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At least 19 records

Polymer blends for LDB applications

A series of LCP/PE blends have been studied to determine the potential of such systems to produce a high modulus balloon film material which retains the balloon fabrication and low temperature flight advantages of the current PE films. Blown films of blends of 5 and 15 percent LCP in PE have been produced which show a 28 percent enhancement in modulus over the neat PE matrix. These results are substantially lower than anticipated and are explained in terms of the LCP reinforcement aspect ratio and fibril diameter.

Lichkus, Andrew M.↗

Extrusion process optimization for toughness in balloon films

An experimental optimization process for blown film extrusion is described and examined in terms of the effects of the technique on the toughness of balloon films. The optimization technique by Cantor (1990) is employed which involves the identification of key process variables including screw speed, nip speed, bubble diameter, and frost-line height for analysis to optimize the merit function. The procedure is employed in the extrusion of a low-density polyethylene polymer, and the resulting optimized materials are toughness- and puncture-tested. Balloon toughness is optimized in the analytical relationship, and the process parameters are modified to attain optimal toughness. The film produced is shown to have an average toughness of 24.5 MPa which is a good value for this key property of balloon materials for high-altitude flights.

Cantor, K. M.↗

Polyethylene Blends for Improved Oxygen Barrier: Processing-Dependent Microstructure and Gas Permeability

Here this work demonstrates a greater than expected enhancement of oxygen barrier properties in linear low-density polyethylene (LLDPE)-based materials by blending LLDPE with high-density polyethylene (HDPE). The films made by melt pressing the LLDPE/HDPE blends had a greater reduction in oxygen permeability coefficients (PO 2 ) than predicted using common permeability reduction models, i.e., the harmonic average model and zero-permeability nanofiller model. The reduction of PO 2 was attributed to the presence of spherulite crystal structures, as revealed by atomic force microscopy combined with infrared spectroscopy (AFM-IR). The LLDPE matrix exhibited significant spherulite formation even at a relatively low addition of HDPEs, which likely formed tortuous pathways for diffusing oxygen molecules. Transport results from melt-pressed films contrast with the results from films with similar compositions prepared by film blowing, which did not show barrier enhancement beyond expectation. AFM-IR revealed that the blown films lacked spherulite crystals likely due to stretching in the machine direction followed by rapid cooling. These findings demonstrate the role of processing in controlling microstructures and thus the oxygen barrier performance. This work offers the possibility of achieving easily recyclable LLDPE-based packaging materials by simple blending of polyethylenes with different crystalline content.

36 MATERIALS SCIENCE↗

Viscoelastic characterization of thin-film polymers exposed to low Earth orbit

The materials made available through the Long Duration Exposure Facility (LDEF) satellite provide a set of specimens that can be well characterized and have a known exposure history with reference to atomic oxygen and ultraviolet radiation exposure. Mechanical characteristics measured from control samples and exposed samples provide a data base for predicting the behavior of polymers in low earth orbit. Samples of 1.0 mil thick low density polyethylene were exposed to the low earth orbit environment for a period of six years. These materials were not directly exposed to ram atomic oxygen and offer a unique opportunity for measuring the effect of atomic oxygen and UV radiation on mechanical properties with little concern to the effect of erosion. The viscoelastic characteristics of these materials were measured and compared to the viscoelastic characteristics of control samples. To aid in differentiating the effects of changes in crystallinity resulting from thermal cycling, from the effects of changes in chemical structure resulting from atomic oxygen/UV attack to the polymer, a second set of control specimens, annealed to increase crystallinity, were measured as well. The resulting characterization of these materials will offer insight into the impact of atomic oxygen/UV on the mechanical properties of polymeric materials. The viscoelastic properties measured for the control, annealed, and exposed specimens were the storage and loss modulus as a function of frequency and temperature. From these datum is calculated the viscoelastic master curve derived using the principle of time/temperature superposition. Using the master curve, the relaxation modulus is calculated using the method of Ninomiya and Ferry. The viscoelastic master curve and the stress relaxation modulus provide a direct measure of the changes in the chemical or morphological structure. In addition, the effect of these changes on long-term and short-term mechanical properties is known directly. It should be noted that the dependence on directionality for the polymer films was considered since these films were manufactured by a blown-film process.

Letton, Alan↗

Effects of additives on the processing and properties of LARC-TPI polyimide

The blending of LARC-TPI polyimide with the thermotropic liquid crystal polymer designated Xydar and with four different oligomeric imide materials has facilitated the resulting resin systems' processing into films while enhancing their mechanical properties and lowering their coefficient of thermal expansion to virtually zero. Two film-formation processes have been evaluated: (1) the casting of polyamic acid films followed by thermal imidization and biaxial stretching, and (2) the blown-film melt-extrusion of fully imidized LARC-TPI polymer. The best results have been obtained through the use of Xydar as a processing aid at levels in the 10-30 percent range.

Elandjian, L.↗

Processing parameters associated with scale-up of balloon film production

A method is set forth for assessing strain-rate profiles that can be used to develop a scale-up theory for blown-film extrusion. Strain rates are evaluated by placing four ink dots on the stalk of an extruded bubble to follow the displacements of the dots as a function of time. The instantaneous Hencky strain is obtained with the displacement data and plotted for analysis. Specific attention is given to potential sources of error in the distance measurements and corrections for these complex bubble geometries. The method is shown to be effective for deriving strain-rate data related to different processing parameters for the production of balloon film. The strain rates can be compared to frostline height, blow-up ratio, and take-up ratio to optimize these processing variables.

Simpson, D. M.↗

Diamondlike Protective Coats For Infrared Windows

Report describes experiments in which four infrared-transparent window materials were coated with diamondlike carbon films. Purpose to investigate ability of films to protect infrared windows against erosion by rain and wind-blown hard particles. Diamondlike films chosen as protective coats because they are transparent over broad spectral range and resist attack by chemicals, moisture, and abrasion. Experiments yield mixed results.

Swec, Diane M.↗

Production of pulsed atomic oxygen beams via laser vaporization methods

Energetic pulsed atomic oxygen beams were generated by laser-driven evaporation of cryogenically frozen ozone/oxygen films and thin films of indium-tin oxide (ITO). Mass and energy characterization of beams from the ozone/oxygen films were carried out by mass spectrometry. The peak flux, found to occur at 10 eV, is estimated from this data to be 3 x 10(20) m(-2) s(-1). Analysis of the time-of-flight data indicates a number of processes contribute to the formation of the atomic oxygen beam. The absence of metastable states such as the 2p(3) 3s(1) (5S) level of atomic oxygen blown off from ITO films is supported by the failure to observe emission at 777.3 nm from the 2p(3) 3p(1) (5P sub J) levels. Reactive scattering experiments with polymer film targets for atomic oxygen bombardment are planned using a universal crossed molecular beam apparatus.

Brinza, David E.↗

Production of pulsed atomic oxygen beams via laser vaporization methods

The generation of energetic pulsed atomic oxygen beams by laser-driven evaporation of cryogenically frozen ozone/oxygen films and thin indium-tin oxide (ITO) films is reported. Mass spectroscopy is used in the mass and energy characterization of beams from the ozone/oxygen films, and a peak flux of 3 x 10 to the 20th/sq m per sec at 10 eV is found. Analysis of the time-of-flight data suggests that several processes contribute to the formation of the oxygen beam. Results show the absence of metastable states such as the 2p(3)3s(1)(5S) level of atomic oxygen blown-off from the ITO films. The present process has application to the study of the oxygen degradation problem of LEO materials.

Brinza, David E.↗

Rapid scalable plasma processing of thin-film Li–La–Zr–O solid-state electrolytes

Solid-state electrolytes, such as lithium lanthanum zirconium oxide (LLZO), show promise as technologies for next-generation high-energy-density batteries, but commercial development has been hindered by a lack of scalable processing methods. Current fabrication methods are costly or require long annealing steps to create dense films. We report an atmospheric pressure blown-arc nitrogen plasma jet process to rapidly form sub-micrometer-thick, dense amorphous LLZO (a-LLZO) films from sol-gel precursors. Films are processed in less than 2 min, an order of magnitude faster than what has previously been reported. We demonstrate 500-nm-thick a-LLZO films processed at 350°C with an ionic conductivity of 2 × 10 −6 S/cm at 30°C and 2 × 10 −3 S/cm at 100°C and a conductance of 19 S at 100°C, the highest conductance of any LLZO phase to date. Here, the films exhibit outstanding smooth surface morphology with low defectivity, advancing atmospheric plasma processing as a scalable processing method for solid-state electrolytes.

25 ENERGY STORAGE↗

Program to stimulate graduate training in the field of aeroacoustics

An experiment is reported to cross correlate the output of hot film probes located at various points in the flow field of a jet-blown flap with the output of microphones in the acoustic far field. Fluid dynamic measurements of the flow fields of the test configuration are reported.

Becker, R. S.↗

Behavior of Windblown Sand on Mars: Results from Single-Particle Experiments

Experiments are investigating the behavior of individual sand grains in the high-energy martian aeolian regime. Energy partitioning during impact of a saltating grain determines grain longevity, but it also influences the way in which the bed becomes mobilized by reptation. When single grains of sand are fired into loose beds, the bed can absorb up to 90% of the impact energy by momentum transfer to other grains; it has been discovered that the impacting grains cause circular craters even at low impact angles. Hundreds of grains can be splashed by a single high-velocity (100 m/s) impact causing more bed disturbance through reptation than previously thought. The research is supported by NASA's PG&G Program. Because the martian aeolian environment in both high energy and of long duration, the most mobile fractions of windblown sand should have eradicated themselves by attrition, unless sand supply has kept pace with destruction. It is therefore important to understand the rate of grain attrition in order to make sense of the existence of vast dune fields on Mars. Attrition, has been addressed in other studies, but precise data for a single saltating grain striking a loose bed of sand have not been acquired -- the quintessential case to be understood for dunes on Mars. To acquire these data, we are employing a compound crossbow which has the bolt-firing mechanism replaced with a pneumatically-automated sabot system. The sabot can launch individual grains of sand of any size between several millimeters and about 50 microns, at velocities up to 100m/s. This is around the maximum velocity expected for saltating grains on Mars. The sabot sled is equipped with photoelectric sensors for measuring shot velocity. Baffling of the grain's exit orifice has enabled projection of single grains without significant aerodynamic effects from the sabot. Grains are fired into loose beds of sand at about 15 degrees from the horizontal (typical saltation trajectory at impact) while being filmed on high-speed video. High-intensity pulse illumination for the grains is triggered by the solenoid-operated bow trigger. A 45 degree mirror over the impact site provides simultaneous horizontal and vertical images of the impact on each video frame. UV fluorescence is enabling grain and grain-fragment recovery. At 100 m/s, grains of all sizes shatter into many fragments when the sand is replaced with a solid target. Kinetic energy of the grains at this velocity exceeds the critical energy for catastrophic failure of minerals. Although probably exceptional as a grain speed, it suggests that conditions on Mars might elevate materials into an attrition regime not encountered on other planets; individual grains blown across rock pavements on Mars will have short lifespans. When experimental grains impact loose (dune) sand, much, if not most of the kinetic energy is converted into momentum of other grains. Using high-speed filming, the energy involved in splashing grains at the impact site can be derived from the size of the crater, the speed of the splashed grains, and the rebound speed of the impactor. The amount of energy partitioned into material failure (as opposed to momentum) is too small a fraction of the total to be calculated under these circumstances. This does not necessarily mean that little damage occurs to the grains (the full extent of the damage has yet to be determined) because only a small fraction of the impact energy is required for inducing brittle fracture. Damage is orders of magnitude less than during impact against solid surfaces.

Marshall, J. R.↗

Acoustic source location in the secondary mixing region of a jet-blown flap using a cross-correlation technique

An experimental investigation of the acoustic sources in the secondary mixing region of a laboratory-scale jet-flap was made using a causality correlation technique. The processed signal of a hot-film anemometer probe was cross correlated with the output signal of a far-field microphone. Axial acoustic source strength distributions were measured for three far-field microphone locations: plus or minus 45 deg in the flyover plane and 45 deg in the sideline plane. These measurements showed that the acoustic sources in the secondary mixing region are highly directional, radiating much more effectively to the -45 deg-microphone, located below the plane of the flap surface. A relative maximum in the acoustic source strength measured for the microphones in the flyover plane occurred very near the flap trailing edge, which may be due to an edge amplification effect predicted by the theoretical work of Ffowcs Williams and Hall.

Becker, R. S.↗

Acoustic source location in a jet-blown flap using a cross-correlation technique

The acoustic source strength distribution in a turbulent flow field was measured for two far field microphones at 45 deg above and below the plane of the flap surface. A processed signal from an inclined hot-film anemometry probe was cross correlated with the signal from the appropriate far field microphone. The contribution made by the sources associated with the fluctuating pressure on the flap surface to the sound received at far field microphone was estimated by cross correlating the processed signals of microphones which were embedded in the flap surface with the far field microphone signals. In addition, detailed fluid dynamic measurements were made in the flow field of the jet flap using dual sensor hot-film anemometry probes.

Becker, R. S.↗

Flap survey test of a combined surface blowing model: Flow measurements at static flow conditions

The Combined Surface Blowing (CSB) V/STOL lift/propulsion system consists of a blown flap system which deflects the exhaust from a turbojet engine over a system of flaps deployed at the trailing edge of the wing. Flow measurements consisting of velocity measurements using split film probes and total measure surveys using a miniature Kiel probe were made at control stations along the flap systems at two spanwise stations, the centerline of the nozzle and 60 percent of the nozzle span outboard of the centerline. Surface pressure measurements were made in the wing cove and the upper surface of the first flap element. The test showed a significant flow separation in the wing cove. The extent of the separation is so large that the flow into the first flap takes place only at the leading edge of the flap. The velocity profile measurements indicate that large spanwise (3 dimensional) flow may exist.

Fukushima, T.↗

Film cooling on a convex wall: Heat transfer and hydrodynamic measurements for full and partial coverage

Turbine-blade cooling is an important issue for high-efficiency turbine engines, and discrete-hole injection is widely used as a cooling method. In the present study, detailed measurements were made of the heat transfer and hydrodynamics of a film-cooled flow on a convex wall, both for full and partial coverage. Two important parameters were altered: the blowing ratio, m, and the number of rows of injection holes. Three values of m were tested: m = 0.2, 0.4, and 0.6. In the blown region, m = 0.4 results in the lowest Stanton numbers of the three blowing ratios tested. This indicates that the value of m = 0.4 is near optimum on the convex wall from the point of view of cooling effect by injection. In the recovery region, Stanton numbers gradually approach the no injection values. Although the heat-transfer behavior during recovery from injection looks relatively complicated, the behavior of Stanton number can be explained in terms of two mechanisms: recovery from the thermal effect of injection and recovery from the turbulence augmentation. This interpretation of the data is supported by the hydrodynamic and temperture-profile measurements. For partial blowing cases, the data follow the full-coverage values inside the blown region. In the unblown region, both in the curved and in the flat plate, the effect of the number of blown rows is clearly seen. Hydrodynamic boundary-layer profiles were measured with the aid of a triple hot-water probe. Three mean-velocity components and six turbulence quantities were simultaneously measured, and inside the blown region strong three-dimensionality was observed.

Furuhama, K.↗

Heat transfer and turbulence measurements of a film-cooled flow over a convexly curved surface

Heat transfer and hydrodynamic boundary layer measurements were made in a turbulent boundary layer on a convex surface with 13 rows of injection. Both full- and partial-coverage cases were tested for three blowing ratios: 0.2, 0.4, and 0.6. Heat transfer results are discussed in terms of Stanton number with injection air temperature equal to wall temperature. In the blown region, for both m (blowing ratio) = 0.2 and 0.4, the local response of the boundary layer is dominated by curvature, and m = 0.4 shows higher cooling effects than m = 0.2 or 0.6, as expected, based on flat-plate results. Hydrodynamic measurements with a triple-hot-wire suggest the existence of two streamwise lanes. Lanes containing injection holes are highly affected by injection and show a definite streamwise evolution. Lanes which do not contain holes are not affected much by injection and show little change in the streamwise direction.

Furuhama, K.↗

Optimization of Photovoltaic Performance Through the Integration of Electrodynamic Dust Shield Layers

The viability of photovoltaics on the Lunar and Martian surfaces may be determined by their ability to withstand significant degradation in the Lunar and Martian environments. One of the greatest threats is posed by fine dust particles which are continually blown about the surfaces. In an effort to determine the extent of the threat, and to investigate some abatement strategies, a series of experiments were conducted outdoors and in the Moon and Mars environmental chamber at the Florida Solar Energy Center. Electrodynamic dust shield prototypes based on the electric curtain concept have been developed by our collaborators at the Kennedy Space Center [1]. These thin film layers can remove dust from surfaces and prevent dust accumulation. Several types of dust shields were designed, built and tested under high vacuum conditions and simulated lunar gravity to validate the technology for lunar exploration applications. Gallium arsenide, single crystal and polycrystalline silicon photovoltaic integrated devices were designed, built and tested under Moon and Mars environmental conditions as well as under ambient conditions. Photovoltaic efficiency measurements were performed on each individual cell with the following configurations; without an encapsulation layer, with a glass covering, and with various thin film dust shields. It was found that the PV efficiency of the hybrid systems was unaffected by these various thin film dust shields, proving that the optical transmission of light through the device is virtually uninhibited by these layers. The future goal of this project is to incorporate a photovoltaic cell as the power source for the electrodynamic dust shield system, and experimentally show the effective removal of dust obstructing any light incident on the cell, thus insuring power production is maximized over time.

Nason, Steven↗