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Cascade mountains volcanic ash deposits elemental abundances correlation by computerized gamma ray spectra analysis of TRIGA reactor activated glass separates
There is increased interest in, and concern about, deposition and corrosion phenomena in combustion systems containing inorganic condensible vapors and particles (salts, ash). To meet the need for a computationally tractable deposition rate theory general enough to embrace multielement/component situations of current and future gas turbine and magnetogasdynamic interest, a multicomponent chemically 'frozen' boundary layer (CFBL) deposition theory is presented and its applicability to the special case of Na2SO4 deposition from seeded laboratory burner combustion products is demonstrated. The coupled effects of Fick (concentration) diffusion and Soret (thermal) diffusion are included, along with explicit corrections for effects of variable properties and free stream turbulence. The present formulation is sufficiently general to include the transport of particles provided they are small enough to be formally treated as heavy molecules. Quantitative criteria developed to delineate the domain of validity of CFBL-rate theory suggest considerable practical promise for the present framework, which is characterized by relatively modest demands for new input information and computer time.
Several large paterae in Arabia Terra are suggested to be calderas that produced colossal explosive eruptions (i.e., supereruptions). If these features are indeed explosive calderas, dispersion modeling suggests extensive ash deposits should be common throughout the region. However, such deposits have not previously been linked with the suggested calderas. Here, we describe layered deposits containing minerals both consistent with and diagnostic of altered volcanic ash throughout Arabia Terra. These deposits include Al-dominant minerals such as montmorillonite, imogolite, and allophane among others. Altered ash deposits are found to thin (from 1-km to 100-m thickness) away from the suggested calderas. We estimate that the volcanic ash observed in Arabia Terra is the result of between 1,000 and 2,000 individual explosive eruptions over 500-million years. Our observations support the hypothesis that Arabia Terra hosted supereruptions in the late Noachian-early Hesperian that repeatedly blanketed the region with layers of ash.
Geologic mapping of high-resolution (30-50 m/pixel) Viking Orbiter images of northern Elysium Planitia has identified seven sites where current problems in martian volcanology, chronology, and stratigraphy can be resolved. These sites, which are discussed in the context of a potential Mars rover/sample return mission, would permit the following investigations: (1) the dating of Lower Amazonian lava flows from Elysium Mons (thereby providing absolute calibration for global crater size/frequency relative chronologies, (2) the petrologic investigation of long run-out lava flows, (3) the geologic interpretation of materials that may either be lava flows or lahar deposits, (4) the analysis of materials believed to be ash deposits produced by explosive eruptions of Hecates Tholus, and (5) the investigation of the stratigraphy of fractured terrain along the boundary between northern Elysium Planitia and southern Utopia Planitia.
The downwind deposition and radiation doses was calculated for the tropospheric part of the ash cloud from the May 18, 1980 eruption of Mount St. Helens, by using a large cloud diffusion model. The naturally occurring radionnuclides of radium and thorium, whose radon daughters normally seep very slowly from the rocks and soil, were violently released to the atmosphere. The largest dose to an individual from these nuclides is small, but the population dose to those affected by the radioactivity in the ash is about 100 person rem. This population dose from Mount St. Helens is much greater than the annual person rem routinely released by a typical large nuclear power plant. It is estimated that subsequent eruptions of Mount St. Helens have doubled or tripled the person rem calculated from the initial large eruption. The long range global ash deposition of the May 18 eruption is estimated through 1984, by use of a global deposition model. The maximum deposition is nearly 1000 kg square km and occurs in the spring of 1981 over middle latitudes of the Northern Hemisphere.
The proposed site is the northernmost occurrence of the Medusae Fossae Formation (MFF), and lies at or below the -2 km contour. The MFF is the famous radar 'stealth' deposit that extends from south of Olympus Mons westward across southern Amazonis Planitia to southern Elysium Planitia. The MFF appears to be composed of some kind of wind-eroded friable material, the origin of which is very problematic. It appears to be a radar-absorbing material, whereas Mars' south polar layered deposits appear bright in the same scenes. Synthetic aperture radar images of young terrestrial ash deposits in the Andes also appear relatively bright. The MFF's radar signature appears to require a uniformly fine-grained material (on the order of dust-sized to fine sand-sized) at least several meters thick, in order not to transmit reflections off underlying terrain or internal reflective horizons. The proposed Pathfinder landing site lies on a relatively smooth, 'unmodified' portion of the MFF, more than 100 km away from its northern and western edges, which exhibit evidence of eolian etching in the form of closely spaced yardings. There are no large craters or steep slopes within a few hundred kilometers of the landing site.
The microbial fossil record encompasses a wide range of information, including cellular remains, stromatolites, biofabrics, trace fossils, biominerals and chemofossils. The preservation of fossils is strongly influenced by the physical, chemical and biological factors of the environment which, acting together, ultimately determine the types of information that will be captured and retained in the rock record. The critical factor in assessing the suitability of a site for a microbial fossil record is the paleoenvironment. The reconstruction of ancient sedimentary environments usually requires the integration of a wide variety of geological information, including the shape, geometry and internal structure of sedimentary deposits, their mineralogy, and geochemistry. For Mars, much of our knowledge about past environments is based on orbital imaging of geomorphic features. This evidence provides an important context and starting point for site selection. However, our knowledge of the martian surface is quite limited, and a major goal of the upcoming exploration effort is to reconstruct the history of Martian volatiles, climate, and hydrology as a context for the exploration for past or present life. Mineralogical mapping from orbit will be an important key in this effort. In exploring for evidence of past life, terrestrial experience suggests that the long-term preservation of biological information as fossils occurs under a fairly narrow range of geological conditions that are well known to paleontologists (1). In detrital sedimentary systems, microbial fossilization is favored by rapid burial in fine-grained, clay-rich sediments. In chemical sedimentary systems, preservation is enhanced by rapid entombment in fine-grained chemical precipitates. For long term preservation, host rocks must be composed of stable minerals that resist chemical weathering, and which form an impermeable matrix and closed chemical system that can protect biosignatures from alteration during subsequent diagenetic change or metamorphism. In this context, host rocks composed of highly ordered, chemically-stable mineral phases, like silica (forming cherts) or phosphate (forming phosphorites), are especially favored. Such lithologies tend to have very long crustal residence times and (along with carbonates and shales), are the most common host rocks for the Precambrian microfossil record on Earth. If we assume that a subsurface hydrosphere has been present throughout martian history, then life could have originated there at any time, perhaps emerging at the surface periodically when climate changes, induced by external forcing or endogenous processes (e.g. volcanism), allowed liquid water to exist at the surface. The recent discovery of subsurface chemolithoautotrophic organisms which are capable of synthesizing organic substrates from C02 and H2 liberated from the aqueous weathering of basalt, is especially. relevant as a model for martian life. While a subsurface habitable zone may yet exist on Mars, access to such environments will likely require drilling to depths of several kilometers. Given the technological challenge of deep drilling, this is unlikely to occur prior to human missions. So, even if there is extant life on Mars today in subsurface habitats, it may be much easier to find its fossil counterparts in ancient deposits exposed at the surface. In exploring for a fossil record in subsurface environments on Mars there are several geological situations that may provide access to the appropriate materials. These include 1) ejecta from impact craters, 2) talus slopes, debris flows or alluvial fans developed below the walls of deep canyons, and 3) the deposits of outflood channels. Examples of aqueous mineral deposits of formed in subsurface environments that could harbor a microbial fossil record include such things as cements in detrital sedimentary rocks, low temperature diagenetic minerals deposited in veins, or filling vesicles in volcanic rocks, and hydrothermal deposits formed below the upper temperature limit for life (about 160 degrees C). There are many sites within the present latitudinal constraints for the 2001 mission (15 deg S to 30 deg N) that meet these requirements. But the practical problem with these kinds of deposits is that they tend to be disseminated, making up only a small percentage of a host rock. Even with mineralogical information provided by the Thermal Emission Spectrometer (TES) presently in orbit around Mars, predicting their occurrence ahead of time may be quite difficult. The deposits of surficial aqueous sedimentary systems are likely to provide the largest targets for site selection in 2001. Of these, the deposits of hydrothermal systems (subaerial and subaqueous thermal springs) have been discussed previously. It is likely that hydrothermal systems were widespread on Mars early in its history and a number of common geo-tectonic settings on Mars are likely to have hosted hydrothermal activity. Most of these are represented within the latitudinal constraints presently identified for 2001. However, the deposits of surface spring systems are likely to be difficult to find as well. On Earth, exposure areas for hydrothermal spring mounds are typically a few square kms, less than a single TES pixel. But such deposits may be quite abundant within some volcanic terrains, It is estimated, for example, that between 15-20% of the floor of Yellowstone caldera is covered by thermal spring deposits. In such abundances, subaerial sinters could well be detected by TES. Where exposed, the shallow subsurface portions of these systems may be quite a lot larger (perhaps tens of square kms), although (as noted above) mineralization may be finely disseminated in the basement rock, making remote detection more difficult. Paleolake Basins. There are a large number of potential paleolake basins on Mars (inclusive of impact craters and volcanic calderas) that have been previously identified using Viking images. Most of these lie in the southern highlands beyond the l5 deg S constraint for 2001. However, deposits of paleolakes may offer the largest and most easily identified exopaleontological targets from orbit. Based on a variety of arguments, some workers have suggested that there was once an ancient ocean on the northern plains, and some sites of interest (potential shoreline terraces) fall within the 30 deg N constraint. From a paleontological standpoint the most interesting places of this type are terminal paleolake basins which are likely to have been both saline and alkaline. Models by Schaefer suggest such environments could be widespread on Mars. The conditions in terminal lake basin settings favor widespread chemical sedimentation, an important condition for microbial fossilization. Important lithological targets for a microbial fossil record in terminal lake basins include spring-deposited carbonates, shoreline cements, a wide variety of evaporite minerals and fine-grained detrital sediments including shales, marls, and water-lain volcanic ash deposits. In developing a strategy to explore for ancient hydrothermal deposits on Mars, we can learn from the methods that have been developed by explorationists to explore for economic mineral deposits on Earth. Due to their simple mineralogy, hydrothermal deposits can often be detected using remote sensing methods. Common thermal spring mineral assemblages include silica, carbonate, and various metallic oxides and sulfides. But there are also a number of diagnostic silicate minerals, including clays, formed by the hydrothermal alteration of country rocks. These hydrothermal minerals have characteristic spectral signatures that could be detected from Mars orbit using high resolution infrared remote sensing methods. In playa lake settings, evaporite deposits often form a predictable "bull's eye" pattern with carbonates being deposited in marginal basin areas, and sulfates and halides occurring progressively more basinward. The floors of some impact craters on Mars, such as "White Rock" and Bequeral Crater (see Oxia Palus NE, Site 148), have floor deposits that could be evaporites, inclusive of carbonates. Evaporite minerals possess characteristic spectral signatures in the infrared and could similarly be identified from Mars orbit using high resolution remote sensing methods. Clearly, utilization of TES data will be important for optimizing site selection for Exopaleontology, and every effort should be made to benefit from that data before a final decision is made.
The study of volcanoes is important for both purely scientific and human survival reasons. From a scientific standpoint, volcanic gas and ash emissions contribute significantly to the terrestrial atmosphere. Ash depositions and lava flows can also greatly affect local environments. From a human survival standpoint, many people live within the reach of active volcanoes, and therefore can be endangered by both atmospheric (ash, debris) toxicity and lava flow. There are many potential information sources that can be used to determine how to best monitor volcanic activity worldwide. These are of varying temporal frequency, spatial regard, method of access, and reliability. The problem is how to incorporate all of these inputs in a general framework to assign/task/reconfigure assets to monitor events in a timely fashion. In situ sensing can provide a valuable range of complementary information such as seismographic, discharge, acoustic, and other data. However, many volcanoes are not instrumented with in situ sensors, and those that have sensor networks are restricted to a relatively small numbers of point sensors. Consequently, ideal volcanic study synergistically combines space and in situ measurements. This work demonstrates an effort to integrate spaceborne sensing from MODIS (Terra and Aqua), ALI (EO-1), Worldview-2, and in situ sensing in an automated scheme to improve global volcano monitoring. Specifically, it is a "sensor web" concept in which a number of volcano monitoring systems are linked together to monitor volcanic activity more accurately, and this activity measurement automatically tasks space assets to acquire further satellite imagery of ongoing volcanic activity. A general framework was developed for evidence combination that accounts for multiple information sources in a scientist-directed fashion to weigh inputs and allocate observations based on the confidence of an events occurrence, rarity of the event at that location, and other scientists' inputs. The software framework uses multiple source languages and is a general framework for combining inputs and incrementally submitting observation requests/reconfigurations, accounting for prior requests. The autonomous aspect of operations is unique, especially in the context of the wide range of inputs that includes manually inputted electronic reports (such as the Air Force Weather Advisories), automated satellite-based detection methods (such as MODVOLC and GOESVOLC), and in situ sensor networks.
The 1980 eruptions of Mount St. Helens in southeast Washington resulted in a pronounced effect on the surface and ground water resources of the state. In response to the volcanic activity, the U.S. Geological Survey intensified statewide surface and ground water sampling programs to determine the nature and magnitude of the volcanic-induced variations. Streams to the east of Mount St. Helens received the major ash fallout. Chemical effects were best noted in smaller streams sampled 60 to 70 miles northeast of Mount St. Helens. The chemical variations observed were pronounced but short lived. Sulfate and chloride increases in anionic composition were prevalent immediately following the eruption; however, the original bicarbonate predominance was again attained within several days. Suspended iron and aluminum concentrations were similarly elevated during the period of greatest ash deposition (highest turbidity); however, the dissolved concentrations remained relatively constant. Depressions of pH were minor and short lived. Streams draining to the south, tributaries to the Columbia river, showed little observable changes in water chemistry. Streams draining to the west (Toutle river and its tributaries) were compositionally affected by the various volcanic activities. Chloride and sulfate anion percentage exceeded the bicarbonate percentage up to one month following the eruption period. Streams and lakes sampled in the immediate vicinity of Mount St. Helens, in addition to trace metals, contained organic compounds derived from decomposing wood buried in the debris deposits. This organic material may constitute a significant source of organic compounds to surface and ground water for some time to come.
A brief review of the effects of climate and weather on the 1980 Mount St. Helens eruptions and the subsequent dispersion of ash and gases and the reciprocal influences of the eruptions on climate and climatology is presented. The effects of mesoscale destruction of snow fields and vegetation, a revised mountain profile, and ash deposits are addressed along with impacts on hemispheric climate and disruption of normal climatological observations, in the areas directly affected by the explosions and ashfall. Environmental and economic consequences are also considered.
From a reexamination of the medium and high-resolution Viking images of Amazonian and Hesperian age volcanic centers on Mars, it is believed that an excellent example of well-preserved explosive activity does indeed exist close to the summit of Hecates Tholus. A mantled region to the west of the summit caldera is seen as an example of a geologically very recent plinian air fall ash deposit. Morphological evidence is presented for describing this as explosively generated material, and numerical models of magma ascent and eruption in the Martian environment are used to estimate the physical characteristics (eruption cloud height, magma discharge rate, magma volatile content, duration of activity, and vent size) for this event. Attention is also given to the implication of this eruptive style for the composition of the erupted magma.
The results of analyses of near infrared reflectance spectra are inconsistent with numerous previous interpretations of the Reiner Gamma Formation. These include: (1) nue ardente or volcanic ash deposits, (2) volcanically derived sublimates, (3) high albedo volcanic deposits, and (4) highlands debris emplaced as impact ejecta. These results, strongly suggest that the selective preservation of high albedo features (formed by secondaries) by a local magnetic field enhancement is not a viable hypothesis. The results are generally consistent with, but place constraints on, the cometary impact hypothesis of Schultz and co-workers. While the presence of a magnetized component was not detected in either the bright or dark portions of the Reiner Gamma Formation, this material may be present in amounts under the current detection limits.
Several alternative models were proposed for the origin and mode of formation of channels and valley networks on Martian volcanoes, notably Hecates Tholus, Ceraunius Tholus, and Alba Patera. Early interpretations of Mariner 9 and Viking images suggested that these features on Alba were lava channels, while those on Ceraunius Tholus were interpreted as fluvial or volcanic debris channels. Subsequent mapping of Tyrrehna Patera and Hecate Tholus has suggested that pyroclastic activity may have characterized eruptions on these volcanoes, and that at least for Hecates the channels were probably formed by fluvial erosion of unconsolidated ash deposits on the flanks of the volcano. As part of a continuing program to better understand the eruptive history of the young volcanic centers on Mars, numerous channels were identified on the flanks of Alba Patera that resemble the channels on Hecates. As a result, the possibility is being explored that some of the small channels on the flanks of Alba Patera may be fluvial in origin and potentail water sources and modes of formation are being explored.
The Martian surface exhibits numerous volcanic landforms displaying great diversity in size, age, and morphology. Most research regarding Martian volcanology has centered around effusive basaltic volcanism, including analyses of individual lava flows, extensive lava plains, and large shield volcanoes. These studies were hindered by a lack of definitive morphologic criteria for the remote identification of ash deposits. Knowledge of the abundances, ages, and geologic settings of explosive volcanic deposits on Mars is essential to a comprehensive understanding of the evolution of the Martian surface, with implications for the evolution of the lithosphere and atmosphere as well as the histories of specific volcanic centers and provinces.
Remote sensing measurements provide information about the Martian surface at scales smaller than can be inferred from imaging data alone. Measurements of Martian volcanoes obtained at visual, infrared, and radar wavelengths are discussed in order to evaluate the physical properties. A related issue involves identifying possible ash deposits by distinctive or anomalous physical characteristics.
The analysis of samples of volcanic ash dust layers from the Lewis Cliff/Beardmore Glacier in Antarctica shows that some of the samples contain Ir concentrations up to 7.5 ppb. It is shown that the Ir is positively correlated with Se, As, Sb, and other volcanogenic elements. The results show that Ir may be present in some volcanic ash deposits, suggesting that the Ir in the K/T boundary clays is not necessarily of cosmic origin, but may have originated from mantle reservoirs tapped during extensive volcanic eruptions possibly triggered by impact events.
The focus of our investigation was on the application of digital topographic data in conducting first-order volcanological and structural studies of tropical volcanoes, focusing on the Java, the Philippines and the Galapagos Islands. Kilauea volcano, Hawaii, served as our test site for SRTM data validation. Volcanoes in humid tropical environments are frequently cloud covered, typically densely vegetated and erode rapidly, so that it was expected that new insights into the styles of eruption of these volcanoes could be obtained from analysis of topographic data. For instance, in certain parts of the world, such as Indonesia, even the regional structural context of volcanic centers is poorly known, and the distribution of volcanic products (e.g., lava flows, pyroclastic flows, and lahars) are not well mapped. SRTM and Vegetation Canopy Lidar (VCL) data were expected to provide new information on these volcanoes. Due to the cancellation of the VCL mission, we did not conduct any lidar studies during the duration of this project. Digital elevation models (DEMs) such as those collected by SRTM provide quantitative information about the time-integrated typical activity on a volcano and allow an assessment of the spatial and temporal contributions of various constructional and destructional processes to each volcano's present morphology. For basaltic volcanoes, P_c?w!m-d and Garbed (2000) have shown that gradual slopes (less than 5 deg.) occur where lava and tephra pond within calderas or in the saddles between adjacent volcanoes, as well as where lava deltas coalesce to form coastal plains. Vent concentration zones (axes of rift zones) have slopes ranging from 10 deg. to 12 deg. Differential vertical growth rates between vent concentration zones and adjacent mostly-lava flanks produce steep constructional slopes up to 40". The steepest slopes (locally approaching 90 deg.) are produced by fluvial erosion, caldera collapse, faulting, and catastrophic avalanches, all of which are usually identifiable. Due to the delay in the release of the SRTM data following the February 2000 flight, a significant part of our effort was devoted to the analog studies of the SRTM topographic data using topographic data from airborne interferometric radars. As part of the original SRTM Science Team, we proposed four study sites (Kilauea, Hawaii; Mt. Pinatubo, Philippines; Cerro Am1 and Femandina volcanoes, Galapagos Islands; and Tengger caldera, Java) where we could conduct detailed geologic studies to evaluate the uses of SRTM data for the analysis of lava flows, lahars, erosion of ash deposits, and an evaluation of the structural setting of the volcanoes. Only near the end of this project was one of these SRTM Science Team products (Luzon Island, the Philippines) released to the community, and we only had limited time to work on these data.
This project focused on the evolution of the summit areas of Martian volcanoes. By using data collected from the Mars Orbiter Camera (MOC) and Mars Laser Altimeter (MOLA) instruments, we tried to better understand the diversity of constructional volcanism on Mars, and hence further understand eruption processes. We investigated the styles of volcanism on the major volcanic constructs (Olympus, Arsia, Pavonis, and Ascraeus Montes), and also studied the role of magma-volatile interactions within the shallow subsurface of these volcanoes and the surrounding areas. Theoretical models for internal processes within volcanoes, including the thermal influences of dike intrusions on pre-existing volatiles, were developed based on our identification of landform distributions. Our work provided new insights into the diversity of volcanism on Mars, and the distribution of Martian volatiles in space and time. Highlights of our results include: 1) The identification of large ash deposits at the summit of Arsia Mons; 2) The study of a large flank eruption on Elysium Mons and the estimation of the effusion rate needed to produce the observed lava channel; 3) The quantitative description of dike intrusion into volatile-rich terrain to explain the origin of Hrad Vallis; 4) The identification of constructional ridges on top of very young lava flows from Olympus Mons, with the interpretation that these ridges were formed by very recent phreatomagmatic eruptions; and 5) The characterization of the dimensions and slope distributions on 18 volcanic edifices on Mars.