Results for “Writing Competitive Proposals”

DOE OSTI2023

Writing Competitive Proposals [Slides]

A proposal is a written response to an opportunity offered by a funding organization. Proposals must meet a SOLICITOR’S needs, not YOUR needs. A solicited proposal is a written response to a specific solicitation issued by a sponsor. These solicitations are typically called RFPs, or Requests for Proposals. RFPs are specific in their requirements regarding format and technical content. Scientists at Los Alamos often deal with this type of proposal — Laboratory-Directed Research and Development (LDRD) proposals are one example. An unsolicited proposal is one submitted to a sponsor who has not issued a specific solicitation. It usually comes about during interactions at meetings or conferences. In some instances, a sponsor may be visiting for another reason when the possibility for an unsolicited proposal becomes available. A pre-proposal is one in which a sponsor wishes to gage competition before having participants prepare a formal, full-length proposal. These types of scenarios imply that the actual proposal could be highly competitive and will usually be by invitation only.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

DOE OSTI2023

Direct Laser Writing of Multimetal Bifunctional Catalysts for Overall Water Splitting

Water electrolysis is of interest as a sustainable way to produce clean hydrogen and oxygen fuel and help mitigate the rising problems of climate change while meeting global energy demands. High-efficiency, stable, and earth-abundant bifunctional catalysts are needed to enable more effective electrochemical cells for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Here, we investigate the synthesis, composition, performance, and mechanism of multimetal catalysts serving dual functionality in both OER and HER of water electrolysis. Through a laser synthesis method, we synthesized heterogeneous catalysts of nanocrystalline multimetallic alloy pockets embedded within an amorphous oxide matrix. We evaluated the performance and composition of a range of mixed transition-metal oxide materials for both OER and HER, ultimately synthesizing a Cr 0.01 Fe 0.27 Co 0.34 Ni 0.38 O x /C y catalyst that has a stable, high-rate, and competitive overall water splitting performance of 1.76 V at 100 mA cm –2 in an alkaline medium. Using density functional theory to gain insight as the active site and mechanism, we propose that the inclusion of a minor amount of Cr increases the degeneracy of energetic states that lowers the cost of forming the O 2 p–d bond and H 1 s–d bond due to the hybridization of s, p, and d orbitals from Cr. Using a two-electrode water electrolysis cell with a constant potential of 1.636 V to mimic the setup for fuel production, we found the catalyst to be stable at 14–15 mA cm –2 for 40 h. Furthermore, this laser synthesis method allowing for facile and rapid synthesis of complex multimetal systems demonstrates how doping a Fe, Co, and Ni heterogeneous amorphous/nanocrystalline structure with small amounts of Cr is important for bifunctional catalytic behavior, particularly for increasing HER functionality in advancing our understanding for future electrocatalytic design.

08 HYDROGEN↗