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At least 19 records

Basin-wide gradients in dolomite d26Mg and 87Sr/86Sr identify the structural centre of the Williston Basin as a source of magnesium for dolomitization of the Middle Devonian Winnipegosis Formation

Dolomitized carbonates in the Williston Basin are common below the Middle Devonian Prairie Evaporite Formation, indicating a plausible role for brine-reflux as the source of Mg for dolomitization. However, the Lower Member Winnipegosis Formation, which directly underlies the evaporite sequence, exhibits dolomite 87Sr/86Sr ratios that are higher than expected for Middle Devonian seawater, instead suggesting that the dolomitizing fluids ascended from the deep basin where present-day formation waters are known to be more radiogenic. This interpretation is supported in this study by Mg isotope data showing a basin-scale gradient of increasing d26Mg values from the deep center (–2.03‰) to the edge (–1.34‰) of the Williston Basin along the lower Member Winnipegosis bed. Dolomite favors light isotopes of Mg when it forms, thus driving dolomitizing solutions, and the produced dolomite, towards heavier isotopic compositions in the direction of fluid flow. However, dolomite is also Mg-deficient when it forms, and its initial Mg isotope composition is susceptible to alteration by fluid-rock interactions occurring later in the depositional history of the deposit. We argue that the Mg isotope gradient in the Lower Member Winnipegosis was created by an ascending flow of isotopically light Mg-bearing fluid that differentially altered an earlier formed brine-reflux dolomite, with more alteration occurring deeper in the basin and less towards to edges. Alteration of pre-existing dolomite by an Mg isotope exchange mechanism requires large supplies of Mg. This fact, and the direction of fluid flow point to the underlying crystalline basement as an important Mg source for dolomitization in the Williston Basin. We speculate that ultramafic rocks supplied the Mg when they were hydrothermally altered during an anomalous heating event that affected the Williston Basin in the Late Devonian / Early Carboniferous. Seismic pumping drove these fluids upwards through fracture networks in the crust, and eventually into the deep center of the Williston Basin along vertically-oriented down-to-the-basement faults, pressuring deep aquifers like the Winnipegosis, which resulted in fluids migrating up the stratigraphic dip of the beds towards the edges of the basin. Plotting and contouring the dolomite d26Mg data on a map of the Williston Basin reveals the pathways taken by the migrating fluids. One prominent pathway extending outwards from the center of the basin towards the northeast bears a strong resemblance to petroleum migration fairways deduced for the underlying Late Ordovician Red River Formation. This study demonstrates that Mg isotopic mapping of large dolomite bodies is a useful tool for deciphering fluid flow histories in sedimentary basins and may assist in locating migrated petroleum and Mississippi Valley Type ore deposits.

Magnesium Isotopes, Strontium Isotopes, Dolomitiza↗

Flood Inundation Generation Mechanisms and Their Changes in 1953-2004 in Global Major River Basins

Despite the serious threats posed by floods, the driving mechanisms of floods are still not well understood. Here, we apply a physically-based inundation model coupled with a river routing model (Model for Scale Adaptive River Transport, MOSART) within the Energy Exascale Earth System Model (E3SM) framework to investigate flood inundation dynamics. After calibration using observed streamflow and satellite-derived flood extent, the model is used to simulate global flood inundation from 1953 to 2004. The mean date and seasonality of annual maximum flood, defined based on flood extent, exhibit significant regional differences across 16 major basins. Generally, soil moisture and monthly maximum daily rainfall (MMR) are the dominant drivers of flood in tropical basins while monthly maximum daily snowmelt (MMS) is the dominant driver in high latitude basins. From 1953-1982 to 1975-2004, significant changes in flood generation mechanisms are found in some basins such as Amazon, Lena, Yenisey, and Kolyma. Analysis of the rainfall seasonality and water balance at grid scale reveals a stronger rainfall seasonality in the Amazon during the later period that increases the synchrony between extreme rainfall and wet soil. With high antecedent soil moisture coinciding with rainfall, MMR contributes more to flood in the later period. Fewer extreme rainfall events and increasing soil moisture reduced the contribution of MMR and increased the role of MMS in floods in the Lena and Yenisey basins, respectively. Lastly, increased soil moisture and frequency of large MMS reduced the contribution of the latter to floods in the Kolyma basin.

Mao, Yuna↗

HydroFish: freshwater fish co-occurrence with hydropower plants and non-powered dams in conterminous United States sub-basins

The HydroFish dataset lists all existing hydropower plants (EHAs) and non-powered dams (NPDs; ≥ 0.001 MW potential nominal capacity), delineates the hydrologic sub-basins in which they are situated, and then lists all freshwater fish species reported to occur in those sub-basins. This dataset was compiled using the HydroBio dataset (https://hydrosource.ornl.gov/data/datasets/hydrobio/) and contains 24 total variables that describe hydrologic sub-basins, each unique EHA (plant ID and name, geographic coordinates, permit type, capacity, etc.) and NPD (ID value, known names, geographic coordinates, and estimated potential nominal capacity), and freshwater fish species in the sub-basin (common and scientific name, origin, and migratory and threat status). The HydroBio dataset was built using Oak Ridge National Laboratory’s Existing Hydropower Assets Dataset (2024 version) and Non-powered Dam Technical Potential Dataset (2024 version), and NatureServe’s fish species distribution dataset (2023 version). The dataset also contains summary variables that report the unique number of EHAs, NPDs, and freshwater fish species per sub-basin. The HydroFish dataset contains two unique data files: 1) a .csv metadata file describing the dataset variables, and 2) a .csv data file containing the actual dataset. Note that there may be many rows per unique existing hydropower plant or non-powered dam given that distinct species are listed per existing plant or NPD per sub-basin. The dataset is downloadable as a zip file containing the metadata and dataset files.

Bozeman, Bryan [Oak Ridge National Laboratory (ORN↗

HydroBio: Hydropower Capacity and Freshwater Biodiversity in Conterminous United States Sub-basins

This dataset summarizes existing and potential hydropower capacity and freshwater biodiversity at the sub-basin level throughout the conterminous United States (CONUS). It contains descriptive information regarding each sub-basin (e.g., 8-digit hydrologic unit code identifier, name, states, and size) along with sub-basin-level summaries of: 1) existing hydropower capacity (MW), 2) potential nominal non-powered dam (NPD) capacity (MW), 3) potential capacity of new stream reach development (NSD) (MW), and 4) freshwater biodiversity, including the total richness of fish, crayfish, and mussels and metrics that account for how rare and threatened those species tend to be. Hydropower data were obtained from Oak Ridge National Laboratory data resources (Existing Hydropower Assets, Non-Powered Dam Technical Potential, and New Stream Reach Development). Freshwater biodiversity data were obtained from NatureServe. Sub-basin characteristic information was obtained from the United States Geological Survey. Additionally, long data that provide lists of unique elements within each sub-basin for each constituent data resource (e.g., NatureServe, Existing Hydropower Assets) are provided to enhance dataset utility for users. The dataset provides, for the first time, a national-level assessment of existing and potential hydropower capacity in the context of freshwater biodiversity and is a valuable resource for stakeholders tasked with providing affordable, reliable energy to the American public while maintaining or enhancing invaluable freshwater resources. The dataset contains six data files in comma separated (*.csv) format that are within a zipped file.

Bozeman, Bryan [Oak Ridge National Laboratory (ORN↗

Amplicon Sequencing Reveals Microbiological Signatures in Spent Nuclear Fuel Storage Basins

Water quality is an important determinant for the structural integrity of alloy cladded fuels and assemblies during long-term wet storage. Detailed characterization of a water filled storage basin for spent nuclear reactor fuel was performed following the formation and proliferation of an amorphous white flocculent. White precipitant was sampled throughout the storage basin for chemical and spectroscopic characterization, and eDNA was extracted for pyrosequencing of bacterial rRNA gene diversity. Accordingly, spectroscopic analyses indicated the precipitant to be primarily amorphous to crystalline aluminum (oxy) hydroxides with minor associated elemental components including Fe, Si, Ti, and U. High levels of dissolved carbon were co-localized with the precipitant relative to bulk water. Bacterial densities were highly variable between sampling locations and with depth; cell numbers (log scale) ranged from 5.6 to 4.89 cells / mL. Bacterial diversity that was physically associated with the aluminum (oxy) hydroxide complexes exceeded an estimated 4,000 OTUs / amplicon library (3% cutoff) and the greatest percent majority of sequences were aligned to the families Burkholderiales (23%), Nitrospiraceae (23%), Hyphomicrobiaceae (17%), and Comamonadaceae (6%). We surmise that episodic changes in the physical and chemical properties of the basin contribute to the polymerization of aluminum (oxy) hydroxides, which in turn can chemisorb nutrients, carbon ligands and bacterial cells from the surrounding bulk aqueous phase. As such, these precipitants should establish favorable microhabitats for bacterial colonization and growth. Comparative analyses of 16S rRNA gene amplicon libraries across diverse environmental landscapes were performed and microbiological signatures unique to the spent nuclear fuel storage basin environment were revealed. These insights could spur the development of tractable bioindicators that are specific of and diagnostic for water quality at discrete locations and finer scales of resolution, marking an important contribution for improved water quality and management of spent nuclear fuel storage facilities.

aluminum↗

Analysis of Seismic Wave Amplification in Sedimentary Basins Using 3D Wavefield Simulations: Nenana Basin, Central Alaska

We investigate seismic wave amplification in Nenana basin, central Alaska, using 3D seismic wavefield simulations. We quantify frequency-dependent amplification by comparing synthetic seismograms among four different seismic velocity models: (a) a tomographic model, (b) a tomographic model with the uppermost 6.5 km replaced by a 1D basin profile, (c) a tomographic model with an embedded ellipsoidal basin, and (d) a tomographic model with an embedded realistic basin. For each model we perform wavefield simulations accurate up to 2 Hz for a set of 10 different earthquakes, which provide a range of frequencies and incident angles for waves interacting with the basin. Average amplification ratios are four on the horizontal components and seven on the vertical component. The dominant influence of the amplification is the 3D geometry of the basin, not the slow-velocity profile near the surface. Our synthetic amplification ratios are in general agreement with amplification estimates obtained from 14 stations that recorded the same set of earthquakes. Our approach offers a general strategy for documenting frequency-dependent basin amplification for a region with realistic basin structures and local earthquakes.

Geosciences↗

BASIN-3D: A brokering framework to integrate diverse environmental data

Diverse observational and simulation datasets are needed to understand and predict complex ecosystem behavior over seasonal to decadal and century time-scales. Integration of these datasets poses a major barrier towards advancing environmental science, particularly due to differences in the structure and formats of data provided by various sources. Here, we describe BASIN-3D (Broker for Assimilation, Synthesis and Integration of eNvironmental Diverse, Distributed Datasets), a data integration framework designed to dynamically retrieve and transform heterogeneous data from different sources into a common format to provide an integrated view. BASIN-3D enables users to adopt a standardized approach for data retrieval and avoid customizations for the data type or source. We demonstrate the value of BASIN-3D with two use cases that require integration of data from regional to watershed spatial scales. The first application uses the BASIN-3D Python library to integrate time-series hydrological and meteorological data to provide standardized inputs to analytical and machine learning codes in order to predict the impacts of hydrological disturbances on large river corridors of the United States. The second application uses the BASIN-3D Django framework to integrate diverse time-series data in a mountainous watershed in East River, Colorado, United States to enable scientific researchers to explore and download data through an interactive web portal. Thus, BASIN-3D can be used to support data integration for both web-based tools, as well as data analytics using Python scripting and extensions like Jupyter notebooks. The framework is expected to be transferable to and useful for many other field and modeling studies.

Varadharajan, C↗

Machine Learning Classification Strategy to Improve Streamflow Estimates in Diverse River Basins in the Colorado River Basin

Streamflow in the Colorado River Basin (CRB) is significantly altered by human activities including land use/cover alterations, reservoir operation, irrigation, and water exports. Climate is also highly varied across the CRB which contains snowpack-dominated watersheds and arid, precipitation-dominated basins. Recently, machine learning methods have improved the generalizability and accuracy of streamflow models. Previous successes with LSTM modeling have primarily focused on unimpacted basins, and few studies have included human impacted systems in either regional or single-basin modeling. We demonstrate that the diverse hydrological behavior of river basins in the CRB are too difficult to model with a single, regional model. We propose a method to delineate catchments into categories based on the level of predictability, hydrological characteristics, and the level of human influence. Lastly, we model streamflow in each category with climate and anthropogenic proxy data sets and use feature importance methods to assess whether model performance improves with additional relevant data. Overall, land use cover data at a low temporal resolution was not sufficient to capture the irregular patterns of reservoir releases, demonstrating the importance of having high-resolution reservoir release data sets at a global scale. On the other hand, the classification approach reduced the complexity of the data and has the potential to improve streamflow forecasts in human-altered regions.

54 ENVIRONMENTAL SCIENCES↗

Geothermal Play Fairway Analysis of Low-Temperature Resources for Sedimentary Basin Geothermal Play Types: An Example in the Denver Basin

This project is part of a nationwide effort to highlight the advantages of incorporating low-temperature geothermal resource evaluation into the implementation of combined heat and power (CHP), and geothermal direct use (GDU) technologies (e.g., space heating and/or cooling). The initiative aims to hasten the nation's decarbonization process by exploring the potential for using low-temperature geothermal resources (< 150 Degrees Celsius) in selected sedimentary basins that have several population centers. The Play Fairway Analysis (PFA) techniques were modified from earlier studies of sedimentary basin geothermal play types (SBGPTs) that assessed the viability of low-temperature resources. The decision-making process for leveraging low-temperature geothermal resources for GDU and CHP applications is complex and considers a variety of factors, including geological, economic, and risk criteria. This study covers workflows, relevant datasets, python code, and both common and composite maps used to create low-temperature geothermal resource favorability maps for the Denver Basin, which extends across Colorado, Nebraska, and Wyoming. The replication of these methodologies in other SBGPTs can evaluate potential for low-temperature resources. The proposed geothermal PFA approach for low-temperature geothermal resources includes: (1) identifying available relevant data and grouping data sets into PFA criteria (e.g., geological, economic, and risk criteria); (2) analyzing data gaps enable future focalized exploration; (3) performing uncertainty quantification; (4) weighting relevant data; (5) developing favorability and common risk maps for low-temperature geothermal resources to identify potential locations for more focused data collection. This project will facilitate future deployment of CHP and GDU by providing data, tools, and a workflow applicable to low-temperature geothermal resources in sedimentary basins.

15 GEOTHERMAL ENERGY↗

The Power Reclamation of Utilizing Micro-Hydro Turbines in the Aeration Basins of Wastewater Treatment Plants

Upgrading the aeration basin technology can improve the oxygen transfer efficiency (OTE), while keeping the energy consumption at its minimum level. Therefore, this paper introduces a new idea of installing micro-propeller turbines in the aeration basin of a wastewater treatment plant (WWTP) to extract power from the high-velocity location in the water column. This extracted power can be used to operate a mixer at the top of the membrane to induce the mixing in that region, which will drive the less oxygenated wastewater into the water column. The rest of the extracted power will rotate microturbine rotors for electric power generation. By applying the proposed microturbines to the 13 audited facilities, it was demonstrated to achieve a gross annual energy-savings of 3,836.9 MWh, a gross annual cost-saving of $260,497, and total CO 2 emissions that would be reduced by 2,714 metric tons/year. Generally, the addition of the proposed microturbines can save up to 15.7% of the annual plant electricity consumption (1.3–12.8% of the plant annual electricity bills).

13 HYDRO ENERGY↗

Combined Effects of Stream Hydrology and Land Use on Basin‐Scale Hyporheic Zone Denitrification in the Columbia River Basin

Abstract Denitrification in the hyporheic zone (HZ) of river corridors is crucial to removing excess nitrogen in rivers from anthropogenic activities. However, previous modeling studies of the effectiveness of river corridors in removing excess nitrogen via denitrification were often limited to the reach‐scale and low‐order stream watersheds. We developed a basin‐scale river corridor model for the Columbia River Basin with random forest models to identify the dominant factors associated with the spatial variation of HZ denitrification. Our modeling results suggest that the combined effects of hydrologic variability in reaches and substrate availability influenced by land use are associated with the spatial variability of modeled HZ denitrification at the basin scale. Hyporheic exchange flux can explain most of spatial variation of denitrification amounts in reaches of different sizes, while among the reaches affected by different land uses, the combination of hyporheic exchange flux and stream dissolved organic carbon (DOC) concentration can explain the denitrification differences. Also, we can generalize that the most influential watershed and channel variables controlling denitrification variation are channel morphology parameters (median grain size (D50), stream slope), climate (annual precipitation and evapotranspiration), and stream DOC‐related parameters (percent of shrub area). The modeling framework in our study can serve as a valuable tool to identify the limiting factors in removing excess nitrogen pollution in large river basins where direct measurement is often infeasible.

54 ENVIRONMENTAL SCIENCES↗

Early burial mud diapirism and its impact on stratigraphic architecture in the Carboniferous of the Shannon Basin, County Clare, Ireland

Delta fronts are often characterized by high rates of sediment supply that result in unstable slopes and a wide variety of soft-sediment deformation, including the formation of overpressured and mobile muds that may flow plastically during early burial, potentially forming mud diapirs. The coastal cliffs of County Clare, western Ireland, expose Pennsylvanian (Namurian) delta-front deposits of the Shannon Basin at large scale and in three dimensions. These deposits include decametre-scale, internally chaotic mudstone masses that clearly impact the surrounding sedimentary strata. Evidence indicates that these were true mud (unlithified sediment) diapirs that pierced overlying strata. This study documents a well-exposed ca 20 m tall mud diapir and its impact on the surrounding mouth-bar deposits of the Tullig Cyclothem. A synsedimentary fault and associated rollover dome, evident from stratal thicknesses and the dip of the beds, define one edge of the diapir. These features are interpreted as recording the reactive rise of the mud diapir in response to extensional faulting along its margin. Above the diapir, heterolithic sandstones and siltstones contain evidence for the creation of localized accommodation, suggesting synsedimentary filling, tilting and erosion of a shallow sag basin accommodated by the progressive collapse of the diapir. Two other diapirs are investigated using three-dimensional models built from ‘structure from motion’ drone imagery. Both diapirs are interpreted to have grown predominantly through passive rise (downbuilding). Stratal relationships for all three diapirs indicate that they were uncompacted and fluid-rich mud beds that became mobilized through soft-sediment deformation during early burial (i.e. <50 m, likely <10 m depth). Each diapir locally controlled the stratigraphic architecture in the shallow subsurface and potentially influenced local palaeocurrents on the delta. The mud diapirs studied herein are distinct from deeper ‘shale diapirs’ that have been inferred from seismic sections worldwide, now largely disputed.

defects, mechanical behavior, carbon sequestration↗

Identification and Characterization of Persistent Cold Pool Events from Temperature and Wind Profilers in the Columbia River Basin

Cold pool events occur when deep layers of stable, cold air remain trapped in a valley or basin for multiple days, without mixing out from daytime heating. With large impacts on air quality, freezing events, and es-pecially on wind energy production, they are often poorly forecast by modern mesoscale numerical weather prediction (NWP) models. Understanding the characteristics of cold pools is, therefore, important to provide more accurate forecasts. This study analyzes cold pool characteristics with data collected during the Second Wind Forecast Improvement Project (WFIP2), which took place in the Columbia River basin and Gorge of Oregon and Washington from fall 2015 until spring 2017. A subset of the instrumentation included three microwave radiometer pro?lers, six radar wind pro?lers with radio acoustic sounding systems, and seven sodars, which together provided seven sites with collocated vertical pro?les of temperature, humidity, wind speed, and wind direction. Using these collocated observations, we developed a set of criteria to determine if a cold pool was present based on stability, wind speed, direction, and temporal continuity, and then developed an automated algorithm based on these criteria to identify all cold pool events over the 18 months of the ?eld project. Characteristics of these events are described, including statistics of the wind speed distributions and pro?les, stability conditions, cold pool depths, and descent rates of the cold pool top. The goal of this study is a better understanding of these characteristics and their processes to ultimately lead to improved physical parameterizations in NWP models, and consequently improve forecasts of cold pool events in the study region as well at other locations that experiences similar events.

McCaffrey, Katherine L.↗

Regional Geologic Evaluations for Disposal of HLW and SNF: Alluvial Basins of the Basin and Range Province

The DOE Spent Fuel and Waste Technology (SFWT) R&D Campaign supports research on crystalline rock, shale (argillite) and salt as potential host rocks for disposal of HLW and SNF in a mined geologic repository. Modeling involving these host rocks for the generic GDSA reference cases has assumed saturated conditions at repository depths. In order to test two-phase flow capabilities of the GDSA flow and transport models, the SFWT Campaign is developing an unsaturated zone reference case. Alluvial basin-fill deposits within the Basin and Range province have unsaturated zones that can be as thick as 600 meters, although the thickness is typically much less. Basin-fill alluvium has been considered as a potential medium for HLW disposal in the US since the 1950s (NAS,1957; Smyth et al., 1979; Winograd, 1981). Attributes considered favorable for HLW disposal in alluvium in the Basin and Range province include an arid environment, low water flux , high sorption capacity (from clay s and zeolites), and ease of construction and stability of repository openings (Hardin et al., 2012). Hardin et al. (2012) also address the thermal issues inherent in the design of a HLW repository in alluvium with low thermal conductivity, which are not discussed in this report.

58 GEOSCIENCES↗

Assessing Seismic Risk for CO2 Geologic Storage: Comparative Analysis of the Delaware Basin and Basin and Range Province Projects

ABSTRACT: Effective management of induced seismicity is critical for safe and sustainable CO2 storage. This study evaluates fault slippage risks in the Delaware Basin (Texas) and Basin and Range Province (Utah), integrating geological, operational, and geomechanical parameters to assess fault stability and seismic hazard mitigation. In the Delaware Basin, two sites were analyzed under an injection rate of 20,000 bbl/day over 25 years. One site showed low fault slip risk, while the other exhibited higher reactivation potential due to proximity to critically stressed faults. Sensitivity analysis revealed that increased pore pressure significantly heightened slip potential, highlighting the necessity of precise pressure control and real-time monitoring. In the Basin and Range Province, fault stability was evaluated at Neck of the Desert, Escalante Desert, Parowan, and Beaver sites under injection rates of 8,750 bbl/day per site over 30 years. Minimal fault slip risk was observed at Neck of the Desert and Escalante Desert sites, whereas Parowan and Beaver sites exhibited elevated slip potential due to semi-critically stressed faults sensitive to modest pore pressure increases. The findings demonstrate that fault slippage analysis, combined with sensitivity analysis of pore pressure and friction coefficients, is essential for understanding seismic risks. Continuous monitoring, adaptive injection management, and rigorous geomechanical analysis are key strategies for minimizing induced seismicity in CO2 sequestration projects.

58 GEOSCIENCES↗