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Results for “aqueous battery”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

The electrochemical fluorination of polymeric materials for high energy density aqueous and non-aqueous battery and fuel cell separators

A computerized system was established and the electrochemical fluorination of trichloroethylene, polyacrylic acid and polyvinyl alcohol in anhydrous hydrogen fluoride was attempted. Both solid substrates as well as membranes were used. Some difficulties were found in handling and analyzing the solid substrates and membranes. Further studies are needed in this area. A microprocessor aided electrochemical fluorination system capable of obtaining highly reproducible experimental results was established.

Liu, C. C.↗

Aqueous, QUick-Charging Battery Integration For Electric Flight Research

AQUIFER establishes technical feasibility of an early-stage technology, a high-energy density, aqueous-based, flow battery, resulting in a near-term increase of 1.7 times range over an all-electric battery, while retiring fire and explosion hazards associated with lithium-based chemistries. The Nano-electrofuel (NEF) flow battery will be integrated with a rim-driven motor (RDM) as a multi-functional design to eliminate conductive EMI and weight from long cable runs, and provide liquid cooling from the aqueous fuel. When successful, the technology provides an improved safety energy storage solution for emission-free electric propulsion in commercial aviation.

power systems↗

Advanced Vehicle system concepts

Various nonpetroleum vehicle system concepts for passenger vehicles in the 1990's are being considered as part of the Advanced Vehicle (AV) Assessment at the Jet Propulsion Laboratory. The vehicle system and subsystem performance requirements, the projected characteristics of mature subsystem candidates, and promising systems are presented. The system candidates include electric and hybrid vehicles powered by electricity with or without a nonpetroleum power source. The subsystem candidates include batteries (aqueous-mobile, flow, high-temperature, and metal-air), fuel cells (phosphoric acid, advanced acids, and solid polymer electrolyte), nonpetroleum heat engines, advanced dc and ac propulsion components, power-peaking devices, and transmissions.

Hardy, K. S.↗

Advanced Small Rechargeable Batteries

Lithium-based units offer highest performance. Paper reviews status of advanced, small rechargeable batteries. Covers aqueous systems including lead/lead dioxide, cadmium/nickel oxide, hydrogen/nickel oxide, and zinc/nickel oxide, as well as nonaqueous systems. All based on lithium anodes, nonaqueous systems include solid-cathode cells (lithium/molybdenum disulfide, lithium/titanium disulfide, and lithium/vanadium oxide); liquid-cathode cells (lithium/sulfur dioxide cells); and new category, lithium/polymer cells.

Halpert, Gerald↗

Design and Development of Nano-electro Fuel Batteries and Rim-driven Motors for Electrified Aircraft Applications

The National Aeronautics and Space Administration Convergent Aeronautics Solutions project seeks to determine feasibility of emerging technologies in aeronautics. The Aqueous, QUick-Charging Battery Integration For Electric flight Research study pursued the feasibility of nano-electro fuel and rim-driven motor technologies integrated together for aircraft implementation. Development of the NEF technology was in partnership with Influit Energy, LLC (Chicago, Illinois). A rim-driven motor, designed by the project team, sized to represent one of 24 motors in the propulsion system of the tandem electric super-short takeoff and landing aircraft is discussed. The development of this electric super-short takeoff and landing concept was in partnership with The Boeing Company (Chicago, Illinois). The integrated system design of the nano-electro fuel and rim-driven motor technologies within the wing section was in partnership with Empirical Systems Aerospace, Inc. (ESAero) (San Luis Obispo, California). The feasibility benchmark for the nano-electro fuel battery was to attain 100 mA/sq. cm within two years, a 50-fold increase over the demonstrated cell performance before the Convergent Aeronautics Solutions Aqueous, QUick-Charging Battery Integration For Electric flight Research activity. The team achieved 85 mA/sq. cm in the nano-electro fuel flow cell at the end of the two years. The Aqueous, QUick-Charging Battery Integration For Electric flight Research project team determined the technology to be both inflammable and nonexplosive (unless multiple, simultaneous system failures occur) which would provide a safer alternative to conventional lithium-ion based battery systems.

Kurt V. Papathakis↗

AQUIFER Nano-Electrofuel Energy Economy and Powered Aircraft Operations

The Aqueous, QUick-charging battery Integration For Electric flight Research project is explained and the major subsystems are described, including nano-electric fluid, rim-driven motors, and integration concepts. The nano-electric fluid concept is a new type of aqueous flow battery that could reduce or retire the fire and explosion hazards of conventional batteries and fuel cells. The nano-electric fluid itself could enable energy storage and increased available energy per fuel weight ratios. The rim-driven motor is being developed to improve propulsion system safety and stability and to reduce noise. The rim-driven motor concept could enable motors that are more efficient both electrically and aerodynamically. The Energy Economy of the project concept is presented as a potential renewable or green energy sustainment for utilizing in-place infrastructure. The nano-electric fluid energy charge-use-recharge cycle is presented using renewable energy input from solar, wind, and hydroelectricity. Powered aircraft operations are presented, and the logistics of the new nano-electric fluid technology are explored. Powered aircraft operations topics include weight and balance, fueling, recharging, safety, and derivative considerations.

Lechniak, Jason A.↗

State-of-charge coulometer

A coulometer for accurately measuring the state-of-charge of an open-cell battery utilizing an aqueous electrolyte, includes a current meter for measuring the battery/discharge current and a flow meter for measuring the rate at which the battery produces gas during charge and discharge. Coupled to the flow meter is gas analyzer which measures the oxygen fraction of the battery gas. The outputs of the current meter, flow meter, and gas analyzer are coupled to a programmed microcomputer which includes a CPU and program and data memories. The microcomputer calculates that fraction of charge and discharge current consumed in the generation of gas so that the actual state-of-charge can be determined. The state-of-charge is then shown on a visual display.

Rowlette, J. J.↗

Hydrophobic, Porous Battery Boxes

Boxes made of porous, hydrophobic polymers developed to contain aqueous potassium hydroxide electrolyte solutions of zinc/air batteries while allowing air to diffuse in as needed for operation. Used on other types of batteries for in-cabin use in which electrolytes aqueous and from which gases generated during operation must be vented without allowing electrolytes to leak out.

Bragg, Bobby J.↗

The Research and Development of a Soluble Reactants and Products Secondary Battery System

A redox battery system which employs an aqueous dectrolyte is developed. Results are presented of the following experimental studies (1) measurement of the essential physical and chemical properties of the reactants and products; (2) evaluation of commerically available anion membranes as the cell separator, (3) determination of the composition and degradation mechanism of the anion membrane, and/or developing an anion membrane separator; and (4) evaluation of the performance of prototype secondary battery systems.

Liu, C. C.↗

Progress of Aluminum/Air Battery Development for SUSAN Electrofan Project

Safe and high-performance battery technologies are demanded by the Subsonic Single Aft eNgine (SUSAN) Electrofan concept design project under National Aeronautics and Space Administration (NASA) electrified aircraft development program. Aluminum (Al)-air battery with very high theoretical specific energy density, is considered as promising battery chemistry which has the potential to meet the targeted specific energy goal of primary battery energy technology for the SUSAN project. In addition to having the exceptional electrochemical properties, aluminum is light weight, rich abundance, low cost, environmentally friendly, and has a good electrical conductivity and recyclability, which is among the key characteristics of SUSAN project on battery energy needs. A non-flammable aqueous electrolyte is used to prevent the fire and thermal runaway hazard for the safety of this battery chemistry. However, there are challenges for Al-air battery in practical application, mainly due to self-corrosion of Al and slow kinetics of oxygen reduction in air-cathode to impact the high-rate performance. Progress on addressing these challenges was made and some of the results were reported in our previous paper. In this paper, the focus is on the investigation of various factors, including electrolyte concentrations, temperature, and air-cathode loadings on ionic transport properties and discharge performance at different current densities. The results are discussed, and the progress is reported.

James J Wu↗

In-situ cross linking of polyvinyl alcohol

A method of producing a crosslinked polyvinyl alcohol structure, such as a battery separator membrane or electrode envelope is described. An aqueous solution of a film-forming polyvinyl alcohol is admixed with an aldehyde crosslinking agent a basic pH to inhibit crosslinking. The crosslinking agent, perferably a dialdehyde such as glutaraldehyde, is used in an amount of from about 1/2 to about 20% of the theoretical amount required to crosslink all of the hydroxyl groups of the polymer. The aqueous admixture is formed into a desired physical shape, such as by casting a sheet of the solution. The sheet is then dried to form a self-supporting film. Crosslinking is then effected by immersing the film in aqueous acid solution. The resultant product has excellent properties for use as a battery separator.

Philipp, W. H.↗

Positive electrode processing for Hughes NiH2 cells

The basic procedures were developed for the manufacture of nickel cadmium batteries. An electrochemical impregnation in an aqueous ethanol solution is used in this process. Several additional controls were instituted for production of flight electrodes, including a Hughes controlled MCD, a solution reserved exclusively for the impregnation of Hughes positive electrodes a system of complete traceability for individual electrodes, an electrical characterization test to provide information on weight and capacity at the plaque level, and a stress test to provide data on capacity, weight, and physical parameters at the electrode level.

Bleser, C. A.↗

Chemically rechargeable battery

Batteries (50) containing oxidized, discharged metal electrodes such as an iron-air battery are charged by removing and storing electrolyte in a reservoir (98), pumping fluid reductant such as formalin (aqueous formaldehyde) from a storage tank (106) into the battery in contact with the surfaces of the electrodes. After sufficient iron hydroxide has been reduced to iron, the spent reductant is drained, the electrodes rinsed with water from rinse tank (102) and then the electrolyte in the reservoir (106) is returned to the battery. The battery can be slowly electrically charged when in overnight storage but can be quickly charged in about 10 minutes by the chemical procedure of the invention.

Graf, James E.↗

Process of treating cellulosic membrane and alkaline with membrane separator

The improvement of water-soluble cellulose ether membranes for use as separators in concentrated alkaline battery cells is discussed. The process of contacting membranes with an aqueous alkali solution of concentration less than that of the alkali solution to be used in the battery but above that at which the membrane is soluble is described.

Hoyt, H. E.↗