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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Development of a pyrolysis waste recovery model with designs, test plans, and applications for space-based habitats

Extensive literature searches revealed the numerous advantages of using pyrolysis as a means of recovering usable resources from inedible plant biomass, paper, plastics, other polymers, and human waste. A possible design of a pyrolysis reactor with test plans and applications for use on a space-based habitat are proposed. The proposed system will accommodate the wastes generated by a four-person crew while requiring solar energy as the only power source. Waste materials will be collected and stored during the 15-day lunar darkness periods. Resource recovery will occur during the daylight periods. Usable gases such as methane and hydrogen and a solid char will be produced while reducing the mass and volume of the waste to almost infinitely small levels. The system will be operated economically, safely, and in a non-polluting manner.

Roberson, Bobby J.↗

Production of gaseous fuel by pyrolysis of municipal solid waste

Pilot plant tests were conducted on a simulated solid waste which was a mixture of shredded newspaper, wood waste, polyethylene plastics, crushed glass, steel turnings, and water. Tests were conducted at 1400 F in a lead-bath pyrolyser. Cold feed was deaerated by compression and was dropped onto a moving hearth of molten lead before being transported to a sealed storage container. About 80 percent of the feed's organic content was converted to gaseous products which contain over 90 percent of the potential waste energy; 12 percent was converted to water; and 8 percent remained as partially pyrolyzed char and tars. Nearly half of the carbon in the feed is converted to benzene, toluene and medium-quality fuel gas, a potential credit of over $25 per ton of solid waste. The system was shown to require minimal preprocessing and less sorting then other methods.

Crane, T. H.↗

Investigating pyrolysis/incineration as a method of resource recovery from solid waste

Pyrolysis/incineration (P/I) is a physicochemical method for the generation of recoverable resources from solid waste materials such as inedible plant biomass (IPB), paper, plastics, cardboard, etc. P/I permits the collection of numerous gases with a minimal amount of solid residue. Pyrolysis, also known as starved air incineration, is usually conducted at relatively high temperatures (greater than 500 deg C) in the absence of oxygen. Incineration is conducted at lower temperatures in the presence of oxygen. The primary purpose of this study was to design, construct, and test a model P/I. The system design includes safety requirements for temperature and pressure. The objectives of this study were: (1) to design and construct a P/I system for incorporation with the Hybrid Regenerative Water Recovery System; (2) to initiate testing of the P/I system; (3) to collect and analyze P/I system data; (4) to consider test variables; and (5) to determine the feasibility of P/I as an effective method of resource recovery. A P/I system for the recovery of reuseable resources from solid waste materials was designed, constructed, and tested. Since a large amount of inedible plant biomass (IPB) will be generated in a space-based habitat on the lunar surface and Mars, IPB was the primary waste material tested in the system. Analysis of the effluent gases was performed to determine which gases could be used in a life support system.

Robertson, Bobby J.↗

Flash Cracking Reactor for Waste Plastic Processing

Conversion of waste plastic to energy is a growing problem that is especially acute in space exploration applications. Moreover, utilization of heavy hydrocarbon resources (wastes, waxes, etc.) as fuels and chemicals will be a growing need in the future. Existing technologies require a trade-off between product selectivity and feedstock conversion. The objective of this work was to maintain high plastic-to-fuel conversion without sacrificing the liquid yield. The developed technology accomplishes this goal with a combined understanding of thermodynamics, reaction rates, and mass transport to achieve high feed conversion without sacrificing product selectivity. The innovation requires a reaction vessel, hydrocarbon feed, gas feed, and pressure and temperature control equipment. Depending on the feedstock and desired product distribution, catalyst can be added. The reactor is heated to the desired tempera ture, pressurized to the desired pressure, and subject to a sweep flow at the optimized superficial velocity. Software developed under this project can be used to determine optimal values for these parameters. Product is vaporized, transferred to a receiver, and cooled to a liquid - a form suitable for long-term storage as a fuel or chemical. An important NASA application is the use of solar energy to convert waste plastic into a form that can be utilized during periods of low solar energy flux. Unlike previous work in this field, this innovation uses thermodynamic, mass transport, and reaction parameters to tune product distribution of pyrolysis cracking. Previous work in this field has used some of these variables, but never all in conjunction for process optimization. This method is useful for municipal waste incinerator operators and gas-to-liquids companies.

Timko, Michael T.↗