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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Artificial Neural Network-based State Estimation for Low Observable, Unbalanced Microgrids for Microgrid Building Blocks

The microgrid building blocks (MBB) were proposed as microgrid components with combined sub-components with power conversion, communication, and microgrid control capability, or a subset of such sub-components. This work addresses the microgrid controller, present in an MBB, which requires accurate state estimation to perform its tasks, including for monitoring, power flow (dispatch), fault detection, etc. In this paper, an artificial neural network (ANN)-based framework for state estimation is proposed for an MBB, especially for unbalanced and low observable microgrids. To overcome the challenge of low observability in unbalanced systems, a concept of extended adjacent matrix is introduced to reduce the required number of measurements for state estimation. Addressing the challenges, a feed forward neural network (FNN) is utilized to enhance estimation accuracy and reliability with the reduced number of measurements. The proposed state estimation is validated through extensive simulations on a microgrid, which was achieved from the modified IEEE 34-bus distribution test feeder with multiple distributed energy resources (DERs) and demonstrated superior performance in estimation accuracy and low observability.

Choi, Jongchan↗

Rapid design of top-performing metal-organic frameworks with qualitative representations of building blocks

Abstract Data-driven materials design often encounters challenges where systems possess qualitative (categorical) information. Specifically, representing Metal-organic frameworks (MOFs) through different building blocks poses a challenge for designers to incorporate qualitative information into design optimization, and leads to a combinatorial challenge, with large number of MOFs that could be explored. In this work, we integrated Latent Variable Gaussian Process (LVGP) and Multi-Objective Batch-Bayesian Optimization (MOBBO) to identify top-performing MOFs adaptively, autonomously, and efficiently. We showcased that our method (i) requires no specific physical descriptors and only uses building blocks that construct the MOFs for global optimization through qualitative representations, (ii) is application and property independent, and (iii) provides an interpretable model of building blocks with physical justification. By searching only ~1% of the design space, LVGP-MOBBO identified all MOFs on the Pareto front and 97% of the 50 top-performing designs for the CO 2 working capacity and CO 2 /N 2 selectivity properties.

36 MATERIALS SCIENCE↗

Control Oriented Models for Co-Design: Technical Overview of MT HVDC, MVDC, and Solid State Transformer Building Blocks

The electric power system is shifting toward a power electronics–enabled grid, where converter based “building blocks” (e.g., high voltage direct current (HVDC) links, multi terminal HVDC (MT HVDC) networks, medium voltage DC (MVDC) links, and solid state transformers (SSTs)) provide fast, precise control of power flows, voltage, and frequency. This report develops and applies publicly shareable electromagnetic transient (EMT) and phasor models to examine how such building blocks can be composed and coordinated to support offshore wind integration, inter area transfers, feeder support, and resilience. Section 2 documents a modular multilevel converter (MMC)–based MT HVDC modeling framework and two use cases: a compact WSCC/IEEE 9 bus test system and a 240 bus “mini WECC” case with five offshore wind plants (OWFs). Phasor to EMT transfer, initialization, and sanity checks are summarized, and neutral demonstrations of normal and contingency operation are reported. Section 3 frames the problem of wind plant inertial frequency response (IFR): shaping energy release and recovery to improve nadir while avoiding aerodynamic stall; representative simulations illustrate the issues without disclosing proprietary control. Section 4 develops MVDC concepts through an IEEE 16 bus loop and an Olympic Peninsula case study that compares AC vs. MVDC corridors and shows how feeder headroom can be pooled via DC couplers. Section 5 surveys SST architectures and identifies a gap: scalable, communication free coordination of multiple SSTs for islanded feeder networks. Across the report, novel methods and configurations under separate publication and IP review are not disclosed; only topic oriented, replicable setups and non proprietary results are shown. These models and use cases are intended as foundations for future publications and co design studies on architecture, control, and coordination of PE enabled grids.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Microgrid Building Block Architecture, and Subcomponents Modeling and Demonstration in Controller Hardware-in-the-Loop

The recently proposed Microgrid Building Blocks (MBB) are ready-to-use components to build microgrids quickly, cheaply, and modularly. This work presents and demonstrates in controller hardware-in-the-loop (CHIL) three key subcomponents of an MBB architecture: power converter topology, control scheme, and communication framework. The addressed architecture aims for systems interconnection such as microgrid to grid and microgrid to microgrid. This paper studies each subcomponent in detail and validates the efficacy of the architecture through CHIL results.

Adib, Aswad [ORNL] (ORCID:000000020997056X)↗

Using small building blocks to assemble ultra-complex, multifaceted metal-organic frameworks with zeolitic, mesoporous subnetwork

The assembly of ultra-complex structures from simple building units remains a long-term challenge in chemistry. Using small molecular building blocks (MBBs) in a mixed-ligand approach permitted the assembly of unprecedented metal-organic frameworks (MOFs), M-kum-MOF-1 (M = Y, Tb), exhibiting extra-large mesoporous cavities with small access windows. The ultra-complex cage of M-kum-MOF-1 consists of 240 vertices bridged by 432 edges, leading to a 194 faces-containing tile. This tile exhibits more faces than in any periodic structures (zeolites, MOFs, metal-organic polyhedra [MOPs], etc.) known to date. M-kum-MOF-1 not only possess zeolitic features (anionic framework), but they also contain an underlying wse zeolitic topology, which is observed for the first time.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ligated Cluster Building Blocks as Chemical Donors and Acceptors for Two-Dimensional Metal Chalcogenides and Phosphorene Nanoribbons

Final report for studies on ligated transition metal chalcogenide clusters building blocks for serving as dopants in two dimensional semiconductors. The primary result is extending the superatom concept to transition metal chalcogenide clusters including a similarity with the perioidic electronic structures that are found in the periodic table. These results have found both new magic numbers, and new magic clusters with large spin magnetic moments.

36 MATERIALS SCIENCE↗

Decoupling Power Quality Issues in Grid-Microgrid Network Using Microgrid Building Blocks

Microgrids are evolving as promising options to enhance reliability of the connected transmission and distribution systems. Traditional design and deployment of microgrids require significant engineering analysis. However, Microgrid Building Blocks (MBB), consisting of modular blocks that integrate seamlessly to form effective microgrids, are promising technologies to enable faster and broader adoption of microgrids. Back-to-Back converter placed at the point of common coupling of microgrid is an integral part of MBB. This paper presents applications of MBB to decouple power quality issues in grid-microgrid network serving power quality sensitive critical loads such as data centers, new grid-edge technologies such as vehicle-to-grid generation, and emergency condition loads such as electric vehicle charging loads during evacuation prior disaster events. Simulation results show that MBB effectively decouple the power quality issues across networks and allow network with low power quality to transfer high-power quality power to connected networks during emergency conditions.

Acharya, Samrat S. [BATTELLE (PACIFIC NW LAB)]↗

Small Business Voucher Program: Scaling-Up of Bio-Based C5 Building Block Production: Cooperative Research and Development Final Report, CRADA Number CRD-16-00611

Visolis, Inc. is an early stage industrial biotechnology company developing next generation of processes for producing building blocks for bulk polymers and fuels. The company is developing low-cost routes to the chemicals of the future in support of DOE, EERE and BETO goals to grow the U.S. bioeconomy. NREL has capabilities in scale-up of fermentation processes from bench top through pilot scales and also has expertise and technologies related to production of lignocellulosic sugars from cellulosic feedstocks. NREL's Integrated Biorefinery Research Facility (IBRF) houses multiple fermentation vessels/systems ranging in size from 0.5 to 9,000 L along with ancillary capabilities in compositional analysis, separations, and purification. NREL's role will be to scale-up the Visolis process to produce an intermediate product, mevalonic acid, from both dextrose and biomass derived sugars. The goals of the project are to: 1) transfer and reproduce one of Visolis's proprietary fermentation processes at bench top and pilot scale at NREL's IBRF using dextrose as the feedstock, 2) carry out bench-scale fermentations using Visolis's organism and cellulosic sugars, and 3) produce mevalonic acid from the bench top and pilot scale runs for catalyst lifetime testing and conversion to isoprene.

09 BIOMASS FUELS↗

Design of Controller Hardware-In-the-Loop Model of Microgrid with Modular Building Blocks and Automated Design Script

The scalability of controller hardware-in-the-loop (CHIL) simulation is critical for validating control coordination and energy management in microgrids with distributed energy resources, especially as these modern systems become more complex and decentralized. This paper presents a CHIL modeling methodology that combines modular building blocks with an automated design script to streamline the development of high-fidelity microgrid models. Standardized subsystem templates for resources, converters, and buses are integrated with a Python-based script that compiles structured JSON configuration files into simulation-ready initialization code. The proposed approach reduces development time, improves model consistency, and enhances simulation fidelity. The methodology is validated on a Typhoon HIL604 platform and is broadly applicable to real-time simulation of complex, networked microgrid systems. This framework establishes a foundation for automated, scalable CHIL validation and accelerates the design of next-generation distributed energy systems.

Kim, Namwon [ORNL] (ORCID:0000000200438489)↗

Reconfigurable Magnetic Liquid Building Blocks for Constructing Artificial Spinal Column Tissues

All-liquid molding can be used to transform a liquid into free-form solid constructs, while maintaining internal fluidity. Traditional biological scaffolds, such as cured pre-gels, are normally processed in solid state, sacrificing flowability and permeability. However, it is essential to maintain the fluidity of the scaffold to truly mimic the complexity and heterogeneity of natural human tissues. Here, this work molds an aqueous biomaterial ink into liquid building blocks with rigid shapes while preserving internal fluidity. The molded ink blocks for bone-like vertebrae and cartilaginous-intervertebral-disc shapes, are magnetically manipulated to assemble into hierarchical structures as a scaffold for subsequent spinal column tissue growth. It is also possible to join separate ink blocks by interfacial coalescence, different from bridging solid blocks by interfacial fixation. Generally, aqueous biomaterial inks are molded into shapes with high fidelity by the interfacial jamming of alginate surfactants. The molded liquid blocks can be reconfigured using induced magnetic dipoles, that dictated the magnetic assembly behavior of liquid blocks. The implanted spinal column tissue exhibits a biocompatibility based on in vitro seeding and in vivo cultivating results, showing potential physiological function such as bending of the spinal column.

60 APPLIED LIFE SCIENCES↗

Testbed Demonstration of a Microgrid Building Block Prototype

With the adoption of ambitious climate action goals, the penetration level of distributed energy resources (DERs) is rapidly increasing. Microgrids are an efficient way to integrate these DERs, facilitating their operation and control. Additionally, microgrids enhance the overall resilience of the distribution system by serving critical loads both within and outside their boundaries. However, the need for substantial customized engineering leads to a high cost of development, installation and maintenance of microgrids. To address this challenge, Microgrid Building Blocks (MBB) are proposed to reduce the deployment cost of microgrids through modular, standardized design and implementation. This work presents a testbed demonstrating the integrated power conversion, control, and communication functionalities of an MBB. The testbed is formed by a real-time electromagnetic transient (EMT) simulation combined with a hardware and software prototype of MBB. The use cases supported by the MBB testbed are enumerated. The islanded operation, voltage regulation, and optimal dispatch capabilities of an MBB-based microgrid controller are validated through a case study.

Somda, Baza [Virginia Tech]↗

Synthesis and functionalization of electron-deficient perfluoroalkyl porphyrin building blocks for supermolecular systems

Synthetic strategies for electron-deficient meso-perfluoroalkylporphyrins bearing diverse functional groups are described. Scalable and efficient syntheses for 5-triisopropylsilylethynyl-10,15,20-tris(heptafluoropropyl)porphyrin and 5-triisopropylsilylethynyl-10,20-bis(heptafluoropropyl)porphyrin that equip meso-ethynyl functional groups via the bilane route have been established, along with a refined route to [5,15-bis(heptafluoropropyl)porphinato]zinc(II). meso-Position halogenation of [5,15-bis(heptafluoropropyl)porphinato]zinc(II) was achieved by selective meso-nitration and subsequent reduction, diazonium salt formation, and iodination reactions. Computational data describe the low energy excited states of these chromophores and the electronic structural factors that control reactivity of these meso-perfluoroalkyl substituted porphyrin complexes. meso-Functionalized [5-triisopropylsilylethynyl-10,20-bis(heptafluoropropyl)porphinato]zinc(II) and [5-iodo-10,20-bis(heptafluoropropyl)porphinato]zinc(II) building blocks lay the foundation for the construction of highly conjugated multiporphyrin arrays that feature electronic structural properties important for the development of n-type materials and high potential photooxidants.

Chemistry↗

1,8-Dihydroxy Naphthalene—A New Building Block for the Self-Assembly with Boronic Acids and 4,4′-Bipyridine to Stable Host–Guest Complexes with Aromatic Hydrocarbons

The new Lewis acid–base adducts of general formula X(nad)B←NC5H4-C5H4N→B(nad)X [nad = 1,8-O2C10H6, X = C6H5 (2c), 3,4,5-F3-C6H2 (2d)] were synthesized in high yields via reactions of 1,8-dihydroxy naphthalene [nadH2] and 4,4′-bipyridine with the aryl boronic acids C6H5B(OH)2 and 3,4,5-F3-C6H2B(OH)2, respectively, and structurally characterized by multi-nuclear NMR spectroscopy and SCXRD. Self-assembled H-shaped Lewis acid–base adduct 2d proved to be effective in forming thermally stable host–guest complexes, 2d × solvent, with aromatic hydrocarbon solvents such as benzene, toluene, mesitylene, aniline, and m-, p-, and o-xylene. Crystallographic analysis of these solvent adducts revealed host–guest interactions to primarily occur via π···π contacts between the 4,4′-bipyridyl linker and the aromatic solvents, resulting in the formation of 1:1 and 1:2 host–guest complexes. Thermogravimetric analysis of the isolated complexes 2d × solvent revealed their high thermal stability with peak temperatures associated with the loss of solvent ranging from 122 to 147 °C. 2d, when self-assembled in an equimolar mixture of m-, p-, and o-xylene (1:1:1), preferentially binds to o-xylene. Collectively, these results demonstrate the ability of 1,8-dihydroxy naphthalene to serve as an effective building block in the selective self-assembly to supramolecular aggregates through dative covalent N→B bonds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

SPC-70808 Rev 0 AL-30 Secondary Support Standoff Blocks Build to Print Fabrication for Use in MARVEL

A. Idaho National Laboratory (INL) is developing a microreactor to produce electrical power utilizing a small nuclear core and Stirling engines under the Microreactor Application Research Validation and Evaluation (MARVEL) program. This procurement specification defines the requirements for fabrication of the MARVEL AL-30 Secondary Support Standoff Blocks manufactured by Zircar. The design requires twelve blocks; however, the requested quantity shall be 16 to account for required testing after receipt of materials. B. Any conflict between this specification and referenced Codes and Standards, or any supplementary specifications in the procurement documents requires written clarification from the Contractor prior to proceeding with any work. Any deviation from the procurement documents requires approval by the Contractor with the change request process.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

Building Blocks for Secure and Prosperous Defense Critical Supply Chains: A Case Study from Microelectronics

Securing defense-critical supply chains, built on resilient and sustainable microelectronics fabrication and deployment, is a national imperative and one that requires an investment in basic and applied research, development, and deployment into industries in (and out of) the Defense Industrial Base (DIB). Critical next steps include the development of pilots for revolutionary concepts in a new formal verification model and the Cyber-Physical Passport (CPP) concept for chain of custody. Critical infrastructure leadership should take action with a sense of urgency. Working in conjunction with the Under Secretary for Acquisition and Sustainment, the Assistant Secretary of Defense for Research and Engineering should establish pilot programs with the Defense Advanced Research Projects Agency and the service labs to build and test both concepts in legacy and new system development.. Additionally, the Pentagon may be aware that an existing Manufacturing Innovation Institute is piloting, with the semiconductor industry, cyber innovations to provide verifiable security properties and guarantees of physical functions to build a more cyber secure, resilient and efficient micro-electronics supply chain.

99 GENERAL AND MISCELLANEOUS↗

RNA oligomers at atomic resolution containing 1‐methylpseudouridine, an essential building block of mRNA vaccines

Abstract All widely used mRNA vaccines against COVID‐19 contain in their sequence 1‐methylpseudouridine ( m1Ψ ) instead of uridine. In this publication, we report two high resolution crystal structures (at up to 1.01 and 1.32 Å, respectively) of one such double‐stranded 12‐mer RNA sequence crystallized in two crystal forms. The structures are compared with similar structures which do not contain this modification. Additionally, the X‐ray structure of 1‐methyl‐pseudouridine itself was determined.

Nievergelt, Philipp↗

Shedding Light on the Vibrational Signatures in Halogen‐Bonded Graphitic Carbon Nitride Building Blocks

Abstract The relative contributions of halogen and hydrogen bonding to the interaction between graphitic carbon nitride monomers and halogen bond (XB) donors containing C−X and C≡C bonds were evaluated using computational vibrational spectroscopy. Conventional probes into select vibrational stretching frequencies can often lead to disconnected results. To elucidate this behavior, local mode analyses were performed on the XB donors and complexes identified previously at the M06‐2X/aVDZ‐PP level of theory. Due to coupling between low and high energy C−X vibrations, the C≡C stretch is deemed a better candidate when analyzing XB complex properties or detecting XB formation. The local force constants support this conclusion, as the C≡C values correlate much better with the σ ‐hole magnitude than their C−X counterparts. The intermolecular local stretching force constants were also assessed, and it was found that attractive forces other than halogen bonding play a supporting role in complex formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗