Current Water Policy Boundaries at U.S. Department of Energy, Paducah Gaseous Diffusion Plant, Paducah, Kentucky

In 1988, groundwater contaminated with trichloroethene (TCE) and technetium-99 (Tc-99) was identified in samples collected from residential water wells withdrawing groundwater from the Regional Gravel Aquifer (RGA) north of the Paducah Gaseous Diffusion Plant (PGDP) facility. In response, the U.S. Department of Energy (DOE) provided temporary drinking water supplies to approximately 100 potentially affected residents by initially supplying bottled water, water tanks, and water-treatment systems, and then by extending municipal water lines, all at no cost, to those persons whose wells could be affected by contaminated groundwater. The Water Policy boundary was established in 1993. In the Policy, DOE agreed to pay the reasonable monthly cost of water for homes and businesses and, in exchange, many of the land owners signed license agreements committing to cease using the groundwater via rural water wells. In 2012, DOE requested that Oak Ridge Associated Universities (ORAU), managing contractor of Oak Ridge Institute for Science and Education (ORISE), provide an independent assessment of the quality and quantity of the existing groundwater monitoring data and determine if there is sufficient information to support a modification to the boundary of the current Water Policy. As a result of the assessment, ORAU concludes that sufficient groundwater monitoring data exists to determine that a shrinkage and/or shift of the plume(s) responsible for the initial development of this policy has occurred. Specifically, there is compelling evidence that the TCE plume is undergoing shrinkage due to natural attenuation and associated degradation. The plume shrinkage (and migration) has also been augmented in local areas where large volumes of groundwater were recovered by pump-and treat remedial systems along the eastern and western boundaries of the Northwest Plume, and in other areas where pump-and-treat systems have been deployed by DOE to remove source contaminants. The available evidence supports adjusting the western and northwestern Water Policy boundary. Based on the historical and modeled hydrogeological data reflecting past flow and plume attenuation, along with associated plume migration toward the northeast, the establishment of a new boundary along the westernmost margin of the earliest indication of the TCE plume is proposed and justified on hydrogeological grounds. Approximately 30% of the original area would remain within the adjusted Water Policy area west and northwest of the PGDP facility. This modification would release about 70% of the area, although individual properties would overlap the new boundary.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Preliminary structural design conceptualization for composite rotor for verdant power water current turbine

Sandia National Laboratories (SNL) and Verdant Power Inc. (VPI) have partnered under a Cooperative Research and Development Agreement (CRADA) to develop a new kinetic hydropower rotor. The rotor features an improved hydrodynamic and structural design which features state-of-the-art technology developed for the wind industry. The new rotor will have higher energy capture, increased system reliability, and reduction of overall cost of energy. This project was divided into six tasks: (1) Composite Rotor Project Planning and Design Specification; (2) Baseline Fatigue Testing and Failure analysis; (3) Develop Blade/Rotor Performance Model; (4) Hydrofoil Survey and Selection; (5) FEM Structural Design; and (6) Develop Candidate Rotor Designs and Prepare Final Report.

13 HYDRO ENERGY↗

Water limiting current measurements in anion exchange membrane fuel cells (AEMFCs); part 1: Water limiting current method development

We report water management is critical in optimizing anion exchange membrane fuel cell (AEMFCs) performance and durability. The role of membranes on determining cell water balance in AEMFCs has received limited study. A more thorough understanding of membrane water transport parameters is necessary for thorough cell optimization. In this study, a novel method for probing limiting current based on water flux across an AEMFC is presented for the first time. The water limiting current has been investigated as a function of relative humidity of anode and cathode streams, cathode backpressure and cell operating temperature. From these studies, it is clearly shown that water diffusion through the membrane from the anode is the most critical mechanism for achieving high current density performance and durability. The developed method can act as a novel screening technique that focuses on the impacts of water transport parameters and helps identify promising membrane materials based on their water transport properties. A critical but underappreciated facet of AEMFC performance and durability.

30 DIRECT ENERGY CONVERSION↗

Synchrotron-based imaging of chromium and γ-H2AX immunostaining in the duodenum following repeated exposure to Cr(VI) in drinking water

Current drinking water standards for chromium are for the combined total of both hexavalent and trivalent chromium (Cr(VI) and Cr(III)). However, recent studies have shown that Cr(III) is not carcinogenic to rodents, whereas mice chronically exposed to high levels of Cr(VI) developed duodenal tumors. These findings may suggest the need for environmental standards specific for Cr(VI). Whether the intestinal tumors arose through a mutagenic or non-mutagenic mode of action (MOA) greatly impacts how drinking water standards for Cr(VI) are derived. Herein, X-ray fluorescence (spectro)microscopy (µ-XRF) was used to image the Cr content in the villus and crypt regions of duodena from B6C3F1 mice exposed to 180 mg/l Cr(VI) in drinking water for 13 weeks. DNA damage was also assessed by γ-H2AX immunostaining. Exposure to Cr(VI) induced villus blunting and crypt hyperplasia in the duodenum—the latter evidenced by lengthening of the crypt compartment by ~2-fold with a concomitant 1.5-fold increase in the number of crypt enterocytes. γ-H2AX immunostaining was elevated in villi, but not in the crypt compartment. µ-XRF maps revealed mean Cr levels >30 times higher in duodenal villi than crypt regions; mean Cr levels in crypt regions were only slightly above background signal. Despite the presence of Cr and elevated γ-H2AX immunoreactivity in villi, no aberrant foci indicative of transformation were evident. Lastly, these findings do not support a MOA for intestinal carcinogenesis involving direct Cr-DNA interaction in intestinal stem cells, but rather support a non-mutagenic MOA involving chronic wounding of intestinal villi and crypt cell hyperplasia.

47 OTHER INSTRUMENTATION↗

Planning for sustained water-electricity resilience over the U.S.: Persistence of current water-electricity operations and long-term transformative plans

The electricity system relies upon the availability and predictability of water to support hydropower operations and cooling of thermoelectric plants, implying that water plays a fundamental role in power operations and that water-related stresses may have a critical effect on the electricity system. Designing for electricity system resilience to changing societal demands and environmental conditions is a complex and urgent endeavor, one that requires robust diagnosis and an articulation of interdependencies among key system components. Here we consider the argument that water may help to navigate that complexity, revealing thresholds for system change and the transformations that may be required for enduring resilience of the electricity sector. To assess this thesis, we apply a framework for understanding resilient systems following Folke et al., that is extended in this special issue, by which resilience comprises three capabilities: system persistence, adaptability, and transformation. We apply this resilience diagnosis approach to the bulk electricity system of the contiguous United States, with particular attention to water-driven stressors. We provide a qualitative narrative that discusses the spectrum of resilience capabilities (persistence, adaptability, and transformability) of the water-electricity system in the United States over three scales of inter-dependencies: individual power plant, urban and grid scales.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Performance Monitoring of Residential Hot Water Distribution Systems

Current water distribution systems are designed such that users need to run the water for some time to achieve the desired temperature, wasting energy and water in the process. We developed a wireless sensor network for large-scale, long time-series monitoring of residential water end use. Our system consists of flow meters connected to wireless motes transmitting data to a central manager mote, which in turn posts data to our server via the internet. This project also demonstrates a reliable and flexible data collection system that could be configured for various other forms of end use metering in buildings. The purpose of this study was to determine water and energy use and waste in hot water distribution systems in California residences. We installed meters at every end use point and the water heater in 20 homes and collected 1s flow and temperature data over an 8 month period. For a typical shower and dishwasher events, approximately half the energy is wasted. This relatively low efficiency highlights the importance of further examining the energy and water waste in hot water distribution systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Mass of Water Turbine Current Energy Converter CFD Results

The CFD (computational fluid dynamics) results for the Mass of Water Turbine (MOWT) current energy converter from MWNW Consulting (formerly Ecosse IP). Each case is self-contained in its own tar.gz archive file. The archive contains the scripts required to perform a full simulation using OpenFOAM v1906. The scripts to process the output and plot forces are included in "Plotting Scripts", and all computational meshes generated are included in "Computational Grids".

16 TIDAL AND WAVE POWER↗

Investigating Mountain Watershed Headwater‐To‐Groundwater Connections, Water Sources, and Storage Selection Behavior With Dynamic‐Flux Particle Tracking

Abstract Climate change will impact mountain watershed streamflow both directly—with changing precipitation amounts and variability—and indirectly—through temperature shifts altering snowpack, melt, and evapotranspiration. To understand how these complex processes will affect ecosystem functioning and water resources, we need tools to distinguish connections between water sources (rain/snowmelt), groundwater storage, and exit fluxes (streamflow/evapotranspiration), and to determine how these connections change seasonally and as climate shifts. Here, we develop novel watershed‐scale approaches to understand water source, storage, and exit flux connections using a dynamic‐flux particle tracking model (EcoSLIM) applied in California's Cosumnes Watershed, which connects the Sierra Nevada and Central Valley. This work develops new visualizations and applications to provide mechanistic understanding that underpins the interpretation of isotopic field data at watershed scales to distinguish sources, flow paths, residence times, and storage selection. In our simulations, streamflow comes primarily from snow‐derived water while evapotranspiration generally comes from rain. Most streamflow starts above 1,000 m while evapotranspiration is sourced relatively evenly across the watershed and is generally younger than streamflow. Modeled streamflow consists primarily of water sourced from precipitation in the previous 5 years but before the current water year, while ET consists primarily of water from precipitation in the current water year. ET, and to a lesser extent streamflow, are both younger than water in groundwater storage. However, snowmelt‐derived streamflow preferentially discharges older water from snow‐derived storage. Dynamic‐flux particle tracking and new approaches presented here enable novel model‐tracer comparisons in large‐scale watersheds to better understand watershed behavior in a changing climate.

54 ENVIRONMENTAL SCIENCES↗

Power Law Growth and Delayed Feedbacks in Socio-Hydrological Systems

Water infrastructure dynamics result from coupled social and physical hydrological processes embedded in “socio-hydrological systems” (SHSs). Freshwater fuels socioeconomic activity, which in turn exerts pressure on water resources through increased water demand and water quality degradation. Many factors emphasize the need for quantitative tools to predict the future of these systems, including SHS failures due to growing water scarcity from population growth and climate change. However, unfolding the interactions between social and hydrological factors continues to resist theoretical treatment, impeding progress toward a predictive framework. To resolve this issue, we propose and evaluate time delays as surrogates for the social dynamics in SHS models. This approach permits the development of models that describe SHS dynamics in terms of observable, physical, hydrological state variables. We apply this approach to two case studies: (a) reservoir storage capacity growth in the world and the U.S. Water Resources Regions and (b) global water withdrawals. Substantial variability was identified in empirical estimates of growth rates and time delays. Reservoir construction typically follows a saturating, logistic curve with periodic, punctuated equilibria, separated by delays ranging from 5 to 20 years both globally and regionally. In contrast, global water withdrawal data display faster-than-exponential growth, characteristic of a positive feedback through which water use drives further water development. Historical analysis suggests that growth trends in water resources systems are superimposed by recurring periods of innovation and inactivity which are indicative of slow memory dissipation and delayed effects of past water use on current water infrastructure decisions.

54 ENVIRONMENTAL SCIENCES↗

An integrated modelling framework to assess long-term impacts of water management strategies steering soil subsidence in peatlands

Around the world many peatlands are managed unsustainably. Drainage of the peat causes soil subsidence and a range of negative societal impacts. Integrated strategies are required to ensure more sustainable long-term settings, based on impact assessment models that simulate the interrelated dynamics of water management and soil subsidence, and determine the spatial and temporal range of societal impacts. This paper presents an integrated modelling framework that meets these requirements. We used the framework to assess the impacts of a range of water management strategies in Dutch peatlands. Average soil subsidence rates were shown to range from 0.6 to 4.5 mm·y{sup −1}, resulting in marked differences in societal impacts that affect stakeholders unequally. Moreover, the impacts on real estate damage and water system maintenance revealed inverse trends that result in increasingly unbalanced cost-benefit ratios. The generated insights led the regional water authority to change their current water management strategy, preventing unsustainable future developments. We find the results relevant for improving stakeholders' awareness of long-term impacts of management strategies, and making negotiation processes on goals, means, and possible future pathways more transparent. - Highlights: •We developed an integrated modelling framework to support peatland management. •We used the case of Dutch peatlands to illustrate the added value of the framework. •Spatial patterns and temporal trends show how stakeholders are affected unequally. •The results were used to improve water management strategies.

02 PETROLEUM↗

The effects of total dissolved gas on chum salmon fry survival, growth, gas bubble disease, and seawater tolerance

Chum salmon Oncorhynchus keta alevin developing in gravel habitats downstream of Bonneville Dam on the Columbia River are exposed to elevated levels of total dissolved gas (TDG) when water is spilled at the dam to move migrating salmon smolts downstream to the Pacific Ocean. Current water quality criteria for the management of dissolved gas in dam tailwaters were developed primarily to protect salmonid smolts and are assumed to be protective of alevin if adequate depth compensation is provided. We studied whether chum salmon alevin exposed to six levels of dissolved gas ranging from 100% to 130% TDG at three development periods between hatch and emergence (hereafter early, middle, and late stage) suffered differential mortality, growth, gas bubble disease, or seawater tolerance. Each life stage was exposed for 50 d (early stage), 29 d (middle stage), or 16 d (late stage) beginning at 13, 34, and 37 d post-hatch, respectively, through 50% emergence. The mortality for all stages from exposure to emergence was estimated to be 8% (95% confidence interval (CI) of 4% to 12%) when dissolved gas levels were between 100% and 117% TDG. Mortality significantly increased as dissolved gas levels rose above 117% TDG,; with the lethal concentration that produced 50% mortality (LC50 ) was estimated to be 128.7% TDG (95% CI of 127.2% to 130.2% TDG) in the early and middle stages. By contrast, there was no evidence that dissolved gas level significantly affected growth in any life stage except that the mean wet weight at emergence of early stage fish exposed to 130% TDG was significantly less than the modeled growth of unexposed fish. The proportion of fish afflicted with gas bubble disease increased with increasing gas concentrations and occurred most commonly in the nares and gastrointestinal tract. Early stage fish exhibited higher ratios of filament to lamellar gill chloride cells than late stage fish, and these ratios increased and decreased for early and late stage fish, respectively, as gas levels increased; however, there were no significant differences in mortality between life stages after 96 h in seawater. The study results suggest that current water quality guidelines for the management of dissolved gas appear to offer a conservative level of protection to chum salmon alevin incubating in gravel habitat downstream of Bonneville Dam.

Geist, David R↗

Method for automatic correction of offset drift in online sensors

Abstract Successful operation and optimization of water treatment systems hinge on the availability of high-quality online sensor measurements. Ideally, the available measurements should be simultaneously accurate (i.e., unbiased and precise), representative, voluminous, and timely. This remains a pain-point in current water infrastructures, forming a barrier to a wider adoption of advanced and autonomous control systems. While short-lived symptoms, such as outliers and spikes, can be detected or corrected with state-of-the-art tools for fault detection and identification, it is much more difficult to detect, diagnose, and correct the symptoms of slow faults, such as changes in offset or sensitivity due to drift. The time scale of drift is often longer than the time scales of the system dynamics of interest. Moreover, sensor drift has been shown to occur at the same time and with similar rates when sensors are exposed to the same conditions. This challenges data quality management strategies based on redundancy. In this contribution, we develop a new method, including both a hands-off sensor calibration mechanism and an information-seeking control architecture that can handle the unique challenge of simultaneous and similar drift in online sensors.

Chowdhury, Dhrubajit↗

Using Salmon as a Bio-indicator of the Health of the Columbia River at Hanford - 15534

Assessing human, ecological, and cultural health and well-being on- and off-site is an important aspect of managing legacy wastes and environmental remediation on U.S. Department of Energy sites. Such an assessment is especially important at places such as Hanford because the Columbia River runs through the site. The Columbia River is central to the culture and economy of the northwest, especially to the Tribes. While a full range of other bio-indicators are used to determine the health of the river with respect to contaminants, salmon are the iconic, keystone species in the Columbia River of concern to the full range of regulators, managers, Tribes, and the public. A bio-monitoring plan that will assure the public and others that the activities of DOE are not adversely impacting the salmon populations in the Columbia River is critical for long term stewardship, both of the Hanford Site and the River and its resources Numerous factors affect salmon populations, including different life stages, habitat variables, and anthropogenic effects, including hexavalent chromium. Based on a literature review of the factors affecting populations, a conceptual model was developed for effects on salmon population stability. Salmon have a life history that includes laying eggs in gravel (redds) at the river bottom and then spending several life stages in fresh water and maturing in saltwater before they return to their natal streams or rivers to breed. All of these phases are potentially vulnerable to a range of natural and anthropogenic factors. Eggs in redds in the river bottom are vulnerable to water erosion, dewatering, oxygen levels, predators, and contaminants, while juveniles (fry, parr, smolts) are vulnerable to water currents, oxygen levels, predators, contaminants, and negotiating dams. When adults return to the river up to 7 years later, they face these same factors, as well as intense fishing pressures. The major factor affecting salmon populations may well be the fight to swim upstream, around dams, to reach traditional spawning grounds. While the data provided in this study relate to salmon at Hanford, the overall conceptual framework provides a paradigm for evaluating other sensitive indicators at other Department of Energy sites. The framework provides a method to insure the Tribes and public that the health and well-being of an important economic, cultural, and aesthetic species is being adequately addressed, and suggests the types of data needed to address the issue. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Produced Water Treatment Technologies: An Overview

Chapter 1 of <em>Solid-Liquid Separation Technologies: Applications for Produced Water.</em> Current and emerging produced water technologies are briefly reviewed. These technologies enable the reuse, safe disposal, and reinjection of produced water..

Gamwo, Isaac↗

Water Treatment: Are Membranes the Panacea?

Alongside the rising global water demand, continued stress on current water supplies has sparked interest in using nontraditional source waters for energy, agriculture, industry, and domestic needs. Membrane technologies have emerged as one of the most promising approaches to achieve water security, but implementation of membrane processes for increasingly complex waters remains a challenge. The technical feasibility of membrane processes replacing conventional treatment of alternative water supplies (e.g., wastewater, seawater, and produced water) is considered in the context of typical and emerging water quality goals. This review considers the effectiveness of current technologies (both conventional and membrane based), as well as the potential for recent advancements in membrane research to achieve these water quality goals. We envision the future of water treatment to integrate advanced membranes (e.g., mixed-matrix membranes, block copolymers) into smart treatment trains that achieve several goals, including fit-for-purpose water generation, resource recovery, and energy conservation.

catalysis (heterogeneous)↗

Geohydrodynamic Parameters and Their Implications on the Coastal Conservation: A Case Study of Abak Local Government Area (LGA), Akwa Ibom State, Southern Nigeria

A total of 14 vertical electrical soundings using Schlumberger electrode configuration and the complementary laboratory analysis of aquifer samples were carried out in the Abak Local Government Area of Akwa Ibom State, the coastal region of Nigeria. The study focused on the estimation of geohydrodynamic parameters of the frequently exploited aquifers and the implication of hydrodynamic parameters on the lithostratigraphy and the anticipated exposure of the assessed geologic formation at the shorelines. These parameters were porosity (&straightphi;), tortuosity (τ), formation factor (F), aquifer water formation resistivity (R{sub w}) and coefficient of permeability/hydraulic conductivity (K). Computation of the effective porosities from the aquifer cuttings was carried out using wet weight–dry weight technique and petrophysical techniques. The F values were computed using the aquifer formation bulk resistivity measured from field 1-D resistivity data analysis, whose interpretation was constrained by nearby borehole information. The formation pore water resistivities were estimated from the laboratory using electrical resistivity metre. The Win RESIST software program was used in interpreting the field data electronically. The results of interpretation gave the primary parameters of saturated and unsaturated units of the coastal regions used in this work. The area generally shows seemingly high porosity with high coefficient of permeability. The primary and secondary parameters have been contoured to model their distributions. Besides, some functional relations have been realized through regression analyses. The contour distribution of the geohydrodynamic parameters indicates the vulnerability of the water repositories to contaminations as well as the vulnerability of the shoreline to waterborne erosion. The seemingly high effective porosity in the compliant laboratory and calculated values indicate that the coastal region is neither lithified nor compacted/consolidated. This signals the possibility of the formation to be easily eroded, weathered or flooded where these units are exposed to water current. With these revelations, the shorelines could be properly managed and conserved by geotechnically reinforcing with hard and water-resistant concrete that can protect the vulnerable and erosion-prone porous sediments.

58 GEOSCIENCES↗