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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Composite engines for application to a single-stage-to-orbit vehicle

Seven composite engines were designed for application to a reusable single-stage-to-orbit vehicle. The engine designs were variations of the supercharged ejector ramjet engine. The resulting performance, weight, and drawings of each engine form a data base for establishing a potential of this class of composite engine to various missions, including the single-stage-to-orbit application. The impact of advanced technology in the design of the critical fan turbine was established.

Bendot, J. G.↗

Design concepts for low cost composite engine frames

Design concepts for low-cost, lightweight composite engine frames were applied to the design requirements for the frame of commercial, high-bypass turbine engines. The concepts consist of generic-type components and subcomponents that could be adapted for use in different locations in the engine and to different engine sizes. A variety of materials and manufacturing methods were assessed with a goal of having the lowest number of parts possible at the lowest possible cost. The evaluation of the design concepts resulted in the identification of a hybrid composite frame which would weigh about 70 percent of the state-of-the-art metal frame and cost would be about 60 percent.

Chamis, C. C.↗

Design concepts for low-cost composite engine frames

Design concepts for low-cost, lightweight composite engine frames were applied to the design requirements for the frame of commercial, high-bypass turbine engines. The concepts consist of generic-type components and subcomponents that could be adapted for use in different locations in the engine and to different engine sizes. A variety of materials and manufacturing methods were assessed with a goal of having the lowest number of parts possible at the lowest possible cost. The evaluation of the design concepts resulted in the identification of a hybrid composite frame which would weigh about 70 percent of the state-of-the-art metal frame and cost would be about 60 percent.

Chamis, C. C.↗

Void swelling of conventional and composition engineered HT9 alloys after high-dose self-ion irradiation

Ferritic/martensitic (F/M) steels are being considered as potential structural materials for next generation nuclear reactors, and variants of the alloy HT9 are some of the most promising candidates. In this study, two conventional and two composition engineered HT9 alloys were irradiated using 3.5 MeV Fe 2+ up to 600 peak displacement-per-atom (dpa) at 450 °C. Void swelling and microstructure evolution were characterized for each alloy and compared. The two conventional HT9 alloys (INL and ACO3) showed similar void swelling behavior due to their similar elemental composition and processing conditions. The INL HT9 exhibited a maximum of 2.4% swelling and the ACO3 HT9 showed a maximum of 2.8% swelling at 342 and 393 average local dpa, respectively. On the other hand, the two-composition engineered HT9 alloys with varying N contents (10 ppm for low N and 440 ppm for high N) showed disparate swelling behavior. The low N HT9 exhibited a maximum of 4.6% swelling, while the high N HT9 showed a maximum of 0.7% swelling at 342 average local dpa. Changes in the N content also affected Ni/Si rich G-phase formation. The low N HT9 showed a larger size and lower density of G-phase precipitates compared with the high N HT9 after 600 peak dpa irradiation. This study compares the void swelling behavior of the ion irradiated four current HT9 alloys to extremely high doses, with the void swelling data from neutron irradiated HT9 alloys. Furthermore, the comparison lends critical insights into how well these current alloys can withstand high neutron fluxes in future reactors, especially since the low N and high N HT9 alloys have never been exposed to such high doses before.

36 MATERIALS SCIENCE↗

Observation of large Rashba spin–orbit coupling at room temperature in compositionally engineered perovskite single crystals and application in high performance photodetectors

Indirect absorption extended below the direct transition edge and increase in carrier lifetime derived from Rashba spin–orbit coupling may advance the optoelectronic applications of metal halide perovskites. Spin-orbit coupling in halide perovskites is due to the presence of heavy elements in their structure. However, when these materials lack an inversion symmetry, for example by the application of strain, spin–orbit coupling becomes odd in the electron’s momentum giving rise to a splitting in the electronic energy bands. Here we report on the observation of a large Rashba splitting of 117 meV at room temperature, as predicted by relativistic first-principles calculations, in halide perovskite single crystals through a facile compositional engineering approach. Partial substitution of organic cations by rubidium in single crystals induces significant indirect absorption and dual peak photoluminescence as a result of a large Rashba splitting. We measured circularly polarized photoluminescence and magneto-photoluminescence in perovskite films printed by single crystals as well as magneto-electroluminescence and magneto-photocurrent in spin-LEDs based on perovskite single crystals. They indicated significant spin-momentum locking due to the large Rashba effect. A hybrid perovskite single crystal photodetector achieved record figures of merit, including detectivity of more than 1.3 × 10 18 Jones which represents a three orders of magnitude improvement compared to the to date record. Furthermore, these findings show that facile compositional engineering of perovskite single crystals holds great promise for further advancing the optoelectronic properties of existing materials.

36 MATERIALS SCIENCE↗

Optimization of matrix viscosity improves polypropylene fiber dispersion and properties of engineered cementitious composites

Engineered cementitious composites (ECC) is a durable cementitious material with high tensile ductility and strain-hardening characteristics. Although considered as a cost-effective fiber for ECC, polypropylene (PP) fiber is reportedly difficult to disperse in mortar matrix due to its high aspect ratio and hydrophobicity. In this study, the matrix viscosity of a low-carbon ECC based on limestone calcined clay cement was tailored as a variable to improve PP fiber dispersion under a pre-determined mixing protocol. The effect of matrix viscosity on the composite fresh and hardened properties was investigated experimentally. Results suggested an optimal range of matrix viscosity (10.3–11.5 Pa . s) favors the composite tensile strength and strain capacity at 28 days. At the optimal state with a 0.1 % viscosity modifying admixture (VMA)-to-binder mass ratio, PP-ECC achieved 7.0 % tensile strain capacity and 3.5 MPa ultimate tensile strength. When matrix viscosity falls outside the desired range, both ultimate tensile strength and strain capacity were diminished. By tailoring the VMA dosage, the matrix viscosity can be adjusted for desired fiber dispersion, workability, and mechanical properties. Finally, the findings of this study provide a technical reference for the practical design and application of PP-ECC.

36 MATERIALS SCIENCE↗

Coupled multi-disciplinary simulation of composite engine structures in propulsion environment

A computational simulation procedure is described for the coupled response of multi-layered multi-material composite engine structural components which are subjected to simultaneous multi-disciplinary thermal, structural, vibration, and acoustic loadings including the effect of hostile environments. The simulation is based on a three dimensional finite element analysis technique in conjunction with structural mechanics codes and with acoustic analysis methods. The composite material behavior is assessed at the various composite scales, i.e., the laminate/ply/constituents (fiber/matrix), via nonlinear material characterization model. Sample cases exhibiting nonlinear geometrical, material, loading, and environmental behavior of aircraft engine fan blades, are presented. Results for deformed shape, vibration frequency mode shapes, and acoustic noise emitted from the fan blade, are discussed for their coupled effect in hot and humid environments. Results such as acoustic noise for coupled composite-mechanics/heat transfer/structural/vibration/acoustic analyses demonstrate the effectiveness of coupled multi-disciplinary computational simulation the various advantages of composite materials compared to metals.

Chamis, Christos C.↗

Coupled multi-disciplinary simulation of composite engine structures in propulsion environment

A computational simulation procedure is described for the coupled response of multi-layered multi-material composite engine structural components which are subjected to simultaneous multi-disciplinary thermal, structural, vibration, and acoustic loadings including the effect of hostile environments. The simulation is based on a three dimensional finite element analysis technique in conjunction with structural mechanics codes and with acoustic analysis methods. The composite material behavior is assessed at the various composite scales, i.e., the laminate/ply/constituents (fiber/matrix), via a nonlinear material characterization model. Sample cases exhibiting nonlinear geometrical, material, loading, and environmental behavior of aircraft engine fan blades, are presented. Results for deformed shape, vibration frequency, mode shapes, and acoustic noise emitted from the fan blade, are discussed for their coupled effect in hot and humid environments. Results such as acoustic noise for coupled composite-mechanics/heat transfer/structural/vibration/acoustic analyses demonstrate the effectiveness of coupled multi-disciplinary computational simulation and the various advantages of composite materials compared to metals.

Chamis, Christos C.↗

Comparison of Polymer AM Technologies for Automotive Tooling for Composite Engines

Oak Ridge National Laboratory’s (ORNL) Manufacturing Demonstration Facility (MDF) worked with Polimotor to complete a set of molds for fabricating the oil pan for a composite engine. This project used multiple different AM processes to fabricate the mold set. The assembled parts were measured for tolerance and then sent to Polimotor to be used in the manufacture of engine components.

42 ENGINEERING↗

Advanced Constituents and Processes for Ceramic Composite Engine Components

The successful replacement of metal alloys by ceramic matrix composites (CMC) in hot-section engine components will depend strongly on optimizing the processes and properties of the CMC microstructural constituents so that they can synergistically provide the total CMC system with improved temperature capability and with the key properties required by the components for long-term structural service. This presentation provides the results of recent activities at NASA aimed at developing advanced silicon carbide (Sic) fiber-reinforced hybrid Sic matrix composite systems that can operate under mechanical loading and oxidizing conditions for hundreds of hours at 2400 and 2600 F, temperatures well above current metal capability. These SiC/SiC composite systems are lightweight (-30% metal density) and, in comparison to monolithic ceramics and carbon fiber-reinforced ceramic composites, are able to reliably retain their structural properties for long times under aggressive engine environments. It is shown that the improved temperature capability of the SiC/SiC systems is related first to the NASA development of the Sylramic-iBN Sic fiber, which displays high thermal stability, creep resistance, rupture resistance, and thermal conductivity, and possesses an in-situ grown BN surface layer for added environmental durability. This fiber is simply derived from Sylramic Sic fiber type that is currently produced at ATK COI Ceramics. Further capability is then derived by using chemical vapor infiltration (CVI) to form the initial portion of the hybrid Sic matrix. Because of its high creep resistance and thermal conductivity, the CVI Sic matrix is a required base constituent for all the high temperature SiC/SiC systems. By subsequently thermo- mechanical-treating the CMC preform, which consists of the S ylramic-iBN fibers and CVI Sic matrix, process-related defects in the matrix are removed, further improving matrix and CMC creep resistance and conductivity.

Yun, H. M.↗

Quiet Clean Short-haul Experimental Engine (QCSEE) under-the-wing engine composite fan blade design report

A total of 38 quiet clean short haul experimental engine under the wing composite fan blades were manufactured for various component tests, process and tooling, checkout, and use in the QCSEE UTW engine. The component tests included frequency characterization, strain distribution, bench fatigue, platform static load, whirligig high cycle fatigue, whirligig low cycle fatigue, whirligig strain distribution, and whirligig over-speed. All tests were successfully completed. All blades planned for use in the engine were subjected to and passed a whirligig proof spin test.

Ravenhall, R.↗

High‐Performance and Stable Semi‐Transparent Perovskite Solar Cells through Composition Engineering

Abstract Semi‐transparent perovskite solar cells (ST‐PeSCs) have tremendous potential as solar windows owing to their higher efficiency and visible transmittance. However, studies toward this application are still nascent, particularly in unraveling the interplay between how the perovskite composition impacts the achievable device performance and stability. Here, the role of A‐ and X‐site modification in APbX 3 perovskites is studied to understand their influence on these factors. Through detailed experimental and simulation work, it is found that a perovskite composition consisting of cesium (Cs) and formamidinium (FA) at the A‐site delivers the best device performance over a range of band gaps, which are tuned by changes to the X‐site anion. Using this optimized perovskite composition, power conversion efficiencies of 15.5% and 4.1% are achieved for ST‐PeSCs with average visible transmittance values between 20.7% and 52.4%, respectively. Furthermore, the CsFA‐based ST‐PeSCs show excellent long‐term stability under continuous illumination and heating. The stability of the precursor solutions across each of the studied compositions has also been considered, showing dramatic differences in the structural properties of the perovskites and their device performance for all mixed A‐site compositions possessing the archetypal methyl ammonium species, while also confirming the superior stability of the CsFA precursor solutions.

14 SOLAR ENERGY↗

Composite engine duct fabrication

The trimonomer polyimide resin reinforced with graphite fibers, PMR15, is lower in weight (by 20 percent) and less expensive than titanium. The duct walls are of solid laminate and are made of woven T300 graphite cloth. The original concept for the duct involved a solid shell of T300/PMR15 made up of seven plies of cloth tapered to eleven plies at each end. The bosses and built-up areas around the cutouts are also of T300/PMR15. The end flages riveted to the shell, however, are of titanium. A buckling test demonstrated the ability of the composite analytical design techniques employed to predict the buckling strength of the composite shell. Engines tests are described, noting that the successful repair of a hole demonstrated an important advantage over titanium. The development work now being done to eliminate the titanium end flanges is described, noting that an all-composite duct is in prospect. The savings estimated with a titanium-flanged composite duct are $16,891,000 (1982 dollars) and $35,504,000 (then-year dollars); the savings possible with an all-composite duct are put at $27,025,000 (1982 dollars) and $56,806,000 (then-year dollars).

Pratt, R. D.↗

Quiet Clean Short-haul Experimental Engine (QCSEE) under-the-wing engine composite fan blade: Preliminary design test report

Results of tests conducted on preliminary design polymeric-composite fan blade for the under the wing (UTW) OCSEE engine are presented. During this phase of the program a total of 17preliminary OCSEE UTW composite fan blades were manufactured for various component tests including frequency characteristics, strain distribution, bench fatigue, dovetail pull, whirligig overspeed and whirligig impact. All tests were successfully completed with the exception of whirligig impact tests. Improvements in local impact capability are being evaluated for the OCSEE blade under other NASA and related programs.

Source record↗

Quiet Clean Short-haul Experimental Engine (QCSEE) Under-The-Wing (UTW) engine composite nacelle test report. Volume 1: Summary, aerodynamic and mechanical performance

The performance test results of the final under-the-wing engine configuration are presented. One hundred and six hours of engine operation were completed, including mechanical and performance checkout, baseline acoustic testing with a bellmouth inlet, reverse thrust testing, acoustic technology tests, and limited controls testing. The engine includes a variable pitch fan having advanced composite fan blades and using a ball-spline pitch actuation system.

Source record↗

Upper Stage Engine Composite Nozzle Extensions

Carbon-carbon (C-C) composite nozzle extensions are of interest for use on a variety of launch vehicle upper stage engines and in-space propulsion systems. The C-C nozzle extension technology and test capabilities being developed are intended to support National Aeronautics and Space Administration (NASA) and United States Air Force (USAF) requirements, as well as broader industry needs. Recent and on-going efforts at the Marshall Space Flight Center (MSFC) are aimed at both (a) further developing the technology and databases for nozzle extensions fabricated from specific CC materials, and (b) developing and demonstrating low-cost capabilities for testing composite nozzle extensions. At present, materials development work is concentrating on developing a database for lyocell-based C-C that can be used for upper stage engine nozzle extension design, modeling, and analysis efforts. Lyocell-based C-C behaves in a manner similar to rayon-based CC, but does not have the environmental issues associated with the use of rayon. Future work will also further investigate technology and database gaps and needs for more-established polyacrylonitrile- (PAN-) based C-C's. As a low-cost means of being able to rapidly test and screen nozzle extension materials and structures, MSFC has recently established and demonstrated a test rig at MSFC's Test Stand (TS) 115 for testing subscale nozzle extensions with 3.5-inch inside diameters at the attachment plane. Test durations of up to 120 seconds have been demonstrated using oxygen/hydrogen propellants. Other propellant combinations, including the use of hydrocarbon fuels, can be used if desired. Another test capability being developed will allow the testing of larger nozzle extensions (13.5- inch inside diameters at the attachment plane) in environments more similar to those of actual oxygen/hydrogen upper stage engines. Two C-C nozzle extensions (one lyocell-based, one PAN-based) have been fabricated for testing with the larger-scale facility.

Valentine, Peter G.↗

Damage-Tolerant, Affordable Composite Engine Cases Designed and Fabricated

An integrated team of NASA personnel, Government contractors, industry partners, and university staff have developed an innovative new technology for commercial fan cases that will substantially influence the safety and efficiency of future turbine engines. This effective team, under the direction of the NASA Glenn Research Center and with the support of the Federal Aviation Administration, has matured a new class of carbon/polymer composites and demonstrated a 30- to 50-percent improvement in specific containment capacity (blade fragment kinetic energy/containment system weight). As the heaviest engine component, the engine case/containment system greatly affects both the safety and efficiency of aircraft engines. The ballistic impact research team has developed unique test facilities and methods for screening numerous candidate material systems to replace the traditional heavy, metallic engine cases. This research has culminated in the selection of a polymer matrix composite reinforced with triaxially braided carbon fibers and technology demonstration through the fabrication of prototype engine cases for three major commercial engine manufacturing companies.

Hopkins, Dale A.↗

Functionally graded magnetic materials: a perspective to advance charged particle optics through compositional engineering

Additive manufacturing has ushered in a new paradigm of bottom-up materials-by-design of spatially non-uniform materials. Functionally graded materials have locally tailored compositions to provide optimized global properties and performance. In this letter, we propose an opportunity for the application of graded magnetic materials as lens elements for charged particle optics. A Hiperco50/Hymu80 (FeCo-2 V/Fe-80Ni-5Mo) graded magnetic alloy was successfully additively manufactured via Laser Directed Energy Deposition with spatially varying magnetic properties. The compositional gradient is then applied using computational simulations to demonstrate how a tailored material can enhance the magnetic performance of a critical, image-forming component of a transmission electron microscope.

36 MATERIALS SCIENCE↗