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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Argon content of the Martian atmosphere at the Viking 1 landing site - Analysis by X-ray fluorescence spectroscopy

Spectra provided by the Viking 1 X-ray fluorescence spectrometer operating in the calibration mode (without a soil sample in the analysis chamber) were analyzed to determine the argon content of the Martian atmosphere at the landing site. This was found to be less than or equal to 0.15 millibar, or not more than 2% by volume, consistent with data obtained by the entry mass spectrometer and by the mass spectrometer on the lander. It is anticipated that analysis of the K content of surface samples using X-ray fluorescence data will provide information on the evolution of the atmosphere, since most atmospheric argon is apparently produced by decay of K-40.

Clark, B. C.↗
NASA NTRS1966

New techniques in geochemical analysis

Thin layer and gas chromatography, Mossbauer and atomic absorption spectrometry, fission track analysis, X-ray fluorescence spectroscopy, and other methods employed in geochemistry

X-RAY FLUORESCENCE SPECTROSCOPY↗
NASA NTRS1981

Planetary exploration sensor systems

Most of the instruments that have been used in planetary exploration have been either spectrometers or imaging devices. Instruments of these types are being developed for the Galileo and VOIR (Venus Orbiting Imaging Radar) missions. Galileo will take advantage of new CCD (charge-coupled device) technology, and VOIR will use techniques of synthetic aperture radar developed for Seasat. For determining the macrostructure of mineral resources, the best approach is believed to involve acoustic imaging, essentially a seismic data processing technique. Determinations of microstructure would require a light microscope and an electron microscope. For determining the nature and form of volatiles, a differential scanning calorimeter could be used. To determine the mineral composition, an electron beam microprobe with X-ray fluorescence and spectroscopy would be used.

Saunders, R. S.↗
NASA NTRS1977

Geology orbiter comparison study

Instrument requirements of planetary geology orbiters were examined with the objective of determining the feasibility of applying standard instrument designs to a host of terrestrial targets. Within the basic discipline area of geochemistry, gamma-ray, X-ray fluorescence, and atomic spectroscopy remote sensing techniques were considered. Within the discipline area of geophysics, the complementary techniques of gravimetry and radar were studied. Experiments using these techniques were analyzed for comparison at the Moon, Mercury, Mars and the Galilean satellites. On the basis of these comparative assessments, the adaptability of each sensing technique was judged as a basic technique for many targets, as a single instrument applied to many targets, as a single instrument used in different mission modes, and as an instrument capability for nongeoscience objectives.

Cutts, J. A. J.↗
NASA NTRS1979

Smectite clays in Mars soil - Evidence for their presence and role in Viking biology experimental results

Evidence for the presence of smectite clays in Martian soils is reviewed and results of experiments with certain active clays simulating the Viking biology experiments are reported. Analyses of Martian soil composition by means of X-ray fluorescence spectrometry and dust storm spectroscopy and Martian geological history strongly suggest the presence of a mixture of weathered ferro-silicate minerals, mainly nontronite and montmorillonite, accompanied by soluble sulphate salts, as major constituents. Samples of montmorillonite and nontronite incubated with (C-14)-formate or the radioactive nutrient medium solution used in the Viking Labeled Release experiment, were found to produce patterns of release of radioactive gas very similar to those observed in the Viking experiments, indicating the iron-catalyzed decomposition of formate as the reaction responsible for the Viking results. The experimental results of Hubbard (1979) simulating the results of the Viking Pyrolytic Release experiment using iron montmorillonites are pointed out, and it is concluded that many of the results of the Viking biology experiments can be explained in terms of the surface activity of smectite clays in catalysis and adsorption.

Banin, A.↗
NASA NTRS1994

X-Ray Absorption Spectroscopy in High Temperature Oxidation of Metals and Alloys

An experimental technique is described that allows for the joint study of the kinetics and of the oxide structure during the high temperature oxidation of metal surfaces. Oxygen is supplied at the metal through an electrochemical oxygen pump and the oxygen pressure, at the metal surface, is measured during oxidation by a YSZ (yttria stabilized zirconia) oxygen sensor. XAS (x-ray absorption spectroscopy) is performed in fluorescence mode at the cation K edge and after each oxidation step. An appropriate analysis of the XAS spectra could provide information on both the oxidation kinetics and oxide structure. Experimental data on the high temperature oxidation of nickel, cobalt, and Fe(64%)Ni(36%) alloy, at low oxygen pressure, are reported and analyzed according to the proposed data reduction. These results indicate the presented technique to be particularly suitable for studying the hot corrosion of oxide film too thick for common surface spectroscopy (AUGER, ESCA) and too thin for conventional thermogravimetric technique.

Daniele Gozzi↗
NASA NTRS1976

Terrestrial bodies orbiter, LUNAR - A system for detailed global measurements of a planet's properties

The NASA Lunar Polar Orbiter, to be launched by a Delta vehicle in 1980, is designed to perform a global exploration of such moon properties as the gravity field, figure, and surface composition, as well as a lunar resource survey. The paper reviews the mission, spacecraft, and data system concepts in terms of baseline mission sequence, choice of orbits, spacecraft configuration requirements, mission sequence requirements and data system and operations. Scientific experiments planned for the Orbiter mission include geophysical altimetry and gravity experiments, heat flow experiment, magnetic field experiments, measurements of the moon's natural gamma-ray spectrum, X-ray fluorescence of lunar surface materials, sunlight reflectance spectroscopy, and spectro-stereo imaging. Characteristics of instruments designed for use in these investigations are examined. Through the use of advanced sensors and data-system techniques, coupled with well-developed spacecraft systems, the mission promises to return a very large quantity and variety of lunar data at a cost comparable with that of simpler missions in the past.

Burke, J. D.↗
NASA NTRS1978

Infrared spectroscopy of simulated Martian surface materials

Mineralogy inferred from the Viking X-ray fluorescence spectrometry (XRFS) is compared with mineralogy indicated by spectral data. The comparison is done by taking laboratory spectra of Viking analog minerals. Both XRFS and infrared data are consistent with clays as the dominant SiO2 containing minerals on Mars. The X-ray fluorescence data might also be consistent with the dominance of certain mafic SiO2 igneous minerals, but the spectral data are probably inconsistent with such materials. Sulfates, inferred by XRFS, are consistent with the spectral data. Inferences following Mariner 9 that high-SiO2 minerals were important on Mars may have been biased by the presence of sulfates. Calcium carbonate, in the quantities indirectly suggested by XRFS are inconsistent with the spectral data, but smaller quantities of CaCO3 are consistent, as are large quantities of other carbonates.

Toon, O. B.↗
NASA NTRS1979

Measurement techniques for trace metals in coal-plant effluents: A brief review

The strong features and limitations of techniques for determining trace elements in aerosols emitted from coal plants are discussed. Techniques reviewed include atomic absorption spectroscopy, charged particle scattering and activation, instrumental neutron activation analysis, gas/liquid chromatography, gas chromatographic/mass spectrometric methods, X-ray fluorescence, and charged-particle-induced X-ray emission. The latter two methods are emphasized. They provide simultaneous, sensitive multielement analyses and lend themselves readily to depth profiling. It is recommended that whenever feasible, two or more complementary techniques should be used for analyzing environmental samples.

Singh, J. J.↗
NASA NTRS1981

Spectroscopy from 2 to 200 keV

The astrophysical processes responsible for line and continuum emission in the spectra range 2 keV to 200 keV are examined from the viewpoint of designing a spectrometer which would operate in this regime. Phenomena considered include fluorescent line radiation in X-ray binaries, magnetically shifted iron lines and cyclotron emission from neutron star surfaces, line emission from cosmically abundant elements in thermal plasmas, and nuclear deexcitation lines in fresh nucleosynthetically produced matter. An instrument consisting of a approximately 10 sq cm array of planar germanium detectors surrounded by a large sodium-iodide anticoincidence shield is described and projected background rates and sensitivities are considered. A sample observing program for a two-day shuttle-based mission is included as an example of the wide range of scientific questions which could be addressed by such an instrument.

Helfand, D. J.↗
NASA NTRS1980

Enhanced orbital geochemical images by the Laplacian subtraction method

Orbital geochemical studies of the moon based on X-ray fluorescence and gamma-ray spectroscopy have been successful. There are, however, difficulties if geologic units or other features to be investigated are too small. Investigations have been conducted with the objective to improve with the aid of image enhancement methods both spatial resolution and contrast for the geochemical experiments. A description is provided of the Laplacian subtraction method of enhancement. It was found that the application of a least-squares version of this method to the Mg/Al ratios obtained by orbital X-ray fluorescence improved geochemical images considerably. The spatial resolution increased by about a factor of 2 and the contrast also increased. The Laplacian of an image can also be used to detect very small 'hot' or 'cold' spots in an image.

Schonfeld, E.↗
NASA NTRS1983

A portable x-ray analyzer for wearmetal particles in lubricants

An extensive program exists for the systematic sampling and analysis of lubricants in U.S. Air Force aircraft engines. The sudden development of excessive engine wear can usually be detected on the basis of monitoring the concentration of several key metallic elements for each aircraft engine. In many cases even the specific fault within an engine can be recognized. The two types of equipment which are currently being employed for the conduction of oil analyses make use of atomic emission or atomic absorption spectroscopy. In both cases, heavy, large, and relatively fragile pieces of equipment are involved. Difficulties concerning the transportation of these devices have led to the development of a small, sturdy, and easily portable wearmetal analyzer. The analyzer makes use of an X-ray fluorescence technique.

Clark, B. C.↗