Discharge characteristics of some copper oxide-magnesium thermal cells.
Design influence on discharge characteristics of copper oxide magnesium thermal cells
Thaller, L. H.↗
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Thermal Management of Primary Fuel Cell Systems
Seminar providing an overview of thermal management for primary fuel cells. This presentation does not provide detailed engineering solutions or specific fuel cell designs but is intended to help scientists and engineers from multiple technical disciplines outside of Thermal learn to ask the most pertinent questions when considering a fuel cell thermal design.
Primary Fuel Cell↗
Inverted Metamorphic AlGaInAs/GaInAs Tandem Thermophotovoltaic Cell Designed for Thermal Energy Grid Storage Application
We demonstrate an inverted metamorphic multijunction (IMM) photovoltaic cell comprising lattice-mismatched 1.2 eV AlGaInAs and 1.0 eV GaInAs junctions optimized for high-temperature thermophotovoltaic (TPV) applications. This device differs from traditional IMM solar cells because the mismatched junctions are grown at a single lattice constant. This architecture enables removal of the compositionally graded buffer that otherwise filters light from the junctions below and absorbs sub-bandgap light via free-carrier absorption. Sub-bandgap absorption dramatically reduces the efficiency of TPV systems using high reflectivity cells to enable band edge spectrum filtering. Three components required development to enable this device: (1) a lattice-mismatched 1.2 eV AlGaInAs junction, (2) a metamorphic contact layer grown after the graded buffer, and (3) a transparent tunnel junction that sits in front of the 1.0 eV GaInAs junction. Growth conditions that minimize oxygen defect incorporation maximize AlGaInAs cell quality, enabling a 0.41 V bandgap open circuit voltage offset at 22 mA/cm2 under AM1.5D. A mismatched GaInAs:Se layer is developed as a low resistance contact. Lastly, we develop a GaAsSb:C/GaInP:Se tunnel junction suitable for high-power densities with more transparency than the GaAsSb:C/GaInAs:Se structure used in past IMM cells. We characterize the tandem device under a high-intensity spectrum that approximates the emission from a 2150°C blackbody radiator and deduce a projected ideal TPV efficiency of 39.9% at ~30% of the blackbody irradiance and 36% ideal TPV efficiency under the full 118 W/cm2 irradiance. Improvements to the back-surface reflectivity and series resistance are expected to increase the ideal TPV efficiency well above 40%.
25 ENERGY STORAGE↗
32 bit digital optical computer - A hardware update
Such state-of-the-art devices as multielement linear laser diode arrays, multichannel acoustooptic modulators, optical relays, and avalanche photodiode arrays, are presently applied to the implementation of a 32-bit supercomputer's general-purpose optical central processing architecture. Shannon's theorem, Morozov's control operator method (in conjunction with combinatorial arithmetic), and DeMorgan's law have been used to design an architecture whose 100 MHz clock renders it fully competitive with emerging planar-semiconductor technology. Attention is given to the architecture's multichannel Bragg cells, thermal design and RF crosstalk considerations, and the first and second anamorphic relay legs.
Guilfoyle, Peter S.↗
Nickel cadmium battery performance modelling
The development of a model to predict cell/battery behavior given databases of temperature is described. The model accommodates batteries of various structural as well as thermal designs. Cell internal design modifications can be accommodated as long as the databases reflect the cell's performance characteristics. Operational parameters can be varied to simulate any number of charge or discharge methods under any orbital regime. The flexibility of the model stems from the broad scope of input variables and allows the prediction of battery performance under simulated mission or test conditions.
Clark, K.↗
Barrier Design to Prevent Metal-Induced Degradation and Improve Thermal Stability in Perovskite Solar Cells
Metal-contact-induced degradation and escape of volatile species from perovskite solar cells necessitate excellent diffusion barrier layers. We show that metal-induced degradation limits thermal stability in several perovskite chemistries with Au, Cu, and Ag gridlines even when the metal is separated from the perovskite by a layer of indium tin oxide (ITO). Channels in a sputtered ITO layer that align with perovskite grain boundaries are pathways for metal and halide diffusion into or out of the perovskite. Planarizing the perovskite morphology with a spin-cast organic charge-transport layer results in a subsequently deposited ITO layer that is uniform and impermeable. We show that it is critical to seal the edges of the active layers to prevent escape of volatile species. We demonstrate 1000 h thermal stability at 85 °C in CH 3 NH 3 PbI 3 solar cells with complete-coverage silver contacts. Lastly, our barrier layer design enables long-term thermal stability of perovskite solar cells, a critical step to commercialization.
14 SOLAR ENERGY↗
Thermal Runaway Severity Reduction Assessment and Implementation: On Li-Ion Batteries
Preventing cell-cell thermal runaway propagation and flames/sparks from exiting battery enclosure is possible with proper thermal & electrical design and cell thermal runaway ejecta/effluent management and can be had with minimal mass/volume penalty.
Darcy, Eric↗
Enabling fast charging – Battery thermal considerations
Battery thermal barriers are reviewed with regards to extreme fast charging. Present-day thermal management systems for battery electric vehicles are inadequate in limiting the maximum temperature rise of the battery during extreme fast charging. If the battery thermal management system is not designed correctly, the temperature of the cells could reach abuse temperatures and potentially send the cells into thermal runaway. Furthermore, the cell and battery interconnect design needs to be improved to meet the lifetime expectations of the consumer. Each of these aspects is explored and addressed as well as outlining where the heat is generated in a cell, the efficiencies of power and energy cells, and what type of battery thermal management solutions are available in today’s market. Here, thermal management is not a limiting condition with regard to extreme fast charging, but many factors need to be addressed especially for future high specific energy density cells to meet U.S. Department of Energy cost and volume goals.
25 ENERGY STORAGE↗
Thermal Implications for Extreme Fast Charge
Present-day thermal management systems for battery electric vehicles are inadequate in limiting the maximum temperature rise of the battery during extreme fast charging. If the battery thermal management system is not designed correctly, the temperature of the cells could reach abuse temperatures and potentially send the cells into thermal runaway. Furthermore, the cell and battery interconnect design needs to be improved to meet the lifetime expectations of the consumer. Each of these aspects is explored and addressed as well as outlining where the heat is generated in a cell, the efficiencies of power and energy cells, and what type of battery thermal management solutions are available in today's market. Thermal management is not a limiting condition with regard to extreme fast charging, but many factors need to be addressed especially for future high specific energy density cells to meet U.S. Department of Energy cost and volume goals.
33 ADVANCED PROPULSION SYSTEMS↗
Thermally-Integrated Fuel-Cell/Electrolyzer Systems
New and more efficient method of thermally integrating fuel cell and electrolyzer designed. Design addresses thermal integration of fuel cell and water electrolyzer in regenerative fuel-cell system. System configuration provides thermal integration with single coolant loop. Configuration does not have thermal limitations associated with trying to transfer heat between two coolant loops. Design less complex and more reliable than prior designs. Adaptable to standalone power systems in conjunction with solar panels for remote-area applications.
Garow, J.↗
Battery Thermal Characterization
The operating temperature is critical in achieving the right balance between performance, cost, and life for both Li-ion batteries and ultracapacitors. The chemistries of advanced energy-storage devices - such as lithium-based batteries - are very sensitive to operating temperature. High temperatures degrade batteries faster while low temperatures decrease their power and capacity, affecting vehicle range, performance, and cost. Understanding heat generation in battery systems - from the individual cells within a module, to the inter-connects between the cells, and across the entire battery system - is imperative for designing effective thermal-management systems and battery packs. At NREL, we have developed unique capabilities to measure the thermal properties of cells and evaluate thermal performance of battery packs (air or liquid cooled). We also use our electro-thermal finite element models to analyze the thermal performance of battery systems in order to aid battery developers with improved thermal designs. NREL's tools are used to meet the weight, life, cost, and volume goals set by the U.S. Department of Energy for electric drive vehicles.
25 ENERGY STORAGE↗
Feasibility study: Atmospheric general circulation experiment, volume 1
The atmospheric general circulation experiment (AGCE) uses a rotating fluid flow cell assembly. The key technical areas affecting the feasibility of the design and operation of the AGCE are investigated. The areas investigated include materials for the flow cell assembly, thermal design, high voltage power supply design, effective retrieval and handling of experiment data and apparatus configuration. Several materials, DMSO and m-tolunitrile, were selected as candidate fluids for the flow cell principally for their high dielectric constant which permits the high voltage power supply design to be held to 15 kV and still simulate terrestrial gravity. Achievement of a low dissipation factor in the fluid to minimize internal heating from the applied electrical field depends strongly on purification and handling procedures. The use of sapphire as the outer hemisphere for the flow cell provides excellent viewing conditions without a significant impact on attaining the desired thermal gradients. Birefringent effects from sapphire can be held to acceptably low limits. Visualization of flow fluid is achieved through the motion of a dot matrix formed by photochromic dyes. Two dyes found compatible with the candidate fluids are spiropyran and triarylmethane. The observation of the dot motion is accomplished using a flying spot scanner.
Homsey, R. J.↗
Thermal analysis of prismatic Li-SOCl2 primary cells
A thermally efficient design for prismatic Li-SOCl2 primary cells is proposed, for application to NASA missions requiring overall power capacities of 20-22 Ah. Thermal resistances of 20 Ah capacity cells were calculated along paths parallel to and normal to the electrodes. Stacking six cells in series to achieve the required 17-28 V potential, it is found that safe operation at C/5 rates (4 A discharge) is possible, maintaining the internal cell temperature below 80 C. Higher discharge rates than C/5 are possible by decreasing the total thermal resistance via providing free spaces between cells.
Cho, Young I.↗
(sup 4)He Experiments Near T(sub lambda) in a Low-Gravity Simulator
We report on our latest measurements of gravity reduction in the low-gravity simulator. We made these measurements using a new thermal conductivity cell design that is 0.5cm in diameter and 0.5cm in height.
gravity low-gravity simulator thermal conductivity↗
Effect of NASA advanced designs on thermal behavior of Ni-H2 cells
As part of an overall effort to advance the technology of nickel-hydrogen batteries for low Earth orbit (LEO) applications, advanced designs for individual pressure vessel (IPV) nickel-hydrogen cells have been conceived. These designs incorporate alternative methods of oxygen recombination which affect the thermal behavior of the cells. The effect of these oxygen recombination methods on the cell temperature profiles is examined.
Gonzalez-Sanabria, Olga D.↗
Effect of NASA advanced designs on thermal behavior of Ni-H2 cells
As part of an overall effort to advance the technology of nickel-hydrogen batteries for low earth orbit (LEO) applications, advanced designs for individual pressure vessel (IPV) nickel-hydrogen cells have been conceived. These designs incorporate alternative methods of oxygen recombination which affect the thermal behavior of the cells. The effect of these oxygen recombination methods on the cell temperature profiles will be examined.
Gonzalez-Sanabria, Olga D.↗
He-4 Experiments Near T_Lambda in a Low-Gravity Simulator
We report on our latest measurements of gravity reduction in the low-gravity simulator. We made these measurements using a new thermal conductivity cell design that is 0.5cm in diameter and 0.5cm in height.
Helium-4↗
Bipolar nickel-hydrogen battery design
The initial design for the NASA-Lewis advanced nickel-hydrogen battery is discussed. Fabrication of two 10-cell boilerplate battery stacks will soon begin. The test batteries will undergo characterization testing and low Earth orbit life cycling. The design effectively deals with waste heat generated in the cell stack. Stack temperatures and temperature gradients are maintained to acceptable limits by utilizing the bipolar conduction plate as a heat path to the active cooling fluid panel external to the edge of the cell stack. The thermal design and mechanical design of the battery stack together maintain a materials balance within the cell. An electrolyte seal on each cell frame prohibits electrolyte bridging. An oxygen recombination site and electrolyte reservoir/separator design does not allow oxygen to leave the cell in which it was generated.
Koehler, C. W.↗