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The data was analyzed and two papers were written and published in the refereed journal: Meteoritics and Planetary Science. These paper describes the results of the study of the surface chemical composition of the asteroid Eros by the NEAR X-ray Fluorescence Spectrometer.
An operational mapping algorithm was developed to process measurements of individual species observed by different satellite instruments on board UARS. Based on Fast Fourier Synoptic Mapping (FFSM), the algorithm accounts for the precessing orbit of UARS, the error of individual instruments, and gaps associated with instrument duty cycle and the satellite yaw maneuver. It provides synoptic structure and evolution on periods as short as 1 day, derived collectively from all observations of an individual species. The algorithm was applied to synoptically map temperature, thickness, and several chemical constituents observed by the instruments: MLS, CLAES, ISAMS, and HALOE. Each field variable observed by these instruments was mapped twice-daily in continuous global time series several months long. Mapped behavior produced via FFSM was compared against standard archived products generated via Kalman filtering. The standard map products reveal similar behavior, but are limited to features of larger scale. Tracer structure that develops through flow deformation and attending transport is therefore represented in those products more coarsely, eventually being sheared down to scales that are no longer represented properly. The synoptic time series also reveal a diurnal cycle for several of the constituents, one that emerges clearly in their space-time spectra. The zonal and meridional structure of diurnal variability was mapped by filtering the space-time spectrum, an intermediate product of FFSM, to those scales resolved by the UARS sampling. Geographical variations of the diurnal cycle have also been evaluated in its seasonal-mean structure by compositing distributions at individual local times. Both were compared to diurnal variations in chemical models and in dynamical models that account for transport by the diurnal tide. Diurnal variations were found to introduce spurious behavior into the archived products generated via Kalman filtering, behavior that is misrepresented in those synoptic time series. Aliasing by under-sampled diurnal variations introduces a bias into the time-mean structure of archived products. That systematic error is manifested as anomalous wave structure in the time-mean fields. By contrast, synoptic time series generated via FFSM faithfully represent such behavior as varying diurnally, so it does not corrupt time-mean structure. Tracer structure mapped via the above algorithm was being applied to determine the Brewer-Dobson circulation of the stratosphere through Lagrangian considerations. Preliminary results are encouraging: They reveal diabatic ascent in the tropics, balanced by diabatic descent over the winter hemisphere. This Lagrangian description of transport derived from UARS tracer measurements would be potentially valuable for diagnosing interannual changes of transport, specifically, in relation to interannual changes of total ozone. Regrettably, support was reduced to 50% of the approved funding level, leaving this component incomplete.
Imaging spectrometers are invaluable instruments for robotic science exploration, enabling quantitative maps of physical and chemical properties at high spatial resolution. This is particularly valuable in remote missions to other planetary bodies like Mars. The PIXL instrument on the Mars 2020 rover will deploy an arm-mounted X-Ray fluorescence spectrometer to map chemical composition at sub-millimeter scales. Its high resolution places dramatic new demands on instrument placement accuracy and measurement time. We address these challenges using novel on board data analysis strategies inspired by FRC science autonomy research.
Vesta s surface mineralogy and composition have been studied for decades via telescopic spectroscopy and laboratory analyses of the howardite, eucrite, and diogenite (HED) meteorites, which are thought to originate from Vesta. Visible and infrared reflectance measurements by Dawn have broadly confirmed the paradigm established by Earth-based work, strengthening the Vesta-HED connection. The Dawn mission has achieved a milestone by completing the first chemical measurements of a main-belt asteroid using nuclear spectroscopy. Dawn s Gamma Ray and Neutron Detector (GRaND) has globally mapped the composition of Vesta, including the portions of the northern hemisphere not illuminated by solar radiation. GRaND is sensitive to the composition of the bulk regolith to depths of several decimeters. Abundances and/or detection limits for specific elements and elemental ratios, such as H, Fe, Si, Fe/O, Fe/Si, and K, have been measured. Variations in the average atomic mass and neutron macroscopic absorption cross section have been characterized. The measurements constrain the relative proportions of HED whole-rock end-members, providing measurements of the pyroxene and plagioclase content of the regolith, thereby constraining the processes underlying Vesta s differentiation and crustal evolution. The spatial resolution of GRaND is sufficient to determine basin-average compositions of Veneneia and Rheasilvia, which may contain outcrops of Vesta s olivine-rich mantle. While the elemental composition of Vesta s regolith is similar to the meteorites, there are notable departures from HED whole-rock compositions. While these differences are not sufficient to topple the Vesta-HED paradigm, they provide insight into global-scale processes that have shaped Vesta s surface. Questions addressed by the analysis of GRaND data include: (i) Is Vesta the source of the Fe-rich mesosiderites? (ii) Are evolved, igneous lithologies present on Vesta s surface? (iii) What are the origins of exogenic materials found in Vesta s regolith? (iv) Is the vestan mantle exposed within the southern basins?
Results from studies of the 2.1- to 0.3-my-old Springerville volcanic field are summarized, including research on geologic mapping, volume, age, chemical characterization, composition, temporal variations, and effusion and migration rates. It is found that the rocks of the field are predominantly alkali olivine and transitional basalts, with subordinate proportions of hawaiite and tholeiite. The evolution of the field is described as an early pulse of tholeiitic volcanism followed by a peak in alkali olivine basalt production in the middle of the field's eruptive history, and a late peak in evolved alkalic rock production about 0.5 my after the alkali olivine basalt peak.
The 1992 Mars Observer Mission is highlighted in this video overview of the mission objectives and planning. Using previous photography and computer graphics and simulation, the main objectives of the 687 day (one Martian year) consecutive orbit by the Mars Observer Satellite around Mars are explained. Dr. Arden Albee, the project scientist, speaks about the pole-to-pole mapping of the Martian surface topography, the planned relief maps, the chemical and mineral composition analysis, the gravity fields analysis, and the proposed search for any Mars magnetic fields.
Since the advent of LANDSAT I in 1972, many different multispectral satellites have been orbited by the U.S. and other countries. These satellites have varied from 4 spectral bands in LANDSAT I to 14 spectral bands in the ASTER sensor aboard the TERRA space platform. Hyperion is a relatively new hyperspectral sensor with over 220 spectral bands. The huge increase in the number of spectral bands offers a substantial challenge to computers and analysts alike when it comes to the task of mapping features on the basis of chemical composition, especially if little or no ground truth is available beforehand from the area being mapped. One approach is the theoretical approach of the modeler, where all extraneous information (atmospheric attenuation, sensor electronic gain and offset, etc.) is subtracted off and divided out, and laboratory (or field) spectra of materials are used as training sets to map features in the scene of similar composition. This approach is very difficult to keep accurate because of variations in the atmosphere, solar illumination, and sensor electronic gain and offset that are not always perfectly recorded or accounted for. For instance, to apply laboratory or field spectra of materials as data sets from the theoretical approach, the header information of the files must reflect the correct, up-to-date sensor electronic gain and offset and the analyst must pick the exact atmospheric model that is appropriate for the day of data collection in order for classification procedures to accurately match pixels in the scene with the laboratory or field spectrum of a desired target on the basis of the hyperspectral data. The modeling process is so complex that it is difficult to tell when it is operating well or determine how to fix it when it is incorrect. Recently RSI has announced that the latest version of their ENVI software package is not performing atmospheric corrections correctly with the FLAASH atmospheric model. It took a long time to determine that it was wrong, and may take an equally long time (or longer) to fix.
A bibliography of articles entered into the data base at the Lunar and Planetary Institute Library from November 1982 through January 1983 is presented. An abstract of each article is given. The subjects covered by the articles include: the motion of the moon and dynamics of the earth-moon system: shape and gravity field of the moon; the physical structure of the moon, its thermal and stress history; the morphology of the lunar surface, the origin and stratigraphy of lunar formations, and mapping of the moon; the chemical composition of the moon, lunar petrology, mineralogy, and crystallography; electromagnetic properties of the moon; the planets; and other objects, including asteroids, comets, meteorites, and cosmic dust.
The Galileo Mission's Near-Infrared Mapping Spectrometer (NIMS) combines imaging and spectroscopic methods to map morphological features, ascertain their chemical composition and mineralogy, investigate surface-geology evolution, and measure the parameters of transient atmospheric phenomena. NIMS will investigate Jupiter and the Galilean satellites during a two-year orbital operation period, beginning in December, 1995. En route, NIMS will have obtained data for Venus, the earth/moon system, and two asteroids. NIMS covers the 0.7-5.2 micron spectral range, thereby encompassing the reflected-sunlight and thermal-radiation regimes for numerous solar system objects.
Space weathering processes - driven primarily by solar wind ion and micrometeorite bombardment, are constantly changing the surface regoliths of airless bodies, such as the Moon. It is essential to study lunar soils in order to fully under-stand the processes of space weathering, and how they alter the optical reflectance spectral properties of the lunar surface relative to bedrock. Lunar agglutinates are aggregates of regolith grains fused together in a glassy matrix of shock melt produced during micrometeorite impacts into the lunar regolith. The formation of the shock melt component in agglutinates involves reduction of Fe in the target material to generate nm-scale spherules of metallic Fe (nanophase Fe0 or npFe0). The ratio of elemental Fe, in the form of npFe0, to FeO in a given bulk soil indicates its maturity, which increases with length of surface exposure as well as being typically higher in the finer-size fraction of soils. The melting and mixing process in agglutinate formation remain poorly understood. This includes incomplete knowledge regarding how the homogeneity and overall compositional trends of the agglutinate glass portions (agglutinitic glass) evolve with maturity. The aim of this study is to use sub-micrometer scale X-ray compositional mapping and image analysis to quantify the chemical homogeneity of agglutinitic glass, correlate its homogeneity to its parent soil maturity, and identify the principal chemical components contributing to the shock melt composition variations. An additional focus is to see if agglutinitic glass contains anomalously high Fe sub-micron scale compositional domains similar to those recently reported in glassy patina coatings on lunar rocks.
Infrared (IR) spectroscopy is a powerful analytical tool in the chemical fingerprinting of materials. The technique is rapid, reproducible and usually non-invasive. With the appropriate accessories, the technique can be used to examine samples in either a solid, liquid or gas phase. Solid samples of varying sizes and shapes may be used, and with the addition of microscopic IR (microspectroscopy) capabilities, minute materials such as single fibers and threads may be examined. With the addition of appropriate software, microspectroscopy can be used for automated discrete point or compositional surface area mapping, with the latter providing a means to record changes in the chemical composition of a material surface over a defined area. Both aqueous and non-aqueous free-flowing solutions can be analyzed using appropriate IR techniques, as can viscous liquids such as heavy oils and greases. Due to the ability to characterize gaseous samples, IR spectroscopy can also be coupled with thermal processes such as thermogravimetric (TG) analyses to provide both thermal and chemical data in a single run. In this configuration, solids (or liquids) heated in a TG analyzer undergo decomposition, with the evolving gases directed into the IR spectrometer. Thus, information is provided on the thermal properties of a material and the order in which its chemical constituents are broken down during incremental heating. Specific examples of these varied applications will be cited, with data interpretation and method limitations further discussed.
Bibliographical listing of recently published work pertaining to 15 subject areas of lunar research, with brief abstracts for each item listed. Subject areas covered include: motion of the moon in space, dynamics of the earth-moon system, and lunar astronautics; librations; shape and gravitational field; internal structure, thermal and stress history; chemical composition; lunar exosphere; lunar coordinates and mapping of the moon; physical structure of the lunar surface; photometry of the moon; thermal emission of the lunar surface; electromagnetic properties; exploration of the moon by spacecraft.
Environmental (ESEM) and Field Emission Scanning Electron Microscopy (FESEM) investigations have resulted in the detection of a large number of complex filaments in a variety of carbonaceous meteorites. Many of the filaments were observed to be clearly embedded the rock matrix of freshly fractured interior surfaces of the meteorites. The high resolution images obtained combined with tilt and rotation of the stage provide 3-dimensional morphological and morphometric data for the filaments. Calibrated Energy Dispersive X-ray Spectroscopy (EDS) and 2-D elemental X-ray maps have provided information on the chemical compositions of the filaments and the minerals of the associated meteorite rock matrix. These observations are used to evaluate diverse hypotheses regarding the possible abiotic or biogenic nature of the filaments found embedded in these meteorites.
Infrared (IR) spectroscopy is a powerful analytical tool in the chemical fingerprinting of materials. Any sample material that will interact with infrared light produces a spectrum and, although normally associated with organic materials, inorganic compounds may also be infrared active. The technique is rapid, reproducible and usually non-invasive to the sample. That it is non-invasive allows for additional characterization of the original material using other analytical techniques including thermal analysis and RAMAN spectroscopic techniques. With the appropriate accessories, the technique can be used to examine samples in liquid, solid or gas phase. Both aqueous and non-aqueous free-flowing solutions can be analyzed, as can viscous liquids such as heavy oils and greases. Solid samples of varying sizes and shapes may also be examined and with the addition of microscopic IR (microspectroscopy) capabilities, minute materials such as single fibers and threads may be analyzed. With the addition of appropriate software, microspectroscopy can be used for automated discrete point or compositional surface area mapping, with the latter providing a means to record changes in the chemical composition of a material surface over a defined area. Due to the ability to characterize gaseous samples, IR spectroscopy can also be coupled with thermal processes such as thermogravimetric (TG) analyses to provide both thermal and chemical data in a single run. In this configuration, solids (or liquids) heated in a TG analyzer undergo decomposition, with the evolving gases directed into the IR spectrometer. Thus, information is provided on the thermal properties of a material and the order in which its chemical constituents are broken down during incremental heating. Specific examples of these varied applications will be cited, with data interpretation and method limitations further discussed.
Papers from the conference are presented, and the topics covered include the following: planetary geology, meteorites, planetary composition, meteoritic composition, planetary craters, lunar craters, meteorite craters, petrology, petrography, volcanology, planetary crusts, geochronology, geomorphism, mineralogy, lithology, planetary atmospheres, impact melts, volcanoes, planetary evolution, tectonics, planetary mapping, asteroids, comets, lunar soil, lunar rocks, lunar geology, metamorphism, chemical composition, meteorite craters, and planetary mantles.
Papers from the conference are presented, and the topics covered include the following: planetary geology, meteorites, planetary composition, meteoritic composition, planetary craters, lunar craters, meteorite craters, petrology, petrography, volcanology, planetary crusts, geochronology, geomorphism, mineralogy, lithology, planetary atmospheres, impact melts, K-T Boundary Layer, volcanoes, planetary evolution, tectonics, planetary mapping, asteroids, comets, lunar soil, lunar rocks, lunar geology, metamorphism, chemical composition, meteorite craters, planetary mantles, and space exploration.
The prime purpose of the X-ray fluorescence spectrometer carried in the Scientific Instrument Module of the Command-Service Module was to map the lunar surface with respect to its chemical composition. Results are presented for Al, Mg, and Si as Al/Si and Mg/Si ratios for the various features overflow by the spacecraft. The lunar surface measurements involved observations of the intensity and characteristic energy distribution of the secondary or fluorescent X rays produced by the interaction of solar X rays with the lunar surface. The results showed that the highlands and maria are chemically different, with the highlands having considerably more Al and less Mg than the maria. The mare-highland contact is quite sharp and puts a limit on the amount of horizontal transport of material. The X-ray data suggest that the dominant rock type of the lunar highlands is a plagioclase-rich pyroxene bearing rock probably anorthositic gabbro or feldspathic basalt.
The location and nature of the defect in mineralization known to occur in growing animals after spaceflight are studied. The distribution of bone mineral density in situ is mapped, and these images are correlated with the chemical composition of the diaphyseal bone. Concentrations of mineral and osteocalcin are found to be low in the distal half of the diaphysis and concentrations of collagen to be low with evidence of increased synthesis in the proximal half of the diaphysis of the flight bones. X-ray microtomography indicates a longitudinal gradient of decreasing mineralization toward the distal diaphysis. Analysis of embedded sections by backscattered electrons reveals patterns of mineral distribution in the proximal, central, and distal regions of the diaphysis and also shows a net reduction in mineral levels toward the distal shaft. Increases in mineral density to higher fractions in controls are less in the flight bones at all three levels.