Reaction Behaviors of Al-Killed Medium-Manganese Steel with Different Refractories
In order to understand the reaction mechanism between medium-manganese steel and different refractories, some laboratory experiments were carried out at 1873 K (1600 °C). Three types of refractory plates (Al{sub 2}O{sub 3}, MgO, and MgO·Al{sub 2}O{sub 3}) were used. The results show that Mn in liquid medium-manganese steel does not react easily with the Al{sub 2}O{sub 3} refractory, but can react with the MgO refractory to generate a (Mn, Mg)O layer at the boundary between the refractory plate and liquid steel. After the formation of (Mn, Mg)O, a layer of (Mn, Mg)O·Al{sub 2}O{sub 3} spinel is also formed at the edge of the MgO refractory. Similar to the MgO refractory, the dissolved Mn can react with the MgO·Al{sub 2}O{sub 3} refractory as well, and a layer of (Mn, Mg)O·Al{sub 2}O{sub 3} was also detected after reaction. It was found that the formation of (Mn, Mg)O·Al{sub 2}O{sub 3} at the edge of the refractory is a source of (Mn, Mg)O·Al{sub 2}O{sub 3} inclusions in liquid steel. The flush-off of the (Mn, Mg)O·Al{sub 2}O{sub 3} layer would result in the formation of (Mn, Mg)O·Al{sub 2}O{sub 3} inclusions.