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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Changes in water vapor adsorption and water film thickness in clayey materials as a function of relative humidity

Abstract Soil water, with adsorbed water being an important component, plays an important role in fluid flow and chemical movement in the unsaturated zone. The adsorbed water consists of water film and interlayer water, and its content is related to the relative humidity (RH). This study theoretically and experimentally focuses on the variation in adsorbed water content in clayey materials as the RH changes. Based on a slit‐pore model, three types of water (water film, interlayer water, and capillary water) could be present in the water vapor adsorption process. The variation of water film is obtained from the analysis of interfacial forces, and then the total water content can be quantitatively subdivided into these three types of water for different RH values. The slit‐pore adsorption model was used with experimental measurements (water vapor adsorption and N 2 physisorption) to quantify the amounts and interrelationships of these three different types of water to six clayey materials, namely three clay minerals (kaolinite, montmorillonite, and illite–smectite mixed layer) and three clay‐rich sediments from the Jianghan Plain in China. The main results are that (a) the volumes of water vapor adsorption are much greater than those of N 2 adsorption except for kaolinite; (b) interlayer water largely dominates the growth of total water content in montmorillonite and results in a concentration of 0.090 ml g −1 at 95% RH; and (c) the minimum thickness of water film is calculated to be 0.23 nm, and the maximum value is one‐third of the pore width by considering the interfacial forces.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Amphiphilic nanopores that condense undersaturated water vapor and exude water droplets

Condensation of water vapor in confined geometries, known as capillary condensation, is a fundamental phenomenon with far-reaching implications. While hydrophilic pores enable liquid formation from undersaturated vapor without energy input, the condensate typically remains confined, limiting practical utility. Here, we explore the use of amphiphilic nanoporous polymer-infiltrated nanoparticle films that condense and release liquid water under isothermal and undersaturated conditions. By tuning the polymer fraction and nanoparticle size, we optimize condensation and droplet formation. As vapor pressure increases, voids fill with condensate, which subsequently exudes onto the surface as microscopic droplets. This behavior, enabled by a balance of polymer hydrophobicity and capillarity, reveals how amphiphilic nanostructures can drive accessible water collection. Our findings provide design insights for materials supporting energy-efficient water harvesting and heat management without external input.

Science & Technology - Other Topics↗
DOE OSTI2020

Micro-Pulse DIAL for Atmospheric Water Vapor Profiling (Phase I Final Report)

Water vapor plays a key role in Earth’s climate and weather patterns. Accurate, high resolution measurements of the water vapor vertical profiles in a region have been found to significantly improve the numerical weather prediction models’ short-term forecasts, precipitation forecasts, as well as severe weather forecasts. However, current measurement techniques provide very coarse resolution in space, time, and/or altitude. A network of continuously sampling water vapor profilers would greatly expand the scientific knowledge of the atmosphere and serve as a valuable input into numerical weather models. This would be of interest not only to the Department of Energy’s Environmental Sciences Division but to other institutions such as the National Weather Service, the National Center for Atmospheric Research, the Federal Emergency Management Agency, and the military.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Effects of Water Vapor on the Reactivity of Aluminosilicates in Vapor-Phase Propanal Aldol Condensation

Aluminosilicate materials have been extensively studied as efficient aldol catalysts for C-C coupling reactions due to their acidic nature, high surface area, thermal stability, and porous structure. This work investigated the impact of water vapor pressure on the catalytic reactivity of aluminosilicates for the aldol condensation of propanal to 2-methyl-2-pentenal (MP). The catalytic performance of amorphous SiO2-Al2O3 (A-Si-Al) and aluminated MCM-41 (Al-MCM-41) for the vapor-phase aldol condensation of propanal was evaluated at 200 degrees C as a function of vapor-phase water content at atmospheric pressure. Our findings demonstrate that co-feeding low water vapor pressures (1-18 kPa) with propanal enhances the rates of MP production at 200 degrees C on A-Si-Al. Conversely, water vapor pressures of 25 kPa result in a decrease in aldol dimer formation rates. The rate of MP production evaluated on Al-MCM-41 also increased in the presence of 5 kPa water compared to anhydrous conditions. Propylamine temperature-programmed desorption analyses revealed an increase in Bronsted acid site density when both catalysts were exposed to water, which likely accounts for the observed enhancement in aldol condensation reactivity under hydrous conditions. Reversibility testing of the water vapor effect under reaction conditions, combined with X-ray diffraction analysis of fresh, spent, and regenerated catalysts, revealed no structural changes in either aluminosilicate upon exposure to water or reaction conditions. The rates of aldol condensation and the impact of water vapor were highly consistent across both materials, suggesting that zeolite crystallinity has minimal influence on the catalytic performance.

acid catalysts↗
DOE OSTI2020

The Incredible Lightness of Water Vapor

The molar mass of water vapor is much less than that of dry air. This makes a moist parcel lighter than a dry parcel of the same temperature and pressure. This effect is referred to as the vapor buoyancy effect and has often been overlooked in climate studies. We propose that the vapor buoyancy effect increases Earth’s outgoing longwave radiation (OLR) and that this negative radiative effect increases with warming, stabilizing Earth’s climate. We illustrate this mechanism in an idealized tropical atmosphere, where there is no horizontal buoyancy gradient in the free troposphere. Temperature increases toward dry atmosphere columns to compensate the reduced vapor buoyancy, increasing OLR by O(1 W m −2 ) at the reference climate. In warmer climates, the temperature difference between moist and dry columns would increase as a result of increasing atmospheric water vapor, leading to enhanced radiative effect and thereby stabilizing Earth’s climate. We estimate that this feedback strength is about O(0.2 W m −2 K −1 ) in the idealized atmosphere, which compares to cloud feedback and surface albedo feedback in the current climate. We further show evidence from observations and real-gas radiative transfer calculations for a significant radiative effect of vapor buoyancy in the tropical atmosphere.

Yang, Da↗
DOE OSTI2022

Variability of Water Vapor in the Tropical Middle Atmosphere Observed From Satellites and Interpreted Using SD-WACCM Simulations

Water vapor in the middle atmosphere plays an essential role in global warming, ozone depletion, and the formation of polar stratospheric and mesospheric clouds. We show that tropical middle atmospheric water vapor simulated with the specified-dynamics version of the Whole Atmosphere Community Climate Model (SD-WACCM) is consistent with changes observed in a merged satellite data set, which encompasses the period 1993–2020. Consistent with previous work, we find no significant trend in the stratosphere in either the observations or the simulation; in the mesosphere, we find a long-term trend of 0.1 ppmv per decade, but only in the observations. We also analyze an SD-WACCM simulation for the longer period 1980–2019 to quantify the contribution of various factors to the decadal variation of middle atmospheric water vapor. Over 1980–1995, the simulated water vapor in the upper stratosphere and mesosphere, averaged zonally and over ±30° latitude, increases by 0.30 ppmv per decade due to increasing methane emissions. After 1995, a significant abrupt decrease of water vapor of 0.37 ppmv per decade and then a gradual increase of 0.33 ppmv per decade result from changes in stratospheric cold point temperature. The cold-point temperature is strongly influenced by the strength of the Brewer-Dobson circulation. The acceleration of the Brewer-Dobson circulation before about 2003 leads to a cooler tropical tropopause and a decrease of water vapor, and the deceleration thereafter leads to corresponding warming of the tropopause and an increase in water vapor.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Effect of water vapor and thermal history on nuclear waste feed conversion to glass

Water affects the glass melting process by interacting with the foam layer at the glass melt surface and by influencing the batch conversion reactions. Water vapor from the nuclear waste slurry feed maintains a high water vapor pressure in the melter atmosphere. To investigate to what extent water vapor affects the vitrification of nuclear waste in joule-heated, cold-top melters, a series of feed expansion experiments were performed under humid and dry atmospheres using samples of low-activity waste (LAW) melter feed simulants. Melting of feed pellets in the presence of water vapor slightly decreased the temperature of primary foam onset, but did not significantly affect the feed volume expansion by foaming or the foam-collapse temperature. Sets of feed expansion experiments and evolved gas analyses were also performed to check the effect of thermal history on LAW feed samples tested as direct slurry, loose powder, and slow- and fast-dried pellets.

Marcial, Jose↗
DOE OSTI2022

Disentangling the mechanism of temperature and water vapor modulation on ozone under a warming climate

Temperature and water vapor have been considered as important factors affecting ozone concentrations, however, their synergistic effect on ozone, as well as its response to a warming climate remains unclear. Here, numerical experiments with different combinations of climate and emissions highlighted opposite changes of annual ozone over the contiguous U.S. under scenarios with high vs. low ozone precursor emissions in the future with warming. Comparing the occurrence of heat waves on higher vs. lower ozone days, we found significant suppression of the heat wave exacerbation of ozone by anthropogenic emissions reductions. Variations of ozone with temperature (T) and water vapor (Q) over the western U.S. and southeastern U.S. in the simulations are clearly revealed through the construction of an O 3 -T-Q diagram. Based on the diagram, we further identified a T-dominant regime at higher temperatures where ozone increases with temperature increase, and a Q-dominant regime at lower temperatures where ozone decreases with temperature increase due to the negative effect of water vapor. With larger anthropogenic emission reductions, ozone may increase at a lower rate with temperature in the T-dominant regime, or even decrease with temperature in the Q-dominant regime. Our results show that with large emission reductions, substantial ozone pollution due to warming and increasing heat waves may be counteracted by water vapor, partly turning the ‘climate penalty’ on ozone into ‘climate benefit’. Hence controlling anthropogenic emissions may be an increasingly important strategy in a warmer and wetter climate to improve air quality and public health.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Exploring the elevated water vapor signal associated with the free tropospheric biomass burning plume over the southeast Atlantic Ocean

In southern Africa, widespread agricultural fires produce substantial biomass burning (BB) emissions over the region. The seasonal smoke plumes associated with these emissions are then advected westward over the persistent stratocumulus cloud deck in the southeast Atlantic (SEA) Ocean, resulting in aerosol effects which vary with time and location. Much work has focused on the effects of these aerosol plumes, but previous studies have also described an elevated free tropospheric water vapor signal over the SEA. Water vapor influences climate in its own right, and it is especially important to consider atmospheric water vapor when quantifying aerosol-cloud interactions and aerosol radiative effects. Here we present airborne observations made during the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign over the SEA Ocean. In observations collected from multiple independent instruments on the NASA P-3 aircraft (from near-surface to 6-7 km), we observe a strongly linear correlation between pollution indicators (carbon monoxide (CO) and aerosol loading) and atmospheric water vapor content, seen at all altitudes above the boundary layer. The focus of the current study is on the especially strong correlation observed during the ORACLES-2016 deployment (out of Walvis Bay, Namibia), but a similar relationship is also observed in the August 2017 and October 2018 ORACLES deployments. Using reanalyses from the European Centre for Medium-Range Weather Forecasts (ECMWF) and Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), and specialized WRF-Chem simulations, we trace the plume-vapor relationship to an initial humid, smoky continental source region, where it mixes with clean, dry upper tropospheric air and then is subjected to conditions of strong westward advection, namely the southern African easterly jet (AEJ-S). Our analysis indicates that air masses likely left the continent with the same relationship between water vapor and carbon monoxide as was observed by aircraft. This linear relationship developed over the continent due to daytime convection within a deep continental boundary layer (up to ~5-6 km) and mixing with higher-altitude air, which resulted in fairly consistent vertical gradients in CO and water vapor, decreasing with altitude and varying in time, but this water vapor does not originate as a product of the BB combustion itself. Due to a combination of conditions and mixing between the smoky, moist continental boundary layer and the dry and fairly clean upper-troposphere air above (~6 km), the smoky, humid air is transported by strong zonal winds and then advected over the SEA (to the ORACLES flight region) following largely isentropic trajectories. Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT) back trajectories support this interpretation. This work thus gives insights into the conditions and processes which cause water vapor to covary with plume strength. Better understanding of this relationship, including how it varies spatially and temporally, is important to accurately quantify direct, semi-direct, and indirect aerosol effects over this region.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Marine Boundary Layer Decoupling and the Stable Isotopic Composition of Water Vapor

Decoupling of the subcloud layer in stratocumulus-topped marine boundary layers (STMBL) influences low-cloud cover by limiting the supply of water vapor from the surface. However, the relative importance of mixing between surface fluxes and other reservoirs of water vapor as a function of the degree of decoupling is poorly understood. Water vapor transport within the STMBL and its response to decoupling is explored using surface measurements of water vapor isotopic composition that were obtained from Graciosa Island, Azores, during the summer and fall of 2018. The data show an inverse relationship between the decoupling metric, Δq, and the degree of drying from an isotopically depleted water vapor source. The isotopic data require some degree of drying with an isotopically depleted source for coupled conditions, and likely require a small amount of mixing even for strongly decoupled conditions. The data are consistent with mixing between purely local reservoirs of water vapor, subjected to a small amount of condensation and fractionation, and do not require the invocation of large-scale transport of water vapor aloft or additional cloud-formation effects aloft.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

CAPE-K_ISO: Water vapor isotopic measurements from Western Tasmania

This dataset provides processed 1-minute water vapor isotope observations from the Water Vapor Isotopic Measurements During CAPE-K project at the Kennaook/Cape Grim Baseline Air Pollution Station in northwestern Tasmania. Measurements were made with a Picarro L-2130 cavity ring-down spectroscopy analyzer during the CAPE-K deployment. The dataset includes water vapor mixing ratio, d18O, dD, deuterium excess, and propagated 1-sigma uncertainties. Isotope ratios are calibrated to the VSMOW/SLAP scale. Calibration intervals, transition periods, and obvious isotope outliers have been removed. The processed record spans 11 June 2024 to 15 October 2025 and is intended for studies of Southern Ocean marine boundary-layer moisture, isotope variability, air-sea exchange, and cloud and precipitation processes.

Water Vapor Isotopic Composition↗
DOE OSTI2025

In situ atomic-resolution imaging of water vapor–driven multistep oxidation dynamics in strontium cobaltite

Understanding how water vapor interacts with transition metal oxides (TMOs) is critical for tailoring material properties to improve performance and enable new technologies. Despite extensive research efforts, atomic-scale mechanisms underpinning dynamic reactions and reaction-induced phase transitions remain elusive. Here, we use in situ environmental transmission electron microscopy to investigate how water vapor oxidizes vacancy-ordered SrCoO 2.5 at moderately elevated temperatures, demonstrating that water molecules can initiate oxidation more effectively than oxygen under comparable conditions. We discover a distinct “staging” behavior during the oxidation process: A fully ordered intermediate phase, SrCoO 2.75 , forms before transitioning into a near-perovskite SrCoO 3−δ . In addition, antiphase boundaries, originating at step terraces of SrTiO 3 , alleviate strain by creating reversible nanoscale “gaps” during lattice contraction under oxidation, providing a pathway for preserving structural integrity throughout redox cycling. This work provides atomic-level guidance for engineering TMOs by leveraging water vapor to control their redox behavior and tailor functional properties.

Science & Technology - Other Topics↗
DOE OSTI2023

Aerosol Indirect Effects on Water Vapor in the UTLS of Typhoon Saomai (2006)

The evolution of landfalling Typhoon Saomai (2006) is simulated using the Weather Research and Forecasting model with spectral bin microphysics scheme, showing tropical cyclone (TC) could vertically transport water vapor from troposphere to upper troposphere and lower stratosphere (UTLS). Three aerosol sensitivity experiments are conducted to explore the indirect effects of aerosol served as cloud condensation nuclei (CCN) on overshooting convection (OTC) and water vapor content in UTLS, namely MAR (maritime), MIX (semi‐continental) and CON (continental). Results revealed that CON simulation with high initial aerosol concentration showing invigorated convection at the periphery of the TC, which interfered with the reformation of TC eyewall, leading to TC weakening finally. In addition, CON simulated the least water content in UTLS through suppressing the number of convection overshooting the tropopause level. Most overshooting events take place during TC developing stage in the eyewall region before landfall. Higher levels of CCN concentration could lead to decreased number of OTC in TC, consistently reduced the water vapor content in UTLS. CON and MIX experiments simulated respectively 21.9% (16.2%) and 9.96% (1.5%) less OTC (water vapor content in UTLS) than MAR simulation. Further, water vapor content in UTLS is affected by the interaction of OTC and ice‐phase microphysics. The interesting point is that the CCN sensitivity experiments show that water vapor content in UTLS of a TC is sensitive to the CCN concentration in the boundary layer.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Water vapor isotopic composition during TRACER IOP

The TRACER-Iso project took place from June 1 to September 30, 2022 as part of the intensive observation period (IOP) of the Tracking Aerosol Convection Interactions (TRACER) project at the main project site at the La Porte, Texas, municipal airport. The project sought to use measurements of the stable isotopic composition of water vapor to better understand cloud-aerosol interactions in deep convection in a polluted urban setting. Water vapor isotopologue and humidity measurements were determined using a Picarro L2130 Water Vapor Isotope Analyzer. The instrument was deployed in the guest van and consists of three main components: a water vapor isotope analyzer, and a Los Gatos Research Water Vapor Isotope Standard Source (WVISS), and a Los Gatos Research Dry Air Source. Ambient air samples were collected through an inlet located about one meter above roof of the shipping container. Samples were then delivered to the analyzer through teflon tubing by use of an external pump to minimize the transport time between the inlet and analyzer. The inlet tubing was surrounded by a Briskheat heat trace and insulating material to ensure ambient air samples did not fall below the dew point and result in condensation. The analyzer uses cavity ringdown spectroscopy to report isotopic ratios of ambient air samples at a frequency of 1 Hz. The calibration unit of the instrument was used in conjunction with the dry air source to periodically measure the δ values of standard waters. It uses a nebulizer to push small water droplets into a hot chamber that vaporizes the water without fractionation. This vapor was then transported to the analyzer using a built-in compressor and the dry air source, which allows each standard with known δ values to be measured at a wide range of humidity values for post-measurement calibration of ambient air samples. There are multiple sources of uncertainty introduced at different stages during the data collection and processing. These include (1) instrument precision, (2) uncertainty in the secondary standards, (3) humidity-correction uncertainty, and (4) VSMOW-SLAP calibration uncertainty. Uncertainty from each step is propagated in quadrature to calculate a total uncertainty of each isotopologue. Uncertainty was determined to be 2.3‰ for δD and 0.4‰ for δ18O.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Using ground-based lidar data to investigate the water–vapor budget in the daytime atmospheric boundary layer

The moisture advection term in the water–vapor budget equation is investigated with a combination of a vertically-staring water–vapor lidar and Doppler lidar systems. These instruments make it possible to get the mean profile of moisture tendency and the latent heat flux (LHF) divergence. We use data of the Land–Atmosphere Feedback Experiment (LAFE) at the Atmospheric Radiation Measurement (ARM) Program’s Southern Great Plains (SGP) site, Oklahoma, USA, collected on 30 August 2017 between 15 and 24 UTC, which corresponds to 09 to 18 LT. The lidars provide turbulence resolving profiles of moisture and vertical wind fluctuations. The LHF profile is derived from the covariance of these moisture and vertical wind fluctuations. The mean boundary layer height z i is determined from the peak of the moisture variance. The results demonstrate that the combination of two remote sensing instruments can be applied for determining the dominant water–vapor budget terms, namely moisture tendency, latent heat flux divergence and moisture advection.

Advection↗
DOE OSTI2022

How the Hydrophobic Interface between a Perfluorosulfonic Acid Polymer and Water Vapor Controls Membrane Hydration

Stable hydration in perfluorinated polyelectrolyte membranes such as Nafion is essential to maintain good ion conductivity and manage permeation, especially in vapor-fed devices where water content depends on relative humidity in a gas stream. Extensive studies in the literature have shown that Nafion hydration in water vapor is controlled by its interfacial transport resistance. Nafion forms a fluorine-rich layer at the polymer-gas interface, and it has been proposed that this layer blocks water transport due to its hydrophobicity. To develop a molecular-level description of the physics underlying transport resistance in this system, we have performed a computational reaction-diffusion kinetics study of water evaporation from Nafion. Two distinct models are examined, one mimicking the blocking function proposed in the literature and the other assuming that there is no blocking, treating instead water evaporation as a dynamic balance between uptake from the gas and desorption from the polymer surface. Simulation results are compared to time-dependent infrared data over a range of 100-0% relative humidity from the literature. Only the dynamic model successfully reproduces experimental observations. This indicates that the physical nature of interfacial transport resistance is not slow diffusion across an interfacial layer; rather, it is due to the competition between dehydration and rehydration. The simulation data provide details on the accompanying water distributions throughout the membrane and on interfacial kinetics, showing that they are characterized by strong fluctuations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Recent trends and variability of temperature and atmospheric water vapor over South Asia

This study examines the recent trends and variability of temperature and atmospheric water vapor over South Asia during the summer monsoon season from 1970 to 2022. We employ gridded reanalysis and observational datasets to assess the trends and variability in surface temperature and further investigate the associated physical processes. Our results show that the surface temperature over South Asia has increased by 0.5 °C per decade. Notably, we find a statistically significant major transition in the surface temperature series in 1995, such that 1970–1994 (1995–2022) is associated with anomalous cooling (anomalous warming). Since 1995, not only have the temporal variations in regional surface temperature, atmospheric water vapor, and clear-sky downward longwave radiation been synchronous at interannual scales, but their largest spatial variations have been located mainly over the same region. A diagnosis of the atmospheric moisture budget reveals that the observed changes in water vapor convergence over South Asia are dominated by changes in mean circulation dynamics, while the change in thermodynamics is relatively small. The enhancement of the Somali low-level jet may contribute to increased water vapor in South Asia by modulating low-level circulations.

Atmospheric circulations↗
DOE OSTI2022

Nonequilibrium plasma in water vapor

A kinetic model of a non-equilibrium water vapor plasma created by a nanosecond pulsed discharge at elevated temperatures and at low pressure is presented. The model includes equations for electron, vibrational and gas temperatures combined with equations for neutral, charged, electronically and vibrationally excited species. Simulation results are compared with the available experimental data and show good agreement in dynamics of the plasma decay and electron drift velocities. It is shown that the plasma decay in pure water vapor is controlled by the dissociative recombination. Under the conditions simulated, the concentration of electronically excited species is low, but we observe a formation of vibrationally excited species. Finally, a significant decrease in the electrical conductivity of water plasma with time, which depends on the level of initial ionization, is shown.

42 ENGINEERING↗