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Results for “critical onset phenomena”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Electrostatic limits on charge selectivity in ultrahigh charge density polymer membranes

Ion-exchange membranes (IEMs) with ultrahigh charge densities offer the promise of enhanced ion transport for electrochemical technologies, yet the fundamental limits of this membrane design strategy are not yet understood. In this work, we present a systematic study of bis(1-vinyl-3-imidazolium) cross-linked polymer membranes with fixed charge contents ranging from 6 to 9 mol/L[dry polymer], synthesized to isolate the effects of charge density at constant membrane water content. While ionic conductivity increases monotonically with increasing charge density, a sharp decline in charge selectivity is observed for the most densely charged membranes, defying conventional expectations. Structural, thermal, and mechanical analyses reveal a critical onset of network disruption and anomalous ion partitioning behavior in these densely charged membranes. With proper consideration of cross-linker geometry, these results are interpreted using Manning's counter-ion condensation theory, which suggests that closely packed charged cross-linkers amplify inter-chain electrostatic interactions and trigger excess counter-ion condensation. Our findings suggest that, beyond a threshold spacing between fixed charges, increased functionalization may harm rather than help charge selectivity of IEMs.

36 MATERIALS SCIENCE↗
NASA NTRS2003

Cellular Instabilities and Self-Acceleration of Expanding Spherical Flames

In the present investigation we aim to provide experimental information on and thereby understanding of the generation and propagation of spark-ignited, outwardly propagating cellular flames, with three major focuses. The first is to unambiguously demonstrate the influence of the four most important parameters in inducing hydrodynamic and diffusional-thermal cellularities, namely thermal expansion, flame thickness, non-unity Lewis number, and global activation energy. The second is to investigate the critical state for the onset of cellularity for the stretch-affected, expanding flame. The third is to identify and consequently quantify the phenomena of self-acceleration and possibly auto-turbulization of cellular flames. Due to space limitation the effects of activation energy and the critical state for the onset of cellularity will not be discussed herein. Experiments were conducted using C3H8-air and H2-O2-N2 mixtures for their opposite influences of non-equidiffusivity. The additional system parameters varied were the chamber pressure (p) and the mixture composition including the equivalence ratio (phi). From a sequence of the flame images we can assess the propensity of cell formation, and determine the instantaneous flame radius (R), the flame propagation rate, the global stretch rate experienced by the flame, the critical flame radius at which cells start to grow, and the average cell size.

Law, C. K.↗
NASA NTRS1983

Influence of unbalance on the nonlinear dynamical response and stability of flexible rotor-bearing systems

In this paper, some of the effects of unbalance on the nonlinear response and stability of flexible rotor-bearing systems is presented from both a theoretical and experimental standpoint. In a linear system, operating above its stability threshold, the amplitude of motion grows exponentially with time and the orbits become unbounded. In an actual system, this is not necessarily the case. The actual amplitudes of motion may be bounded due to various nonlinear effects in the system. These nonlinear effects cause limit cycles of motion. Nonlinear effects are inherent in fluid film bearings and seals. Other contributors to nonlinear effects are shafts, couplings and foundations. In addition to affecting the threshold of stability, the nonlinear effects can cause jump phenomena to occur at not only the critical speeds, but also at stability onset or restabilization speeds.

Gunter, E. J.↗
DOE OSTI2025

Understanding (La,Sr)(Co,Fe)O$_{3-δ}$ Phase Instability within SOECs Using a Combined Experimental and Atomistic Modeling Approach

Understanding the onset of degradation in the air electrode within solid oxide electrolysis cells (SOECs), and the subsequent impact on cell performance, is a critical step in mitigating the performance losses and stability issues of SOECs. In an effort to identify early onset degradation phenomena, SOECs were characterized as fabricated and after testing potentiostatically at 1.3 V for 1000 h at 750 °C. SOEC air electrodes composed of a 1:1 composite of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3–δ (6428-LSCF) and Gd 0.1 Ce 0.9 O 1.95 (GDC) were studied using synchrotron X-ray diffraction (XRD), scanning transmission electron microscopy coupled with energy dispersive X-ray spectroscopy (STEM-EDS), and X-ray absorption near-edge spectroscopy (XANES) to evaluate the changes in the air electrode structurally and chemically. These techniques show the migration of Sr species from the air electrode through pores in the GDC barrier layer, progressing to the electrolyte boundary, where it accumulates and reacts with (Zr 0.84 Y 0.16 )O 2–δ (YSZ) to form SrZrO 3 . Microscopy results are paired with atomistic simulations to better understand the relationship between the thermodynamic instability of 6428-LSCF and cell fabrication/testing conditions. First-principles calculations reveal that LSCF-6428 is not stable during cell manufacturing and testing conditions, which supports the experimental identification of secondary phases in both as-fabricated and tested cells. Together, these results demonstrate that the challenging environments encountered by SOECs during cell manufacturing and operation lead to instabilities of the target 6428-LSCF anode material and underscore the need for more durable, high-performing SOEC components.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Quantum fluctuations lead to glassy electron dynamics in the good metal regime of electron doped KTaO 3

One of the central challenges in condensed matter physics is to comprehend systems that have strong disorder and strong interactions. In the strongly localized regime, their subtle competition leads to glassy electron dynamics which ceases to exist well before the insulator-to-metal transition is approached as a function of doping. Here, we report on the discovery of glassy electron dynamics deep inside the good metal regime of an electron-doped quantum paraelectric system: KTaO 3 . We reveal that upon excitation of electrons from defect states to the conduction band, the excess injected carriers in the conduction band relax in a stretched exponential manner with a large relaxation time, and the system evinces simple aging phenomena—a telltale sign of glassy dynamics. Most significantly, we observe a critical slowing down of carrier dynamics below 35 K, concomitant with the onset of quantum paraelectricity in the undoped KTaO 3 . Our combined investigation using second harmonic generation technique, density functional theory and phenomenological modeling demonstrates quantum fluctuation-stabilized soft polar modes as the impetus for the glassy behavior. This study addresses one of the most fundamental questions regarding the potential promotion of glassiness by quantum fluctuations and opens a route for exploring glassy dynamics of electrons in a well-delocalized regime.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1985

Pump instability phenomena generated by fluid forces

Rotor dynamic behavior of high energy centrifugal pumps is significantly affected by two types of fluid forces; one due to the hydraulic interaction of the impeller with the surrounding volute or diffuser and the other due to the effect of the wear rings. The available data on these forces is first reviewed. A simple one degree-of-freedom system containing these forces is analytically solved to exhibit the rotor dynamic effects. To illustrate the relative magnitude of these phenomena, an example of a multistage boiler feed pump is worked out. It is shown that the wear ring effects tend to suppress critical speed and postpone instability onset. But the volute-impeller forces tend to lower the critical speed and the instability onset speed. However, for typical boiler feed pumps under normal running clearances, the wear ring effects are much more significant than the destabilizing hydraulic interaction effects.

Gopalakrishnan, S.↗
NASA NTRS1989

Numerical modeling of enclosure convection

A numerical study on the steady and unsteady natural convection in two-dimensional rectangular enclosures has been performed by a time-accurate ADI finite difference scheme. The study covered a range of Rayleigh numbers between 1000 and 10 to the 7th, aspect ratios between 0.2 and 10.0, and tilt angles between -90 (heating from bottom) and +90 deg (heating from top). Various Prandtl numbers have been studied, but only the results of water (Pr = 7.0) are reported here due to space limitations. The physics revealed, however, includes the convection phenomena and the Rayleigh-Benard stability, as well as the combined mechanism of these two. The onset of secondary cells is determined by using a velocity map, which is simpler and cleaner, instead of a streamline plot. The critical Ra number for the occurrence of these secondary cells is shown to be lower than can be detected by experimental studies. On the Rayleigh-Benard stability part, a second transition from stable single-cell convection to periodic multicellular convection is disclosed.

Duh, J. C.↗
NASA NTRS1978

Cryogenic-coolant He-4-superconductor interaction

The thermodynamic and thermal interaction between a type 2 composite alloy and cryo-coolant He4 was studied with emphasis on post quench phenomena of formvar coated conductors. The latter were investigated using a heater simulation technique. Overall heat transfer coefficients were evaluated for the quench onset point. Heat flux densities were determined for phenomena of thermal switching between a peak and a recovery value. The study covered near saturated liquid, pressurized He4, both above and below the lambda transition, and above and below the thermodynamic critical pressure. In addition, friction coefficients for relative motion between formvar insulated conductors were determined.

Caspi, S.↗
NASA NTRS1984

The vertical structure and stability of alpha model accretion disks

In order to understand the physical processes that determine the time-dependent characteristics of accretion disks, a parameter investigation is conducted of the vertically explicit structure corresponding to steady state, alpha-model thin disk accretion for accreting objects of 1 solar mass. Attention is given to the role of convection in the vertical structure and the location of critical points representing the onset of thermal instability, as well as optically thin conditions. It is shown that the temperature in quiescence is likely to be low for most of the matter, and scaling laws are presented for the fundamental properties of the vertically explicit models from which the time scales for various idealized phenomena are derived. The ordering of three disk time scales obtained should allow discrimination among different models.

Cannizzo, J. K.↗
DOE OSTI2020

Ferroelectricity in Si-Doped Hafnia: Probing Challenges in Absence of Screening Charges

The ability to develop ferroelectric materials using binary oxides is critical to enable novel low-power, high-density non-volatile memory and fast switching logic. The discovery of ferroelectricity in hafnia-based thin films, has focused the hopes of the community on this class of materials to overcome the existing problems of perovskite-based integrated ferroelectrics. However, both the control of ferroelectricity in doped-HfO2 and the direct characterization at the nanoscale of ferroelectric phenomena, are increasingly difficult to achieve. The main limitations are imposed by the inherent intertwining of ferroelectric and dielectric properties, the role of strain, interfaces and electric field-mediated phase, and polarization changes. In this work, using Si-doped HfO2 as a material system, we performed a correlative study with four scanning probe techniques for the local sensing of intrinsic ferroelectricity on the oxide surface. Putting each technique in perspective, we demonstrated that different origins of spatially resolved contrast can be obtained, thus highlighting possible crosstalk not originated by a genuine ferroelectric response. By leveraging the strength of each method, we showed how intrinsic processes in ultrathin dielectrics, i.e., electronic leakage, existence and generation of energy states, charge trapping (de-trapping) phenomena, and electrochemical effects, can influence the sensed response. We then proceeded to initiate hysteresis loops by means of tip-induced spectroscopic cycling (i.e., “wake-up”), thus observing the onset of oxide degradation processes associated with this step. Finally, direct piezoelectric effects were studied using the high pressure resulting from the probe’s confinement, noticing the absence of a net time-invariant piezo-generated charge. Our results are critical in providing a general framework of interpretation for multiple nanoscale processes impacting ferroelectricity in doped-hafnia and strategies for sensing it.

36 MATERIALS SCIENCE↗
NASA NTRS1996

Study of Critical Heat Flux and Two-Phase Pressure Drop Under Reduced Gravity

The design of the two-phase flow systems which are anticipated to be utilized in future spacecraft thermal management systems requires a knowledge of two-phase flow and heat transfer phenomena in reduced gravities. This program was funded by NASA headquarters in response to NRA-91-OSSA-17 and was managed by Lewis Research Center. The main objective of this program was to design and construct a two-phase test loop, and perform a series of normal gravity and aircraft trajectory experiments to study the effect of gravity on the Critical Heat Flux (CHF) and onset of instability. The test loop was packaged on two aircraft racks and was also instrumented to generate data for two-phase pressure drop. The normal gravity tests were performed with vertical up and downflow configurations to bound the effect of gravity on the test parameters. One set of aircraft trajectory tests was performed aboard the NASA DC-9 aircraft. These tests were mainly intended to evaluate the test loop and its operational performance under actual reduced gravity conditions, and to produce preliminary data for the test parameters. The test results were used to demonstrate the applicability of the normal gravity models for prediction of the two-phase friction pressure drop. It was shown that the two-phase friction multipliers for vertical upflow and reduced gravity conditions can be successfully predicted by the appropriate normal gravity models. Limited critical heat flux data showed that the measured CHF under reduced gravities are of the same order of magnitude as the test results with vertical upflow configuration. A simplified correlation was only successful in predicting the measured CHF for low flow rates. Instability tests with vertical upflow showed that flow becomes unstable and critical heat flux occurs at smaller powers when a parallel flow path exists. However, downflow tests and a single reduced gravity instability experiment indicated that the system actually became more stable with a parallel single-phase flow path. Several design modifications have been identified which will improve the system performance for generating reduced gravity data. The modified test loop can provide two-phase flow data for a range of operating conditions and can serve as a test bed for component evaluation.

Abdollahian, Davood↗
NASA NTRS1978

Onset phenomena in self-field MPD arcjets

Voltage fluctuations in a multi-megawatt quasi-steady MPD accelerator, indicative of increased ablation and a consequent degradation in performance, are found to exist only over a narrow range of currents, above which the ablation continues. Within this range, the discharge is characterized by a thin cylindrical shell, 4.0 cm in diameter, concentric with the cathode surface, containing steep radial gradients in plasma luminosity, number density, current density, electric field and Hall parameter, and within which a significant fraction of the propellant is first ionized. Experiments have shown that this cylindrical shell can be totally eliminated by immersing a small object at critical locations within it, thereby increasing the local mass density by preferential ablation and suggesting further means of improving the accelerator design.

Rudolph, L. K.↗
DOE OSTI2025

Ferroelectric phase transition in group-IV monochalcogenides from an equivariant machine learned force field

Group-IV monochalcogenides are a class of layered ferroelectric semiconductors that have demonstrated spontaneous intrinsic polarization above room temperature. Here, in this study, we use the multi-atomic cluster expansion (MACE) machine learning architecture to train and test a force field capable of modeling the structural properties and second-order ferroelectric-to-paraelectric phase transition in a Group-IV monochalcogenide, GeSe. The model captures the double-well potential energy surface associated with the onset of macroscopic polarization in bulk GeSe within 12.5 meV/atom, as well as near-equilibrium properties like the phonon dispersion. The development of this quantitatively accurate force field enables long-time molecular dynamics simulations, which predict the critical temperature of the ferroelectric-to-paraelectric phase transition in bulk GeSe to be T c = 600 K. This study demonstrates the capabilities of equivariant force-fields to accurately describe phenomena associated with structural symmetry breaking.

ferroelectricity↗
NASA NTRS1972

Slow and fast motion of cracks in inelastic solids. Part 1: Slow growth of cracks in a rate sensitive tresca solid. Part 2: Dynamic crack represented by the Dugdale model

An extension is proposed of the classical theory of fracture to viscoelastic and elastic-plastic materials in which the plasticity effects are confined to a narrow band encompassing the crack front. It is suggested that the Griffith-Irwin criterion of fracture, which requires that the energy release rate computed for a given boundary value problem equals the critical threshold, ought to be replaced by a differential equation governing the slow growth of a crack prior to the onset of rapid propagation. A new term which enters the equation of motion in the dissipative media is proportional to the energy lost within the end sections of the crack, and thus reflects the extent of inelastic behavior of a solid. A concept of apparent surface energy is introduced to account for the geometry dependent and the rate dependent phenomena which influence toughness of an inelastic solid. Three hypotheses regarding the condition for fracture in the subcritical range of load are compared. These are: (1) constant fracture energy (Cherepanov), (2) constant opening displacement at instability (Morozov) and (3) final stretch criterion (Wnuk).

Wnuk, M. P.↗
NASA NTRS1973

Slow growth of cracks in a rate sensitive Tresca solid.

Extension of the classical theory of fracture to viscoelastic and elastic-plastic materials in which the plasticity effects are confined to a narrow band encompassing the crack front. It is suggested that the Griffith-Irwin criterion of fracture, which requires that the energy release rate computed for a given boundary value problem equal the critical threshold, ought to be replaced by a differential equation governing the slow growth of a crack prior to the onset of rapid propagation. A new term which enters the equation of motion in the dissipative media is proportional to the energy lost within the end sections of the crack, and thus it reflects the extent of inelastic behavior of a solid. A concept of 'apparent' surface energy is introduced to account for the geometry-dependent and the rate-dependent phenomena which influence toughness of an inelastic solid. Three hypotheses regarding the condition for fracture in the subcritical range of load are compared.

Wnuk, M. P.↗
NASA NTRS1994

Study of two-phase flow and heat transfer in reduced gravities

Design of the two-phase systems which are anticipated to be utilized in future spacecraft thermal management systems requires a knowledge of two-phase flow and heat transfer parameters in reduced gravities. A program has been initiated by NASA to design a two-phase test loop and perform a series of experiments to generate the data for the Critical Heat Flux (CHF) and onset of instability under reduced gravities. In addition to low gravity airplane trajectory testing, the experimental program consists of a set of laboratory tests with vertical upflow and downflow configurations. Modularity is considered in the design of this experiment and the test loop in instrumented to provide data for two-phase pressure drop and flow regime behavior. Since the program is in the final stages of the design and construction task, this article is intended to discuss the phenomena, design approach, and the description of the test loop.

Abdollahian, Davood↗
DOE OSTI2025

Nonideal stability analysis of differentially rotating plasmas with global curvature effects

The linear stability of global nonaxisymmetric modes in differentially rotating, magnetized, nonideal plasma is critical to classifying turbulence and transport phenomena. We investigate the competition between the local magneto-rotational instability (MRI) and the magneto-curvature instability (MCI)—a distinct nonaxisymmetric low-frequency curvature-driven global branch that appears alongside MRI. Here, to accomplish this, we developed a nonideal global spectral method, which is validated against NIMROD code simulations. This spectral approach allows for the direct derivation of an extended effective potential formalism and a resistive Alfvénic resonance condition, providing a framework for direct analysis of energy contributions and confinement mechanisms. Our study reveals that the global, low-frequency MCI persists at low magnetic Reynolds numbers (Rm), whereas the localized, high-frequency MRI is stabilized by diffusive broadening of its structure around its Alfvénic resonances. Consequently, we identify the global MCI branch as the primary onset mechanism for nonaxisymmetric magnetohydrodynamic instability in systems with finite curvature, e.g., astrophysical rotators. We establish distinct parameter regimes for mode dominance: MCI prevails in geometrically moderate-thickness disks with intermediate curvature and radial gaps, while MRI dominates in thin, low-curvature disks with large radial gaps. Mode competition is also highly sensitive to the flow profile, particularly vorticity and its gradient, with nonuniform shear profiles exhibiting more robust instability due to flow curvature (i.e., the second derivative of the flow profile) and shear contributions. A key outcome is the development of spectral diagrams derived from the global spectral method. These diagrams comprehensively map dominant instabilities and their characteristics, offering a predictive tool for critical onset parameters (i.e., flow curvature, magnetic field, and Rm) and facilitating the interpretation of experimental and simulation results. Notably, these diagrams demonstrate that the global MCI is generally the sole unstable mode at the initial onset of nonaxisymmetric instability.

Haywood, Alexander [Princeton Univ., NJ (United St↗
DOE OSTI2024

Static magnetic order with strong quantum fluctuations in spin-1/2 honeycomb magnet Na 2 Co 2 TeO 6

Kitaev interactions, arising from the interplay of frustration and bond anisotropy, can lead to strong quantum fluctuations and, in an ideal case, to a quantum-spin-liquid state. However, in many nonideal materials, spurious non-Kitaev interactions typically promote a zigzag antiferromagnetic order in the d-orbital transition-metal compounds. Here, by combining neutron scattering with muon-spin rotation and relaxation techniques, we provide mechanism insights into the exotic properties of Na 2 Co 2 TeO 6 , a candidate material of the Kitaev model. Below T N , the zero-field muon-spin relaxation rate becomes almost constant (~0.45 μs –1 ). We attribute this temperature-independent relaxation rate to the strong quantum fluctuations, as well as to the frustrated Kitaev interactions. As the magnetic field increases, neutron scattering data indicate a broader spin-wave excitation at the K-point. Therefore, quantum fluctuations seem not only robust but are even enhanced by the applied magnetic field. Our findings provide valuable hints for understanding the onset of the quantum-spin-liquid state in Kitaev materials.

36 MATERIALS SCIENCE↗