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At least 19 records

Rotational excitation in collisions between two rigid rotors - Alternate angular momentum coupling and pressure broadening of HCl by H2

In order to compute relaxation 'cross sections' for molecule-molecule collisions, it is convenient to employ a coupled angular-momentum representation which differs from that generally used. An explicit expression for collision-induced spectral pressure broadening in this representation is given, and this is used to examine the difference between para- and ortho-H2 for broadening of HCl.

Green, S.↗

Is photon angular momentum important in molecular collision processes occurring in a laser field

The importance of the rigorous treatment of photon angular momentum in molecular-collision processes occurring in the presence of intense radiation is investigated. An alternate approximate treatment, which essentially neglects the angular momentum coupling between the photon and the molecular degrees of freedom by averaging over the angular dependence of the interaction matrix elements, is presented and applied to a model calculation. The degeneracy-averaged results of this calculation compare remarkably well with the results of a rigorous calculation, from which we conclude (with reservation) that the explicit consideration of photoangular momentum coupling in molecular-collision problems is unnecessary.

Devries, P. L.↗

Signatures of troposphere-stratosphere momentum coupling Implications for global atmospheric angular momentum and earth rotation budgets

During January-August 1978, the global atmospheric angular momentum (M) exhibits distinct patterns of short term momentum interchange across latitudes. In the Northern Hemisphere winter-spring season, 30-50 day modulations of M are present in which momentum enhancements at mid-latitudes (20-30 deg) are closely matched by momentum depressions at high latitudes (50-60 deg). During the same interval there are no corresponding variations in M evident in the Southern Hemisphere. Conversely, during Southern Hemisphere fall-winter, similar anti-correlations in monthly scale momentum excursions are evident between mid and high latitudes. In the Northern Hemisphere, the winter-spring momentum signatures are detected throughout the atmosphere, from the lower troposphere to the stratosphere. During the Southern Hemisphere fall-winter, the modulation patterns are not evident at the higher altitudes. Structural details of the momentum signatures indicate that the coupling is sometimes effective on very short time scales, e.g., 1-2 days, or less. The evidence of distinct anti-correlation between large regions has interesting implications for studies of global atmospheric circulation, and also for studies of the excitation of variations in earth rotation in response to short term modulations of M.

Taylor, H. A.↗

Relative fine-structure intensities in two-photon excitation

A discrepancy is pointed out between experimental determinations of the relative intensities for different fine-structure components of the two-photon transitions 2p3P 3p3P in oxygen and 2p3 4S0 - 2p2 3p4D0 in nitrogen, which agreed well with calculations involving a single virtual intermediate level, and a two-photon selection rule dJ not equal to one, derived in a purely theoretical and erroneous treatment of these transitions. Five other experiments are also briefly examined, with the conclusion that relative fine-structure intensities in two-photon transitions are well understood as straightforward extensions of angular momentum coupling in single-photon cases, in accordance with allowed dJ = 0, + or -1, and + or -2 transitions.

Crosley, D. R.↗

Electromagnetic angular momentum transport in Saturn's rings

It is shown here that submicrometer dust particles sporadically elevated above Saturn's ring are subject to electromagnetic forces which will reduce their angular momentum inside synchronous orbit and increase it outside. When the dust is reabsorbed by the ring the angular momentum of the ring is decreased (increased) inside (outside) of synchronous orbit. For the case of the spokes in Saturn's B-ring it is estimated that the timescale for transporting ring material due to this angular momentum coupling effect is comparable to the viscous transport time or even smaller. It is suggested that the minimum in the optical depth of the B-ring at synchronous orbit is due to this effect.

Goertz, C. K.↗

Iron and molecular opacities and the evolution of Population I stars

Effects of recent opacity revisions on the evolution of Population I stars are explored over the range 1.5-60 solar masses. Opacity parameters considered include the angular momentum coupling scheme for iron, the relative iron abundance, the total metal abundance, and diatomic and triatomic molecular sources. Only the total metal abundance exerts an important control over the evolutionary tracks. Blue loops on the H-R diagram during core helium burning can be very sensitive to opacity, but only insofar as the simple formation or suppression of a blue loop is concerned. The blue loops are most robust for stellar masses around 10 solar masses. We confirm, from a comparison of stellar models with observational data, that the total metal abundance is close to solar and that convective core overshooting is likely to be very slight. The new models predict the existence of an iron convection zone in the envelope and a great widening of the main-sequence band in the H-R diagram at luminosities brighter than 100,000 solar luminosities.

Stothers, Richard B.↗

Molecular processes in comets

Classical trajectory calculations of the cross sections for vibrational and rotational energy exchange in direct and reactive collisions of hydrogen atoms and hydrogen molecules have been carried out. To test the sensitivity, three potential energy surfaces have been used. For the exchange transitions which occur at small internuclear distances, the rate coefficients for the three surfaces agree quite well. For the direct transitions, there are significant differences for the pure rotational transitions from j=0 to 2 and from j=1 to j=3 in which there is no change in vibration. For higher j the differences tend to disappear, suggesting that the rotational angular momentum can couple to the orbital angular momentum to overcome the centrifugal barrier. Complete numerically exact quantum mechanical calculations for the process in which vJ changes have been performed. Dr. M. A'Hearn has provided data on the fluorescent population of the NH rotational and fine-structure levels from which we should be able to predict accurate photodissociation lifetimes. The distribution rate of C2 is being investigated. A review of H3(+) in terrestrial and extraterrestrial environments was prepared for a volume of Advances in Atomic, Molecular and Optical Physics.

Dalgarno, A.↗

The coupled states approximation for scattering of two diatoms

The paper presents a detailed development of the coupled-states approximation for the general case of two colliding diatomic molecules. The high-energy limit of the exact Lippman-Schwinger equation is applied, and the analysis follows the Shimoni and Kouri (1977) treatment of atom-diatom collisions where the coupled rotor angular momentum and projection replace the single diatom angular momentum and projection. Parallels to the expression for the differential scattering amplitude, the opacity function, and the nondiagonality of the T matrix are reported. Symmetrized expressions and symmetrized coupled equations are derived. The present correctly labeled coupled-states theory is tested by comparing its calculated results with other computed results for three cases: H2-H2 collisions, ortho-para H2-H2 scattering, and H2-HCl.

Heil, T. G.↗

Rotation of the solar wind plasma.

Sun rotation effect on azimuthal components of solar wind velocity and interplanetary magnetic field, solving angular momentum equation coupled with Maxwell equations

Alfonso-Faus, A.↗

Earth Rotation and Coupling to Changes in Atmospheric Angular Momentum

The research supported under the contract dealt primarily with: (a) the mechanisms responsible for the exchange of angular momentum between the solid Earth and atmosphere; (b) the quality of the data sets used to estimate atmospheric angular momentum; and (c) the ability of these data and of global climate models to detect low-frequency signals in the momentum and, hence, circulation of the atmosphere. Three scientific papers reporting on the results of this research were produced during the course of the contract. These papers identified the particular torques responsible for the peak in atmospheric angular momentum and length-of-day during the 1982-93 El Nino event, and, more generally, the relative roles of torques over land and ocean in explaining the broad spectrum of variability in the length-of-day. In addition, a tendency for interannual variability in atmospheric angular momentum to increase during the last several decades of the 20th century was found in both observations and a global climate model experiment.

Rosen, Richard D.↗

Principal modes of atmospheric circulation anomalies associated with global angular momentum fluctuations

This paper provides a description of the variability of global atmospheric angular momentum (GAM) and its relationship with principal modes of three-dimensional atmospheric circulation anomalies. The data used are 5-day mean global wind fields from the European Centre for Medium-Range Weather Forecasts initialized dataset for 1980-1989. Significant seasonal variation of GAM is observed with maxima in April and November and a minimum during late July. The amplitude of the annual cycle is largest in the upper troposphere and decreases toward the surface. Although the lower tropospheric contribution to the total angular momentum is relatively small, its annual cycle is out of phase with those of the upper atmosphere and GAM. Also identified is a distinct semiannual component, with double peaks appearing in April and November. This signal is most noticeable in the upper troposphere above the 300-mb level. The principal modes of zonal-mean angular momentum and meridional circulation anomalies and their coupled modes are obtained by using empirical orthogonal function analysis and singular value decomposition. It is shown that the leading modes of the angular momentum and meridional circulation are coupled with each other and are responsible for much of the variability in GAM. The coupled modes represent fluctuations of upper-level subtropical zonal flow, which are linked to the modulation of Hadley circulation intensity in both hemispheres. It is found that GAM is highly correlated with the first eigenvector of upper-level streamfunction anomalies, which consists of a superrotational flow in the tropics and subtropics, except over the central Pacific where a 'blocked' flow with two subtropical anticyclonic circulation cells straddling the equator is found. Much of the blocked flow is due to the establishment of dipole anomalies in the velocity potential with centers over the central Pacific and the Maritime Continent on the interannual time scale. On the intraseasonal time scale, GAM fluctuation is dominated by superrotational flow in the tropics, with the blocked flow present to a much lesser extent. The associated velocity potential anomaly has a weak dipole structure with centers over the Indian Ocean and the eastern Pacific. The implications of the above results on the total angular momentum balance of the earth-atmosphere system are also discussed.

Kang, In-Sik↗

Discrepancies in the earth-atmosphere angular momentum budget

Modern geodetic and atmospheric data sets have demonstrated that changes in the solid earth's rotation rate are closely coupled to changes in the atmosphere's angular momentum over a range of subseasonal through interannual time scales. Nevertheless, limits to the correspondence between changes in the momenta of the two bodies exist at both ends of the spectrum resolvable by the data. It is shown that, at high frequencies, changes in the length of day as short as a fortnight can now be attributed almost entirely to atmospheric forcing; more rapid fluctuations in the length of day, however, cannot be shown to coincide with atmospheric behavior, a result blamed mostly on errors remaining in both the geodetic and atmospheric series rather than on the neglect of some other component of the momentum budget. On the decadal time scale, nonatmospheric processes, believed primarily to involve core-mantle coupling, dominate the global momentum budget.

Rosen, Richard D.↗

Geodynamo Modeling of Core-Mantle Interactions

Angular momentum exchange between the Earth's mantle and core influences the Earth's rotation on time scales of decades and longer, in particular in the length of day (LOD) which have been measured with progressively increasing accuracy for the last two centuries. There are four possible coupling mechanisms for transferring the axial angular momentum across the core-mantle boundary (CMB): viscous, magnetic, topography, and gravitational torques. Here we use our scalable, modularized, fully dynamic geodynamo model for the core to assess the importance of these torques. This numerical model, as an extension of the Kuang-Bloxham model that has successfully simulated the generation of the Earth's magnetic field, is used to obtain numerical results in various physical conditions in terms of specific parameterization consistent with the dynamical processes in the fluid outer core. The results show that depending on the electrical conductivity of the lower mantle and the amplitude of the boundary topography at CMB, both magnetic and topographic couplings can contribute significantly to the angular momentum exchange. This implies that the core-mantle interactions are far more complex than has been assumed and that there is unlikely a single dominant coupling mechanism for the observed decadal LOD variation.

Kuang, Wei-Jia↗