Determination of weldability and elevated temperature stability of refractory metal alloys. 1 - Weldability of refractory metal alloys
Weldability and thermal stability of refractory metal alloys
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Weldability and thermal stability of refractory metal alloys
Effect of oxygen contamination on weldability of refractory metal alloys
Weldability of tungsten base alloys and elevated temperature stability
Three exceptionally high toughness Fe-12Ni alloys designed for cryogenic service were welded by using the gas tungsten arc welding process. Evaluation of their weldability included equivalent energy fracture toughness tests, transverse weld tensile tests at -196 and 25 C, and weld crack sensitivity tests. The Fe-12Ni-0.25Ti alloy proved extremely weldable for cryogenic applications, having weld and heat affected zone properties comparable to those of the wrought base alloy. The Fe-12Ni-0.5Al alloy had good weld properties only after the weld joint was heat treated. The Fe-12Ni-0.25Nb alloy was not considered weldable for cryogenic use because of its poor weld joint properties at -196 C and its susceptibility to hot cracking.
Three exceptionally high-toughness Fe-12%Ni alloys designed for cryogenic service were welded using the GTA welding process. Evaluation of weldability included equivalent energy (KIed) fracture toughness tests, transverse-weld tensile tests at -196 and 25 C and weld crack sensitivity tests. The Fe-12%Ni-0.25%Ti alloy proved extremely weldable for cryogenic applications, having weld and HAZ properties comparable with those of the wrought base alloy. The Fe-12%Ni-0.5%Al had good weld properties only after the weld joint was heat treated. The Fe-12%Ni-0.25%Nb alloy was not considered weldable for cryogenic use because of its poor weld joint properties at -196 C and its susceptibility to hot cracking.
This report describes the development of a user friendly weldable strain gage employing the NASA Lewis PdCr/Pt wire strain sensor. The NASA sensors are pre-attached to Hastelloy X or Titanium alloy shims using name spray techniques developed under previous NASA programs. The weldable sensors are then pre-stabilized for 50 hours at 780 C in air. A weldable terminal and high temperature cable is then connected to the sensor and the assembly is pre-calibrated over the full test temperature range. Calibrated resistors are inserted into a bridge completion module at the cool end of the cable to condition the sensor in half or full bridge configuration. The sensor is attached to the structure using a common capacitive discharge spot welder. No additional high temperature stabilization or calibration is required. The resultant device is a pre-calibrated strain transducer which can be plugged into any common variety strain instrumentation.
Service performance has shown that cryogenic treatment of some metals provides improved strength, fatigue life, and wear resistance to the processed material. Effects such as these were initially discovered by NASA engineers while evaluating spacecraft that had returned from the cold vacuum of space. Factors such as high cost, poor repairability, and poor machinability are currently prohibitive for wide range use of some aerospace aluminum alloys. Application of a cryogenic treatment process to these alloys is expected provide improvements in weldability and weld properties coupled with a reduction in repairs resulting in a significant reduction in the cost to manufacture and life cycle cost of aerospace hardware. The primary purpose of this effort was to evaluate the effects of deep cryogenic treatment of some aluminum alloy plate products, welds, and weld repairs, and optimize a process for the treatment of these materials. The optimized process is being evaluated for improvements in properties of plate and welds, improvements in weldability and repairability of treated materials, and as an alternative technique for the reduction of residual stresses in repaired welds. This paper will present the results of testing and evaluation conducted in this effort. These results will include assessments of changes in strength, toughness, stress corrosion susceptability, weldability, repairability, and reduction in residual stresses of repaired welds.
The effects are assessed of TiB2 reinforcement and parent alloy Li content on the weldability of Weldalite (tm) 049 type alloys. Welding trials were performed using either AC or DC polarity gas tungsten arc (GTA) welding according to described procedures. The welding was performed under conditions of high restraint on 5 cm (2 in) wide x 25.4 cm (10 in) long plates machined from the 0.952 cm (0.375 in) extruded bar parallel to the extrusion direction. A 37.5 deg bevel was machined on the center edge of the extruded bar. Cut rod filler wire was machined from three alloys, and one commercially available 2319 filler wire was also used. The preliminary assessment of the weldability revealed no propensity for hot cracking under conditions of high restraint. This result is significant, because hot cracking has been reported for all other leading aluminum lithium alloys welded with certain conventional filler alloys. The strengths for Weldalite parent welded with parent filler obtained were higher than those for alloys used in launch systems, such as 2219 and 2014 welded with 2319 and 4043 fillers, respectively. Even higher values were obtained by variable polarity plasma arc welding (e.g., 54 ksi (372 MPa) mean tensile strength).
Technology innovations directed at the advanced development of a potentially low cost and weldable graphite/magnesium metal matrix composites (MMC) through near net shape pressure casting are described. These MMC components uniquely have built-in metallic inserts to provide an innovative approach for joining or connecting other MMC components through conventional joining techniques such as welding, brazing, mechanical fasteners, etc. Moreover, the metallic inserts trapped within the MMC components can be made to transfer the imposed load efficiently to the continuous graphite fiber reinforcement thus producing stronger, stiffer, and more reliable MMC components. The use of low pressure near net shape casting is economical compared to other MMC fabrication processes. These castable and potentially weldable MMC components can provide great payoffs in terms of high strength, high stiffness, low thermal expansion, lightweight, and easily joinable MMC components for several future NASA space structural, industrial, and commercial applications.
The electron beam welding process is used to investigate the weldability of the Ni-based superalloy Udimet 720LI. This is a modified form of the alloy Udimet 720, which has reduced concentrations of interstitial elements such as boron, silicon, and carbon. The history of high strength superalloys like this one suggests that welding will be difficult because of their tendency towards hot cracking during the welding process, or strain-age cracking during the post-weld aging process. Studies were done on several sizes of weldability test specimens to determine if Udimet 720LI will exhibit cracking tendencies. It was found that the alloy was not susceptible to hot cracking unless it had received the four-step aging heat treatment that is recommended by the manufacturer. It was also found that a restrained weldment is susceptible to strain-age cracking; however, if the weldment is allowed to deform then warpage can occur instead of cracking.
Weldability and elevated temperature stability of refractory metal alloys
Refractory metal alloys rating on basis of weldability emphasizing metallurgical considerations, taking into account process control and welding as thermal process
In this study the NASA MSFC welding and manufacturing team investigated a new-age aluminum filler wire designed for welding and additive manufacturing (AM) of high strength aluminum alloys. High strength aluminum alloys are known to exhibit hot cracking and hot tearing issues during fusion welding operations. The goal of this investigation was to determine whether this new-age family of alloys can suppress the hot cracking and hot tearing issues exhibited during welding of high strength aluminum alloys and to do an initial characterization of the mechanical performance of welds created using these filler wires. This study focuses on fusion welding of aluminum alloy 6061 and compares the weldability characteristics of five aluminum filler metals and two forms of 6061 base material. The MSFC team utilized manual gas tungsten arc welding (GTAW) to conduct all welding operations and carried out metallographic analysis accompanied with mechanical testing to evaluate the performance of the welds created during this study. During the study it was observed that the new-age filler wires facilitated grain refinement in the weld fusion zone and were capable of creating crack free welds in aluminum alloy 6061 while exhibiting properties that met or exceeded conventional off the shelf aluminum filler metals.
Cast Monel alloys are used in many industrial applications that require a combination of good mechanical properties and excellent resistance to corrosion. Despite relative widespread use, there has been limited prior research investigating the fundamental composition–structure–property relationships. Here in this work, microstructural characterization, thermal analysis, electron probe microanalysis, tensile testing, and Varestraint testing were used to assess the effects of variations in nominal composition on the solidification path, microstructure, mechanical properties, and solidification cracking susceptibility of cast Monel alloys. It was found that Si segregation caused the formation of silicides at the end of solidification in grades containing at least 3 wt pct Si. While increases to Si content led to significant improvements in strengthening due to the precipitation of β 1 -Ni 3 Si, the silicide eutectics acted as crack nucleation sites during tensile loading which severely reduced ductility. The solidification cracking susceptibility of low-Si Monel alloys was found to be relatively low. However, increases to Si concentration and the onset of associated eutectic reactions increased the solidification temperature range and drastically reduced cracking resistance. Increases in the Cu and Mn concentrations were found to reduce the solubility limit of Si in austenite which promoted additional eutectic formation and exacerbated the reductions in ductility and/or weldability.
In this work, the weldability of the neutron-irradiated Stainless Steel 304 (SS 304) materials containing estimated helium levels of 12 to 44 appm has been studied through a Collaborative Research and Development Agreement between the Canadian Nuclear Laboratories and Oak Ridge National Laboratory. The work utilizes a SS 304 component harvested from the National Research Universal reactor. Laser beam welding was used to explore suitable welding conditions and associated parameters, to determine helium concentration limits for successful welding of irradiated stainless-steels. The experimental results show that maximum fusion zone void sizes, fusion zone void quantity and total heat affected zone helium-induced crack length generally increased with increasing He levels and effective weld heat input. A proper combination of welding parameters with low effective heat input, such as, laser power, weld travel speed and wire feed speed, were shown to improve the welding quality, and potentially reduce the length and probability of the formation of grain boundary helium-induced cracking and voids of irradiated SS 304 even with He concentrations as high as about 44 appm.
Large-batch numerical, CALculation of PHAse Diagrams (CALPHAD)-based solidification cracking calculations are performed and then analyzed with machine learning methods to generate models that relate chemistry of refractory alloys to cracking susceptibility. Kou’s solidification cracking index is used to study the refractory alloys including O, N, C binary mixtures with Mo, Ta, Nb, and W, the molybdenum-based TZM, Niobium-based C103, and Tantalum-based T111 and Ta-10 W, as well as hypothetical refractory ternary alloys. Findings strongly validate Kou’s Crack Susceptibility Index (CSI) against Varestraint test data for Nb- and Ta-based alloys, establishing CSI thresholds where refractory alloys with CSI < 15,000 K are likely weldable, CSI > 15,000 K are prone to cracking, and CSI > 25,000 K are likely unweldable (or unprintable). Furthermore, interstitial elements C, N, and O significantly increase crack susceptibility, with some existing material specifications coinciding with peak cracking susceptibility concentrations. Finally, machine learning-derived elemental potency factors enable rapid prediction of CSI from alloy chemistry for C103, TZM, Ta-10 W, and T-111 alloys. These results provide practical guidance for feedstock selection, powder reuse limits, and alloy specification amendments for welding and additive manufacturing applications.
A collaborative research on developing advanced welding technologies for irradiated stainless steel 304 materials between CNL and ORNL has been established to support both U.S. and Canadian interests in evaluation of weld repair techniques on irradiated materials to support continuous operation of commercial nuclear power. The work utilizes unique material from the National Research Universal (NRU) reactor and the specialized welding hot cell facility at ORNL. The objective is to explore suitable welding technique and parameters and to determine the helium concentration limitation in terms of irradiated stainless-steel weldability. An additional objective is to develop the knowledge and understanding of cracking mechanisms induced by high concentration of helium in the process of weld repair of the irradiated structural alloys. This report summarizes the experimental welding evaluation on irradiated material from the NRU reactor containing helium concentrations ranging from 12 to 45 atomic parts per million (appm).
PURPOSE What? • Determine the weldability of additively manufactured (AM) 304L Stainless Steel ( • Why? • Use AM to make gas containing vessels that will be seal welded • How? • Prepare • Weld • Compare mock tubes to SS tubing