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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

Space Weathering Rates in Lunar and Itokawa Samples

Space weathering alters the chemistry, microstructure, and spectral proper-ties of grains on the surfaces of airless bodies by two major processes: micrometeorite impacts and solar wind interactions. Investigating the nature of space weathering processes both in returned samples and in remote sensing observations provides information fundamental to understanding the evolution of airless body regoliths, improving our ability to determine the surface composition of asteroids, and linking meteorites to specific asteroidal parent bodies. Despite decades of research into space weathering processes and their effects, we still know very little about weathering rates. For example, what is the timescale to alter the reflectance spectrum of an ordinary chondrite meteorite to resemble the overall spectral shape and slope from an S-type asteroid? One approach to answering this question has been to determine ages of asteroid families by dynamical modeling and determine the spectral proper-ties of the daughter fragments. However, large differences exist between inferred space weathering rates and timescales derived from laboratory experiments, analysis of asteroid family spectra and the space weathering styles; estimated timescales range from 5000 years up to 108 years. Vernazza et al. concluded that solar wind interactions dominate asteroid space weathering on rapid timescales of 10(exp 4)-10(exp 6) years. Shestopalov et al. suggested that impact-gardening of regolith particles and asteroid resurfacing counteract the rapid progress of solar wind optical maturation of asteroid surfaces and proposed a space weathering timescale of 10(exp 5)-10(exp 6) years.

Keller, L. P.↗
NASA NTRS2016

Direct Determination of the Space Weathering Rates in Lunar Soils and Itokawa Regolith from Sample Analyses

Space weathering effects on airless bodies result largely from micrometeorite impacts and solar wind interactions. Decades of research have provided insights into space weathering processes and their effects, but a major unanswered question still remains: what is the rate at which these space weathering effects are acquired in lunar and asteroidal regolith materials? To determine the space weathering rate for the formation of rims on lunar anorthite grains, we combine the rim width and type with the exposure ages of the grains, as determined by the accumulation of solar flare particle tracks. From these analyses, we recently showed that space weathering effects in mature lunar soils (both vapor-deposited rims and solar wind amorphized rims) accumulate and attain steady state in 10(sup 6)-10(sup 7) y. Regolith grains from Itokawa also show evidence for space weathering effects, but in these samples, solar wind interactions appear to dominate over impactrelated effects such as vapor-deposition. While in our lunar work, we focused on anorthite, given its high abundance on the lunar surface, for the Itokawa grains, we focused on olivine. We previously studied 3 olivine grains from Itokawa and determined their solar flare track densities and described their solar wind damaged rims]. We also analyzed olivine grains from lunar soils, measured their track densities and rim widths, and used this data along with the Itokawa results to constrain the space weathering rate on Itokawa. We observe that olivine and anorthite have different responses to solar wind irradiation.

Keller, L. P.↗
NASA NTRS1995

The Weathering of Antarctic Meteorites: Climatic Controls on Weathering Rates and Implications for Meteorite Accumulation

Weathering of meteorites includes a variety of chemical and mineralogical changes, including conversion of metal to iron oxides, or rust. Other changes include the devitrification of glass, especially in fusion crust. On a longer time scale, major minerals such as olivine, pyroxene, and feldspar are partially or wholly converted to various phyllosilicates. The degree of weathering of meteorite finds is often noted using a qualitative system based on visual inspection of hand specimens. Several quantitative weathering classification systems have been proposed or are currently under development. Wlotzka has proposed a classification system based on mineralogical changes observed in polished sections and Mossbauer properties of meteorite powders have also been used. In the current paper, we discuss induced thermoluminescence (TL) as an indicator of degree of weathering of individual meteorites. The quantitative measures of weathering, including induced TL, suffer from one major flaw, namely that their results only apply to small portions of the meteorite.

Benoit, P. H.↗
NASA NTRS2016

TEM Analyses of Itokawa Regolith Grains and Lunar Soil Grains to Directly Determine Space Weathering Rates on Airless Bodies

Samples returned from the moon and Asteroid Itokawa by NASA's Apollo Missions and JAXA's Hayabusa Mission, respectively, provide a unique record of their interaction with the space environment. Space weathering effects result from micrometeorite impact activity and interactions with the solar wind. While the effects of solar wind interactions, ion implantation and solar flare particle track accumulation, have been studied extensively, the rate at which these effects accumulate in samples on airless bodies has not been conclusively determined. Results of numerical modeling and experimental simulations do not converge with observations from natural samples. We measured track densities and rim thicknesses of three olivine grains from Itokawa and multiple olivine and anorthite grains from lunar soils of varying exposure ages. Samples were prepared for analysis using a Leica EM UC6 ultramicrotome and an FEI Quanta 3D dual beam focused ion beam scanning electron microscope (FIB-SEM). Transmission electron microscope (TEM) analyses were performed on the JEOL 2500SE 200kV field emission STEM. The solar wind damaged rims on lunar anorthite grains are amorphous, lack inclusions, and are compositionally similar to the host grain. The rim width increases as a smooth function of exposure age until it levels off at approximately 180 nm after approximately 20 My (Fig. 1). While solar wind ion damage can only accumulate while the grain is in a direct line of sight to the Sun, solar flare particles can penetrate to mm-depths. To assess whether the track density accurately predicts surface exposure, we measured the rim width and track density in olivine and anorthite from the surface of rock 64455, which was never buried and has a surface exposure age of 2 My based on isotopic measurements. The rim width from 64455 (60-70nm) plots within error of the well-defined trend for solar wind amorphized rims in Fig. 1. Measured solar flare track densities are accurately reflecting the surface exposure of the grains. Track densities correlate with the amorphous rim thicknesses. While the space-weathered rims of anorthite grains are amorphous, the space-weathered rims on both Itokawa and lunar olivine grains show solar wind damaged rims that are not amorphous. Instead, the rims are nanocrystalline with high dislocation densities and sparse inclusions of nanophase Fe metal. The rim thicknesses on the olivine grains also correlate with track density. The Itokawa olivine grains have track densities that indicate surface exposures of approximately 10(exp 5) years. Longer exposures (up to approximately 10(exp 7) years) do not amorphize the rims, as evidenced by lunar soil olivines with high track densities (approximately 10(exp 11) cm(exp -2)). From the combined data, shown in Fig. 1, it is clear that olivine is damaged (but not amorphized) more rapidly by the solar wind compared to anorthite. The olivine damaged rim forms quickly (in approximately 10(exp 6) y) and saturates at approximately 120nm with longer exposure time. The anorthite damaged rims form more slowly, amorphize, and grow thicker than the olivine rims. This is in agreement with numerical modeling data which predicts that solar wind damaged rims on anorthite will be thicker than olivine. However, the models predict that both olivine and anorthite rims will amorphize and reach equilibrium widths in less than 10(exp 3) y, in contrast to what is observed for natural samples. Laboratory irradiation experiments, which show rapid formation of fully amorphous and blistered surfaces from simulated solar wind exposures are also in contrast to observations of natural samples. These results suggest that there is a flux dependence on the type and extent of irradiation damage that develops in olivine. This flux dependence suggests that great caution be used in extrapolating between high-flux laboratory experiments and the natural case, as demonstrated by. We constrain the space weathering rate through analysis of returned samples. Provided that the track densities and the solar wind damaged rim widths exhibited by the Itokawa grains are typical of the fine-grained regions of Itokawa, then the space weathering rate is on the order of 10(exp 5) y. Space weathering effects in lunar soils saturate within a few My of exposure while those in Itokawa regolith grains formed in approximately 10(exp 5) y. Olivine and anorthite respond differently to solar wind irradiation. The space weathering effects in olivine are particularly difficult to reconcile with laboratory irradiation studies and numerical models. Additional measurements, experiments, and modeling are required to resolve the discrepancies among the observations and calculations involving solar wind amorphization of different minerals on airless bodies.

Berger, Eve L.↗
NASA NTRS1991

The mid-Cretaceous super plume, carbon dioxide, and global warming

Carbon-dioxide releases associated with a mid-Cretaceous super plume and the emplacement of the Ontong-Java Plateau have been suggested as a principal cause of the mid-Cretaceous global warming. A carbonate-silicate cycle model is developed to quantify the possible climatic effects of these CO2 releases, utilizing four different formulations for the rate of silicate-rock weathering as a function of atmospheric CO2. CO2 emissions resulting from super-plume tectonics could have produced atmospheric CO2 levels from 3.7 to 14.7 times the modern preindustrial value of 285 ppm. Based on the temperature sensitivity to CO2 increases used in the weathering-rate formulations, this would cause a global warming of from 2.8 to 7.7 C over today's glogal mean temperature. Altered continental positions and higher sea level may have been contributed about 4.8 C to mid-Cretaceous warming. Thus, the combined effects of paleogeographic changes and super-plume related CO2 emissions could be in the range of 7.6 to 12.5 C, within the 6 to 14 C range previously estimated for mid-Cretaceous warming. CO2 releases from oceanic plateaus alone are unlikely to have been directly responsible for more than 20 percent of the mid-Cretaceous increase in atmospheric CO2.

Caldeira, Ken↗
NASA NTRS2020

Cycling phosphorus on the Archean Earth: Part I. Continental weathering and riverine transport of phosphorus

Phosphorus (P) is the key nutrient thought to limit primary productivity on geological timescales. Phosphate levels in Archean marine sediments are low, but quantification of the P cycle and how it changed through a billion years of recorded Archean history remain a challenge, hindering our understanding of the role played by P in biosphere/geosphere co-evolution on the early Earth. Here, we design kinetic and thermodynamic models to quantitatively assess one key component of the early P cycle – continental weathering – by considering the emergence and elevation of continents, as well as the evolution of climate, the atmosphere, and the absence of macroscopic vegetation during the Archean Eon. Our results suggest that the weathering rate of apatite, the major P-hosting mineral in the rocks, was at least five times higher in the Archean Eon than today, attributable to high levels of pCO2,g. Despite this, the weathering flux of P to the oceans was negligible in the early Archean Eon, increasing to a level comparable to or greater than the modern by the end of eon, a consequence of accelerating continental emergence. Furthermore, our thermodynamic calculations indicate high solubilities of primary and secondary P-hosting minerals in the acidic weathering fluids on land, linking to high Archean pCO2,g. Thus, weathering of P was both kinetically and thermodynamically favorable on the Archean Earth, and river water could transport high levels of dissolved P to the oceans, as also supported by the observed P-depletion in our new compilation of Archean paleosols. Lastly, we evaluated the relative rates of physical erosion and chemical weathering of silicates during the Archean Eon. The results suggest that continental weathering on the early and middle Archean Earth might have been transport-limited due to low erosion rates associated with limited subaerial emergence and low plateau elevations; by the late Archean, however, continental weathering would have transited to kinetically-limited state because of continental emergence, increased plateau elevation, and weakening weathering rates. Overall, our weathering calculations together with paleosol evidence indicate an increasing flux of bioavailable P to the oceans through time, associated with late Archean continental emergence, reaching levels comparable to or higher than modern values by the end of the eon. Increased P fluxes could have fueled increasing rates of primary production, including oxygenic photosynthesis, through time, facilitating the irreversible oxidation of the Earth’s atmosphere early in the Proterozoic Eon.

Phosphorus↗
NASA NTRSDate not supplied

Evidence for Present Day Volcanism on Venus: A Case Study of Idunn Mons

Idunn Mons in Imdr Regio on Venus is perhaps one of the best studied volcanoes on Venus in part due to having both radar and night-time emissivity data of the region [1-3]. Smrekar et al. [1] first presented night-time emissivity data of Idunn Mons from the VIRTIS instrument on Venus Express, which showed that some lava flows have high emissivity consistent with unweathered basalt. Smrekar et al. [1], based on known weathering rates at that time, suggested that the lava flows were less than 2.5 million years old and possible as young as 250,000 years old. However, recent experimental work has shown that basaltic rocks and associated minerals in contact with the Venusian caustic atmosphere would react quickly to produce rinds of alteration materials coating the surface and obscure emissivity signatures of igneous minerals within a few to ~10,000 years [4-9]. These new experimentally derived weathering and oxidation rates were used to suggest that lava flows at Idunn Mons with unweathered signatures are quite young and Idunn Mons may be volcanically active today [4, 8]. Independent geologic mapping and related stratigraphic reconstruction over the study area is consistent with the experimental results [2, 10]. Considering all the available evidence, we have taken a comprehensive approach combining these recent experimental results with previous orbital night-time emissivity, as well as atmospheric measurements, to constrain the evolution of Idunn Mons [3,10]. Our results suggest that Idunn Mons is both volcanically and tectonically active today, and that volcanism and tectonic activity are likely related [11]. Venus being volcanically active has been suggested at other volcanic centers, as well [e.g. 12-17]. Therefore, we use Idunn Mons specifically as a case study of a potentially active volcano that may be detectable by the upcoming fleet of missions that will be arriving at Venus in the next decade.

Justin Filiberto↗
NASA NTRS2015

Insights into Regolith Evolution from TEM Studies of Space Weathering of Itokawa Particles

Exposure to solar wind irradiation and micrometeorite impacts alter the properties of regolith materials exposed on airless bodies. However, estimates of space weathering rates for asteroid regoliths span many orders of magnitude. Timescales for space weathering processes on airless bodies can be anchored by analyzing surface samples returned by JAXA's Hayabusa mission to asteroid 25143 Itokawa. Constraints on timescales of solar flare particle track accumulation and formation of solar wind produced ion-damaged rims yield information on regolith dynamics.

Berger, Eve L.↗
NASA NTRS2013

Olivine Weathering aud Sulfate Formation Under Cryogenic Conditions

High resolution photography and spectroscopy of the martian surface (MOC, HiRISE) from orbit has revolutionized our view of Mars with one of the most important discoveries being wide‐spread layered sedimentary deposits associated with sulfate minerals across the low to mid latitude regions of Mars. The mechanism for sulfate formation on Mars has been frequently attributed to playa‐like evaporative environments under prolonged warm conditions. An alternate view of the ancient martian climate contends that prolonged warm temperatures were never present and that the atmosphere and climate has been similar to modern conditions throughout most of its history. This view has had a difficult time explaining the sedimentary history of Mars and in particular the presence of sulfate minerals which seemingly need more water. We suggest here that mixtures of atmospheric aerosols, ice, and dust have the potential for creating small films of cryo‐concentrated acidic solutions that may represent an important unexamined environment for understanding weathering processes on Mars. This study seeks to test whether sulfate formation may be possible at temperatures well below 0degC in water limited environments removing the need for prolonged warm periods to form sulfates on early Mars. To test this idea we performed laboratory experiments to simulate weathering of mafic minerals under Mars‐like conditions. The weathering rates measured in this study suggest that fine grained olivine on Mars would weather into sulfate minerals in short time periods if they are exposed to H2SO4 aerosols at temperatures at or above ‐40degC. In this system, the strength of the acidic solution is maximized through eutectic freezing in an environment where the silicate minerals are extremely fine grained and have high surface areas. This provides an ideal environment despite the very low temperatures. On Mars the presence of large deposits of mixed ice and dust is undisputed. The presence of substantial sulfur‐rich volcanism, and sulfur‐rich surface deposits also makes it very likely that sulfate aerosols have also been an important component of the martian atmosphere. Thus mixtures of ice, dust, and sulfate aerosols are likely to have been common on the martian surface. Given the fact that it is not difficult to achieve surface temperatures above ‐40degC on Mars throughout its history, it seems likely that sulfate formation on Mars is controlled by the availability of sulfate aerosols and not by the martian climate. The current polar regions of Mars and Earth provide interesting analogs. Large regions of sulfaterich material have been detected on and around the modern north polar region of Mars. The prevalence of ice‐dust mixtures in this region and the existence of sulfates within the ice cap itself are strong evidence for the origin of the sulfates from inside the ice deposits. In addition sulfates have been found in ice deposits in Greenland and Mount Fuji on Earth that have been attributed to forming within the ice deposit. These sulfates can form either through interaction with dust particles in the atmosphere or through weathering inside the ice itself.

Niles, Paul B.↗
NASA NTRS2023

Solar-Energetic-Particle Track-Production Rates at 1 au: Comparing In-Situ Particle Fluxes with Lunar Sample-Derived Track Densities

Heavy ( Z > 26) solar energetic particles (SEPs) with energies ~1 MeV/nucleon are known to leave visible damage tracks in meteoritic materials. The density of such `solar flare tracks' in lunar and asteroidal samples has been used as a measure of a sample's exposure time to space, yielding critical information on planetary space weathering rates, the dynamics and lifetimes of interplanetary dust grains, and the long-term history of solar particle fluxes. Knowledge of the SEP track accumulation rate in planetary materials at 1 au is critical for properly interpreting observed track densities. Here, we use in-situ particle observations of the 0.50-3.0 MeV/nuc Fe-group SEP ux taken by NASA's Advanced Composition Explorer (ACE) to calculate a flux of track-inducing particles at 1 au of 6.0 × 10 5 cm -2 yr -1 str -1 . Using the observed energy spectrum of Fe-group SEPs, we find that the depth distribution of SEP-induced damage tracks inferred from ACE measurements matches closely to that recently measured in lunar sample 64455; however, the magnitude of the ACE-inferred rate is approximately 25× higher than that observed in the lunar sample. We discuss several hypotheses for the nature of this discrepancy, including inefficiencies in track formation, thermal annealing of lunar samples, erosion via space weathering processing, and variations in the SEP flux at the Moon, yet find no satisfactory explanation. We encourage further research on both the nature of SEP track formation in meteoritic materials and the flux of Fe-group SEPs at the lunar surface in recent and geologic times to resolve this discrepancy.

Interplanetary dust↗
NASA NTRS1993

Carbon-14 terrestrial ages and weathering of 27 meteorites from the southern high plains and adjacent areas (USA)

We report on a series of 27 C-14 terrestrial ages of meteorites from four states in the central and southwestern U.S. These results were compared to the earlier work of Boeckl (1972). Our results showed that the weathering rate for destruction of meteorites is lower than suggested by Boeckl. We estimate a 'half-life' for removal of meteorites of about 10 to 15 ka, similar to that derived for Roosevelt County meteorites. We also studied the weathering of these meteorites compared to terrestrial age. Only a weak correlation was observed, and for these meteorites the degree of weathering can only be taken as a weak indicator of terrestrial residence time. We also measured the delta-C-13 and C-14 and amount of weathering-product carbonates which show some interesting variations with the length of time the meteorites have been exposed to weathering.

Jull, A. J. T.↗
NASA NTRS2024

Solar-Energetic-Particle Track-Production Rates in Interplanetary Dust Grains at 1 AU

Heavy ( Z >26) solar energetic particles (SEPs) with energies ~1 MeV/nucleon are known to leave visible damage tracks in meteoritic materials. The density of such ‘solar flare tracks’ in lunar and asteroidal samples has been used as a measure of a sample's exposure time to space, yielding critical information on planetary space weathering rates [e.g., 1] and the dynamics and lifetimes of interplanetary dust grains [e.g., 2, 3]. Knowledge of the SEP track accumulation rate in planetary materials at 1 au is critical for properly interpreting observed track densities. Here, we report comparisons of the SEP track-accumulation rate at 1 au from two separate sources: (i) laboratory analysis of returned Apollo sample 64455 and (ii) in-situ measurements of the Z >26, ~1 MeV/nuc SEP flux at the L1 Lagrange point by the Advanced Composition Explorer (ACE) spacecraft. Full details are available in Poppe et al. (2023).

A R Poppe↗
NASA NTRS1984

Dual-Rate Transmission Reduces Weather Effects

Scheme ensures maximum data received on average. Dual-rate scheme for maximizing data returned during spacecraft mission, adaptable, as is or with modifications, to high-frequency terrestrial data transmission. Data rate fixed in advance at minimum value guarantees reasonable prospect of success during bad weather. Dualrate strategy yields net data rate 2.5 times best achievable with single transmission rate.

Posner, E. C.↗
NASA NTRS1985

Planetary Analogs in Antarctica: Mars

A study of chemical and physical weathering rates in Antarctic ice-free areas, sponsored by the National Science Foundation's Antarctic Research Program, permitted observations to be made that also have application other planetary surfaces. Four observations relevent to Mars are addressed: the effects of freezing on sand dune morphology (Mars polar dune field), chemical/physical weathering to create pits (Mars pitted rocks, Viking Lander 1 and 2 sites), armored surfaces (Mars lander sites), and mass movements (movement of Martian debris).

Malin, M. C.↗
NASA NTRS1992

Preliminary results of polarization signatures for glacial moraines in the Mono Basin, Eastern Sierra Nevada

The valleys of the Mono Basin contain several sets of lateral and terminal moraines representing multiple stages of glaciation. The semi-arid climate with slow weathering rates preserved sequences of nested younger moraines within older ones. There is a well established relative chronology and recently exposure dating provided a new set of numerical dates. The moraines span the late Wisconsin (11-25 ka) to the Illinoian (130-190 ka) glaciations. The Mono Basin area was used as a 'calibration site' to establish remote dating techniques for eventual transfer to the more inaccessible but geomorphically and climatically similar moraines of the South American Andes Mountains. Planned polarimetric synthetic aperture radar (SAR) imagery acquired by JPL AIRSAR (South American Campaign) and SIR-C (Andes super-site) are analyzed to establish chronologies of previously undated moraine sequences in a study of Pleistocene climatic change in the Southern Hemisphere. The dry climate and sparse vegetation is also favorable for correlation of ground surface roughness with radar polarization signature. The slow weathering processes acting over thousands of years reduce the size, frequency, and angularity of surface boulders while increasing soil development on the moraines. Field observations based on this hypothesis result in relative ages consistent with those inferred from nested position within the valley. Younger moraines, therefore, will appear rougher than the older smoother moraines at scales measurable at AIRSAR wavelengths. Previously documented effects of ground surface roughness on polarization signatures suggest that analysis of moraine polarization signatures can be useful for relative dating. The technique may be extended to predict numerical ages. The data set reported were acquired on 8 Sep. 1989 with the JPL Airborne SAR (AIRSAR) collecting polarimetric imagery at C- (5.6 cm), L- (24 cm), and P-band (68 cm) with a flight-line parallel to the strike of the mountains. Phase calibration was performed on the analyzed scene by setting the co-phase of a smooth lake to zero as described. Absolute amplitude calibration was not possible because corner reflectors were not deployed.

Forster, Richard R.↗
NASA NTRS1988

Long-term climate change and the geochemical cycle of carbon

The response of the coupled climate-geochemical system to changes in paleography is examined in terms of the biogeochemical carbon cycle. The simple, zonally averaged energy balance climate model combined with a geochemical carbon cycle model, which was developed to study climate changes, is described. The effects of latitudinal distributions of the continents on the carbon cycle are investigated, and the global silicate weathering rate as a function of latitude is measured. It is observed that a concentration of land area at high altitudes results in a high CO2 partial pressure and a high global average temperature, and for land at low latitudes a cold globe and ice are detected. It is noted that the CO2 greenhouse feedback effect is potentially strong and has a stabilizing effect on the climate system.

Marshall, Hal G.↗
NASA NTRS1994

Workshop on Meteorites From Cold and Hot Deserts

The current workshop was organized to address the following points: (1) definition of differences between meteorites from Antarctica, hot deserts, and modern falls; (2) discussion of the causes of these differences; (3) implications of possible different parent populations, infall rates, weathering processes, etc.; (4) collection, curation, and distribution of meteorites; and (5) planning and coordination of future meteorite searches.

Schultz, Ludolf↗
NASA NTRS2012

Rates of Space Weathering in Lunar Regolith Grains

While the processes and products of lunar space weathering are reasonably well-studied, their accumulation rates in lunar soils are poorly constrained. Previously, we showed that the thickness of solar wind irradiated rims on soil grains is a smooth function of their solar flare particle track density, whereas the thickness of vapor-deposited rims was largely independent of track density [1]. Here, we have extended these preliminary results with data on additional grains from other mature soils.

Zhang, S.↗