Soil chemical extractions can alter potassium coordination in agricultural soils: A combined wet che
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Schmidt, Emma J.↗
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Compact, High-Efficiency Air Handling Unit (CHE-AHU) for Residential HVAC Systems
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Dang, Thong↗
Exploring Multidimensional Spatial-Temporal Hydropower Operational Flexibilities by Modeling and Optimizing Water-Constrained Cascading Hydroelectric Systems
Because of unique characteristics such as clean and cost-competitive electricity as well as fast-ramping and storage abilities, the power industry continues to evolve its operation strategies for cascading hydroelectric (CHE) systems for providing enhanced values to the grid, especially under the deeper renewable resource integration. However, existing operation practices of CHEs predate the integration of renewables, which could prohibit the effective utilization of their inherent flexibilities in delivering maximum financial benefits and providing valuable grid services to the power system and electricity market operations. Indeed, modeling and optimizing these resource-limited while flexible CHE assets with uncertainties and imperfect information across multiple spatial-temporal dimensions present significant challenges. To facilitate CHE facility operators in effectively coordinating water usage and hydropower plant operations across multiple timescales, this project aims to fill the existing gaps by developing a suite of accurate water inflow (WI) forecast models as well as enhanced CHE modeling and optimization approaches with proper consideration of their unique characteristics, which would help explore their multidimensional spatial-temporal operational flexibility potentials. The developed approaches could better align reservoir operation strategies with variability and uncertainty of future water availability. They can also promote more effective utilization of multidimensional spatial-temporal hydropower operational flexibility potentials by designing long-term evacuation plans of reservoirs and short-term operation of CHEs, along with their coordination with other types of renewables. The project leverages various resources to facilitate the research and development activities, including actual characteristics data of CHE systems and a library of current and future cases of Portland General Electric (PGE). These realistic data enable the project team to study how to maximize the value of CHEs under current and future portfolios and evaluate opportunities to improve operation practices.
13 HYDRO ENERGY↗
Effects of Liner Length and Attenuation on NASA Langley Impedance Eduction
This study explores the effects of liner length and attenuation on the CHE (convected Helmholtz equation) impedance eduction method, in which the surface impedance of an acoustic liner is inferred through an iterative process based on repeated solutions to the convected Helmholtz equation. Wire mesh-over-honeycomb and perforate-over-honeycomb acoustic liners are tested in the NASA Langley Grazing Flow Impedance Tube, and the resultant data are processed using two impedance eduction methods. The first is the CHE method, and the second is a direct method (labeled the KT method) that uses the Kumaresan and Tufts algorithm to compute the impedance directly. The CHE method has been extensively used for acoustic liner evaluation, but experiences anomalous behavior under some test conditions. It is postulated that the anomalies are related to the liner length and/or attenuation. Since the KT method only employs data measured over the length of the liner, it is expected to be unaffected by liner length. A comparison of results achieved with the two impedance eduction methods is used to explore the interactive effects of liner length and attenuation on the CHE impedance eduction method.
Jones, M. G.↗
Color Histogram Diffusion for Image Enhancement
Various color histogram equalization (CHE) methods have been proposed to extend grayscale histogram equalization (GHE) for color images. In this paper a new method called histogram diffusion that extends the GHE method to arbitrary dimensions is proposed. Ranges in a histogram are specified as overlapping bars of uniform heights and variable widths which are proportional to their frequencies. This diagram is called the vistogram. As an alternative approach to GHE, the squared error of the vistogram from the uniform distribution is minimized. Each bar in the vistogram is approximated by a Gaussian function. Gaussian particles in the vistoram diffuse as a nonlinear autonomous system of ordinary differential equations. CHE results of color images showed that the approach is effective.
Kim, Taemin↗
Evaluation of a Variable Facesheet Liner Configuration in Grazing Incidence for Broadband Noise Reduction
Abstract Tests were conducted in the NASA Langley Grazing Flow Impedance Tube (GFIT) to determine the broadband noise reduction capability of a variable facesheet liner. Three uniform liners were designed to achieve sound absorption over distinct frequency regimes at Mach 0.0. Each liner was fabricated and tested in the GFIT at sound pressure levels of 120 and 140 dB, and at tangential flow velocities up to Mach 0.5. A variable facesheet liner was fabricated to combine the geometries of these three liners, such that the facesheet geometry (hole diameter and porosity) was varied across the liner surface. The Prony method was used to educe the impedance of each sample, and these impedances were input to the CHE (Convected Helmholtz Equation) propagation code to predict the acoustic pressure profiles in the GFIT. Comparisons of predicted and measured acoustic pressure profiles were used to confirm the uniformity of all four liners, and to demonstrate the suitability of the CHE code in analysis of the variable facesheet concept. Results showed good comparison at no flow and Mach 0.3, and acceptable comparison at Mach 0.5. The variable facesheet liner provides enhanced broadband noise reduction at the no-flow condition for which it was designed, but further optimization is needed to target flow conditions.
acoustic↗
Evaluation of a Variable Facesheet Liner Configuration in Grazing Incidence for Broadband Noise Reduction
Tests were conducted in the NASA Langley Grazing Flow Impedance Tube (GFIT) to determine the broadband noise reduction capability of a variable facesheet liner. Three uniform liners were designed to achieve sound absorption over distinct frequency regimes at Mach 0.0. Each liner was fabricated and tested in the GFIT at sound pressure levels of 120 and 140 dB, and at tangential flow velocities up to Mach 0.5. A variable facesheet liner was fabricated to combine the geometries of these three liners, such that the facesheet geometry (hole diameter and porosity) was varied across the liner surface. The Prony method was used to educe the impedance of each sample, and these impedances were input to the CHE (Convected Helmholtz Equation) propagation code to predict the acoustic pressure profiles in the GFIT. Comparisons of predicted and measured acoustic pressure profiles were used to confirm the uniformity of all four liners, and to demonstrate the suitability of the CHE code in the analysis of the variable facesheet concept. Results showed good comparison at no flow and at Mach 0.3, and acceptable comparison at Mach 0.5. The variable facesheet liner provided enhanced broadband noise reduction at the no-flow condition for which it was designed, but further optimization is needed to target flow conditions.
acoustic↗
Theoretical Nuclear Physics (Final Report)
This award from the Department of Energy supported the PI, Che-Ming Ko of Texas A&M University, for the period from April 1, 2022 to August 31, 2025 at an amount of $150,000 to carry out the project entitled “Theoretical nuclear physics”. The scientific goal of the project was to develop transport models for heavy ion collisions at various energies and with both stable and rare isotopes and to carry out systematic comparisons of theoretical predictions with experimental data. Results from this project has led to the publication of 14 papers in and the submission of 10 papers to peer-reviewed journals, the publication of 3 papers in and the submission of 1 paper to conference proceedings. Also, the PI has presented 12 invited talks at international conferences and workshops. In the following, a brief summary of these results is given.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Electrochemical CO2 Reduction over Metal-/Nitrogen-Doped Graphene Single-Atom Catalysts Modeled Using the Grand-Canonical Density Functional Theory
Renewably driven, electrochemical conversion of carbon dioxide into value-added products is expected to be a critical tool in global decarbonization. However, theoretical studies based on the computational hydrogen electrode largely ignore the nonlinear effects of the applied potential on the calculated results, leading to inaccurate predictions of catalytic behavior or mechanistic pathways. Here, we use grand canonical density functional theory (GC-DFT) to model electrochemical CO2 reduction (CO2R) over metal- and nitrogen-doped graphene catalysts (MNCs) and explicitly include the effects of the applied potential. We used GC-DFT to compute the CO2 to CO reaction intermediate energies at -0.3, -0.7, and -1.2 VSHE catalyzed by MNCs each doped with 1 of the 10 3d block metals coordinated by four pyridinic nitrogen atoms. Our results predict that Sc-, Ti-, Co-, Cu-, and Zn-N4Cs effectively catalyze CO2R at moderate to large reducing potentials (-0.7 to -1.2 VSHE). ZnN4C is a particularly promising electrocatalyst for CO2R to CO both at low and moderate applied potentials based on our thermodynamic analysis. Our findings also explain the observed pH independence of CO production over FeN4C and predict that the rate-determining step of CO2R over FeN4C is not *CO2- formation but rather *CO desorption. Additionally, the GC-DFT-computed density of states analysis illustrates how the electronic states of MNCs and adsorbates change non-uniformly with applied potential, resulting in a significantly increased *CO2- stability relative to other intermediates and demonstrating that the formation of the adsorbed *CO2- anion is critical to CO2R activation. This work demonstrates how GC-DFT paves the way for physically realistic and accurate theoretical simulations of reacting electrochemical systems.
CO2 reduction↗
Shock-induced chemical decomposition and overdriven detonation in hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) single crystals
Understanding the differences in the shock compression and detonation response of insensitive high explosives (IHEs) and conventional HEs (CHEs) is a long-standing need in HE science and technology. Having previously examined 1,1-diamino-2,2-dinitroethene (FOX-7) IHE single crystals, the shock and detonation response of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)—a widely used CHE—was determined using wave profile measurements in ~250 μm thick single crystals shock compressed to 63 GPa. In marked contrast to FOX-7, RDX single crystals shocked along the [100] and [111] orientations showed wave profile features consistent with chemical decomposition onset at 15 GPa. These features were more pronounced for [100] RDX, suggesting a higher decomposition rate compared to [111] RDX. At 51 GPa and above, flat-topped single waves were observed for both orientations, showing the classic Chapman–Jouget (C–J) detonation response in which the decomposition is completed within the detonation front. The Hugoniot states and sound speeds determined for the detonation products were similar for both [100] and [111] orientations, showing that the overdriven detonation response for RDX does not depend on crystal orientation. The C–J pressure for RDX single crystals (35 GPa)—determined experimentally—is comparable to that of FOX-7. However, compared to FOX-7, chemical decomposition onset for RDX occurs at much lower pressures and the overdriven C–J detonation response occurs at higher pressures. Lastly, the present findings constitute the first experimental comparison of the shock and detonation response of conventional and insensitive HE single crystals over a broad pressure range below and above the C–J pressure.
36 MATERIALS SCIENCE↗
Large-scale Hydrogen Storage – Risk Assessment Seattle City Light and Port of Seattle [Abstract]
This CRADA presents the strategy that Pacific Northwest National Laboratory (PNNL) and Sandia National Laboratories (SNL) will take to support Seattle City Light (SCL), and the Port of Seattle (Port) in performing a risk assessment of large-scale hydrogen storage. Risk assessment is often used to ensure that adequate measures are taken to protect workers and the public, the environment, infrastructure, and assets. A detailed risk assessment can also be used to direct funding and upgrades, to specific components and sub-systems in order to mitigate risks to the larger system. In this way risk assessments are often employed as a part of a larger risk management strategy, with the goal of minimizing the occurrence of hazards and to identify means to limit their consequences. Risk assessment is often used to engage and inform regulators, and to communicate how specific regulations are being met. However, it is important to note that the proposed work is not intended for SCL and the Port to use in order to gain regulatory acceptance for their proposed activities. The work performed as a part of this effort will be a preliminary risk assessment for early-stage component and system designs and should be considered research and development (R&D). As such, the proposed work will be performed to a quality level and design maturity consistent with R&D and is not considered appropriate for final safety analysis and regulatory compliance purposes. Previous and on-going work at SCL and the Port demonstrated the utility of deploying hydrogen systems at the Port. The deployment of hydrogen at the Port is a part of a larger vision of using hydrogen to address a range of issues for SCL and the Port. These include large-scale fueling of MD/HD vehicles, cargo-handling equipment (CHE), and harbor vessels to reduce emissions; support of adjacent LD vehicles; support of critical port operations during extreme events (i.e., resiliency); deferral of more capital- and time-intensive electrical distribution system upgrades while still supporting evolving port operations and decarbonization efforts; facilitating electrification by establishing energy storage as a grid resource, starting at strategic port locations; creation of a flexible market resource that can be used by SCL to generate revenue via arbitrage; support of planned future maritime operations that involve heavy use of hydrogen for ocean-going vessels; and future end-use applications involving natural gas pipeline hydrogen injection. Ultimately, the success of these activities is underpinned by the deployed storage capacity. Large-scale deployment of hydrogen systems will require hydrogen storage at a scale that has not been demonstrated. In addition, the ideal location for such multi-use systems is near the end user which will often necessitate deploying into urban and/or industrial areas. A detailed risk assessment using the Port as a test case is necessary to ensure the deployment of large-scale hydrogen is successful. Many technologies have been proposed for hydrogen storage; however, these technologies need to be analyzed as they apply to an actual site. The physical infrastructure and hydrogen use cases for the Port will be analyzed, and a risk assessment for compressed hydrogen, liquified hydrogen, and Liquid Organic Hydrogen Carrier (LOHC) storage will be performed. These risk assessments will be useful for understanding how each of these technologies would perform in terms of facility and public safety. The operating states of the proposed hydrogen systems at the Port will be analyzed and incorporated into the storage risk assessment. Scalability will also be analyzed to understand how future port uses would affect the overall risk assessment. Finally, using the risk assessment as a tool to inform engagement and to gain stakeholder acceptance will be explored.
08 HYDROGEN↗
High Spatial Resolution Mid-IR Imaging of V838 Monocerotis: Evidence of New Circumstellar Dust Creation
The eruptive variable V838 Monocerotis experienced three dramatic outbursts in early 2002. Its unexpectedly erratic photometric behavior wes matched by strong spectroscopic variability, in which the srar transitioned through the F, K, G spectral type s in 2002 February, reseabled a M5 supergiant by 2002 Aprll, and had a L-type super qiant spectram in 2002 October. The star is also infamous for producisg e spectacu lar light echo whose evolction has beer traced by HST/ACS. We report high sFatial resolution 11.2 and 18.1 micron imagicq of V838 Nonoceroris obrained with Genini Ob servatory's Klchelle in 2007 March. The 2007 flux density of the unresclved stellar core of is rouqhly 2 tixes brighter than zhaz observed in 2C04. We interpret tkese aata as evidecce t-at V838 Mon has experienced a new circums~ellar dust creatioc evezt. We suggest that this newly c reated dust is Likely clumpy, and speculate that one (or ore) of Ekese clumps migh t have passed through the line-cf-sight in late 2036, prodccing the brief rnalti-wav elength pkotonetric event reported by Bond (2006) and Yunari ez a1 (2007). A gap o f spatially exzended therrrzl (18 micron) emission is present over radial distances of 1860 - 93000 AU from che central source. Assuming ejecta material expands at a constant velocity of 300-500 km/s, this gap suggests that no prior significanz circ unstellar dust production events have occurred withiin the past approx. 900-1500 years.
Winsiewski, John P.↗
Comparative Study of Impedance Eduction Methods: DLR Tests and Methodology - Part 1
The absorption efficiency of acoustic liners used in aircraft engines is characterized by the acoustic impedance. World wide, many grazing ow test rigs and eduction methods are available that provide values for that impedance. However, a direct comparison and assessment of the data of the di erent rigs and methods is often not possible because test objects and test conditions are quite di erent. Only a few papers provide a direct comparison. Therefore, this paper together with a companion paper, present data measured with a reference test object under similar conditions in the DLR and NASA grazing ow test rigs. Additionally, by applying the in-house methods Liner Impedance Non-Uniform ow Solving algorithm (LINUS, DLR) and Convected Helmhholtz Equation approach (CHE, NASA) on the data sets, similarities and differences due to underlying theory are identi ed and discussed.
Busse-Gerstengarbe, Stefan↗
Amorphous Analogs of Martian Global Soil: Pair Distribution Function Analyses and Implications for Scattering Models of Chemin X-ray Diffraction Data
Soils on Mars have been analyzed by the Mars Exploration Rovers (MER) and most recently by the Mars Science Laboratory (MSL) rover. Chemical analyses from a majority of soil samples suggest that there is a relatively uniform global soil composition across much of the planet. A soil site, Rocknest, was sampled by the MSL science payload including the CheMin X-ray diffractometer and the Alpha Particle X-ray Spectrometer (APXS). Che- Min X-ray diffraction (XRD) data revealed crystalline phases and a broad, elevated background, indicating the presence of amorphous or poorly ordered materials (Fig 1). Based on the chemical composition of the bulk soil measured by APXS and the composition of crystalline phases derived from unit-cell parameters determined with CheMin data, the percentages of crystalline and amorphous phases were calculated at 51% and 49%, respectively. Attempts to model the amorphous contribution to CheMin XRD patterns were made using amorphous standards and full-pattern fitting methods and show that the broad, elevated background region can be fitted by basaltic glass, allophane, and palagonite. However, the modeling shows only that these phases have scattering patterns similar to that for the soil, not that they represent unique solutions. Here, we use pair distribution function (PDF) analysis to determine the short-range order of amorphous analogs in martian soils and better constrain the amorphous material detected by CheMin.
Achilles, C. N.↗
Mineralogical and Geochemical Trends of the Murray Mudstones, Gale Crater: A Combined Sample Analysis at Mars-Evolved Gas Analyzer and Chemistry and Mineralogy Instrument Assessment
The Murray formation is predominantly composed of lacustrine mudstone that forms the basal layer of Aeolis Mons (informally Mt. Sharp) in Gale Crater, Mars. The Murray formation has distinct iron and sulfur mineralogical variation within its stratigraphy detectable by the Chemistry Mineralogy (Che-Min) instrument consisting of magnetite/hematite in the lower Murray and higher hematite, CaSO4, and smectite content in the upper Murray. The objectives of this work were to evaluate the Sample Analysis at Mars Evolved Gas Analyzer (SAM-EGA) data to 1) Determine what SAM-EGA-detectable phases correlate or do not correlate with the Murray mineralogical composition detected by CheMin and 2) Utilize CheMin/SAM results to propose possible formation scenarios for the observed Murray mudstone mineralogy.
Sutter, B.↗
Evaluation of Variable Facesheet Liner Configurations for Broadband Noise Reduction
This paper investigates the broadband noise reduction properties of a distributed (variable) facesheet liner. Candidate uniform samples are selected using the Wave Propagation Model and Two-Parameter Model developed at the NASA Langley Research Center. Three uniform and one distributed facesheet samples are tested in the Normal Incidence Tube (NIT) at NASA Langley. Initial results show that the distributed facesheet sample possesses broadband noise reduction properties. Acoustic impedances educed from these NIT tests are used as inputs into the Convected Helmholtz Equation (CHE) propagation code developed at NASA Langley to synthesize the acoustic pressure field in the Grazing Flow Impedance Tube (GFIT) with no flow. Three uniform, one distributed, as well as one three-zone liner, oriented in two different directions, are investigated. Preliminary results showed the distributed facesheet and three-zone liners exhibit broadband noise reduction properties.
M C Brown↗
Biomass Harmonization and SAR Analysis with the Multi-mission Algorithm and Analysis Platform (MAAP)
The Multi‐mission Algorithm and Analysis Platform (MAAP) is a collaborative effort between NASA and the European Space Agency (ESA) to support above ground biomass (AGB) research in an open science framework. MAAP brings together relevant data, algorithms, and computing capabilities in a common cloud environment to address the challenges of sharing and processing data from field, airborne and satellite measurements. MAAP was publicly released in October 2021, providing computing capabilities co-located with the data, a collaborative coding and analysis environment, and a set of interoperable tools and algorithms developed to support the estimation and visualization of data. MAAP has allowed scientists from both North America and Europe to collaborate on the generation and analysis/visualization of data derived from multiple, discipline-adjacent missions in an open, collaborative environment that has reached beyond traditional scientific investigation. MAAP has been used to support multiple scientific activities. To date, existing LiDAR data from multiple platforms has been calibrated with field measurements and combined for more comprehensive and accurate estimates of above ground biomass AGB; these LiDAR platforms include airborne (e.g. LVIS), the International Space Station (NASA’s Global Ecosystem Dynamics Investigation (GEDI), and satellites (e.g. ICESat-2). The current challenge is to effectively and seamlessly combine the aforementioned LiDAR-based data with new data sources such as P-band RADAR from ESA’s upcoming BIOMASS mission, existing ESA Sentinel-1 C-band SAR, and the 30 PB/yr of high cadence global coverage L-band SAR data from the upcoming NASA-ISRO SAR (NISAR) mission. Recent analysis using MAAP merged ICESat-2 and optical data (Harmonized Landsat Sentinel) produced the most comprehensively precise estimate of boreal-wide AGB to date. Another effort using MAAP is the production and open distribution of global comparisons of AGB map estimates, including from ICESat-2 and GEDI, to bolster stakeholder uptake for policy applications. These map estimates will feed into the Intergovernmental Panel on Climate Change (IPCC) database, likely aiding the next Global Carbon Stocktake of the UNFCCC. Furthermore, the biomass retrieval intercomparison exercise BRIX-2 could benefit from the MAAP providing standardized test cases (based on airborne campaign and spaceborne data) allowing the community to develop and apply retrieval algorithms based on these test cases, while forthcoming SAR data training curricula could also use the MAAP as a teaching and learning platform. The MAAP is meeting the challenges inherent in international, open science collaboration and large scale computing with a platform that is entirely open source and cloud native, using open standards for data access, manipulation, protocols, and formats. The MAAP data system consists of a dedicated data store whose data is indexed in an online catalog conforming to established metadata, application programmatic interfaces (APIs), and service interface standards, using an implementation of the open sourced NASA Common Metadata Repository. Federation of user identities allows users from either NASA or ESA to access and consume services from the other using a unified metadata catalog for the data utilized across the ESA and NASA MAAP platforms. Similarly, we are exploring how to increase interoperability to achieve a common approach to packaging, orchestrating and executing algorithms, with interoperable access to data for subsetting, fast browse, and cloud-optimized access, all using interoperable standards such as those from the Open Geospatial Consortium (OGC). Designed for interoperability, ESA and NASA utilize a common architecture for the software platform. It provides a cloud-based algorithm development environment (ADE) that enables scientists to develop algorithms collaboratively with access to the MAAP data catalog as well as other data archives. MAAP provides an Eclipse Che-based ADE supporting both Python and R languages, popular in this biomass community. Algorithms developed and containerized within the ADE can be deployed to run to thousands of computational nodes in the MAAP’s data processing system (DPS), dramatically speeding up processing and giving scientists a rapid, iterative turnaround of results. NASA’s implementation of the DPS is based on the Hybrid Science Data System (HySDS) framework, used by NASA flight projects to produce Earth science standard products.
cloud computing↗
Improved measurement of the branching fraction of hc → γη′/η and search for hc → γπ0
Abstract The processesh c → γP(P=η′, η, π 0 ) are studied with a sample of (27.12±0.14)×10 8 ψ(3686) events collected by the BESIII detector at the BEPCII collider. The decayh c → γηis observed for the first time with the significance of 9.0σ, and the branching fraction is determined to be (3.77±0.55±0.13±0.26)×10 −4 , while$$ \mathcal{B} $$ B (h c → γη′) is measured to be (1.40±0.11±0.04±0.10)×10 −3 , where the first uncertainties are statistical, the second systematic, and the third from the branching fraction ofψ(3686)→ π 0 h c . The combination of these results allows for a precise determination of$$ {R}_{h_c}=\frac{\mathcal{B}\left({h}_c\to {\pi}^0\gamma \eta \right)}{\mathcal{B}\left({h}_c\to {\pi}^0\gamma {\eta}^{\prime}\right)}, $$ R h c = B h c → γη B h c → γ η ′ , which is calculated to be (27.0±4.4±1.0)%. The results are valuable for gaining a deeper understanding ofη − η′ mixing, and its manifestation within quantum chromodynamics. No significant signal is found for the decayh c →γπ 0 , and an upper limit is placed on its branching fraction of$$ \mathcal{B} $$ B (h c →γπ 0 )<5.0×10 −5 , at the 90% confidence level.
Physics↗