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At least 19 records

Universality relationships in condensed matter - Bulk modulus and sound velocity

New forms for the bulk modulus and sound velocity of solids under compression, based on the universal equation of state of Vinet, Ferrante, Smith, and Rose (1987) are presented. These expressions are compared with a number of bulk modulus formulas previously utilized in high-pressure studies. It is demonstrated that this form yields a superior fit to experimental data to very high compressions, for a very wide range of solids. These solids cover the entire range of values of the pressure derivative of the bulk modulus which has been observed in high-pressure measurements.

Schlosser, Herbert↗

Piezoelectric Measurement Of Bulk Modulus

In method of measuring bulk modulus of elasticity of elastomeric material, piezoelectric crystals of various sizes and energized by alternating voltage embedded in material. Concept demonstrated in test cell in which piezoelectric crystal mounted either unconstrained or between two rubber pads and connected as actuator in loud-speaker. The 1-in. diameter crystal excited with 24 Vac at 60 Hz. When crystal was unconstrained, it drew current of 0.8 mA. When crystal was constrained between rubber pads, current fell to 0.65 mA. Low current, minimal heating, and absence of arcing makes technique suitable for measurement of bulk moduli of elasticity of flammable or explosive rubbery materials.

Butler, Barry L.↗

Dynamic measurement of bulk modulus of dielectric materials using a microwave phase shift technique

A microwave Doppler shift technique was developed for measuring the dynamic bulk modulus of dielectric materials such as solid propellants. The system has a demonstrated time resolution on the order of milliseconds and a theoretical spatial resolution of a few microns. Accuracy of the technique is dependent on an accurate knowledge of the wavelength of the microwave in the sample being tested. Such measurement techniques are discussed. Preliminary tests with two solid propellants, one non-aluminized and one containing 16% aluminum, yielded reasonable, reproducible results. It was concluded that with refinements the technique holds promise as a practical means for obtaining accurate dynamic bulk modulus data over a variety of transient conditions.

Barker, B. J.↗

Dynamic measurement of bulk modulus

Technique based on measuring phase difference between microwave reference and test signals and has been used to determine change in bulk modulus of solid-fuel rocket propellants should be useful in studying other dielectric materials.

Dowler, W. L.↗

A model for the influence of pressure on the bulk modulus and the influence of temperature on the solidification pressure for liquid lubricants

Two pressure chambers, for compression experiments with liquids from zero to 2.2 GPa pressure, are described. The experimentally measured compressions are then compared to theoretical values given by an isothermal model of equation of state recently introduced for solids. The model describes the pressure and bulk modulus as a function of compression for different types of lubricants with a very high accuracy up to the pressure limit of the high pressure chamber used (2.2 GPa). In addition the influence of temperature on static solidification pressure was found to be a simple function of the thermal expansion of the fluid.

Jacobson, B. O.↗

A model for the influence of pressure on the bulk modulus and the influence of temperature on the solidification pressure for liquid lubricants

Two pressure chambers, for compression experiments with liquids from zero to 2.2 GPa pressure, are described. The experimentally measured compressions are then compared to theoretical values given by an isothermal model of equation of state recently introduced for solids. The model describes the pressure and bulk modulus as a function of compression for different types of lubricants with a very high accuracy up to the pressure limit of the high pressure chamber used (2.2 GPa). In addition the influence of temperature on static solidification pressure was found to be a simple function of the thermal expansion of the fluid.

Jacobson, Bo O.↗

Liquid alkali metals - Equation of state and reduced-pressure, bulk-modulus, sound-velocity, and specific-heat functions

The previous work of Schlosser and Ferrante (1988) on universality in solids is extended to the study of liquid metals. As in the case of solids, to a good approximation, in the absence of phase transitions, plots of the logarithm of the reduced-pressure function H, of the reduced-isothermal-bulk-modulus function b, and of the reduced-sound-velocity function v are all linear in 1-X. Finally, it is demonstrated that ln(Cp/C/v) is also linear in 1-X, where X = (V/V/0/)exp 1/3), and V(0) is the volume at zero pressure.

Schlosser, Herbert↗

Rare-gas liquids - Equation of state and reduced-pressure, reduced-bulk-modulus, and reduced-sound-velocity functions

This paper is concerned with verification of the applicability of the Vinet et al. (1987) universal equation of state to the liquid phase of the rare-gas elements under pressure. As previously observed in solids and liquids metals, to a good approximation, in the absence of phase transitions, plots of the logarithms of the reduced pressure function, of the reduced sound velocity, and of the reduced bulk modulus, are all linear functions of 1 - X over the entire experimental pressure range. The results obtained on the rare-gas liquids are comparable in accuracy to those obtained in previous work on solids and liquid metals.

Schlosser, Herbert↗

Thermal expansivity, bulk modulus, and melting curve of H2O-ice VII to 20 GPa

Equation of state properties of ice VII and fluid H2O at high pressures and temperatures have been studied experimentally from 6 to 20 GPa and 300-700 K. The techniques involve direct measurements of the unit-cell volume of the solid using synchrotron X-ray diffraction with an externally heated diamond-anvil cell. The pressure dependencies of the volume and bulk modulus of ice VII at room temperature are in good agreement with previous synchrotron X-ray studies. The thermal expansivity was determined as a function of pressure and the results fit to a newly proposed phenomenological relation and to a Mie-Gruneisen equation of state formalism. The onset of melting of ice VII was determined directly by X-ray diffraction at a series of pressures and found to be in accord with previous volumetric determinations. Thermodynamic calculations based on the new data are performed to evaluate the range of validity of previously proposed equations of state for fluid water derived from static and shock-wave compression experiments and from simulations.

Fei, Yingwei↗

Physical property measurements of doped cesium iodide crystals

Mechanical and thermal property values are reported for crystalline cesium iodide doped with sodium and thallium. Young's modulus, bulk modulus, shear modulus, and Poisson's ratio were obtained from ultrasonic measurements. Young's modulus and the samples' elastic and plastic behavior were also measured under tension and compression. Thermal expansion and thermal conductivity were the temperature dependent measurements that were made.

Synder, R. S.↗

Cell wall elasticity: I. A critique of the bulk elastic modulus approach and an analysis using polymer elastic principles

The traditional bulk elastic modulus approach to plant cell pressure-volume relations is inconsistent with its definition. The relationship between the bulk modulus and Young's modulus that forms the basis of their usual application to cell pressure-volume properties is demonstrated to be physically meaningless. The bulk modulus describes stress/strain relations of solid, homogeneous bodies undergoing small deformations, whereas the plant cell is best described as a thin-shelled, fluid-filled structure with a polymer base. Because cell walls possess a polymer structure, an alternative method of mechanical analysis is presented using polymer elasticity principles. This initial study presents the groundwork of polymer mechanics as would be applied to cell walls and discusses how the matrix and microfibrillar network induce nonlinear stress/strain relationships in the cell wall in response to turgor pressure. In subsequent studies, these concepts will be expanded to include anisotropic expansion as regulated by the microfibrillar network.

Plants/chemistry/cytology/ultrastructure↗

Improved bounds on elastic and transport properties of fiber-reinforced composites - Effect of polydispersivity in fiber radius

Improved rigorous bounds were computed on the effective elastic and transport properties (including the effective axial shear modulus, effective transverse bulk modulus, and effective transverse shear modulus) of a transversely isotropic fiber-reinforced material composed of infinitely-long oriented multisized impenetrable circular cylinders distributed throughout a matrix. Results were used to study the effect of fiber-radius polydispersivity on the elastic and transport properties of such unidirectional composites. It was found that increasing the degree of polydispersivity increases the effective transverse conductivity (or axial shear modulus) and the effective transverse bulk modulus, and slightly decreases the effective transverse shear modulus for cases in which the fibers are more conducting or stiffer than the matrix.

Miller, C. A.↗

Cohesive Energy-Lattice Constant and Bulk Modulus-Lattice Constant Relationships: Alkali Halides, Ag Halides, Tl Halides

In this note we present two expressions relating the cohesive energy, E(sub coh), and the zero pressure isothermal bulk modulus, B(sub 0), of the alkali halides. Ag halides and TI halides, with the nearest neighbor distances, d(sub nn). First, we show that the product E(sub coh)d(sub 0) within families of halide crystals with common crystal structure is to a good approximation constant, with maximum rms deviation of plus or minus 2%. Secondly, we demonstrate that within families of halide crystals with a common cation and common crystal structure the product B(sub 0)d(sup 3.5)(sub nn) is a good approximation constant, with maximum rms deviation of plus or minus 1.36%.

Schlosser, Herbert↗

Elastic constants at low temperatures - Recent measurements on technological materials at NBS

Solid-state low-temperature elastic properties have been experimentally studied at the NBS Cryogenic Division for four years. Most studies were between room temperature and liquid-helium temperature; some were only to liquid-nitrogen temperature. Two dynamic (high-frequency) experimental methods were used, pulse-echo and resonance, resulting in adiabatic elastic constants. The present paper reviews these studies for 47 technological materials - metals, alloys, and composites. The elastic constants primarily discussed are Young's modulus, the shear modulus, the bulk modulus (reciprocal compressibility), and Poisson's ratio. A summary table is presented to show which base metals tend to exhibit regular, irregular, or anomalous behavior in their elastic constant/temperature curves.

Ledbetter, H. M.↗

Elastic constant versus temperature behavior of three hardened maraging steels

Elastic constants of three maraging steels were determined by measuring ultrasonic velocities. Annealed steels show slightly lower bulk moduli and considerably lower shear moduli than hardened steels. All the elastic constants (Young's modulus, shear modulus, bulk modulus and Poisson's ratio) show regular temperature behavior between 76 and 400 K. Young's modulus and the shear modulus increase with increasing yield strength, but the bulk modulus and Poisson's ratio are relatively unchanged. Elastic anisotropy is quite small.

Ledbetter, H. M.↗

Solid impingement erosion mechanisms and characterization of erosion resistance of ductile metals

Experimental results pertaining to spherical glass bead and angular crushed glass particle impingement are presented. A concept of energy adsorption to explain the failure of material is proposed. The erosion characteristics of several pure metals were correlated with the proposed energy parameters and with other properties. Correlations of erosion and material properties were also carried out with these materials to study the effect of the angle of impingement. Analyses of extensive erosion data indicate that surface energy, strain energy, melting point, bulk modulus, hardness, ultimate resilience, atomic volume and product of linear coefficient of thermal expansion, bulk modulus, and temperature rise required for melting, and ultimate resilience, and hardness exhibit the best correlations. It appears that both energy and thermal properties contribute to the total erosion.

Rao, V. P.↗

Characterization of solid particle erosion resistance of ductile metals based on their properties

This paper presents experimental results pertaining to spherical glass bead and angular crushed glass particle impingement. A concept of energy absorption to explain the failure of material is proposed and is correlated with the erosion characteristics of several pure metals. Analyses of extensive erosion data indicate that the properties - surface energy, specific melting energy, strain energy, melting point, bulk modulus, hardness, atomic volume - and the product of the parameters - linear coefficient of thermal expansion x bulk modulus x temperature rise required for melting, and ultimate resilience x hardness - exhibit the best correlations. The properties of surface energy and atomic volume are suggested for the first time for correlation purposes and are found to correlate well with erosion rates at different angles of impingement. It further appears that both energy and thermal properties contribute to the total erosion.

Rao, P. V.↗

Compression, nonstoichiometry and bulk viscosity of wuestite

New and existing data on the elasticity of wuestite which indicate virtually no correlation between the bulk modulus and stoichiometry are summarized. There appears, however, to be a systematic difference between static and dynamic measurements. This behavior suggests the presence of a frequency dependence to the bulk modulus that can be formally ascribed to a finite bulk viscosity of Fe(1-x)O. Such an effect has not previously been described in oxide or silicate minerals, and it presumably is caused by pressure-induced changes in defect ordering and subsequent relaxation within the incommensurate structure of wuestite.

Jeanloz, R.↗