Materials Data on ZnSbF6 by Materials Project
ZnSbF6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Zn is bonded to six equivalent F atoms to form ZnF6 octahedra that share corners with six equivalent SbF6 octahedra. The corner-sharing octahedral tilt angles are 29°. All Zn–F bond lengths are 2.06 Å. Sb is bonded to six equivalent F atoms to form SbF6 octahedra that share corners with six equivalent ZnF6 octahedra. The corner-sharing octahedral tilt angles are 29°. All Sb–F bond lengths are 2.06 Å. F is bonded in a bent 150 degrees geometry to one Zn and one Sb atom.
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