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At least 19 records

MRCI Subtask 2.1: Defining Sub-Regional Carbon Storage Systems Final Technical Summary Report

In order to assess the regional and subregional geologic framework of the MRCI area and expand carbon dioxide (CO2) storage characterization efforts in this larger region, the current state of geologic knowledge relative to carbon storage (CS) has been summarized by compiling available geologic data and interpretive results into a centralized resource under Subtask 2.1. The MRCI region is a large area, which includes (1) part of the Forest City Basin and Western Arches, (2) Illinois Basin, (3) Upper Mississippi Embayment, (4) Michigan Basin, (5) Central Arches, (6) Appalachian Basin, and (7) Atlantic Coastal Plain and West Atlantic basins. Basins and arches are subdivided into areas of similar geology based on geologic structures and state-specific stratigraphic nomenclature. A concerted effort was made to present the current understanding of rock-unit stratigraphy in the subsurface of each basin and arch region (and subdivisions therein). Rock units are characterized based on their relative CS potential (saline reservoirs, confining intervals, etc.) within CS systems. CS systems are defined by regional confining units (usually thick, widespread shales), and contain all reservoirs and strata between the regional confining units. Report Authors – Steve Greb and Tom Sparks (Kentucky Geological Survey), Mark Kelley, Sanjay Mawalkar, John Hershberger, Priya Ravi Ganesh, Derrick James, and Stuart Skopec (Battelle), Charles Bopp, Yaghoob Lasemi and Hannes Leetaru (deceased) (Illinois State Geological Survey), Kristin Carter (Pennsylvania Geological Survey), William Harrison (Michigan Geological Repository for Research and Education – Michigan Geological Survey), Susan Pool (West Virginia Geological and Economic Survey), James McDonald (Ohio Geological Survey), John Schmelz (Rutgers University), Ryan Clark (Iowa Geological Survey). Other Technical Contributors – Seth Carpenter and John Hickman (Kentucky Geological Survey), Jessica Moore, Eric Lewis, Philip Dinterman, Timothy Vance, and Gary Daft (West Virginia Geological and Economic Survey), Michele Cooney, Robin Anthony, Cheyenne Woodward, and Katherine Schmid (Pennsylvania Geological Survey), Autumn Haagsma and Amber Conner (Michigan Geological Repository for Research and Education – Michigan Geological Survey), Kenneth Miller (Rutgers University), Ashley Douds and Valerie Beckham-Feller (Indiana Geological & Water Survey), Michael Solis (Ohio Geological Survey).

Appalachian,Arches,Forest City,Illinois,MRCI,Michi↗

Regional tropical rainfall shifts under global warming: an energetic perspective

Abstract Future climate simulations feature pronounced spatial shifts in the structure of tropical rainfall. We apply a novel atmospheric energy flux analysis to diagnose late 21st century tropical rainfall shifts in a large ensemble of simulations of 21st century climate. The method reconstructs 2D spatial changes in rainfall based on horizontal shifts in the lines of zero meridional and zonal divergent energy flux, called the energy flux equator (EFE) and energy flux prime meridian (EFPM), respectively. Two main sources of future atmospheric energy flux changes, and hence rainfall shifts, are identified by the analysis: the high-latitude North Atlantic due to a weakened Atlantic Meridional Overturning Circulation that shifts tropical rainfall southwards over the greater Tropical Atlantic sector and eastern Pacific; and the eastern tropical Pacific due to a permanent El-Niño-like response that produces zonal shifts over the Maritime Continent and South America. To first order, the shifts in the EFE and EFPM mirror gross distributional changes in tropical precipitation, with a southward shift in rainfall over the tropical Atlantic, West Africa, and eastern tropical Pacific and an eastward shift over the Maritime Continent and western Pacific. When used to reconstruct future rainfall shifts in the tropical Atlantic and Sahel, the method reasonably represents the simulated meridional structure of rainfall shifts but does not do so for the zonal structures.

54 ENVIRONMENTAL SCIENCES↗

Subseasonal Variability of Elevated Dust Concentrations Over South Florida

Dust mass concentrations have been measured daily at Miami, Florida, in the summer months, and biweekly throughout the remaining months, since 1974. The 43-year record of dust mass concentrations indicate large daily, seasonal, and interannual variations, with most of the dust arriving within 5–8 episodes each summer. On average, dust arrives to Miami, Florida, 10 days after emission from North Africa, with measured concentrations depending on characteristics of the lower free-tropospheric winds due to the vast travel distance. Daily dust mass concentrations from July and August, the months that contribute the most to the annual mean, are used to characterize the synoptic conditions most favorable for dust transport. Two key regions are linked with the highest daily dust mass concentrations above Miami: (i) easterly winds, averaged over 850–500 mb, over the Tropical West Atlantic [15–25°N, 45–80°W], and (ii) southerly winds, similarly averaged, over the Florida Peninsula [20–30°N,75–80°W]. Winds within these two regions are enhanced when the North Atlantic subtropical high is displaced south and zonally elongated, relocating the western edge over Florida. A dust-transport-efficiency index, based on the maximum potential for dust to arrive above Miami with limited loss to deposition or mixing, identifies high-dust loading cases on the subseasonal scale. Monthly dust-transport-efficiency values agree well with the monthly dust trends over the 43-year time span. While seasonal dust loadings have been decreasing over Florida in the past decade, the transport efficiency has been increasing, possibly due to trends in the North Atlantic subtropical high.

54 ENVIRONMENTAL SCIENCES↗

Nanoscale trace-element zoning in pyrite framboids and implications for paleoproxy applications

Pyrite framboids (spherical masses of nanoscale pyrite) are among the earliest textures of pyrite to form in sediments. It has been proposed that their trace-element (TE) contents can be used to track the TE composition of the water column in which they formed. However, it is not clear how these TEs are associated with the framboidal pyrite grains. For instance, it is important to know whether they are incorporated uniformly or are enriched in different regions of the framboid. Here, we used high-resolution scanning transmission electron microscopy to identify chemical zoning within pyrite framboids. We found that initial, nanoscale pyrite euhedral crystals, which make up the volumetric majority of the framboids, are covered/infilled by later pyrite that templates on the earlier pyrite. Further, this later pyrite is enriched in TEs, suggesting that many TEs are incorporated in pyrite relatively late (during early diagenesis; not in the water column). This observation suggests that although chemical analyses of pyrite framboids may provide ocean-water chemistry trends through time, the details are complex. Specifically, the TEs found in pyrite may be linked to adsorption onto organic matter, detrital material, and authigenic minerals such as Fe- and Mn-oxide phases followed by desorption in the sediments or release via dissolution and incorporation into pyrite as overgrowths on the initial nanoscale euhedral crystals that make up framboids. While the use of pyrite chemistry to understand past ocean conditions remains promising, and even diagenetic additions may not preclude the utility of pyrite for reconstructing ancient ocean conditions, care must be taken in interpretations because the end concentration may be influenced by diagenesis.

58 GEOSCIENCES↗

High Resolution Ocean Surface Wave Hindcast (US Wave) Data

The development of this dataset was funded by the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, Water Power Technologies Office to improve our understanding of the U.S. wave energy resource and to provide critical information for wave energy project development and wave energy converter design. This high resolution publicly available long-term wave hindcast dataset will - when complete - cover the entire U.S. Exclusive Economic Zone (EEZ). Available data includes the Hawaiian Islands, West and Atlantic Coasts, with future additions including the Alaskan coasts, Gulf of Mexico and the Freely associated States. The data can be used to investigate the historical record of wave statistics at any U.S. site. As such, the dataset could also be of value to any entity with marine operations inside the U.S. EEZ. These data are available for download without login credentials through the free and publicly accessible Open Energy Data Initiative (OEDI) data viewer which allows users to browse and download individual or groups of files.

16 TIDAL AND WAVE POWER↗

Episodes of Early Pleistocene West Antarctic Ice Sheet Retreat Recorded by Iceberg Alley Sediments

Abstract Ice loss in the Southern Hemisphere has been greatest over the past 30 years in West Antarctica. The high sensitivity of this region to climate change has motivated geologists to examine marine sedimentary records for evidence of past episodes of West Antarctic Ice Sheet (WAIS) instability. Sediments accumulating in the Scotia Sea are useful to examine for this purpose because they receive iceberg‐rafted debris (IBRD) sourced from the Pacific‐ and Atlantic‐facing sectors of West Antarctica. Here we report on the sedimentology and provenance of the oldest of three cm‐scale coarse‐grained layers recovered from this sea at International Ocean Discovery Program Site U1538. These layers are preserved in opal‐rich sediments deposited ∼1.2 Ma during a relatively warm regional climate. Our microCT‐based analysis of the layer's in‐situ fabric confirms its ice‐rafted origin. We further infer that it is the product of an intense but short‐lived episode of IBRD deposition. Based on the petrography of its sand fraction and the Phanerozoic 40 Ar/ 39 Ar ages of hornblende and mica it contains, we conclude that the IBRD it contains was likely sourced from the Weddell Sea and/or Amundsen Sea embayment(s) of West Antarctica. We attribute the high concentrations of IBRD in these layers to “dirty” icebergs calved from the WAIS following its retreat inland from its modern grounding line. These layers also sit at the top of a ∼366‐m thick Pliocene and early Pleistocene sequence that is much more dropstone‐rich than its overlying sediments. We speculate this fact may reflect that WAIS mass‐balance was highly dynamic during the ∼41‐kyr (inter)glacial world.

Bailey, Ian↗

Three new symbiotic crabs of the genus Glassella Campos & Wicksten, 1997 from Atlantic and Gulf of Mexico coasts of Florida, USA (Decapoda: Brachyura: Pinnotheridae)

Abstract New species of the pinnotherid crab genus GlassellaCampos & Wicksten, 1997 are described from western Atlantic waters along the east and west coasts of Florida, with the generic assignment of one being provisional. Glassella chaneyin. sp., Glassella martinin. sp., and Glassella taylorin. sp., all morphologically resemble the long-known species G. floridana (Rathbun, 1918) and overlap part of its distributional range, there occupying similar habitats and at least sometimes found with similar hosts. While genomic DNA sequencing has previously established the generic assignment of G. floridana, small sizes and suboptimal preservation histories of specimens representing the three new species have rendered all sequencing attempts unsuccessful, and thus not allowed their inclusion in molecular phylogenetic analyses. To facilitate present morphological comparisons, a rediagnosis of G. floridana was undertaken, and previously published illustrations were augmented, the latter now including figures of its previously undescribed male first gonopod and gonopodal plate. Comparisons of G. floridana to the three new species reveal striking diagnostic differences between all four species in their male first gonopods and varied configurations in the gonopodal plate or its probable homologs. These characters support the otherwise established separation of G. floridana from its congeners on the basis of its more strongly armed flexor margins of the fourth and fifth pereopods. In G. taylorin. sp., representing the smallest known member of Glassella, development of the third maxilliped and male first gonopod is so exceptional as to suggest the species may warrant eventual assignment to a separate genus.

Marine & Freshwater Biology↗

Crustal and uppermost mantle structure of Cape Verde from ambient noise tomography

SUMMARY We present a seismic ambient noise tomography of the Cape Verde archipelago, located in the Atlantic Ocean, approximately 600 km west of Senegal. We used 38 seismic broad-band stations that continuously recorded for 10 months, in order to construct the first 3-D model of Sv-wave velocities for the crust and uppermost mantle beneath the Cape Verde region. We started by computing phase cross-correlations for vertical component recordings using all possible inter-island station pairs. Next, a time–frequency phase-weighted stack was applied to obtain robust Rayleigh-wave group-velocity dispersion curves in the period band between 10 and 24 s. Group-velocity maps at different periods are obtained by inverting the dispersion curves. We then inverted the group-velocity maps to obtain the 3-D shear wave velocity structure of the crust and uppermost mantle beneath Cape Verde. The final 3-D model extends from 8 km down to 23 km and has a lateral resolution of about 50 km. The crust in the southwestern sector, encompassing Fogo, presents lower S-wave velocities that may be caused by the presence of melt pockets and/or hydrothermal fluids circulation. The uppermost mantle beneath the northwestern sector is characterized by higher S-wave velocities in agreement with previous results obtained from Ps and Sp receiver functions. Those high-velocity anomalies can reflect non-altered crust or remnants of magma chambers or solidified basaltic intrusions, which fed the volcanism in these islands. Our maps revealed the presence of crustal underplating across the entire archipelago, yet stronger beneath the groups Santo Antão—São Vicente—São Nicolau and Fogo—Santiago—Maio.

Carvalho, J. (ORCID:0000000310778994)↗

Atmospheric Radiation Measurement (ARM) airborne field campaign data products between 2013 and 2018

Airborne measurements are pivotal for providing detailed, spatiotemporally resolved information about atmospheric parameters and aerosol and cloud properties, thereby enhancing our understanding of dynamic atmospheric processes. For 30 years, the US Department of Energy (DOE) Office of Science supported an instrumented Gulfstream 1 (G-1) aircraft for atmospheric field campaigns. Data from the final decade of G-1 operations were archived by the Atmospheric Radiation Measurement (ARM) Data Center and made publicly available at no cost to all registered users. To ensure a consistent data format and to improve the accessibility of the ARM airborne data, an integrated dataset was recently developed covering the final 6 years of G-1 operations (2013 to 2018, https://doi.org/10.5439/1999133; Mei and Gaustad, 2024). The integrated dataset includes data collected from 236 flights (766.4 h), which covered the Arctic, the US Southern Great Plains (SGP), the US West Coast, the eastern North Atlantic (ENA), the Amazon Basin in Brazil, and the Sierras de Córdoba range in Argentina. These comprehensive data streams provide much-needed insight into spatiotemporal variability in the thermodynamic quantities and aerosol and cloud properties for addressing essential science questions in Earth system process studies. This paper describes the DOE ARM merged G-1 datasets, including information on the acquisition, data collection challenges and future potentials, and quality control processes. It further illustrates the usage of this merged dataset to evaluate the Energy Exascale Earth System Model (E3SM) with the Earth System Model Aerosol–Cloud Diagnostics (ESMAC Diags) package.

54 ENVIRONMENTAL SCIENCES↗

New species and records of the symbiotic shrimp genus Leptalpheus Williams, 1965, with notes on Fenneralpheus Felder & Manning, 1986, and preliminary molecular analysis of phylogenetic relationships (Crustacea: Decapoda: Alpheidae)

The shrimp genera Leptalpheus Williams, 1965 and Fenneralpheus Felder & Manning, 1986 are composed entirely of symbiotic species that co-inhabit burrows of infaunal macrocrustaceans. We report extensive collections of these genera from western Atlantic, eastern Pacific and Indo-West Pacific regions. Integrative taxonomy methods, including morphological comparisons and analysis of three mitochondrial genetic markers, are used to test species hypotheses and evolutionary relationships among members of these genera. Our molecular analysis failed to recover Leptalpheus or Fenneralpheus as monophyletic groups. Our results strongly supported the monophyly of three clades composed of species of Leptalpheus, loosely corresponding to previously proposed species groups. Three new species closely related to Leptalpheus forceps Williams, 1965, L. marginalis Anker, 2011, and L. mexicanus Ríos & Carvacho, 1983 are described. Leptalpheus ankeri n. sp., from the Caribbean Sea, Atlantic coast of Florida, and Gulf of Mexico, is a polymorphic species that exhibits two major cheliped morphotypes. Leptalpheus sibo n. sp., from the Pacific coast of Nicaragua, is morphologically very similar to L. ankeri n. sp., likely its transisthmian sister species, and shares its cheliped polymorphism. A reassessment of L. forceps concluded that records of this species from the Caribbean Sea and Brazil are not conspecific with L. forceps sensu stricto from the Atlantic coast of the USA and the Gulf of Mexico, and they are herein described as Leptalpheus degravei n. sp. Based on both molecular and morphological evidence, we found Leptalpheus bicristatus Anker, 2011 to be a junior synonym of L. mexicanus and Leptalpheus canterakintzi Anker & Lazarus, 2015 to be a junior synonym of Leptalpheus azuero Anker, 2011. First reports of Leptalpheus axianassae Dworschak & Coelho, 1999 in Texas and Mexico, Leptalpheus denticulatus Anker & Marin, 2009 in the Mariana Islands, Leptalpheus felderi Anker, Vera Caripe & Lira, 2006 and Leptalpheus lirai Vera Caripe, Pereda & Anker, 2021 in the USA, and Leptalpheus pereirai Anker & Vera Caripe, 2016 in Cuba are included.

Zoology↗

Assessing the link between aerosol mixing state, structure and composition and their optical properties: Ascension Island as a testbed for the South‐East Atlantic aerosol regimes

Forest and savanna fires are a major source of pollution over the globe. Such fire events emit to the atmosphere a considerable amount of “fluffy” fractal black looking particles that are often referred to as black carbon (BC) or soot aerosols. In fact, BC particles (aerosols) emitted from savanna and agricultural fires over the African continent play an important role in the region’s and the global climate. These fires occur each year between July and October, which is referred to as the biomass burning (BB) season and are considered among the globe's largest man-made emission sources of BC particles. However, during these fire events, not only BC particles are emitted, but also other types of particles and gases that can interact with each other to create new particles, generating a slew of particles often generally referred to as BB aerosols. Although the majority of the fire emissions occur inland in the sub-Saharan part of Africa, their effect reaches far beyond the continent due to the prevailing easterly winds, which transport those aerosols over the South-East Atlantic (SEA) ocean, off the west-coast of Africa. The reason why these particles are so important to the regional and global climate is that they absorb sunlight radiation, which overall warms the climate. However, the magnitude of this warming effect is highly uncertain and depends upon a multitude of aspects. Our overarching goal for this project was to better understand the changes in the aerosol properties as they transport from fire sources downstream toward the ocean and how this can eventually affect the earth's radiative budget in terms of warming or cooling. Following the above, our work here was focused on the investigation of the African BB aerosol plumes mixing state (mixing of BB aerosols and other aerosol types), composition and size distribution as they transport from the African continent towards the SEA ocean, and their link with some of the commonly measurable bulk optical properties such as mass absorption coefficient (MAC) and single scattering albedo (SSA). We utilized three field missions that were conducted over the SEA ocean between 2016 and 2018. Specifically, we used (1) ground-based measurements from the DOE ARM Mobile Facility (AMF1), which was deployed at Ascension Island (ASI) for the LASIC (Layered Atlantic Smoke Interactions with Clouds) campaign between June 2016 and October 2017, (2) airborne measurements from the UK CLARIFY (Clouds and Aerosol Radiative impacts and Forcing) campaign during Aug-Sep-2017, and (3) airborne measurements from the ORACLES (Observations of Aerosols above Clouds and their interactions) campaign during Aug-2017, and Sep-Oct-2018. The three campaigns cover a relatively large region, from the western African coast on the east towards Ascension Island in the middle of the SEA to the west. We used the data gathered by these campaigns to find how BB properties and composition change from near emission sources (the ORACLES campaign flights) downstream (the CLARIFY flights and the ground based LASIC measurements). We used particle trajectory following methodologies to connect the measurements from the different campaigns, which allowed us to follow a certain aerosol plume (airmass) from near-source towards Ascension Island. We found out that atmospheric aging processes governed by the UV light from the sun (photochemistry) and cloud processes (aqueous chemistry) govern the changes seen in the particle composition during the transport were more dominant in dictating aerosol composition than specific emission composition or source types. We assessed how aerosol optical properties change during the BB season and what are the main drivers of this change. We found that the enhanced ratio of BC to CO is well correlated with single scattering albedo (SSA) and mass absorption coefficient (MACBC), providing a simple way to estimate the aerosol optical characteristics in the south-eastern Atlantic Ocean. From the analysis of the location of BB, the primary source fuel, the water content in the fuel, combined with the mean cloud cover and precipitation in the transport areas of the BB plume, we conclude that the increase in BC/CO from June to August is likely to be caused by burning becoming more flaming (hot fires), and the decrease in BC/CO in September and October may be caused by smoldering (colder) fires. We found that aerosol hygroscopicity increases with decreasing altitude below 2km, and that enhanced BB hygroscopicity at lower altitudes is mainly due to a lower organic aerosol (OA) fraction, increased sulfate fraction, and greater hygroscopicity parameter of OA at lower altitudes.

54 ENVIRONMENTAL SCIENCES↗

Air pollution control strategies directly limiting national health damages in the US

Exposure to fine particulate matter (PM 2.5 ) from fuel combustion significantly contributes to global and US mortality. Traditional air pollution control strategies typically focus on emission reductions for specific air pollutants or sectors to maintain air pollutant concentrations within acceptable levels. Here we directly set national PM 2.5 mortality cost reduction targets within a global human-earth system model with US state-level energy systems, identifying endogenously the control actions, sectors, and locations that most cost-effectively reduce PM 2.5 mortality. Our results show that substantial health benefits can be cost-effectively achieved by using electricity to replace sources with high primary PM 2.5 emission intensities, including industrial coal, building biomass, and industrial liquids. Increasing the stringency of PM 2.5 reduction targets expedites the phaseout of high emission intensity sources, leading to larger declines in major air pollutant emissions, but very limited co-benefits in reducing CO 2 emissions. Control strategies achieve the greatest mortality cost reductions in the East North Central and Middle Atlantic states.

54 ENVIRONMENTAL SCIENCES↗

Gulf of Mexico Offshore Wind Transmission - Literature Review and Gaps Analysis: Environmental Considerations, Community Readiness, and Infrastructure

The ability to effectively and efficiently connect offshore wind energy resources to end users in the Gulf of Mexico, requires coordinated transmission planning to ensure that electric transmission facilities can adequately support future offshore development. The Gulf of Mexico has substantial wind resources in both shallow shelf waters and deeper waters off the shelf where fixed bottom and floating wind technologies would be most appropriate. Most interest in offshore wind development to date has been in the central and western portions of the Gulf of Mexico (Louisiana and Texas) in federal and state waters. As a companion study to other federal activities in the offshore wind transmission space, including the Atlantic Offshore Wind Transmission Literature Review and Gaps Analysis, the Atlantic Offshore Wind Transmission Study, the West Coast Offshore Wind Transmission Literature Review and Gaps Analysis, the West Coast Offshore Wind Transmission Study, and the Advancing Offshore Wind Energy in the United States: U. S. Department of Energy Strategic Contributions Toward 30 Gigawatts and Beyond Report, this literature review and gaps analysis for offshore wind transmission in the Gulf of Mexico builds off previous literature reviews and supports the role of federal leadership to facilitate offshore wind energy. The overarching goal of this document is to identify gaps and lay the groundwork to inform coordinated transmission planning, ocean co-use, existing energy infrastructure, and siting associated with offshore wind energy development in the Gulf of Mexico. There are unique regional considerations for offshore wind transmission, which are summarized herein based on a review and assessment of publicly available information.

08 HYDROGEN↗

Optimizing DOE Opportunities to Research Land–Atmosphere Interactions in the U.S. Southeast (Workshop Report)

The southeastern United States (Southeast), with its complex and varied environments, is an area of tremendous economic, ecological, and societal importance to the country. The region is characterized by heterogeneous landscapes (i.e., geology and soil type) and a long history of human land use coupled with a warm temperature regime and high precipitation. As a result, soil erosion and deposition are pronounced, vegetation recovery is rapid, and human modification is extensive across the region. To better understand land–atmosphere interactions in this important and complex region, research communities supported by the U.S. Department of Energy’s Biological and Environmental Research (BER) program identified the Southeast as a priority region of interest. In fall 2024, the third Atmospheric Radiation Measurement Mobile Facility (AMF3), one of three mobile monitoring facilities designed to collect atmospheric and climate data from undersampled regions around the world, will begin operations in northwestern Alabama’s Bankhead National Forest (BNF). The AMF3-BNF 5-year deployment, from 2024–2029, will monitor the effects of feedbacks among aerosols, clouds, and precipitation on plant physiology and canopy-scale fluxes. It will also focus on scale aggregation to resolve the role of local forcing on larger-scale processes. To enable broader AMF3 involvement by the science community, the BER Environmental System Science (ESS) program organized the Southeast Land– Atmosphere Research Opportunities (SELARO) workshop in August 2023. The purpose was to identify gaps in scientific understanding of terrestrial processes in the Southeast (defined as states bounded by the Gulf of Mexico to the south, the Atlantic Ocean to east, the Mississippi River to the west, and extending through Tennessee and North Carolina to the north) and explore opportunities to use the AMF3-BNF deployment to coordinate and leverage research efforts across the region. Many parts of the Southeast have experienced repeated anthropogenic forcings. Farming, hunting, burning, and settlement of the region by Indigenous Peoples first shaped the distribution of plant communities, which in turn influenced European colonization patterns. Timber harvesting was common during the expansion of European settlements, and production forestry continues today. Agricultural production was extensive and then waned through the 20th century, creating a period of afforestation following agricultural abandonment. Today, many formerly agricultural landscapes are undergoing rapid urbanization and suburbanization. Overlying these patterns of anthropogenic land use are frequent disturbances from hurricanes, tornadoes, wildfires, drought, flooding, ice storms, and the occasional blizzard. An additional characteristic of the Southeast is its overall landscape complexity. Unlike the western United States, where broad expanses may share similar characteristics, Southeast topography, drainage patterns, vegetation, and development patterns vary widely across relatively small spatial scales (<1 km). This is due to the region’s underlying geology and soil development, species biodiversity patterns, and land ownership and use coupled with strong forces of erosion, weathering, and rapid plant growth in the warm, wet climate.

54 ENVIRONMENTAL SCIENCES↗

Export of Ice Sheet Meltwater from Upernavik Fjord, West Greenland

Meltwater from Greenland is an important freshwater source for the North Atlantic Ocean, released into the ocean at the head of fjords in the form of runoff, submarine melt, and icebergs. The meltwater release gives rise to complex in-fjord transformations that result in its dilution through mixing with other water masses. The transformed waters, which contain the meltwater, are exported from the fjords as a new water mass Glacially Modified Water (GMW). Here we use summer hydrographic data collected from 2013 to 2019 in Upernavik, a major glacial fjord in northwest Greenland, to describe the water masses that flow into the fjord from the shelf and the exported GMWs. Using an optimum multi-parameter technique across multiple years we then show that GMW is composed of 57.8% ± 8.1% Atlantic Water (AW), 41.0% ± 8.3% Polar Water (PW), 1.0% ± 0.1% subglacial discharge, and 0.2% ± 0.2% submarine meltwater. We show that the GMW fractional composition cannot be described by buoyant plume theory alone since it includes lateral mixing within the upper layers of the fjord not accounted for by buoyant plume dynamics. Consistent with its composition, we find that changes in GMW properties reflect changes in the AW and PW source waters. Using the obtained dilution ratios, this study suggests that the exchange across the fjord mouth during summer is on the order of 50 mSv (1 Sv ≡ 10 6 m 3 s –1 ) (compared to a freshwater input of 0.5 mSv). This study provides a first-order parameterization for the exchange at the mouth of glacial fjords for large-scale ocean models.

58 GEOSCIENCES↗

High Synteny and Sequence Identity between Genomes of Nitrosococcus oceani Strains Isolated from Different Oceanic Gyres Reveals Genome Economization and Autochthonous Clonal Evolution

The ammonia-oxidizing obligate aerobic chemolithoautotrophic gammaproteobacterium, Nitrosococcus oceani, is omnipresent in the world’s oceans and as such important to the global nitrogen cycle. We generated and compared high quality draft genome sequences of N. oceani strains isolated from the Northeast (AFC27) and Southeast (AFC132) Pacific Ocean and the coastal waters near Barbados at the interface between the Caribbean Sea and the North Atlantic Ocean (C-27) with the recently published Draft Genome Sequence of N. oceani Strain NS58 (West Pacific Ocean) and the complete genome sequence of N. oceani C-107, the type strain (ATCC 19707) isolated from the open North Atlantic, with the goal to identify indicators for the evolutionary origin of the species. The genomes of strains C–107, NS58, C-27, and AFC27 were highly conserved in content and synteny, and these four genomes contained one nearly sequence-identical plasmid. The genome of strain AFC132 revealed the presence of genetic inventory unknown from other marine ammonia-oxidizing bacteria such as genes encoding NiFe-hydrogenase and a non-ribosomal peptide synthetase (NRPS)-like siderophore biosynthesis module. Comparative genome analysis in context with the literature suggests that AFC132 represents a metabolically more diverse ancestral lineage to the other strains with C-107 and NS58 potentially being the youngest. The results suggest that the N. oceani species evolved by genome economization characterized by the loss of genes encoding catabolic diversity while acquiring a higher redundancy in inventory dedicated to nitrogen catabolism, both of which could have been facilitated by their rich complements of CRISPR/Cas and Restriction Modification systems.

59 BASIC BIOLOGICAL SCIENCES↗

Identification of major moisture sources across the Mediterranean Basin

We employ a Lagrangian based moisture back trajectory method on an ensemble of four reanalysis datasets to provide a comprehensive understanding of moisture sources over the Mediterranean land region (30° N–49.5° N and 9.75° W–61.5° E) at seasonal timescales for 1980–2013 period. Using a source region between 10° S–71.35° N along the latitude and 80° W–84.88° E along the longitude that is subdivided into ten complimentary sub-regions, our analyses is able to backtrack up to > 90% of seasonal precipitation at each grid point within the target region. Our results indicate a significant role of moisture advected from the North Atlantic and Mediterranean Sea, and locally recycled moisture over the target region in shaping the spatial organization of seasonal precipitation. However, a clear east–west contrast is witnessed in determining the relative importance of each of these major moisture sources where the North Atlantic dictates the moisture supply over the western Mediterranean while moisture from Mediterranean Sea and local recycling play a key role over the eastern Mediterranean. Our analyses also demonstrate a major footprint of the North Atlantic Oscillation (NAO) on precipitation variability over the Mediterranean land as dynamic and thermodynamic anomalies during the negative phase of NAO match with those during wet years and vice versa. The findings reported here are generally consistent across the four reanalysis datasets. Overall, this study establishes the relative roles of adjacent and far-off oceanic and terrestrial evaporative sources over the Mediterranean land and should help in understanding the drivers of precipitation variability and change at varying timescales.

54 ENVIRONMENTAL SCIENCES↗

Spring Regional Sea Surface Temperatures as a Precursor of European Summer Heatwaves

Different spring and early summer North Atlantic sea surface temperature anomalies (SSTAs) have been shown to precede recent European summer heatwaves (EuSHWs). So far, the limited number of observed events associated with several physical mechanisms has prevented a robust identification of SSTAs as precursors. Here, we extend beyond previous studies by combining 100 historical simulations (1850–2005) of the MPI Grand-Ensemble with an explainable neural-network method. We find that the spring tripolar North Atlantic pattern with positive SSTAs in the Subtropical Gyre is a precursor of EuSHWs. In addition, positive SSTAs west of the Iberian Peninsula, and in the North Sea, the Baltic Sea and the Mediterranean Sea relate to distinct early summer soil moisture anomaly patterns and are precursors of western and southeastern EuSHWs, respectively. While the phase of the tripolar North Atlantic pattern indicates whether a EuSHW might emerge, regional SSTAs indicate the spatial characteristics of EuSHWs.

54 ENVIRONMENTAL SCIENCES↗