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Chemical process for forming low molecular weight, fully cyclized heteroaromatic prepolymers under conditions which limit chain extension or branching is described. Exact procedures used in conducting chemical reaction are defined. Advantages of process over conventional methods are presented.
Condensations of light have been observed when Saturn's rings are seen almost edge on, and the sun and the earth are on opposite sides of the ring plane. These condensations are associated with ring C and Cassini's division. If the relative brightness between the two condensations and the optical thickness of ring C are known, we can calculate the optical thickness of Cassini's division. Using Barnard's and Sekiguchi's measurements, we have obtained a range from .01 to .05 for the optical thickness of Cassini's division. A brightness profile of the condensations which agrees well with visual observations is also presented.
In the plot of asteroids considered the mass density is substituted for the number density. This approach provides a better definition of the limits of the main belt, and demonstrates more clearly that the asteroids, like the Saturnian rings, have condensed from partially corotating plasma. A diagram shows that the whole main belt is located below 2/3 of Jupiter's orbit. This means that the main belt asteroids may have been derived from condensation which took place inside Jupiter's orbit.
This study investigates the formation of soot from n-dodecane and its blend with m-xylene under pyrolytic and low-oxygen conditions with reactive molecular dynamics (MD) simulations. ReaxFF force field is used to simulate the interactions of fuel and oxygen molecules at engine-relevant conditions (2500-3500 K and 70-75 bar). Fuel molecules with carbon atom density of 0.03 g/cm 3 are dispersed into a cube and constant temperature simulations are carried out with a Nosé-Hoover thermostat. Pyrolysis of n-dodecane and the chemical pathway towards the formation of aromatic hydrocarbons are investigated. The initial pyrolysis rate of n-dodecane is observed to be slightly higher with the addition of aromatic compounds and oxygen. While the first aromatics formed from the decomposed n-dodecane are phenyl radicals at 2500 K, decomposition of the aliphatic fuel compound is observed to be necessary to build a carbon cluster, and eventually soot. Morphological properties of the created soot particles are also analyzed. The maturity, size and aromatics content of the soot particle are slightly affected with the addition of m-xylene and oxygen at 3500 K within the 3 ns simulation time possibly due the formation of larger and more condensed aromatic rings, resulting in larger soot molecules. The outcomes of this study provide important insights into the formation mechanism of soot and its morphological characteristics depending on varying fuel concentrations at pyrolysis and low oxygen engine conditions. Results of this analysis will further contribute to the understanding of contrail formation on generated soot particles originated from the combustion of different chemical components with particle chemistry matching companion experiments.
A condensate cloud on Titan identified by its 220 cm−1 far-infrared signature continues to undergo seasonal changes at both the north and south poles. In the north, the cloud, which extends from 55 N to the pole, has been gradually decreasing in emission intensity since the beginning of the Cassini mission with a half-life of 3.8 years. The cloud in the south did not appear until 2012 but its intensity has increased rapidly, doubling every year. The shape of the cloud at the south pole is very different from that in the north. Mapping in 2013 December showed that the condensate emission was confined to a ring with a maximum at 80 S. The ring was centered 4deg from Titanʼs pole. The pattern of emission from stratospheric trace gases like nitriles and complex hydrocarbons (mapped in 2014 January) was also offset by 4deg, but had a central peak at the pole and a secondary maximum in a ring at about 70 S with a minimum at 80 S. The shape of the gas emission distribution can be explained by abundances that are high at the atmospheric pole and diminish toward the equator, combined with correspondingly increasing temperatures. We discuss possible causes for the condensate ring. The present rapid build up of the condensate cloud at the south pole is likely to transition to a gradual decline from 2015 to 2016. Key words: molecular processes - planets and satellites: atmospheres - planets and satellites: composition - planets and satellites: individual (Titan) - radiation mechanisms: thermal
Observed ring galaxies appear to fall into two major types. The first tends to consist of isolated galaxies which display a smooth, apparently circular ring and a central nucleus. These have been variously classified as R(S) by de Vaucouleurs (1959) and as type O by Few and Madore (1986). The second class of ring galaxy nearly always has a close companion of comparable size (no less than about one tenth that of the ring galaxy). In these objects the ring is knotty in appearance, is usually elliptical, even when deprojected on the sky, and is often open on one side, having a 'horse shoe' or 'banana' shape. The nucleus does not usually appear at the center of the ring and is sometimes apparently absent, giving rise to an 'empty ring' galaxy. deVaucouleurs et al. (1976) designated this second type as RING, while Few and Madore (1986) have classified similar galaxies as P type. These galaxies have elevated far IR emission, bright HII regions, and blue spectral colors. The different environments of the two types or ring galaxy, together with their overall morphological and spectral differences suggest that the R(S)/O type are most probably the result of an instability that occurs in isolated galaxies, whereas the RING/P type appears to be the result of a recent collision between two roughly equal mass objects, at least one of which is a disk galaxy. Theys and Spiegel (1976) studied a sample of this latter type and identified three subclasses: RE: galaxies with crisp, empty rings; RN: galaxies like those of RE but with off-center nuclei; RK: galaxies having single dominant knots or condensations in the rings. A presentation of a preliminary understanding of the connections between these different observed forms in terms of parameters which are intrinsic to the galaxy system, such as time since collision and impact parameter, and in terms of our line of sight view is the purpose of this paper. Here we report results we have obtained from three dimensional computer simulations of collisions between equal mass galaxies, one of which is a rotating, disk galaxy containing both gas and stars and the other is an elliptical containing stars only. We have used a combined n-body/SPH program (see Balsara, 1990) to model fully self consistent models in which the halo mass is 2.5 times that of the disk and gas comprises ten percent of the disk mass.
The J = 1 - 0 transition of (C-13)O over a 3 sq deg region in Heiles Cloud 2 has been mapped using the Five College Radio Astronomy Observatory 14 m telescope. The complete map contains 3600 individual spectra of which 2400 were sampled with 1 arcmin spacing. The map suggests that the structure of Heiles Cloud 2 is dominated by a quasi-equilibrium rotating ring similar to those found in numerical calculations of the gravitational collapse of a rotating cloud. Within this ring, several dense condensations have been identified and partially mapped in C(O-18). These subcondensations, among which is the dense filament TMC-1, probably result from the instability of the ring to fragmentation and have masses on the order of the jeans mass. Thus, they are marginally unstable to further collapse and may be the precursors of fragments that will eventually form stars.
Saturn has bright, broad rings separated by narrow gaps, while the rings of Uranus are dark, narrow and widely spaced. Presumably, both sets of rings lie inside the Roche limit, which is why the ring material has not condensed into satellites. This paper briefly reviews what is known about each ring system, with emphasis on properties of significance to dynamical astronomy.
Voyager 2 UV-photopolarimeter occultation observations toward Gamma Peg, obtained on the nightside of Uranus at planetocentric latitude 68.9 deg N on January 24, 1986, are used to probe the structure of the Uranian atmosphere. The data are presented graphically and compared with the predictions of model atmospheres. The temperature profile for an aerosol-free atmosphere ranges from 85 + or - 2.3 K at 2.7 mbar to 96 + or - 13 K at 370 microbar, and the 1-mbar radius is found to be 25,219 + or - 6.3 km. The extinction coefficient for an aerosol haze layer at 1 mbar or higher is shown to be less than or equal to about 0.0001/km, but it is suggested that a well-mixed haze layer consisting of meteor or ring dust and/or photochemical condensates may well be present below 3 mbar.
The paper investigates constraints imposed on the ice content of Saturn's satellites and rings by the planet's high luminosity during the early part of its quasi-equilibrium contraction phase. It is assumed that the addition of ices to the satellites was not completed until after the start of the quasi-equilibrium contraction and that the condensation of ices ceased at the same time within the primordial nebulae of Jupiter and Saturn. Using previously derived limits on the time of condensation cessation for Jupiter's system, the following tentative conclusions are made: (1) Titan is the innermost satellite at whose position a methane-containing ice could condense; (2) water ice could have condensed at the positions of all the satellites; (3) the systematic decrease in the mass of the regular satellites with decreasing distance from the planet may have been caused, in part, by the larger time intervals, for the closer satellites, between the start of contraction and the first condensation of ices at their positions; and (4) ammonia ices, primarily NH4SH, were able to condense at the positions of all but the innermost satellites. It is also shown that water ice could have condensed in the region of the rings near the end of the condensation period.
Water ices in surface crusts of Europa, Enceladus, Saturn's main rings, and Kuiper Belt Objects can become heavily oxidized from radiolytic chemical alteration of near-surface water ice by space environment irradiation. Oxidant accumulations and gas production are manifested in part through observed H2O2 on Europa. tentatively also on Enceladus, and found elsewhere in gaseous or condensed phases at moons and rings of Jupiter and Saturn. On subsequent chemical contact in sub-surface environments with significant concentrations of primordially abundant reductants such as NH3 and CH4, oxidants of radiolytic origin can react exothermically to power gas-driven cryovolcanism. The gas-piston effect enormously amplifies the mass flow output in the case of gas formation at basal thermal margins of incompressible fluid reservoirs. Surface irradiation, H2O2 production, NH3 oxidation, and resultant heat, gas, and gas-driven mass flow rates are computed in the fluid reservoir case for selected bodies. At Enceladus the oxidant power inputs are comparable to limits on nonthermal kinetic power for the south polar plumes. Total heat output and plume gas abundance may be accounted for at Enceladus if plume activity is cyclic in high and low "Old Faithful" phases, so that oxidants can accumulate during low activity phases. Interior upwelling of primordially abundant NH3 and CH4 hydrates is assumed to resupply the reductant fuels. Much lower irradiation fluxes on Kuiper Belt Objects require correspondingly larger times for accumulation of oxidants to produce comparable resurfacing, but brightness and surface composition of some objects suggest that such activity may be ongoing.
This report gives a concise summary of the conclusions of cosmogonic studies linking the origin of comets with the origin of the Jovian planets at the dawn of the solar system. Cometary nuclei are shown to be original planetesimals ejected from and returning to the solar system. Formation processes for comets are described in detail, emphasizing the preplanetary rings of the Jovian planets, condensation and accretion from diffuse matter, and the origin of Oort's sphere. Physical and mechanical properties of comets are discussed, including the composition of cometary gases, the size and composition of cometary nuclei, the placement of comets in Oort's sphere, and the density of nuclei in that region. Unresolved difficulties in models of planet and comet formation are considered.
The regular satellites of Jupiter and Saturn are generally believed to have accreted within cooling circumplanetary nebulae. Small silicate bodies are lost into the planet by gas drag before ice can condense. Larger silicate protosatellites survive by exerting tidal torques on the gas, clearing low-density 'tunnels' around their orbits. The nebula is thus divided into a series of gas rings depleted in silicates. Cooling eventually allows ice condensation, yielding another generation of icy bodies. Collisional accretion of these objects accounts for stochastic density variations of Saturn's inner satellites. High dynamic pressure may have prevented accretion in the inner part of the Jovian nebula; J5 may be an ablated remnant of a larger body.
Harris (1975) has suggested that the maximum size of particles in a planetary ring is controlled by collisional fragmentation rather than tidal stress. While this conclusion is probably true, estimated radius limits must be revised upward from Harris' values of a few kilometers by at least an order of magnitude. Accretion of particles within the Roche limit is also possible. These considerations affect theories concerning the evolution of Saturn's rings, of the moon, and of possible former satellites of Mercury and Venus. In the case of Saturn's rings, comparison of various theoretical scenarios with available observational evidence suggests that the rings formed from the breakup of larger particles rather than from original condensation as small particles. This process implies a distribution of particle sizes in Saturn's rings possibly ranging up to about 100 km but with most of the cross section in centimeter-scale particles.
NASA supported the development of the CAMECA ims 1270 ion microprobe at UCLA for applications in cosmochemistry. The primary investigations centered on measuring the microscopic distributions of key isotopic abundances in primitive meteoritic materials as a means of constraining the nature of important thermal and chemical processes in the solar nebula and the timescales associated with those processes. Our prior work on oxygen isotope anomalies in a wide variety of meteoritic materials had led us to a view of a spatially heterogeneous nebula, and in particular, a restricted region for CAI formation that is characterized by O-16-rich gas. Because of its production of CAIs in the energetic local environment near the protosun, the existence of a natural transport mechanism via bipolar outflows, and a general astrophysical plausibility, we were attracted to the fluctuating X-wind model which had been put forward by Frank Shu, Typhoon Lee, and colleagues. With our collaborators, we undertook a series of investigations to test the viability of this hypothesis; this work led directly to the discovery of live Be in CAIs and a clear demonstration of the existence of 160-rich condensates, which necessarily implies an O-16-rich gaseous reservoir in the nebula. Both of these observations fit well within the context of X-wind type models, i.e. formation of CAIs (or condensation of their precursors) in the reconnection ring sunward of the inner edge of the accretion disk, however much work remains to be done to test whether the physical parameters of the model can quantitatively predict not only the thermal histories of CAIs but also their radioactivity. The issue of spatial heterogeneity in the nebula, central to the X-wind model, is also at the heart of any chronology based on short-lived radioisotopes. In this work, we followed up on strong hints for presence of exireme:j: (53 day) short-lived Be-7, and have prepared a manuscript (in revision). We also measured A1-Mg systematics by a combined approach of high-precision multiple-collector SIMS analyses, traditional analyses on the UCLA ims 1270, and high-spatial resolution analyses using a NanoSIMS instrument. The data help to deconvolve effects due to partial resetting of the A1-Mg system by multiple thermal events. Finally, we initiated investigations related to nebular heterogeneity with a new initiative of in situ high-precision sulfur isotope analyses of sulfides from a wide variety of components of chondrites. The ultimate goal of all this work is to help develop a better understanding of the relationships between CAIs and chondrules, the astrophysical environments in which they formed, and the timescales of nebular processes. As detailed in Table 1, for the project period, 14 manuscripts were published and 17 abstracts were presented describing the work.
The encounter of the spacecraft Voyager 2 with Neptune and its large satellite Triton in August 1989 will provide a crucial test of ideas regarding the origin and chemical composition of the outer solar system. In this pre-encounter publication, the possibility is quantified that Titron is a captured moon which, like Pluto and Charon, originally condensed as a major planetesimal within the gas ring that was shed by the contracting protosolar cloud at Neptune's orbit. Ideas of supersonic convective turbulence are used to compute the gas pressure, temperature and rat of catalytic synthesis of CH4, CO2, and C(s) within the protosolar cloud, assuming that all C is initially present as CO. The calculations lead to a unique composition for Triton, Pluto, Charon: each body consists of, by mass, 18 1/2 percent solid CO2 ice, 4 percent graphite, 1/2 percent CH4 ice, 29 percent methanated water ice and 48 percent of anhydrous rock. This mix has a density consistent with that of the Pluto-Charon system and yields a predicted mean density for Triton of 2.20 + or - 0.5 g/cu cm, for satellite radius equal to 1,750 km.
The origin of Jupiter and the Galilean satellite system is examined in the light of the new data that has been obtained by the NASA Galileo Project. In particular, special attention is given to a theory of satellite origin which was put forward at the start of the Galileo Mission and on the basis of which several predictions have now been proven successful. These predictions concern the chemical composition of Jupiter's atmosphere and the physical structure of the satellites. According to the proposed theory of satellite origin, each of the Galilean satellites formed by chemical condensation and gravitational accumulation of solid grains within a concentric family of orbiting gas rings. These rings were cast off equatorially by the rotating proto-Jovian cloud (PJC which contracted gravitationally to form Jupiter some 4 1/2 billion years ago. The PJC formed from the gas and grains left over from the gas ring that had been shed at Jupiter's orbit by the contracting proto-solar cloud (PSC Supersonic turbulent convection provides the means for shedding discrete gas rings. The temperatures T (sub n) of the system of gas rings shed by the PSC and PJC vary with their respective mean orbital radii R (sub n) (n = 0, 1,2,...) according as T (sub n) proportional to R (sub n) (exp -0.9). If the planet Mercury condenses at 1640 K, so accounting for the high density of that planet via a process of chemical fractionation between iron and silicates, then T (sub n) at Jupiter's orbit is 158 K. Only 35% of the water vapour condenses out. Thus fractionation between rock and ice, together with an enhancement in the abundance of solids relative to gas which takes place through gravitational sedimentation of solids onto the mean orbit of the gas ring, ensures nearly equal proportions of rock and ice in each of Ganymede and Callisto. Io and Europa condense above the H20 ice point and consist solely of hydrated rock (h-rock). The Ganymedan condensate consists of h-rock and H20 ice. For Callisto, NH3 ice makes up -5% of the condensate mass next to h-rock (approximately 50%) and H2O ice (approximately 45%). Detailed thermal and structural models for each of Europa, Ganymede and Callisto are constructed on the basis of the above initial bulk chemical compositions. For Europa (E), a predicted 2-zone model consisting of a dehydrated rock core of mass 0.912 M (sub E) and a 150 km thick frozen mantle of salty H2O yields a moment-of-inertia coefficient which matches the Galileo Orbiter gravity measurement. For Ganymede (G), a 3-zone model possessing an inner core of solid FeS and mass approximately 0.116 M (sub G), and an outer H2O ice mantle of mass approximately 0.502 M (sub G) is needed to explain the gravity data. Ganymede's native magnetic field was formed by thermoremanent magnetization of Fe3O4. A new Callisto (C) model is proposed consisting of a core of mass 0.826 M (sub C) containing a uniform mixture of h-rock (60% by mass) and H2O and NH3 ices, and capped by a mantle of pure ice. This model may have the capacity to yield a thin layer of liquid NH3 (raised dot) 2H2O at the core boundary, in line with Galileo's discovery of an induced magnetic field.
Among the more intriguing features observed by HST after the impacts of the fragments of Shoemaker-Levy 9 were rings, encircling several of the impact sites, that expanded radially at constant velocities of order 450-500 m/s. One credible suggestion has been that the rings are stratospheric manifestations of linear gravity waves seated in the troposphere (Ingersoll and Kanamori, 1995). In this scenario the waves are made visible by a condensible material of unknown composition. Based on simulations of the comet impact by Zahnle and Mac Low (1995), we suggest an alternative hypothesis, namely that the rings are nonlinear stratospheric gravity waves which break and entrain impact debris material in the breaking wave front. The computations produce just such a feature, with the nonlinear breaking wave front in the stratosphere propagating radially away from the impact site with the correct speed. The computed ring of material is located in an altitude region where the static stability profile has a local maximum and therefore forms a waveguide. Because entrained impact debris forms the ring feature in the model, a condensate of some unknown composition is not required in order to view the wave front. However, there is one severe problem with the computed nonlinear wave: in contrast to a linear wave, it slows down. The computed feature stops within 1000 seconds, while the observed feature lasted at least 10,000 seconds. Since the nonlinear breaking wave front is a natural product of our impact simulations, we are now investigating the conditions that will enable the breaking wave front to propagate further, in accord with the observations. The results of these computations will be presented.