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At least 19 records

Microstructural changes and strain hardening effects in abrasive contacts at different relative velocities and temperatures

Strain hardening is commonly used to reach the full potential of materials and can be beneficial in tribological contacts. 2-body abrasive wear was simulated in a scratch test, aimed at strain hardening effects in various steels. Different working conditions were examined at various temperatures and velocities. Strain hardening effects and microstructural changes were analysed with high resolution scanning electron microscopy (HRSEM), electron backscatter diffraction (EBSD), micro hardness measurements and nanoindentation. Statistical analysing was performed quantifying the influence of different parameters on microstructures. Results show a crucial influence of temperature and velocity on the strain hardening in tribological contacts. Increased velocity leads to higher deformed microstructures and higher increased surface hardness at a lower depth of the deformed zones at all materials investigated. An optimised surface hardness can be achieved knowing the influence of velocity (strain rate) and temperature for a “tailor-made” surface hardening in tribological systems aimed at increased wear resistance. - Highlights: •Hardening mechanisms and their intensity in tribological contacts are dependent on relative velocity and temperature. •Beneficial surface hardened zones are formed at certain running-in conditions; the scientific background is presented here. •Ferritic-pearlitic steels strain hardens via grain size reduction and decreasing interlamellar distances in pearlite. •Austenitic steels show excellent surface hardening (120% hardness increase) by twinning and martensitic transformation. •Ferritic steels with hard phases harden in the ferrite phase as per Hall-Petch equation and degree of deformation.

36 MATERIALS SCIENCE↗

Effect of Abrasion on the Crystal Structure of ZnS and ZnSe Ceramics

Zinc sulfide and zinc selenide ceramic samples prepared by hot pressing (HP) and chemical vapor deposition (CVD) have been subjected to dry grinding simulating dust erosion of these materials under real service conditions. It has been demonstrated that photoluminescence measurements allow one to follow the degradation of the crystal structure of ceramic grains by monitoring the intensity of structure-sensitive emission bands. The crystal structure of ZnS, a harder material, has been shown to be less sensitive to abrasion. Moreover, the abrasion resistance of the ceramics produced by CVD exceeds that of the HP ceramics of the same composition.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NREL's Effort Toward Predicting Soiling

The aim of this works is sharing the research conducted by NREL in the past three years on photovoltaic soiling. Soiling is an issue affecting PV systems worldwide and causing reduction in performance and increase in O&M costs. NREL has been working closing with he community to (i) develop models to predict soiling, in order to help PV owners to better plan optimal cleaning schedules, and identify soiling trends from PV performance data, without the need of expensive soiling detectors, (ii) understand the abrasive effects of soiling and cleanings on PV glasses, (iii) investigate the effectiveness of different cleaning methods. The most important results and some of the resources made available by the NREL research team will be presented.

14 SOLAR ENERGY↗

The Role of Hydraulic Connectivity and Management on Soil Aggregate Size and Stability in the Clear Creek Watershed, Iowa

The role of tillage practices on soil aggregate properties has been mainly addressed at the pedon scale (i.e., soilscape scale) by treating landscape elements as disconnected. However, there is observed heterogeneity in aggregate properties along flowpaths, suggesting that landscape scale hydraulic processes are also important. This study examines this supposition using field, laboratory and modeling analysis to assess aggregate size and stability along flowpaths under different management conditions: (1) tillage-induced abrasion effects on aggregate size were evaluated with the dry mean weight diameter (DMWD); (2) raindrop impact effects were evaluated with small macroaggregate stability (SMAGGSTAB) using rainfall simulators; and (3) these aggregate proxies were studied in the context of connectivity through the excess bed shear stress (δ), quantified using a physically-based landscape model. DMWD and SMAGGSTAB decreased along the flowpaths for all managements, and a negative correspondence between the proxies and δ was observed. δ captured roughness effects on connectivity along the flowpaths: highest connectivity was noted for parallel-ridge-till flowpaths, where δ ranged from 0–8.2 Pa, and lowest connectivity for contour-ridge-till flowpaths, where δ ranged from 0–1.1 Pa. High tillage intensity likely led to an increase in aggregate susceptibility to hydraulic forcing, reflected in the higher gradients of aggregate size and stability trendlines with respect to δ. Finally, a linear relationship between DMWD and SMAGGSTAB was established.

Wacha, Kenneth M. (ORCID:0000000270351071)↗

The Abrasion of Photovoltaic Glass: A Comparison of the Effects of Natural and Artificial Aging

Natural soiling and the subsequent requisite cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of antireflective and/or antisoiling coatings as well as the method and frequency of operating maintenance (cleaning). The abrasion of coatings and glass has been explored in a field study, including the soiling-prone locations of Dubai (United Arab Emirates), Kuwait City (Kuwait), Mesa (Arizona), Mumbai (India), and Sacramento (California). Dry-brush-cleaned specimens will be compared to those subjected to artificial-brush testing. The characteristics of material integrity, surface energy, optical transmittance, surface roughness, and scratch size were examined using an optical microscope, contact goniometer (for water), spectrophotometer, interferometer, and atomic force microscope (AFM), respectively. The findings of this study will be used to provide feedback regarding the cleaning equipment, cleaning methods, and coatings used in the PV industry. The study here will also be used to aid in developing an abrasion standard for the PV industry.

14 SOLAR ENERGY↗

Effect of temperature on abrasion erosion in particle based concentrating solar powerplants

The use of solid particles as a heat transfer medium is being explored for concentrated solar power plants (CSP) to increase their efficiency by achieving operating temperature >700 °C. During operation, these hot particles are expected to move along the various components within the collector system, resulting in material degradation from a combination of high-temperature oxidation and erosion. In the present study, the performance of candidate materials was evaluated through a series of abrasion erosion experiments at room temperature as well as at 800 °C. Wear in metallic and refractory type materials was investigated using CarboBead® HSP 40/70 particles inside a resistance heated kiln. Furthermore, cross-sectional scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS) analysis on the specimens tested at 800 °C determined that the specific wear rate in Inconel 740H and stainless steel 316 metallic specimens was influenced by the thermally grown oxide morphology. High chromium Inconel 740H specimens exhibited greater resistance to wear with a steady state specific wear rate of 1.92E-4 mm 3 N -1 m –1 compared to 5.7E-3 mm 3 N -1 m –1 for Stainless Steel 316.

14 SOLAR ENERGY↗

The homogenous alternative to biomineralization: Zn- and Mn-rich materials enable sharp organismal “tools” that reduce force requirements

We measured hardness, modulus of elasticity, and, for the first time, loss tangent, energy of fracture, abrasion resistance, and impact resistance of zinc- and manganese-enriched materials from fangs, stings and other “tools” of an ant, spider, scorpion and nereid worm. The mechanical properties of the Zn- and Mn-materials tended to cluster together between plain and biomineralized “tool” materials, with the hardness reaching, and most abrasion resistance values exceeding, those of calcified salmon teeth and crab claws. Atom probe tomography indicated that Zn was distributed homogeneously on a nanometer scale and likely bound as individual atoms to more than ¼ of the protein residues in ant mandibular teeth. This homogeneity appears to enable sharper, more precisely sculpted “tools” than materials with biomineral inclusions do, and also eliminates interfaces with the inclusions that could be susceptible to fracture. Based on contact mechanics and simplified models, we hypothesize that, relative to plain materials, the higher elastic modulus, hardness and abrasion resistance minimize temporary or permanent tool blunting, resulting in a roughly 2/3 reduction in the force, energy, and muscle mass required to initiate puncture of stiff materials, and even greater force reductions when the cumulative effects of abrasion are considered. We suggest that the sharpness-related force reductions lead to significant energy savings, and can also enable organisms, especially smaller ones, to puncture, cut, and grasp objects that would not be accessible with plain or biomineralized “tools”.

59 BASIC BIOLOGICAL SCIENCES↗

Processing and Characterization of Fe-Mn-Cu-Sn-C Alloys Prepared by Ball Milling and Spark Plasma Sintering

In this work, Fe-Mn-Cu-Sn-C alloys were prepared by means of powder metallurgy (PM). Powder mixtures were ball-milled for 8, 30 and 120 h and densified to < 1% porosity using spark plasma sintering (SPS) at 900 °C and 35 MPa. After consolidation, all samples of the Fe alloys were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), hardness and flexural strength tests. Resistance to abrasive wear was evaluated in both three-body abrasion and two-body abrasion tests. The SEM observations revealed an evident dependence of grain size and microstructural homogeneity on milling time. The XRD analysis showed a marked increase in austenite content in the as-sintered specimens with milling time. Although the proportion of deformation-induced martensite was small, the strengthening effect of abrasion on the subsurface layer of the investigated alloys was clearly indicated by Knoop hardness measurements.

36 MATERIALS SCIENCE↗

Electrochemically reduced graphene oxide nanosheet coatings as solid lubricants in humid air

Highlights: • A facile, low cost and green approach to fabricate ERGO coatings is reported. • The feasibility of using ERGO coatings as solid lubricants is demonstrated. • ERGO coatings reduce copper’s COF to 1/6 and wear rate to more than 1/260. - Abstract: A facile, low cost and green approach to fabricating graphene nanosheet coatings is reported. It is composed of spraying graphene oxide (GO) suspension to form GO nanosheet coatings followed by a low voltage electrochemical reduction process. The tribological performance of the as-prepared electrochemically reduced graphene oxide (ERGO) nanosheet coatings on copper disk are evaluated by sliding against steel ball in humid air. The friction coefficient of copper is reduced to 1/6 its value, and its specific wear rate is reduced more than two orders of magnitude when copper disk is coated with ERGO nanosheet coatings. These improved tribological performance are attributed to the presence of ERGO nanosheets in the sliding interface of steel vs. copper friction pair. They not only provide easy shearing, reducing the friction coefficient, but also effectively suppress abrasive wear and adhesive wear, decreasing the wear rate of copper disk.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Wear Behavior of an Ultra-High-Strength Eutectoid Steel

Wear behavior of an ultra-high-strength AISI 1080 steel developed through incomplete austenitization-based combined cyclic heat treatment is investigated in comparison with annealed and conventional hardened and tempered conditions against an alumina disk (sliding speed = 1 m s{sup −1}) using a pin-on-disk tribometer at a load range of 7.35-14.7 N. On a gross scale, the mechanism of surface damage involves adhesive wear coupled with abrasive wear (microcutting effects in particular) at lower loads. At higher loads, mainly the abrasive wear (both microcutting and microploughing mechanisms) and evolution of adherent oxide are observed. Besides, microhardness of matrix increases with load indicating substantial strain hardening during wear test. The rate of overall wear is found to increase with load. As-received annealed steel with the lowest initial hardness suffers from severe abrasive wear, thereby exhibiting the highest wear loss. Such a severe wear loss is not observed in conventional hardened and tempered and combined cyclic heat treatment conditions. Combined cyclic heat-treated steel exhibits the greatest wear resistance (lowest wear loss) due to its initial high hardness and evolution of hard abrasion-resistant tribolayer during wear test at higher load.

36 MATERIALS SCIENCE↗

Acidic magnetorheological finishing of infrared polycrystalline materials

Here, chemical-vapor–deposited (CVD) ZnS is an example of a polycrystalline material that is difficult to polish smoothly via the magnetorheological–finishing (MRF) technique. When MRF-polished, the internal infrastructure of the material tends to manifest on the surface as millimeter-sized “pebbles,” and the surface roughness observed is considerably high. The fluid’s parameters important to developing a magnetorheological (MR) fluid that is capable of polishing CVD ZnS smoothly were previously discussed and presented. These parameters were acidic pH (~4.5) and low viscosity (~47 cP). MRF with such a unique MR fluid was shown to reduce surface artifacts in the form of pebbles; however, surface microroughness was still relatively high because of the absence of a polishing abrasive in the formulation. In this study, we examine the effect of two polishing abrasives—alumina and nanodiamond—on the surface finish of several CVD ZnS substrates, and on other important IR polycrystalline materials that were finished with acidic MR fluids containing these two polishing abrasives. Surface microroughness results obtained were as low as ~28 nm peak-to-valley and ~6-nm root mean square.

36 MATERIALS SCIENCE↗

Selective laser melting of oxide dispersion strengthened MA956 alloy and its surface finishing by magnetic field assisted finishing

Selective laser melting (SLM) is a prominent metal additive manufacturing (AM) capable of processing a myriad of engineering materials with high precision and design freedom. However, similar to other AM processes, poor surface finishing has been an omnipresent problem in SLM technology. In this study, magnetic field assisted finishing (MAF) was used to finish SLM fabricated oxide dispersion strengthened (ODS) MA956, an iron-chromium-aluminum alloy. The effect of laser processing parameters on part density and surface roughness was first studied. Using a multi-objective optimization technique, the optimal parameters to obtain the highest density and lowest surface roughness were determined. Finally, MAF was applied to the parts built with the obtained optimal SLM parameters, but without significant improvement on the surfaces of as-printed samples. Hence, the surfaces of as-printed samples were post-processed (ground) to yield better initial surface conditions prior to MAF. The effect of initial roughness, iron particles size, and abrasive size on MAF performance was studied. Initial roughness had the most dominant effect followed by abrasive size. The underlying mechanism behind the dependency on initial roughness on final surface quality was analyzed by studying the change on the surface profiles with different starting initial roughness. The initial roughness required for MAF to be effective was determined. In conclusion, using the optimal processing conditions, MAF was applied to the post-processed samples to attain the final average surface roughness (R a ) as little as 0.36 μm starting from initial average roughness (R a ) of 1.53 μm.

36 MATERIALS SCIENCE↗

Automated instrument for assessing abrasives

An automated instrument for monitoring the destructive compressive load on abrasive grains (measuring 400–1250 μm) between two rotating rollers has been developed. A modernized version of the instrument also permits determination of the grain size, shape, and microgeometric and topographic characteristics of abrasives. Equipped with a photometric unit and a module for processing numerical information, the modernized instrument permits multiple recording of each particle by six cameras (in both directions along three orthogonal axes), with assessment of the microgeometry. Such information regarding the grains, along with identification of their shape (plates, needles, isometric form, etc.), permits their quality assessment; their subsequent separation on vibrational sorters; and their most effective use in the abrasive machining of materials characterized by different hardness, brittleness, and composition, including composites.

36 MATERIALS SCIENCE↗

Chemical abrasion: the mechanics of zircon dissolution

Chemical abrasion is a technique that combines thermal annealing and partial dissolution in hydrofluoric acid (HF) to selectively remove radiation-damaged portions of zircon crystals prior to U–Pb isotopic analysis, and it is applied ubiquitously to zircon prior to U–Pb isotope dilution thermal ionization mass spectrometry (ID-TIMS). The mechanics of zircon dissolution in HF and the impact of different leaching conditions on the zircon structure, however, are poorly resolved. We present a microstructural investigation that integrates microscale X-ray computed tomography (µCT), scanning electron microscopy, and Raman spectroscopy to evaluate zircon dissolution in HF. We show that µCT is an effective tool for imaging metamictization and complex dissolution networks in three dimensions. Acid frequently reaches crystal interiors via fractures spatially associated with radiation damage zoning and inclusions to dissolve soluble high-U zones, some inclusions, and material around fractures, leaving behind a more crystalline zircon residue. Other acid paths to crystal cores include the dissolution of surface-reaching inclusions and the percolation of acid across zones with high defect densities. In highly crystalline samples dissolution is crystallographically controlled with dissolution proceeding almost exclusively along the c axis. Increasing the leaching temperature from 180 to 210 °C results in deeper etching textures, wider acid paths, more complex internal dissolution networks, and greater volume losses. How a grain dissolves strongly depends on its initial radiation damage content and defect distribution as well as the size and position of inclusions. As such, the effectiveness of any chemical abrasion protocol for ID-TIMS U–Pb geochronology is likely sample-dependent. We also briefly discuss the implications of our findings for deep-time (U-Th)/He thermochronology.

58 GEOSCIENCES↗

Assessing the Effectiveness of Solid Lubricants

The effectiveness of a proposed solid lubricant is investigated, on the basis of the abrasive cutting coefficients. Its dependence on the grinding conditions, the characteristics of the boron-nitride wheel, and the alloying of high-speed steel is determined. The lubricant reduces the abrasive cutting coefficient by about 40–50%. A method is proposed for measuring the frictional coefficient. The benefits of lubricant application are assessed. The utility of the abrasive cutting coefficient in estimating the effectiveness of solid lubricant is confirmed.

42 ENGINEERING↗

Experimental study and effect of particulate interference on the microhardness, wear and microstructural properties of ternary doped coating

This paper studies effects of the composite particle infringement of ZnO/Cr{sub 2}O{sub 3} on zinc rich ternary based coating. The corrosion-degradation property in 3.5% NaCl was investigatedusing polarization technique. The structural characteristics of the multilayer produce coatings were evaluated by scanning electron microscope (SEM) equipped with an energy dispersive spectrometer (EDS). The mechanical response of the coated samples was studied using a diamond base Dura –Scan) micro-hardness tester and a MTR-300 dry abrasive wear tester. The combined effect of the coatings gave highly-improved performance on microhardness, corrosion and wear damage. This also implies that protection of wind-energy structures in marine environments can be achieved by composite strengthening capacity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effect of 3D-printed surface textures on wear mechanism in 3-body abrasion of soil

This study systematically investigates the enhancement of wear resistance in 3D printed surface textures through both experimental and theoretical approaches. Three distinct surface morphologies (Smooth Surface, Surface with uniformly distributed Pits, and Surface with uniformly distributed Bumps) were fabricated using High-Impact Polystyrene, where the meso-scale textures were precisely controlled through the 3D printing process. Wear behavior was evaluated using a 3-body wear tester in an abrasive particle environment, analyzing the influence of surface textures under various operating conditions. Systematic wear tests revealed that optimally designed surface textures achieved a remarkable 77 % reduction in wear compared to the worst-performing sample. The wear mechanisms were comprehensively characterized through weight loss measurements, Scanning Electron Microscopy (SEM), and Energy Dispersive Spectroscopy (EDS) analyses, elucidating the surface morphology changes and their interaction with wear particles. Notably, the study identified how the geometric characteristics of surface textures influence the movement of wear particles and the distribution of contact stresses. Discrete element method simulations corroborated the experimental findings, providing theoretical validation for the enhanced wear resistance of the optimal structure. The high correlation between simulated wear patterns and experimental results validates the reliability of the proposed design methodology. In conclusion, these results demonstrate that 3D printed surface texturing offers a cost-effective and scalable approach to significantly improve wear resistance in engineering applications, presenting a practical alternative to conventional, high-cost surface engineering methods.

3-body abrasion↗