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Results for “calibration stability spectrometer”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Absolute calibration of an ultraviolet spectrometer using a stabilized laser and a cryogenic cavity radiometer

We carry out the calibration of an ultraviolet spectrometer by using a cryogenic electrical-substitution radiometer and intensity-stabilized laser sources. A comparison of the error budgets for the laser-based calibration described here and for a calibration using a type-FEL tungsten spectral-irradiance standard indicates that this technique could provide an improvement of a factor of about three in the uncertainty of the spectrometer calibration, resulting in an absolute accuracy (standard deviation of three) of about 1 percent at 257 nm. The technique described here might significantly improve the accuracy of calibrations on NASA ozone-monitoring and solar ultraviolet-monitoring spectrophotometers when used to complement present procedures that employ lamps and the SURF II synchrotron ultraviolet radiation facility at the National Institute of Standards and Technology.

Jauniskis, L.↗

Ion mobility spectrometry of hydrazine, monomethylhydrazine, and ammonia in air with 5-nonanone reagent gas

Hydrazine (HZ) and monomethylhydrazine (MMH) in air were monitored continuously using a hand-held ion mobility spectrometer equipped with membrane inlet, 63Ni ion source, acetone reagent gas, and ambient temperature drift tube. Response characteristics included detection limit, 6 ppb; linear range, 10-600 ppb; saturated response, >2 ppm; and stable response after 15-30 min. Ammonia interfered in hydrazines detection through a product ion with the same drift time as that for MMH and HZ. Acetone reagent gas was replaced with 5-nonanone to alter drift times of product ions and separate ammonia from MMH and HZ. Patterns in mobility spectra, ion identifications from mass spectra, and fragmentation cross-sections from collisional-induced dissociations suggest that drift times are governed by ion-cluster equilibria in the drift region of the mobility spectrometer. Practical aspects including calibration, stability, and reproducibility are reported from the use of a hand-held mobility spectrometer on the space shuttle Atlantis during mission STS-37.

Flight Experiment↗

Long-term changes in the total ozone mapping spectrometer relative to world primary standard Dobson spectrometer 83

The stability of the calibration of the Nimbus 7 solar backscatter UV (SBUV) and total ozone mapping spectrometer (TOMS) instruments by comparing their ozone measurements with those made by a single, very stable Dobson instrument: the world primary standard Dobson spectrometer number 83. Measurements of ozone made with instrument 83 at Mauna Loa observatory in eight summers between 1979 and 1989 were compared with coincident TOMS ozone measurements. The comparison shows that relative to instrument 83, ozone measured by TOMS (and SBUV) was stable between 1979 and approximately 1983, had decreased by 3 percent by 1986, and had decreased by almost 7 percent by 1989. A similar time dependence is seen when data from an ensemble of 39 Dobson stations throughout the world is compared with TOMS over the period 1979-1987. The most likely reason for the relative drift is that the diffuser plate used by both SBUV and TOMS to measure solar flux has suffered an uncorrected wavelength-dependent degradation, with most of the degradation occurring after 1983. The recently released version 6 TOMS data, corrected using the internal 'pair justification' technique, show almost no drift relative to Dobson instrument 83. Accurate measurements of long-term global ozone change will require a coherent system incorporating both ground-based and satellite-based ozone measurements.

Mcpeters, Richard D.↗

Calibration of passive remote observing optical and microwave instrumentation; Proceedings of the Meeting, Orlando, FL, Apr. 3-5, 1991

Various papers on the calibration of passive remote observing optical and microwave instrumentation are presented. Individual topics addressed include: on-board calibration device for a wide field-of-view instrument, calibration for the medium-resolution imaging spectrometer, cryogenic radiometers and intensity-stabilized lasers for EOS radiometric calibrations, radiometric stability of the Shuttle-borne solar backscatter ultraviolet spectrometer, ratioing radiometer for use with a solar diffuser, requirements of a solar diffuser and measurements of some candidate materials, reflectance stability analysis of Spectralon diffuse calibration panels, stray light effects on calibrations using a solar diffuser, radiometric calibration of SPOT 23 HRVs, surface and aerosol models for use in radiative transfer codes. Also addressed are: calibrated intercepts for solar radiometers used in remote sensor calibration, radiometric calibration of an airborne multispectral scanner, in-flight calibration of a helicopter-mounted Daedalus multispectral scanner, technique for improving the calibration of large-area sphere sources, remote colorimetry and its applications, spatial sampling errors for a satellite-borne scanning radiometer, calibration of EOS multispectral imaging sensors and solar irradiance variability.

Guenther, Bruce W.↗

Absolute wind measurements in the lower thermosphere of Venus using infrared heterodyne spectroscopy

The first absolute wind velocities above the Venusian cloud-tops were obtained using NASA/Goddard infrared heterodyne spectrometers at the NASA Infrared Telescope Facility (IRTF) and the McMath Solar Telescope. Beam-integrated Doppler displacements in the non-thermal emission core of (12)C(16)O2 10.33 micron R(8) sampled the line of sight projection of the lower thermospheric wind field (100 to 120 km). A field-usable Lamb-dip laser stabilization system, developed for spectrometer absolute frequency calibration to less than + or - 0.1 MHz, allowed S/N-limited line of sight velocity resolution at the 1 m/s level. The spectrometer's diffraction-limited beam (1.7 arc-second HPBW at McMath, 0.9 arc-second HPBW at IRTF), and 1 to 2 arc-second seeing, provided the spatial resolution necessary for circulation model discrimination. Qualitative analysis of beam-integrated winds provided definitive evidence of a dominant subsolar-antisolar circulation in the lower thermosphere. Beam-integrated winds were modelled with a 100x100 grid over the beam, incorporating beam spatial rolloff and across-the-beam gradients in non-thermal emission intensity, line of sight projection geometry, and horizontal wind velocity. Horizontal wind velocity was derived from a 2-parameter model wind field comprised of subsolar-antisolar and zonal components. Best-fit models indicated a dominant subsolar-antisolar flow with 120 m/s cross-terminator winds and a retrograde zonal component with a 25 m/s equatorial velocity. A review of all dynamical indicators above the cloud-tops allowed development of an integrated and self-consistent picture of circulation in the 70 to 200 km range.

Goldstein, Jeffrey J.↗

Calibration of a mass spectrometer experiment for ozone

A system with which to calibrate a stratospheric mass spectrometer experiment for ozone has been developed and evaluated. The stability of ozone and the formation of impurities within the calibration volume were measured. The half-life of ozone is about 12 hours, its purity ranges from 95% to 99% and is known to within 1%. The total calibration accuracy of the mass spectrometer experiment for ozone is about + or - 2%.

Anderson, S.↗

The Viking X ray fluorescence experiment - Analytical methods and early results

Ten samples of the Martian regolith have been analyzed by the Viking lander X ray fluorescence spectrometers. Because of high-stability electronics, inclusion of calibration targets, and special data encoding within the instruments the quality of the analyses performed on Mars is closely equivalent to that attainable with the same instruments operated in the laboratory. Determination of absolute elemental concentrations requires gain drift adjustments, subtraction of background components, and use of a mathematical response model with adjustable parameters set by prelaunch measurements on selected rock standards. Bulk fines at both Viking landing sites are quite similar in composition, implying that a chemically and mineralogically homogeneous regolith covers much of the surface of the planet. Important differences between samples include a higher sulfur content in what appear to be duricrust fragments than in fines and a lower iron content in fines taken from beneath large rocks than those taken from unprotected surface material. Further extensive reduction of these data will allow more precise and more accurate analytical numbers to be determined and thus a more comprehensive understanding of elemental trends between samples.

Clark, B. C., III↗

The NEID Precision Radial Velocity Spectrometer: Port Adapter Overview, Requirements, and Test Plan

The NEID spectrometer is an optical (380-930 nm), fiber-fed, precision Doppler spectrometer currently in development for the WIYN 3.5 m telescope at Kitt Peak National Observatory as part of the NN-EXPLORE partnership. Designed to achieve a radial velocity precision of < 30 cm/s, NEID will be sensitive enough to detect terrestrial-mass exoplanets around low-mass stars. Light from the target stars is focused by the telescope to a bent Cassegrain port at the edge of the primary mirror mechanical support. The specialized NEID "Port Adapter" system is mounted at this bent Cassegrain port and is responsible for delivering the incident light from the telescope to the NEID fibers. In order to provide stable, high-quality images to the science instrument, the Port Adapter houses several sub-components designed to acquire the target stars, correct for atmospheric dispersion, stabilize the light onto the science fibers, and calibrate the spectrometer by injecting known wavelength sources such as a laser frequency comb. Here we provide an overview of the overall opto-mechanical design and system requirements of the Port Adapter. We also describe the development of system error budgets and testplans to meet those requirements.

Cassegrain port↗

EO-1 Hyperion Reflectance Time Series at Calibration and Validation Sites: Stability and Sensitivity to Seasonal Dynamics

This study evaluated Earth Observing 1 (EO-1) Hyperion reflectance time series at established calibration sites to assess the instrument stability and suitability for monitoring vegetation functional parameters. Our analysis using three pseudo-invariant calibration sites in North America indicated that the reflectance time series are devoid of apparent spectral trends and their stability consistently is within 2.5-5 percent throughout most of the spectral range spanning the 12-plus year data record. Using three vegetated sites instrumented with eddy covariance towers, the Hyperion reflectance time series were evaluated for their ability to determine important variables of ecosystem function. A number of narrowband and derivative vegetation indices (VI) closely described the seasonal profiles in vegetation function and ecosystem carbon exchange (e.g., net and gross ecosystem productivity) in three very different ecosystems, including a hardwood forest and tallgrass prairie in North America, and a Miombo woodland in Africa. Our results demonstrate the potential for scaling the carbon flux tower measurements to local and regional landscape levels. The VIs with stronger relationships to the CO2 parameters were derived using continuous reflectance spectra and included wavelengths associated with chlorophyll content and/or chlorophyll fluorescence. Since these indices cannot be calculated from broadband multispectral instrument data, the opportunity to exploit these spectrometer-based VIs in the future will depend on the launch of satellites such as EnMAP and HyspIRI. This study highlights the practical utility of space-borne spectrometers for characterization of the spectral stability and uniformity of the calibration sites in support of sensor cross-comparisons, and demonstrates the potential of narrowband VIs to track and spatially extend ecosystem functional status as well as carbon processes measured at flux towers.

Calibration↗

Stability Assessment of OCO-2 Radiometric Calibration Using Aqua MODIS as a Reference

With three imaging grating spectrometers, the Orbiting Carbon Observatory-2 (OCO-2)measures high spectral resolution spectra (λ/∆λ≈19,000) of reflected solar radiation within the molecular oxygen (O2) A-band at 0.765 μm and two carbon dioxide (CO2) bands at 1.61 and 2.06 μm. OCO-2 uses onboard lamps with a reflective diffuser, solar observations through a transmissive diffuser, lunar measurements, and surface targets for radiometric calibration and validation. Separating calibrator aging from instrument degradation poses a challenge to OCO-2. Here we present a methodology for trending the OCO-2 Build 8R radiometric calibration using OCO-2 nadir observations over eight desert sites and nearly simultaneous observations from Moderate Resolution Imaging Spectroradiometer (MODIS) with sensor viewing zenith angles of 15 ± 0.5°. For the O2 A-band, this methodology is able to quantify a drift of−0.8 ± 0.1% per year and capture a small error in correcting the aging of the solar calibrator. For the other two OCO-2 bands, no measurable changes were seen, indicating less than 0.1% and less than 0.3% per year drift in the radiometric calibration of Band 2 and Band 3, respectively.

radiometric calibration↗

AIRS radiometric calibration validation for climate research

Climate research using data from satellite based radiometers makes extreme demands on the traceability and stability of the radiometric calibration. The selection of a cooled grating array spectrometer for the Atmospheric Infrared Sounder, AIRS, is key, but does not ensured that AIRS data will be of climate quality. Additional design features, plus additional pre-launch testing, and extensive on-orbit calibration subsystem monitoring beyond what would suffice for application of the data to weather forecasting were required to ensure the radiometric data quality required for climate research. Validation that climate data quality are being generated makes use of the sea surface skin temperatures (SST and (obs-calc).

calibration↗

Spacecraft instrument calibration and stability

The following topics are covered: instrument degradation; the Solar Backscatter Ultraviolet (SBUV) Experiment; the Total Ozone Mapping Spectrometer (TOMS); the Stratospheric Aerosol and Gas Experiment 1 (SAGE-1) and SAGE-2 instruments; the Solar Mesosphere Explorer (SME) UV ozone and near infrared airglow instruments; and the Limb Infrared Monitor of the Stratosphere (LIMS).

Gille, J. C.↗

AIRS Science Accomplishments Version 4.0/Plans for Version 5

This talk is about accomplishments with AIRS data and what we have learned from almost three years of data what part of this is emerging in Version 4.0 what part we would like to see filtering into Version 5.0 and what part constitute limitations in the AIRS requirements, such as spectral and spatial resolution, which have to be deferred to the wish list for the next generation hyperspectral sounder. The AIRS calibration accuracy at the 1OOmK and stability at the 6 mK/year level are amazing. It establishes the unique capability of a cooled grating array spectrometer in Earth orbit for climate research. Data which are sufficiently clear to match the radiometric accuracy of the instrument, have a yield of less than 1%. This is OK for calibration. The 2616/cm window channel combined with the RTG.SST for tropical ocean allow excellent assessment radiometric calibration accuracy and stability. For absolute calibration verification 100mK is the limit due to cloud contamination. The 10 micron window channels can be used for stability assessment, but accuracy is limited at 300mK due to water continuum absorption uncertainties.

lessons learned↗

Application of Atmospheric Infrared Sounder (AIRS) Data to Climate Research

The application of hyper spectral radiometric data to climate research requires very high absolute radiometric accuracy and stability. We use cloud-free tropical ocean data from the Atmospheric InfraRed Sounder (AIR) Calibration Data Subset (ADCS) to show that the radiometric precision and stability required climate applications has been achieved. The sea surface skin temperatures derived from the AIRS 2616cm-1 super window channel are stable relative to the RTG.SST at the better than 8 mK/year level, and the spectral calibration is stable at the 1 ppm/year level. The excellent stability and accuracy are the result of the implementation of AIRS as a grating array spectrometer, which is cooled and stabilized within 10 mK at 155 K. Analysis of daily measurements of the temperature gradient between the surface and 7 km altitude show that the AIRS Calibration Data Subset has applications which extend its original intent for calibration support to climate research. The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua satellite was launched into polar orbit in May 2002. AIRS covers the spectral region from 640 to 2700 cm-1 with 2378 independent channels and represents the first of a new generation of hyper spectral resolution sounders in support of global sounding data for weather forecasting and climate research.

infrared↗

On the radiometric stability of the shuttle borne solar backscatter ultraviolet spectrometer

The Shuttle Solar Backscatter Ultraviolet (SSBUV) spectrometer instrument provides regular in-orbit calibration checks on the SBUV/2 ozone/solar irradiance monitoring instruments which are being flown routinely on NOAA operational satellites. The goal of the long-term ozone monitoring program is to detect possible changes in stratospheic ozone with a two sigma accuracy of approximately 1 percent over the course of a decade. This translates into a requirement that the SSBUV instrument be calibrated to a one sigma precision of 1 percent at the wavelengths used for ozone monitoring. We have previously shown that the precision of the SSBUV calibrations is such that we can meet this requirement. Here we discuss SSBUV radiometric sensitivity changes occurring as a result of the first two Space Shuttle flights. Finally, we present and compare SSBUV solar irradiance measurements taken during these flights.

Cebula, Richard P.↗

In-flight validation and calibration of the spectral and radiometric characteristics of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS)

Through an in-flight calibration experiment at Rogers Dry Lake, California on September 20, 1989, the radiometric and spectral properties of AVIRIS were determined. In-flight spectral channel positions and the spectral response function in 10 regions of the AVIRIS spectral range, taking in all four spectrometers, are shown to agree closely with the corresponding parameters measured in the laboratory. The intraflight stability for the Rogers Dry Lake calibration site is better than 2 percent with the exception of the strong atmospheric water absorptions where the measured radiance is close to zero. This experiment has provided both direct generation of an in-flight spectral and radiometric calibration and validation of the laboratory calibration at the reported level accuracy.

Green, Robert O.↗