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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

The color of polarization in cuprate superconductors

A technique for the identification of individual anisotropic grains in a heterogeneous and opaque material involves the observation of grain color in reflected light through crossed polarizers (color of polarization). Such colors are generally characteristic of particular phases. When grains of many members of the class of hole carrier cuprate superconductors are so viewed, using a xenon light source (600 K color temperature), a characteristic color of polarization is observed. This color was studied in many of these cuprate superconductors and a strong correlation was found between color and the existence of superconductivity. One of the members of the electron carrier cuprate superconductors (Nd(1.85)Ce(.15)CuO(4-x) was examined and found that it possesses the same color of polarization as all the electron hole carrier cuprate superconductors so far examined. The commonality of the characteristic color in the cuprate superconductors indicated that the presence of this color is independent of the nature of charge carriers. The correlation of this color with existence of superconductivity suggests that the origin of the color relates to the origin of superconductivity in the cuprate superconductors. Photometric techniques are also discussed.

Hoff, H. A.↗
NASA NTRS1991

The color of polarization in cuprate superconductors

A technique for the identification of individual anisotropic grains in a heterogeneous and opaque material involves the observation of grain color in reflected light through crossed polarizers (color of polarization). Such colors are generally characteristic of particular phases. When grains of many members of the class of hole carrier cuprate superconductors are so viewed at room temperature with a 'daylight' source, a characteristic color of polarization is observed. This color was studied in many of these cuprate superconductors and a strong correlation was found between color and the existence of superconductivity. Two members were also examined of the electron cuprate superconductors and it was found that they possess the same color of polarization as the hole carrier cuprate superconductors so far examined. The commonality of the characteristic color regardless of charge carrier indicates that the presence of this color is independent of carrier type. The correlation of this color with the existence of superconductivity in the cuprate superconductors suggests that the origin of the color relates to the origin of superconductivity. Photometric techniques are also discussed.

Hoff, H. A.↗
NASA NTRS1990

Preparation and characteristics of superconducting cuprate thin films: Nd(2-x)Ce(x)CuO4 and substituted Bi-system

Characteristics of the electron-doped-type Nd(2-x)Ce(x)CuO4 systems and substituted Bi2(Sr,Ln)3Cu2Oy system were systematically studied using the high quality thin-film samples. The Nd(2-x)Ce(x)CuO4 thin films with various Ce concentrations, x, were prepared by RF magnetron sputtering on SrTiO3 heated at around 500 C. After subsequent annealing at 1100 C in air, the films showed the c-axis orientation normal to the substrates. By means of the reducing treatment (annealing in a vacuum), superconductivity was induced for the films with 0.14 is less than or equal to x is less than or equal to 0.18. The superconductivity and transport properties of the films were strongly affected by the reducing treatment. The x = 0.15 film exhibited a sharp superconducting transition with zero resistivity at 22 K, in consistent with the diamagnetic properties. The resistivity of the films was fairly low with metallic characteristics, and the sight of the Hall coefficient was negative in the normal state. On the other hand, the normal-state optical measurements showed that the undoped Nd2CuO4 is a semiconductor with a charge transfer gap of 1.3 eV, and that, when Ce ions were doped, a plasma reflection due to the free-carriers came to be seen with the plasma frequency of 1.07 eV for 0.14 is less than or equal to x is less than or equal to 0.18. Moreover, x ray photoemission study revealed that the Cu valence of the film decreased for 2(+) for x = 0 to 1(+) for x = 0.15. These physical properties are in contrast with those of hole-doped-type cuprate superconductors. Bi2(Sr,Ln)3Cu2Oy thin films were also prepared on MgO substrates heated at 600 to 700 C by similar methods. It was found that the growth conditions for Bi-systems with two CuO2 planes were different for each composition and species of lanthanoid in the films. Moreover, preparation of Bi-system with three CuO2 planes was very difficult when lanthanoid atoms were doped in the system. Their electric transport properties and x ray photoemission spectroscopy were investigated. Carrier concentration and Cu valence were discussed with regard to the superconductivity.

Adachi, H.↗
NASA NTRS1990

Stabilization of high T(sub c) phase in bismuth cuprate superconductor by lead doping

It has widely been ascertained that doping of lead in Bi:Sr:Ca:Cu:O systems promotes the growth of high T(sub c) (110 K) phase, improves critical current density, and lowers processing temperature. A systematic investigation is undertaken to determine optimum lead content and processing conditions to achieve these. A large number of samples with cationic compositions of Bi(2-x)Pb(x)Sr2Ca2Cu3 (x = 0.2 to 2.0) were prepared by conventional solid state reaction technique. Samples of all compositions were annealed together at a temperature and characterized through resistance-temperature (R-T) measurements and x ray diffraction (XRD) to determine the zero resistance temperature, T(sub c)(0) and to identify presence of phases, respectively. The annealing temperature was varied between 790 C to optimize processing parameters. Results are given. In brief, an optimum process is reported along with composition of leaded bismuth cuprate superconductor which yields nearly a high T(sub c) single phase with highly stable superconducting properties.

Gupta, Ram. P.↗
NASA NTRS1991

Inhomogeneities in single crystals of cuprate oxide superconductors

The next stage in the evolution of experimental research on the high temperature superconductors will require high quality single crystals and epitaxially grown crystalline films. However, inhomogeneities and other defects are not uncommon in single crystals of cuprate oxide superconductors, so a corollary requirement will be a reliable method for judging the quality of these materials. The application of magnetically modulated resistance methods in this task is briefly described and illustrated.

Moorjani, K.↗
NASA NTRS1991

Stabilization of high Tc phase in bismuth cuprate superconductor by lead doping

It has been widely ascertained that doping of lead in Bi-Sr-Ca-Cu-O systems promotes the growth of high T sub c (110 K) phase, improves critical current density, and lowers processing temperature. A systematic study was undertaken to determine optimum lead content and processing conditions to achieve these properties. A large number of samples with cationic compositions of Bi(2-x)Pb(x)Sr2Ca2Cu3 (x = 0.2 to 2.0) were prepared by conventional solid state reaction technique. Samples of all compositions were annealed together at a temperature and characterized through resistance temperature (R-T) measurements and x ray diffraction to determine the zero resistance temperature, T sub c(0) and to identify presence of phases, respectively. The annealing temperature was varied between 790 and 880 C to optimize processing parameters. Results are given. In brief, an optimum process is reported along with composition of leaded bismuth cuprate superconductor which yields nearly a high T sub c single phase with highly stable superconducting properties.

Gupta, Ram. P.↗
NASA NTRS1991

The electronic Hamiltonian for cuprates

A realistic many-body Hamiltonian for the cuprate superconductors should include both copper d and oxygen p states, hopping matrix elements between them, and Coulomb energies, both on-site and inter-site. We have developed a novel computational scheme for deriving the relevant parameters ab initio from a constrained occupation local density functional. The scheme includes numerical calculation of appropriate Wannier functions for the copper and oxygen states. Explicit parameter values are given for La2CuO4. These parameters are generally consistent with other estimates and with the observed superexchange energy. Secondly, we address whether this complicated multi-band Hamiltonian can be reduced to a simpler one with fewer basis states per unit cell. We propose a mapping onto a new two-band effective Hamiltonian with one copper d and one oxygen p derived state per unit cell. This mapping takes into account the large oxygen-oxygen hopping given by the ab initio calculations.

Annett, James F.↗
NASA NTRS1988

Potassium cuprate (3)

The reaction of KO2 and CuO in an O2 atmosphere at 400 to 450 C results in KCuO, which is a steel-blue and nonmagnetic compound. This substance exhibits a characteristic X-ray diagram; it decomposes in dilute acids to form O2 and Cu(II) salts. It decomposes thermally above 500 C.

Wahl, Kurt↗
NASA NTRS1988

High-temperature processing of cuprate oxide superconductors

Superconducting Y1Ba2Cu3O7 ('123') films were fabricated on the Y2BaCuO5 ('211') phase substrate. The superconducting characteristics of these films, in terms of superconducting transition temperature (Tc) and width, are better than those using other oxide compounds as substrates. In addition, using high-temperature processing, the bulk 211 phase was converted into the 123 phase. A new high Tc copper oxide material with non-rare-earth elements (Bi-Sr-Cu-O) was prepared using similar high-temperature processing. High-temperature processing presents an alternative synthetic route in the search of new high Tc superconductors.

Wu, M. K.↗
NASA NTRS1991

Preparation and characteristics of superconducting cuprate thin films: Nd(2-x)Ce(x)CuO4 and substrated Bi-system

Characteristics of the electron-doped-type Nd(sub 2-x)Ce(sub x)CuO4 system and substituted Bi-system were studied using the high quality thin film samples grown by rf magnetron sputtering and/or subsequent heat treatment. The Nd(sub 2-x)Ce(sub x)CuO4 samples with excellent superconducting properties were obtained in thin films and their optical and X-ray photoelectron spectroscopy (XPS) studies were performed with regard to the Ce content and reducing treatment. Substituted BiSr-Ln-Cu-O thin films were prepared and growth conditions for Bi-system with 2-2-1-2 and 2-2-2-2 phases were found. Moreover, a new 2-2-1-2 phase in the simple Bi-Sr-Cu-O system was fabricated by thin film processing and 80 K superconductivity was obtained.

Adachi, H.↗
NASA NTRS1990

The superconducting state of the high-transition temperature superconductors: Experimental basis

Experiments on the high-T(sub c) cuprate superconductors continue to narrow the possible theoretical explanations of the phenomenon. Experimental evidence to date points to a BCS-like state, with pairs in singlet s-states, the familiar gap in the excitation spectrum, type 2 behavior in a magnetic field and a normal state with fermi liquid origins. Several other features of the superconducting state in the cuprates, however, appear to differ from those of conventional alloy superconductors (these relate to the detailed structure of the gap and to the nature of the coupling mechanism). Recent experiments have helped clarify what these differences are, and together with the earlier experiments, they now impose still stronger constraints on theories of these superconductors. These and other developments will be reviewed.

Little, W. A.↗