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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

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NASA NTRS1977

Chemical character of the partially flooded Smythii Basin based on Al/Si orbital X-ray data

Orbital X-ray fluorescence data indicate that continuous mare-basalt flooding is confined to the northeastern quadrant of the Smythii Basin. Al/Si values for soils in the unflooded northwestern section of the Smythii Basin closely approximate those for the adjacent terra to the west. Terra soils east of Mare Smythii, however, are unusually aluminous compared to terra soils west of the basin. This pronounced contrast between Al/Si values for terra soils to the east and west of Smythii as well as the minimal difference in values between the northwestern section of the basin and adjacent terra to the west are most likely due to a chemically homogeneous layer of ejecta from a large impact event west of Mare Smythii, such as that which formed the Crisium Basin. An alternate hypothesis is that the unflooded section of the basin is predominantly original basin floor material, indicating that the impact forming the 4km deep Smythii Basin did not penetrate into a horizon chemically different from the terra west of Smythii. The chemical contrast between the terra east and west of Smythii, then, would be ascribed to lateral heterogeneity within the lunar crust

Andre, C. G.↗

NASA NTRS1984

Characterization of physio-chemical properties of polymeric and electrochemical materials for aerospace flight

Sealed nickel cadmium cells having undergone a large number of cycles were discharged using the Hg/HgO reference electrode. The negative electrode exhibited the second plateau. SEM of negative plates of such cells show clusters of large crystals of cadmium hydroxide. These large crystals on the negative plates disappear after continuous overcharging in flooded cells. Atomic Absorption Spectroscopy and standard wet chemical methods are being used to determine the cell materials viz: nickel, cadmium, cobalt, potassum and carbonate. The anodes and cathodes are analyzed after careful examination and the condition of the separator material is evaluated.

Rock, M.↗

NASA NTRS2008

Geochemical Properties of Rocks and Soils in Gusev Crater, Mars: APXS Results from Cumberland Ridge to Home Plate

The Mars Exploration Rover Spirit landed in Gusev crater on Jan. 4, 2004. Spirit has traversed the Gusev crater plains, ascended to the top of Husband Hill, and entered into the Inner Basin of the Columbia Hills. The Athena science payload onboard Spirit has recorded numerous measurements on the chemistry and mineralogy of materials encountered during nearly 2 Mars years of operation within the crater. Rocks and soils have been grouped into classes based upon their unique differences in mineralogy and chemistry [1-3]. Some of the most significant chemical discoveries include the composition of Adirondack class flood basalts [4-6]; high sulfur in Clovis and Peace Class rocks [7,2]; high P and Ti in Wishstone Class rocks [7,2]; composition of alkalic basalts [2,6]; very high S in Paso Robles class soils [7,2], and the possible occurrence of a smectite-like chemical composition in Independence class rocks [8]. Water has played a significant role in the alteration of rocks and soils in the Columbia Hills. The occurrence of goethite and ferric sulfate alone suggests that liquid water was involved in their formation [3]. The pervasively altered materials in Husband Hill outcrops and rocks may have formed by the aqueous alteration of basaltic rocks, volcaniclastic materials, and/or impact ejecta by solutions that were rich in acid-volatile elements [2]. The objective of this paper is to provide an update on the health of the Alpha Particle X-ray Spectrometer (APXS) and to expand the geochemical dataset from sol 470 to sol 1368. Specific objectives are to (1) update the rock and soil classifications, (2) characterize elemental relationships among the major rock and soil classes, and (3) evaluate the involvement of water in the formation or alteration of the materials in these classes.

Ming, D. W.↗

NASA NTRS1986

Oxygen recombination in individual pressure vessel nickel-hydrogen batteries

A metal-hydrogen cell is described which avoids damage and retards flooding of the hydrogen electrodes by providing for chemical recombination of oxygen and hydrogen in areas or sites remote from the hydrogen electrodes. In the metal-hydrogen cell, a plurality of electrical cell units are place in a back to back relationship. The cells may be lined with a wick, having one or more catalyzed sites on the inner surface of the cell. Separators disposed between the respective metal and hydrogen electrodes of each cell unit are provided with gas directing notches around their peripheries to facilitate the desired movement of gasses within the metal-hydrogen cell. Any two metal electrodes separated by a gas screen are provided with gas tight sealing means between the electrodes at each aperature. The sealing means may be a fing of rubber or elastomeric material which is somewhat compressible but nonreactive with other materials in the cell.

Smithrick, J. J.↗

NASA NTRS2009

Monitoring Disasters by Use of Instrumented Robotic Aircraft

Efforts are under way to develop data-acquisition, data-processing, and data-communication systems for monitoring disasters over large geographic areas by use of uninhabited aerial systems (UAS) robotic aircraft that are typically piloted by remote control. As integral parts of advanced, comprehensive disaster- management programs, these systems would provide (1) real-time data that would be used to coordinate responses to current disasters and (2) recorded data that would be used to model disasters for the purpose of mitigating the effects of future disasters and planning responses to them. The basic idea is to equip UAS with sensors (e.g., conventional video cameras and/or multispectral imaging instruments) and to fly them over disaster areas, where they could transmit data by radio to command centers. Transmission could occur along direct line-of-sight paths and/or along over-the-horizon paths by relay via spacecraft in orbit around the Earth. The initial focus is on demonstrating systems for monitoring wildfires; other disasters to which these developments are expected to be applicable include floods, hurricanes, tornadoes, earthquakes, volcanic eruptions, leaks of toxic chemicals, and military attacks. The figure depicts a typical system for monitoring a wildfire. In this case, instruments aboard a UAS would generate calibrated thermal-infrared digital image data of terrain affected by a wildfire. The data would be sent by radio via satellite to a data-archive server and image-processing computers. In the image-processing computers, the data would be rapidly geo-rectified for processing by one or more of a large variety of geographic-information- system (GIS) and/or image-analysis software packages. After processing by this software, the data would be both stored in the archive and distributed through standard Internet connections to a disaster-mitigation center, an investigator, and/or command center at the scene of the fire. Ground assets (in this case, firefighters and/or firefighting equipment) would also be monitored in real time by use of Global Positioning System (GPS) units and radio communication links between the assets and the UAS. In this scenario, the UAS would serve as a data-relay station in the sky, sending packets of information concerning the locations of assets to the image-processing computer, wherein this information would be incorporated into the geo-rectified images and maps. Hence, the images and maps would enable command-center personnel to monitor locations of assets in real time and in relation to locations affected by the disaster. Optionally, in case of a disaster that disrupted communications, the UAS could be used as an airborne communication relay station to partly restore communications to the affected area. A prototype of a system of this type was demonstrated in a project denoted the First Response Experiment (Project FiRE). In this project, a controlled outdoor fire was observed by use of a thermal multispectral scanning imager on a UAS that delivered image data to a ground station via a satellite uplink/ downlink telemetry system. At the ground station, the image data were geo-rectified in nearly real time for distribution via the Internet to firefighting managers. Project FiRE was deemed a success in demonstrating several advances essential to the eventual success of the continuing development effort.

Wegener, Steven S.↗

NASA NTRS1991

Destructive physical analysis results of Ni/H2 cells cycled in LEO regime

Six 48-Ah individual pressure vessel (IPV) Ni/H2 cells containing 26 and 31 percent KOH electrolyte were life cycle tested in low Earth orbit. All three cells containing 31 percent KOH failed (3729, 4165, and 11,355 cycles), while those with 26 percent KOH were cycled over 14,000 times in the continuing test. Destructive physical analysis (DPA) of the failed cells included visual inspections, measurements of electrode thickness, scanning electron microscopy, chemical analysis, and measurements of nickel electrode capacity in an electrolyte flooded cell. The cycling failure was due to a decrease of nickel electrode capacity. As possible causes of the capacity decrease, researchers observed electrode expansion, rupture, and corrosion of the nickel electrode substrate, active material redistribution, and accumulation of electrochemically undischargeable active material with cycling.

Lim, Hong S.↗

NASA NTRS1991

Destructive physical analysis results of Ni/H2 cells cycled in LEO regime

Six 48-Ah individual pressure vessel (IPV) Ni/H2 cells containing 26 and 31 percent KOH electrolyte were life cycle tested in low earth orbit. All three cells containing 31 percent KOH failed (3729, 4165, and 11,355 cycles), while those with 26 percent KOH were cycled over 14,000 times in the continuing test. Destructive physical analysis (DPA) of the failed cells included visual inspections, measurements of electrode thickness, scanning electron microscopy, chemical analysis, and measurements of nickel electrode capacity in an electrolyte flooded cell. The cycling failure was due to a decrease of nickel electrode capacity. As possible causes of the capacity decrease, researchers observed electrode expansion, rupture, and corrosion of the nickel electrode substrate, active material redistribution, and accumulation of electrochemically undischargeable active material with cycling.

Lim, Hong S.↗

NASA NTRS1983

Light, Compact Pumper for Harbor Fires

Report describes development of new transportable water-pumping unit for fire-fighting. Compact, self-contained unit provides fire protection at coastal and inland ports and is lighter than standard firetruck pumper of same capacity. Used to fight fires in harbors, cities, forests, refineries, chemical plants, and offshore drilling platforms. Other possible applications include cleaning up oilspills, pumping out ships, and flood control pumping.

Burns, R. A.↗

NASA NTRS2020

Massachusetts Water Resources: Assessing Flood Events Resulting from North American Beaver Reintroduction with NASA Earth Observations to Inform Biodiversity and Infrastructure Management

North American beavers (Castor canadensis) are returning to Massachusetts after overhunting decimated their populations in the 1700s. Current regulations have allowed this species to recolonize, resulting in increasingly prevalent human-beaver conflicts. These ecosystem engineers can quickly change their environment through the creation of dams, leading to floods that can adversely affect human infrastructures, such as basements, roads, or septic systems. Conversely, beaver dams can positively influence their environment, modifying the physical and chemical properties of streams and providing crucial habitats to a variety of wildlife. The 2020 Spring Boston NASA DEVELOP team collaborated with the Massachusetts Audubon Society to support their efforts in monitoring beaver impacts and managing human-beaver conflicts. The project-utilized data from Landsat 5 Thematic Mapper, Landsat 7 Enhanced Thematic Mapper Plus, and Landsat 8 Operational Land Imager to map the spectral signature created from beaver-induced flooding. The team created a tool called Beaver-Flood Event Detector (B-FED) in Google Earth Engine using imagery from 1985 to 2019. Ancillary datasets were incorporated into B-FED that allow the tool to highlight flood events in wetland areas and in situ observations of beaver presence. Beaver observations in or near flooded areas indicated likelihood that the flood was beaver induced. Time series and animations were also produced to display key regions of landscape change across Massachusetts. B-FED will allow the partner to identify and assess potential ecosystem changes and infrastructural impacts from beavers across Massachusetts and inform future management practices.

Water Resources↗

NASA NTRS2020

Massachusetts Water Resources: Assessing Flood Events Resulting from North American Beaver Reintroduction with NASA Earth Observations to Inform Biodiversity and Infrastructure Management

Water Resources↗

NASA NTRS1974

Mariner 10 pictures of Mercury - First results

Mercury has a heavily cratered surface containing basins up to at least 1300 kilometers diameter flooded with mare-like material. Many features are closely similar to those on the moon, but significant structural differences exist. Major chemical differentiation before termination of accretion is implied.

Murray, B. C.↗

NASA NTRS1989

Electron spectroscopy for chemical analysis: Sample analysis

Exposure conditions in atomic oxygen (ESCA) was performed on an SSL-100/206 Small Spot Spectrometer. All data were taken with the use of a low voltage electron flood gun and a charge neutralization screen to minimize charging effects on the data. The X-ray spot size and electron flood gun voltage used are recorded on the individual spectra as are the instrumental resolutions. Two types of spectra were obtained for each specimen: (1) general surveys, and (2) high resolution spectra. The two types of data reduction performed are: (1) semiquantitative compositional analysis, and (2) peak fitting. The materials analyzed are: (1) kapton 4, 5, and 6, (2) HDPE 19, 20, and 21, and (3) PVDF 4, 5, and 6.

Carter, W. B.↗

NASA NTRS2010

Tidal Marsh Outwelling of Dissolved Organic Matter and Resulting Temporal Variability in Coastal Water Optical and Biogeochemical Properties

Coastal wetlands are highly dynamic environments at the land-ocean interface where human activities, short-term physical forcings and intense episodic events result in high biological and chemical variability. Long being recognized as among the most productive ecosystems in the world, tidally-influenced coastal marshes are hot spots of biogeochemical transformation and exchange. High temporal resolution observations that we performed in several marsh-estuarine systems of the Chesapeake Bay revealed significant variability in water optical and biogeochemical characteristics at hourly time scales, associated with tidally-driven hydrology. Water in the tidal creek draining each marsh was sampled every hour during several semi-diurnal tidal cycles using ISCO automated samplers. Measurements showed that water leaving the marsh during ebbing tide was consistently enriched in dissolved organic carbon (DOC), frequently by more than a factor of two, compared to water entering the marsh during flooding tide. Estimates of DOC fluxes showed a net DOC export from the marsh to the estuary during seasons of both low and high biomass of marsh vegetation. Chlorophyll amounts were typically lower in the water draining the marsh, compared to that entering the marsh during flooding tide, suggesting that marshes act as transformers of particulate to dissolved organic matter. Moreover, detailed optical and compositional analyses demonstrated that marshes are important sources of optically and chemically distinctive, relatively complex, high molecular weight, aromatic-rich and highly colored dissolved organic compounds. Compared to adjacent estuarine waters, marsh-exported colored dissolved organic matter (CDOM) was characterized by considerably stronger absorption (more than a factor of three in some cases), larger DOC-specific absorption, lower exponential spectral slope, larger fluorescence signal, lower fluorescence per unit absorbance, and higher fluorescence at visible wavelengths. Observed patterns in water optical and biogeochemical variables were very consistent among different marsh systems and throughout the year, despite continued tidal exchange, implying rapid transformation of marsh DOM in the estuary through both photochemical and microbial processes. These findings illustrate the importance of tidal marsh ecosystems as sources, sinks and/or transformers of biologically important nutrients, carbon and colored dissolved organic compounds, and their influence on short-term biological, optical and biogeochemical variability in coastal waters.

Tzortziou, Maria↗

NASA NTRS2012

Nanotube Production Devices Expand Research Capabilities

In order for the Hubble Space Telescope to take incredible, never-seen-before shots of celestial bodies and then send them back to Earth, the spacecraft needs power. While in orbit, Hubble cannot plug into an electrical outlet or stop at a store for some batteries. One of the ways NASA supplies power aboard a spacecraft is by harnessing energy from the most powerful entity in the solar system: the Sun. Since the 1960s, photovoltaic technology, or technology that converts sunlight into electricity, has been instrumental in the exploration of space. To build upon existing photovoltaic technology, NASA s Glenn Research Center has worked on a variety of innovative designs and materials to incorporate into photovoltaic cells, the building blocks of solar power systems. One of these materials is the carbon nanotube - a tiny structure about 50,000 times finer than the average human hair, with notably high electrical and thermal conductivity and an extreme amount of mechanical strength. Such properties give carbon nanotubes great potential to enhance the reliability of power generation and storage devices in space and on Earth. Dennis J. Flood, the branch chief of the photovoltaic division at Glenn in the 1990s, was looking into using carbon nanotubes to improve the efficiency of solar cells when he ran into a major roadblock - high-quality carbon nanotubes were not readily available. To address this problem, one of the chemists in Flood s group came up with a process and system for growing them. A senior chemist at Glenn, Aloysius F. Hepp, devised an injection chemical vapor deposition process using a specific organometallic catalyst in a two-zone furnace. Hepp's group found the unique process produced high-quality carbon nanotubes with less than 5 percent metal impurity. In addition, the process was more efficient than existing techniques, as it eliminated pre-patterning of the substrate used for growing the nanotubes, a timely and cost-prohibitive step.

Source record↗

NASA NTRS1989

KOH concentration effect on the cycle life of nickel-hydrogen cells. 4: Results of failure analyse

Effects of KOH concentrations on failure modes and mechanisms of nickel-hydrogen cells were studied using long cycled boiler plate cells containing electrolytes of various KOH concentrations ranging 21 to 36 percent. Life of these cells were up to 40,000 cycles in an accelerated low earth orbit (LEO) cycle regime at 80 percent depth of discharge. An interim life test results were reported earlier in J. Power Sources, 22, 213-220, 1988. The results of final life test, end-of-life cell performance, and teardown analyses are discussed. These teardown analyses included visual observations, measurements of nickel electrode capacity in an electrolyte-flooded cell, dimensional changes of cell components, SEM studies on cell cross section, BET surface area and pore volume distribution in cycled nickel electrodes, and chemical analyses. Cycle life of a nickel-hydrogen cell was improved tremendously as KOH concentration was decreased from 36 to 31 percent and from 31 to 26 percent while effect of further concentration decrease was complicated as described in our earlier report. Failure mode of high concentration (31 to 36 percent) cells was gradual capacity decrease, while that of low concentration (21 to 26 percent) cells was mainly formation of a soft short. Long cycled (25,000 to 40,000 cycles) nickel electrodes were expanded more than 50 percent of the initial value, but no correlation was found between this expansion and measured capacity. All electrodes cycled in low concentration (21 to 26 percent) cells had higher capacity than those cycled in high concentration (31 to 36 percent) cells.

Lim, H. S.↗

NASA NTRS1984

Planetary geomorphology field studies: Iceland and Antarctica

Field studies of terrestrial landforms and the processes that shape them provide new directions to the study of planetary features. These studies, conducted in Iceland and in Antarctica, investigated physical and chemical weathering mechanisms and rates, eolitan processes, mudflow phenomena, drainage development, and catastrophic fluvial and volcanic phenomena. Continuing investigations in Iceland fall in three main catagories: (1) catastrophic floods of the Jokulsa a Fjollum, (2) lahars associated with explosive volcanic eruptions of Askja caldera, and (3) rates of eolian abrasion in cold, volcanic deserts. The ice-free valleys of Antarctica, in particular those in South Victoria Land, have much is common with the surface of Mars. In addition to providing independent support for the application of the Iceland findings to consideration of the martian erosional system, the Antarctic observations also provide analogies to other martian phenomena. For example, a family of sand dunes in Victoria Valley are stabilized by the incorporation of snow as beds.

Malin, M. C.↗

NASA NTRS2007

Web-Based Real-Time Emergency Monitoring

The Web-based Real-Time Asset Monitoring (RAM) module for emergency operations and facility management enables emergency personnel in federal agencies and local and state governments to monitor and analyze data in the event of a natural disaster or other crisis that threatens a large number of people and property. The software can manage many disparate sources of data within a facility, city, or county. It was developed on industry-standard Geo- Spatial software and is compliant with open GIS standards. RAM View can function as a standalone system, or as an integrated plugin module to Emergency Operations Center (EOC) software suites such as REACT (Real-time Emergency Action Coordination Tool), thus ensuring the widest possible distribution among potential users. RAM has the ability to monitor various data sources, including streaming data. Many disparate systems are included in the initial suite of supported hardware systems, such as mobile GPS units, ambient measurements of temperature, moisture and chemical agents, flow meters, air quality, asset location, and meteorological conditions. RAM View displays real-time data streams such as gauge heights from the U.S. Geological Survey gauging stations, flood crests from the National Weather Service, and meteorological data from numerous sources. Data points are clearly visible on the map interface, and attributes as specified in the user requirements can be viewed and queried.

Harvey, Craig A.↗

NASA NTRS2012

Volatile Transport by Volcanic Plumes on Earth, Venus and Mars

Explosive volcanic eruptions can produce sustained, buoyant columns of ash and gas in the atmosphere (Fig. 1). Large flood basalt eruptions may also include significant explosive phases that generate eruption columns. Such eruptions can transport volcanic volatiles to great heights in the atmosphere. Volcanic eruption columns can also redistribute chemical species within the atmosphere by entraining ambient atmosphere at low altitudes and releasing those species at much higher altitudes.

Glaze, Lori S.↗