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ZrRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Zr is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Zr–Rh bond lengths are 2.86 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Zr atoms.
ZrRh crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Zr sites. In the first Zr site, Zr is bonded in a body-centered cubic geometry to eight Rh atoms. There are a spread of Zr–Rh bond distances ranging from 2.71–2.89 Å. In the second Zr site, Zr is bonded in a 5-coordinate geometry to seven Rh atoms. There are a spread of Zr–Rh bond distances ranging from 2.70–3.22 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 7-coordinate geometry to seven Zr atoms. In the second Rh site, Rh is bonded in a 8-coordinate geometry to eight Zr atoms.
ZrRh is alpha-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Zr is bonded in a 7-coordinate geometry to seven equivalent Rh atoms. There are a spread of Zr–Rh bond distances ranging from 2.64–2.93 Å. Rh is bonded in a 7-coordinate geometry to seven equivalent Zr atoms.
ZrRh is Tetraauricupride structured and crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Zr is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. There are a spread of Zr–Rh bond distances ranging from 2.83–2.90 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Zr atoms.