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Three Way Catalyst-Selective Catalytic Reduction Aftertreatment System Evaluation for a Lean Burn Gasoline Engine Operating in Homogenous Charge Compression Ignition, Spark-Assisted Compression Ignition, and Spark-Ignited Combustion Modes
Low temperature and dilute homogenous charge compression ignition (HCCI) and spark-assisted compression ignition (SACI) can improve fuel efficiency and reduce engine-out NO x emissions, especially during lean operation. However, under lean operation, these combustion modes are unable to achieve Environmental Protection Agency (EPA) Tier 3 emissions standards without the use of lean aftertreatment. The three way catalyst (TWC)-SCR lean aftertreatment concept investigated in this work uses periodic-rich operation to produce NH 3 over a TWC to be stored on a selective catalytic reduction (SCR) catalyst for NO x conversion during subsequent lean operation. Experiments were performed with a modified 2.0 L gasoline engine that was cycled between lean HCCI and rich SACI operation and between lean and rich spark-ignited (SI) combustion to evaluate NO x conversion and fuel efficiency benefits. Different lambda values during rich operation and different times held in rich operation were investigated. Results are compared to a baseline case in which the engine is always operated at stoichiometric conditions. SCR system calculations are also presented to allow for comparisons of system performance for different levels of stored NH 3 . With the configuration used in this study, lean/rich HCCI/SACI operation resulted in a maximum NO x conversion efficiency of only 10%, while lean/rich SI operation resulted in a maximum NO x conversion efficiency of 60%. If the low conversion efficiency of HCCI/SACI operation could be improved through higher brick temperatures or additional SCR bricks, calculations indicate that TWC-SCR aftertreatment has the potential to provide attractive fuel efficiency benefits and near-zero tailpipe NO x . Calculated potential fuel efficiency improvement relative to stoichiometric SI is 7–17% for lean/rich HCCI/SACI with zero tailpipe NO x and -1 to 5% for lean/rich SI with zero tailpipe NO x emissions. Although the previous work indicated that the use of HCCI/SACI increases the time for NH 3 to start forming over the TWC during rich operation, reduces NH 3 production over the TWC per fuel amount, and increases NH 3 slip over the SCR catalyst, if NO x conversion efficiency could be enhanced, improvements in fuel efficiency could be realized while meeting stringent tailpipe NO x standards.
Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Mixing Controlled Compression Ignition Combustion
Mixing controlled compression ignition or diesel engines are highly efficient and are likely to continue to be the primary means for movement of goods for many years to come. Low-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could potentially have advantageous properties for combustion such as high cetane number and reduced engine out particle emissions. In this study, we developed a list of potential biomass-derived diesel blendstocks. An online database of properties and characteristics of these bioblendstocks was populated with data. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number =40, flashpoint =52 degrees C, and boiling point or final boiling point <338 degrees C. Blendstocks needed to be soluble in diesel fuel, have a toxicity no worse than conventional diesel, and not be corrosive. Additionally, cloud point or freezing point below 0 degrees C was required. This screening produced a list of 27 potential bioblendstocks. Of these candidates, 13 were available commercially or could be synthesized by biofuels production researchers and included 11 nominally pure components and two mixtures. These 13 candidates were then subjected to further study based on how they impact fuel properties upon blending. Blend properties included cetane number, lubricity, conductivity, oxidation stability and viscosity. Results indicate that all thirteen candidates can meet the basic requirements for diesel fuel blending and are likely to reduce particle emissions from diesel combustion.
Methanol mixing−controlled compression ignition enabled via homogeneous charge compression ignition of dimethyl ether through catalytic decomposition of methanol
Methanol is a potentially attractive fuel for marine and off−road engines owing to its availability at bunkering and global distribution locations. Although methanol is well−distributed worldwide, its fuel chemistry and ignition properties make it poorly suited as a direct drop−in replacement for diesel fuel in compression−ignition engines. However, industrial processes are regularly used to convert methanol, via catalytic dehydration, to dimethyl ether (DME) over nonprecious metal catalysts. This chemical conversion can occur at relatively low pressures, temperatures, and catalyst space velocities, highlighting a potential opportunity to generate DME via onboard catalytic dehydration of methanol. DME’s fuel kinetic and ignition properties for compression ignition are much more favorable than those of methanol or even diesel fuel, but DME is more challenging than diesel fuel or methanol to pump, store, and deliver through conventional diesel fueling injection hardware. Thus, a potential opportunity exists to use the ignition and kinetic properties of DME, with the transportation and delivery advantages of methanol, in a methanol−fueled mixing−controlled compression−ignition engine. The present work explores performance, combustion behavior, and emissions reduction opportunities for methanol mixing−controlled combustion, enabled by a HCCI of DME that represents a small fraction of the total fuel energy that can be generated onboard via catalytic dehydration of methanol.
Direct Numerical Simulation of Conventional and Alternative Jet Fuel Mixing and Ignition in Compression Ignition Engine Environments.
Abstract not provided.
Direct Numerical Simulation of Conventional and Alternative Jet Fuel Mixing and Ignition in Compression Ignition Engine Environments.
Abstract not provided.
Using Ducted Fuel Injection to Attenuate Soot Formation in a Mixing-Controlled Compression Ignition Engine
Ducted fuel injection (DFI) has been introduced as a strategy to enhance the fuel/charge gas mixing within the combustion chamber of a direct-injection mixing-controlled compression ignition engine. The concept involves injecting each fuel spray through a small tube within the combustion chamber to facilitate the creation of a leaner mixture in the autoignition zone, relative to a conventional free-spray configuration (i.e., a fuel spray that is not surrounded by a duct). While previous experiments demonstrated that DFI lowers both soot incandescence and soot mass in a constant-volume combustion vessel with a single-component normal-alkane fuel (n-dodecane), here we provide the first evidence that the technology provides similar benefits in an engine application using a commercial diesel fuel containing ~30 wt% aromatics. The present study investigates the effects on engine-out emissions and efficiency with a two-orifice injector tip for charge gas mixtures containing 16 and 21 mol% oxygen. The result is that DFI is confirmed to be effective at curtailing engine-out soot emissions. It also breaks the tradeoff between emissions of soot and nitrogen oxides (NOx) by simultaneously attenuating soot and NO x with increasing dilution.
Mapping the combustion modes of a dual-fuel compression ignition engine
Compression-ignition (CI) engines can produce higher thermal efficiency (TE) and thus lower carbon dioxide (CO 2 ) emissions than spark-ignition (SI) engines. Unfortunately, the overall fuel economy of CI engine vehicles is limited by their emissions of nitrogen oxides (NO x ) and soot, which must be mitigated with costly, resource- and energy-intensive aftertreatment. NO x and soot could also be mitigated by adding premixed gasoline to complement the conventional, non-premixed direct injection (DI) of diesel fuel in CI engines. Several such “dual-fuel” combustion modes have been introduced in recent years, but these modes are usually studied individually at discrete conditions. This paper introduces a mapping system for dual-fuel CI modes that links together several previously studied modes across a continuous two-dimensional diagram. This system includes the conventional diesel combustion (CDC) and conventional dual-fuel (CDF) modes; the well-explored advanced combustion modes of HCCI, RCCI, PCCI, and PPCI; and a previously discovered but relatively unexplored combustion mode that is herein titled “Piston-split Dual-Fuel Combustion” or PDFC. Tests show that dual-fuel CI engines can simultaneously increase TE and lower NO x and/or soot emissions at high loads through the use of Partial HCCI (PHCCI). At low loads, PHCCI is not possible, but either PDFC or RCCI can be used to further improve NO x and/or soot emissions, albeit at slightly lower TE. These results lead to a “partial dual-fuel” multi-mode strategy of PHCCI at high loads and CDC at low loads, linked together by PDFC. Drive cycle simulations show that this strategy, when tuned to balance NO x and soot reductions, can reduce engine-out CO 2 emissions by about 1% while reducing NO x and soot by about 20% each with respect to CDC. This increases emissions of unburnt hydrocarbons (UHC), still in a treatable range (2.0 g/kWh) but five times as high as CDC, requiring changes in aftertreatment strategy.
Calculations of the Performance of a Compression-Ignition Engine-Compressor Turbine Combination I : Performance of a Highly Supercharged Compression-Ignition Engine
Small high-speed single-cylinder compression-ignition engines were tested to determine their performance characteristics under high supercharging. Calculations were made on the energy available in the exhaust gas of the compression-ignition engines. The maximum power at any given maximum cylinder pressure was obtained when the compression pressure was equal to the maximum cylinder pressure. Constant-pressure combustion was found possible at an engine speed of 2200 rpm. Exhaust pressures and temperatures were determined from an analysis of indicator cards. The analysis showed that, at rich mixtures with the exhaust back pressure equal to the inlet-air pressure, there is excess energy available for driving a turbine over that required for supercharging. The presence of this excess energy indicates that a highly supercharged compression-ignition engine might be desirable as a compressor and combustion chamber for a turbine.
A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications
A mixture of n-dodecane and m-xylene is investigated as a diesel fuel surrogate for compression ignition engine applications. Compared to neat n-dodecane, this binary mixture is more representative of diesel fuel because it contains an alkyl-benzene which represents an important chemical class present in diesel fuels. A detailed multi-component mechanism for n-dodecane and m-xylene was developed by combining a previously developed n-dodecane mechanism with a recently developed mechanism for xylenes. The xylene mechanism is shown to reproduce experimental ignition data from a rapid compression machine and shock tube, speciation data from the jet stirred reactor and flame speed data. This combined mechanism was validated by comparing predictions from the model with experimental data for ignition in shock tubes and for reactivity in a flow reactor. The combined mechanism, consisting of 2885 species and 11754 reactions, was reduced to a skeletal mechanism consisting 163 species and 887 reactions for 3D diesel engine simulations. The mechanism reduction was performed using directed relation graph (DRG) with expert knowledge (DRG-X) and DRG-aided sensitivity analysis (DRGASA) at a fixed fuel composition of 77% of n-dodecane and 23% m-xylene by volume. The sample space for the reduction covered pressure of 1 – 80 bar, equivalence ratio of 0.5 – 2.0, and initial temperature of 700 – 1600 K for ignition. The skeletal mechanism was compared with the detailed mechanism for ignition and flow reactor predictions. Finally, the skeletal mechanism was validated against a spray flame dataset under diesel engine conditions documented on the Engine Combustion Network (ECN) website. These multidimensional simulations were performed using a Representative Interactive Flame (RIF) turbulent combustion model. In conclusion, encouraging results were obtained compared to the experiments with regards to the predictions of ignition delay and lift-off length at different ambient temperatures.
Poly(oxymethylene) Ethers as a High Cetane, Low Sooting Biofuel Blendstock for Use in Medium to Heavy Duty Mixing Controlled Compression Ignition Engines
Compression ignition (CI) engines are currently the most common prime mover for medium and heavy duty vehicles; these engines contribute roughly a quarter of US greenhouse gas emissions from transportation, and even higher percentages of particulate and nitrogen oxide emissions. As a result, there have been significant efforts made to reduce these emissions, particularly through selection of low-emissions alternative fuels. Oxymethylene ethers (OMEs) are a class of molecule, typically structured R-O-(CH2O)n-R', which have been considered as a possible blendstock in CI fuels for the goal of soot reduction. Generally, past work has focused on methyl-terminated OMEs, CH3-O-(CH2O)n-CH3, which by virtue of containing no C--C bonds, produce negligible soot. These molecules show significant reductions in soot emission from engines when blended in moderate to high ratios with traditional diesels, however, they have been shown to have inferior physical properties and poor compatibility with some legacy systems. Recent theoretical work has shown that OMEs with non-methyl alkyl groups may have superior performance, albeit at the cost of increased soot formation. In this work, a variety of OMEs with terminating alkyl groups from methyl to butyl are considered for their suitability as CI fuels. The synthesis of these extended OMEs is studied, including formation of n=1 OMEs from common chemical sources, and extension of the chain length to heavier molecules, via reactions over acidic ion exchange resins. Following the synthesis, the properties of these OMEs are studied with respect to their engine applicability. It is found that heavier (propyl- and butyl-terminated) OMEs have superior properties for diesel compatibility, particularly in reactivity, volatility, and water solubility. Extended-alkyl OMEs are found to have higher soot production than methyl-terminated OMEs, but remain superior to diesel soot production on a per-unit-energy basis. A sample of a butyl-terminated OME mixture, n=2-4, is selected as the ideal OME blend for close compatibility with legacy diesel systems. This mixture is blended with certified diesel and tested for ASTM D975 compatibility, passing all required tests but lubricity; decreased heat of combustion is observed but not governed by the diesel standard. Fundamental combustion tests of various mid-weight OMEs are performed in a rapid compression machine, where it is shown that low-temperature chemistry causes a region of decreased dependence of ignition delay on temperature, consistent with methyl-terminated OME behavior. An isopropyl-terminated OME is observed to have low reactivity compared to other OMEs; this fuel is investigated via further rapid compression machine testing and CFR engine testing. It is found that this OME has strong negative-temperature-coefficient ignition behavior - a first for OMEs - and has reactivity lower than other OMEs, but insufficient for direct spark ignition engine testing.
Cycle-to-cycle variability in spark-assisted compression ignition engines near optimal mean combustion phasing
Stoichiometric spark-assisted compression ignition (SACI) combustion with exhaust gas recirculation (EGR) dilution has demonstrated higher part-load thermal efficiencies compared to spark-ignited engines, while maintaining ultra-low tailpipe emissions. However, SACI is often characterized by high cyclic variability in heat release or torque output, which poses a challenge to its implementation in light-duty vehicles. This paper presents an experimental investigation of cyclic variability in stoichiometric SACI combustion under EGR-dilute conditions, while maintaining mean combustion phasing (θ 50 ) near optimal timing for thermal efficiency. The present work focuses on SACI conditions where the flame-based heat release fraction is between approximately 10% and 40% of the overall heat release, and therefore contributes significantly to the combustion process. For the SACI conditions examined, the variability in θ 50 was driven by variability in autoignition timing, which in turn correlated with the start of measurable heat release (θ 02 ). High variability in θ 50 caused unstable work output due to very late combustion with poor or no end-gas autoignition. The use of a high ignition energy dual-coil offset ignition system had negligible impact in reducing θ 50 variability. Analysis of experimental data from close to 1000 operating conditions showed that the magnitude of θ 50 variability correlates with the flame-based heat release fraction ([Formula: see text]), for a large range of intake pressures, spark timings and exhaust gas recirculation levels. For the SACI conditions examined, combustion phasing variability was largely determined by flame-based combustion and particularly the initial flame formation (θ IGN-02 ), and minimally by the end-gas autoignition heat release. The analysis also demonstrated that θ 50 variability is amplified as the contribution of the flame to the overall heat release increases.
Computational Fluid Dynamics Simulation of Gasoline Compression Ignition
Gasoline compression ignition (GCI) is a low temperature combustion (LTC) concept that has been gaining increasing interest over the recent years owing to its potential to achieve diesel-like thermal efficiencies with significantly reduced engine-out nitrogen oxides (NOx) and soot emissions compared to diesel engines. In this work, closed-cycle computational fluid dynamics (CFD) simulations are performed of this combustion mode using a sector mesh in an effort to understand effects of model settings on simulation results. One goal of this work is to provide recommendations for grid resolution, combustion model, chemical kinetic mechanism, and turbulence model to accurately capture experimental combustion characteristics. Grid resolutions ranging from 0.7 mm to 0.1 mm minimum cell sizes were evaluated in conjunction with both Reynolds averaged Navier-Stokes (RANS) and Large Eddy Simulation (LES) based turbulence models. Solution of chemical kinetics using the multi-zone approach is evaluated against the detailed approach of solving chemistry in every cell. The relatively small primary reference fuel (PRF) mechanism (48 species) used in this study is also evaluated against a larger 312-species gasoline mechanism. Based on these studies the following model settings are chosen keeping in mind both accuracy and computation costs – 0.175 mm minimum cell size grid, RANS turbulence model, 48-species PRF mechanism, and multi-zone chemistry solution with bin limits of 5 K in temperature and 0.05 in equivalence ratio. With these settings, the performance of the CFD model is evaluated against experimental results corresponding to a low load start of injection (SOI) timing sweep. The model is then exercised to investigate the effect of SOI on combustion phasing with constant intake valve closing (IVC) conditions and fueling over a range of SOI timings to isolate the impact of SOI on charge preparation and ignition. Simulation results indicate that there is an optimum SOI timing, in this case -30?aTDC (after top dead center), which results in the most stable combustion. Advancing injection with respect to this point leads to significant fuel mass burning in the colder squish region, leading to retarded phasing and ultimately misfire for SOI timings earlier than -42?aTDC. On the other hand, retarding injection beyond this optimum timing results in reduced residence time available for gasoline ignition kinetics, and also leads to retarded phasing, with misfire at SOI timings later than -15?aTDC.
Wet biofuel compression ignition
A compression ignition engine system allows use of hydrous fuels, in particular hydrous biofuels, with high water content (e.g., 20-85% water). The hydrous fuel is pressurized, and also preferably heated via the engine's exhaust gas, to increase its enthalpy, and is then directly injected into the engine cylinder(s) near top dead center. The system provides brake thermal efficiency increases of 20% or more versus a comparable system using conventional diesel fuel, while allowing the use of inexpensive undistilled or lightly distilled biofuels.
Model predictive combustion control of a Gasoline Compression Ignition engine
Gasoline Compression Ignition is a novel combustion concept that derives its superiority from the high compression ratio of a compression ignition engine as well as the properties of gasoline fuel, such as longer ignition delay and higher volatility compared to diesel. Here, this combustion concept was experimentally tested on a 12.4L Class 8 truck engine. Based on these experimental data, prior efforts by the authors focused on the development of an engine model for a heavy-duty engine operating on a low-reactivity fuel. This engine model was leveraged within this study to investigate a combustion control strategy at different engine conditions and injection methods and was augmented to incorporate cycle-to-cycle combustion variations. State estimation is performed by means of a Kalman filter which feeds into a model predictive controller. The model predictive controller chooses control actions based on a predefined cost function under consideration of bounds reflecting physical constraints. The engine model was utilized to establish a state-space model that serves the Kalman filter and model predictive controller for estimation and prediction. A comparative study investigating control actions and engine behavior was performed with and without limiting in-cylinder peak pressure as well as combustion noise, which is of particular interest for early pilot injection strategies. In addition, the proposed control architecture was investigated at two different levels of cycle-to-cycle variations and compared to the performance of a control structure with input disturbance rejection. For increased cycle-to-cycle variations, disturbance estimation reduces state fluctuations and control effort. In general, this investigation highlights control aspects specific to a compression-ignited combustion regime with low-reactivity fuel. The control algorithm is able to maintain the desired references for brake mean effective pressure and combustion phasing while controlling peak in-cylinder pressure and combustion noise.
The effects of boost pressure on stratification and burn duration of gasoline homogeneous charge compression ignition combustion
This article investigates the effects of intake pressure (boost) on the pre-ignition stratification and burn duration of homogeneous charge compression ignition combustion. Full cycle computational fluid dynamics simulations are performed with gasoline kinetics. An intake pressure sweep is performed while maintaining the same combustion timing and mean composition. The burn duration reduces with increasing boost, even though intake temperature is reduced to hold combustion timing constant. It is shown that the compositional stratification increases with boost whereas thermal stratification decreases. A quasi-dimensional model is employed to assess the effect of compositional stratification, pressure, mean temperature and isolate the effect of thermal stratification on burn duration. The analysis reveals that reducing charge temperature neutralizes the effect of increased boost on reactivity and the shorter burn durations at higher boost are primarily due to the lower thermal stratification. It is shown that higher pressures do not significantly increase the mixing and the lower thermal stratification is due to lower wall heat losses per unit charge mass. A follow-up set of non-reacting simulations with adiabatic walls corroborate this claim by revealing a constant magnitude of thermal stratification across the boost sweep.