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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Environmental Controls on Water Vapor Deuterium Excess in the Coastal Boundary Layer: An Information Theory Perspective

We use information theory to quantify the environmental controls on water vapor deuterium excess (D-excess) in coastal Southern California from June 2023 through February 2024. Using Shannon entropy, mutual information (MI), and joint mutual information, metrics that capture both linear and nonlinear relationships, we identify the most informative variables and variable combinations governing D-excess across contrasting marine and continental regimes. Relative humidity with respect to sea surface temperature (RHS) is consistently the strongest individual predictor, explaining up to 27% of D-excess variability during marine conditions but only 10% in continental air masses. The Relative humidity(RHS) + sea surface temperature (SST) combination demonstrates synergistic effects, where their joint influence (explaining up to 36% of D-excess variability) exceeds what either variable achieves individually, confirming their coupled influence on deuterium excess. Wind direction complements RHS most effectively during continental conditions. The best three-variable combination (RHS + SST + Planetary Boundary Layer height) explains 38% of D-excess variability in marine air, while no combination exceeds 20% explanatory power during continental periods. Information theory shows that heteroscedasticity in D-excess relationships indicates regime shifts in controlling processes and quantifies fundamental constraints on predictor variables: some environmental factors like surface pressure or water vapor flux contain insufficient information content to explain D-excess variability regardless of their physical relevance. These results highlight the different predictability limits between marine and continental regimes, challenging the adequacy of linear models and providing a rigorous framework for quantifying the information content of isotope-climate relationships with implications for both modern and paleoclimate applications.

information theory↗
DOE OSTI2021

Comparing deuterium excess to large-scale precipitation recycling models in the tropics

Precipitation recycling is essential to sustaining regional ecosystems and water supplies, and it is impacted by land development and climate change. This is especially true in the tropics, where dense vegetation greatly influences recycling. Unfortunately, large-scale models of recycling often exhibit high uncertainty, complicating efforts to estimate recycling. Here, we examine how deuterium excess (d-excess), a stable-isotope quantity sensitive to recycling effects, acts as an observational proxy for recycling. While past studies have connected variability in d-excess to precipitation origins at local or regional scales, our study leverages >3000 precipitation isotope samples to quantitatively compare d-excess against three contemporary recycling models across the global tropics. Using rank-correlation, we find statistically significant agreement ( $\bar \tau = 0.52$ τ ¯ = 0.52 to $0.70$ 0.70 ) between tropical d-excess and recycling that is strongly mediated by seasonal precipitation, vegetation density, and scale mismatch. Our results detail the complex relationship between d-excess and precipitation recycling, suggesting avenues for further investigation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater dependent ecosystems in areas with industrial and military land use are at risk of direct exposure to a wide range of contaminants, including PFAS chemicals. Glaciated terrain often has mixed high and low permeability sediments coupled with groundwater flow-through lake features. These hydrogeologic attributes create highly complex ‘source to seep’ dynamics that make spatiotemporal contaminant transport patterns difficult to predict. We investigated one such system in detail using a suite of heat-tracing and chemical methods. Numerous (n=57) preferential groundwater discharge zones (vertical flux rates ranging 0.2 to 3.2 m/d) were identified across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, adjacent to an Air Force Base with several known PFAS source areas. Surface-water and groundwater samples were collected and analyzed (n=145) for precursors and terminal PFAS compounds between March and September 2022. Samples were collected at identified seeps along the Quashnet River (n=59), from wells upgradient from the stream-wetland system (n= 44), from contributing flow-through kettle lakes (n=8), and at multiple locations along the Quashnet River (n=34). Samples from seeps and wells had measured PFAS concentrations ranging from non-detect to approximate 3,500 ng/L (mean= 1,650 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to emergence at the discharge zones. Groundwater-lake interaction along flowpaths that sourced the sampled seeps was farther supported by significant correlations (p < 0.01) between deuterium excess and %PFAS precursors, and between %PFAS precursors and multiple terminal PFAS compounds (e.g., PFPeS, PFBS, PFHxS). However, some sampled seeps contributing groundwater to the stream-wetland system had much higher total PFAS concentrations (>1000 ng/L) than the upgradient kettle lakes, despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. PFAS compounds and water isotopic composition at sampled multilevel groundwater wells, rivers, lakes, and seeps suggest that a complex mixture of source groundwater and flowpath characteristics are responsible for diverse observed PFAS mixtures at preferential discharge zones across the stream-wetland system. Further, total PFAS loading patterns to the Quashnet River via groundwater discharge remained remarkably similar from winter to summer to fall conditions, despite a regional dry period in late summer 2022 with the upper river channel completely drying. This work addresses gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations in controlling contaminant mass loading in preferential groundwater discharge zones and presents a transferrable field toolkit for efficient characterization of spatially preferential PFAS transport dynamics.

Contaminant transport↗
DOE OSTI2026

A New Theoretical Framework for Parameterizing Nonequilibrium Fractionation During Evaporation From the Ocean

The evaporation model for water isotopes proposed by Craig and Gordon (1965, https://books.google.co.in/books?id=6wIKAQAAIAAJ) is used in most isotope-enabled atmospheric models for the parameterization of nonequilibrium fractionation during evaporation from the ocean. In this model, one of the most uncertain parameters is the nonequilibrium fractionation factor 𝛼 𝑘 . Many isotope models use the formulation of Merlivat and Jouzel (1979, https://doi.org/10.1029/jc084ic08p05029), which parameterizes 𝛼 𝑘 as a function of wind speed and distinguishes between a smooth and a rough regime to account for the effect of ocean waves. The resulting discontinuity in 𝛼 𝑘 between smooth and rough regimes has been disputed by several empirical studies. Here, we present a new approach to parameterizing 𝛼𝑘 by explicitly accounting for the influence of wave drag on the momentum flux near the surface. Following Cifuentes-Lorenzen et al. (2018, https://doi.org/10.1007/s10546-018-0376-0), we add a third wave-induced component to the total momentum flux, in addition to the viscous and turbulent components, and extend the definition of the eddy viscosity to account for the momentum flux due to waves and turbulent dissipation near the surface. The new scheme predicts a slight decrease of 𝛼 𝑘 with wind speed, similar to the smooth-regime parameterization of Merlivat and Jouzel (1979, https://doi.org/10.1029/jc084ic08p05029). This new parameterization is incorporated into the isotope-enabled Community Atmosphere Model, where it improves the correlation of simulated and measured vapor deuterium excess relative to the default version and a version with constant 𝛼 𝑘 , suggesting that it may be used as a valid representation of fractionation during evaporation from the ocean in future isotope models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Stream water sourcing from high-elevation snowpack inferred from stable isotopes of water: a novel application of d-excess values

About 80 % of the precipitation at the Colorado River's headwaters is snow, and the resulting snowmelt-driven hydrograph is a crucial water source for about 40 million people. Snowmelt from alpine and subalpine snowpack contributes substantially to groundwater recharge and river flow. However, the dynamics of snowmelt progression are not well understood because observations of the high-elevation snowpack are difficult due to challenging access in complex mountainous terrain as well as the cost and labor intensity of currently available methods. We present a novel approach to infer the processes and dynamics of high-elevation snowmelt contributions predicated upon stable hydrogen and oxygen isotope ratios observed in streamflow. We show that deuterium-excess (d-excess) values of stream water could serve as a comparatively cost-effective proxy for a catchment-integrated signal of high-elevation snowmelt contributions to catchment runoff. We sampled stable hydrogen and oxygen isotope ratios of the precipitation, snowpack, and stream water in the East River, a headwater catchment of the Colorado River, and the stream water of larger catchments at sites on the Gunnison River and Colorado River. The d-excess of snowpack increased with elevation; the upper subalpine and alpine snowpack (> 3200 m) had substantially higher d-excess compared to lower elevations (< 3200 m) in the study area. The d-excess values of stream water reflected this because d-excess values increased as the higher-elevation snowpack contributed more to stream water generation later in the snowmelt/runoff season. End-member mixing analyses based on the d-excess data showed that the share of high-elevation snowmelt contributions within the snowmelt hydrograph was on average 44 % and generally increased during melt period progression, up to 70 %. The observed pattern was consistent during 6 years for the East River, and a similar relation was found for the larger catchments on the Gunnison and Colorado rivers. High-elevation snowpack contributions were found to be higher for years with lower snowpack and warmer spring temperatures. Thus, we conclude that the d-excess of stream water is a viable proxy to observe changes in high-elevation snowmelt contributions in catchments at various scales. Inter-catchment comparisons and temporal trends of the d-excess of stream water could therefore serve as a catchment-integrated measure to monitor if mountain systems rely on high-elevation water inputs more during snow drought compared to years of average snowpack depths.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Deep desert aquifers as an archive for Mid- to Late Pleistocene hydroclimate: An example from the southeastern Mediterranean

Many efforts have been made to illuminate the nature of past hydroclimates in semi-arid and arid regions, where current and future shifts in water availability have enormous consequences on human subsistence. Deep desert aquifers, where groundwater is stored for prolonged periods, might serve as a direct record of major paleo-recharge events. To date, groundwater-based paleoclimate reconstructions have mainly focused on a relatively narrow timescale (up to ∼40 kyr), limited by the relatively short half-life of the widely used radiocarbon (5.73 kyr). Here we demonstrate the usage of deep regional aquifers in the arid southeastern Mediterranean as a hydroclimate archive for earlier Mid-to-Late Pleistocene epochs. State-of-the-art dating tools, primarily the 81 Kr radioisotope (t 1/2 = 229 kyr), were combined with other atmosphere-derived tracers to illuminate the impact of four distinguishable wetter episodes over the past 400 kyr, with differences in climatic conditions and paleo-recharge locations. Variations in stable water isotope composition suggest moisture transport from more proximal (Mediterranean) and distal (Atlantic) sources to different parts of the region at distinct times. Large variability in the computed noble gas-based recharge temperature (NGT), ranging ~15–30 °C, cannot be explained by climate variations solely, and points to different recharge pathways, including geothermal heating in the deep unsaturated zone and recharge from high-elevation (colder) regions. The obtained groundwater record complements and enhances the interpretation of other terrestrial archives in the arid region, including a contribution of valuable information regarding the moisture source origin as reflected in the deuterium-excess values, which is unattainable from the common practice analysis of calcitic cave deposits. We conclude that similar applications in other deep (hundred-m-order) regional groundwater systems (e.g., the Sahara desert aquifers) can significantly advance our understanding of long-term (up to 1 Myr) paleo-hydroclimate in arid regions, including places where no terrestrial remnants, such as cave, lake, and spring sediments, are available.

Atom Trap Trace Analysis↗
DOE OSTI2026

Water Vapor Isotopic Measurements during CAPE-K Field Campaign Report

CAPE-K_ISO deployed a Picarro L-2130 water vapor isotope analyzer to the Kennaook/Cape Grim Baseline Air Pollution Station in northwest Tasmania as a guest instrument within the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility’s Cloud and Precipitation Experiment at Kennaook (CAPE-K). The project was led by Joseph Galewsky at the University of New Mexico and supported the second ARM Mobile Facility (AMF2) deployment by adding continuous measurements of water vapor mixing ratio, delta-18O, delta-D, and deuterium excess in marine boundary-layer air.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

CAPE-K_ISO: Water vapor isotopic measurements from Western Tasmania

This dataset provides processed 1-minute water vapor isotope observations from the Water Vapor Isotopic Measurements During CAPE-K project at the Kennaook/Cape Grim Baseline Air Pollution Station in northwestern Tasmania. Measurements were made with a Picarro L-2130 cavity ring-down spectroscopy analyzer during the CAPE-K deployment. The dataset includes water vapor mixing ratio, d18O, dD, deuterium excess, and propagated 1-sigma uncertainties. Isotope ratios are calibrated to the VSMOW/SLAP scale. Calibration intervals, transition periods, and obvious isotope outliers have been removed. The processed record spans 11 June 2024 to 15 October 2025 and is intended for studies of Southern Ocean marine boundary-layer moisture, isotope variability, air-sea exchange, and cloud and precipitation processes.

Water Vapor Isotopic Composition↗
DOE OSTI2023

Methane, ethane, and propane production in Greenland ice core samples and a first isotopic characterization of excess methane

Air trapped in polar ice provides unique records of the past atmospheric composition ranging from key greenhouse gases such as methane (CH 4 ) to short-lived trace gases like ethane (C 2 H 6 ) and propane (C 3 H 8 ). Recently, the comparison of CH 4 records obtained using different extraction methods revealed disagreements in the CH 4 concentration for the last glacial in Greenland ice. Elevated methane levels were detected in dust-rich ice core sections measured discretely, pointing to a process sensitive to the melt extraction technique. To shed light on the underlying mechanism, we performed targeted experiments and analyzed samples for methane and the short-chain alkanes ethane and propane covering the time interval from 12 to 42 kyr. Here, we report our findings of these elevated alkane concentrations, which scale linearly with the amount of mineral dust within the ice samples. The alkane production happens during the melt extraction step of the classic wet-extraction technique and reaches 14 to 91 ppb of CH 4 excess in dusty ice samples. We document for the first time a co-production of excess methane, ethane, and propane, with the observed concentrations for ethane and propane exceeding their past atmospheric background at least by a factor of 10. Independent of the produced amounts, excess alkanes were produced in a fixed molar ratio of approximately 14 : 2 : 1, indicating a shared origin. The measured carbon isotopic signature of excess methane is (-47.0 ± 2.9) ‰ and its deuterium isotopic signature is (-326 ± 57) ‰. With the co-production ratios of excess alkanes and the isotopic composition of excess methane we established a fingerprint that allows us to constrain potential formation processes. This fingerprint is not in line with a microbial origin. Moreover, an adsorption–desorption process of thermogenic gas on dust particles transported to Greenland does not appear very likely. Instead, the alkane pattern appears to be indicative of abiotic decomposition of organic matter as found in soils and plant leaves.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Mechanism for Acetone and Crotonaldehyde Production during Steam Reforming of Ethanol over La 0.7 Sr 0.3 MnO 3–x Perovskite: Evidence for a Shared C4 Aldol Addition Intermediate

Here a mechanistic study was conducted on the catalytic conversion of ethanol over La 0.7 Sr 0.3 MnO 3–x perovskite catalysts in the presence and absence of water. The study sought insights into the path of C–C coupling toward acetone and crotonaldehyde and also into clarifying whether the lack of previous reports of C–C coupling over La 0.7 Sr 0.3 MnO 3–x (100) could be due to a “pressure gap”. Several types of experiments were performed at 400–800 K: flow experiments with a torr range reactant gas flown over La 0.7 Sr 0.3 MnO 3–x powders; ultra-high vacuum experiments with continuous gas exposures to a La 0.7 Sr 0.3 MnO 3–x (100) single-crystal sample; and torr range continuous gas exposures to a La 0.7 Sr 0.3 MnO 3–x (100) single-crystal sample. When ethanol and water were flown over La 0.7 Sr 0.3 MnO 3–x powders at 400–800 K, the products detected were ethene, acetaldehyde, acetone, crotonaldehyde, CO, CO 2 , and H 2 . Acetone was catalytically produced over both the La 0.7 Sr 0.3 MnO 3–x powder and the La 0.7 Sr 0.3 MnO 3–x (100) single-crystal sample at temperatures of 700–800 K when reaction conditions were on the order of 1 Torr of reactant gas and with an excess of water relative to ethanol (1 ethanol/9 water). Isotopic labeling with deuterium was used to gain insights into the C–C coupling reaction mechanism and paths in species with three and four carbons (C 3 and C 4 species). Additionally, steady-state isotopic transient kinetic analysis (SSITKA) experiments + simulations using carbon labeling of the ethanol feed were performed. Three mechanistic paths were considered for the C–C coupling step: the first two paths, A and B, involve coupling between two intermediates which are both in oxygen vacancies; and the third path, C, involves coupling between one intermediate in an oxygen vacancy and one intermediate outside of an oxygen vacancy. The results suggest that the dominant path to the C 3 product, acetone, depends on the conditions. The less active path (attributed to path A or B) occurs at 600–700 K and involves coupling between two irreversibly bound species. The more active path (attributed to path C) requires an excess of water, becomes dominant at 600–800 K, and involves coupling between one irreversibly bound species and one reversibly bound species. Based on these various observations from experiments and simulations, an elementary step is proposed for acetone formation involving a previously unreported C 4 transition state that is formed after aldol addition. Density functional theory calculations were performed based on this hypothesis, and it confirmed that this specific and previously unreported aldol addition path to acetone does exist and that this path consistent with the experimental data. In this path, C–C formation occurs to create a C 4 intermediate that is bound to an oxygen vacancy, then a hydrogen transfer with C–C bond breaking occurs that results in the production of the acetone molecule. The proposed mechanism is also consistent with the experimental observation that acetone formation has a greater than first-order dependence on the water vapor pressure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

The very high n Rydberg series of Ar 16+ in Alcator C-Mod tokamak plasmas

We report x-ray transitions of the very high-n Rydberg series in Ar 16+ have been observed from Alcator C-Mod tokamak plasmas. Individual emission lines up to 1s16p-1s 2 have been resolved and the central chord line brightnesses with principal quantum number n between 7 and 16 are generally found to decay as 1/n α , with α slightly larger than 3. In the plasma periphery, emission from 1s9p-1s 2 and 1s10p-1s 2 are found to be significantly enhanced relative to this decrease, indicative of selected population of these levels through charge exchange between background neutral deuterium in the ground state and Ar 17+ . An unresolved feature between the wavelengths of 1s27p-1s 2 and 1s30p-1s 2 is also present, which arises through charge exchange with neutral deuterium in the n* = 3 excited state. The brightnesses of transitions populated by charge exchange are spatially up/down asymmetric, with an excess on the side of the magnetic surface X-point. The relative brightness of the unresolved very high-n feature compared to 1s7p-1s 2 is found to increase with electron temperature and decrease with electron density. Simulations of line emission just on the long wavelength side of the Ar 16+ ionization limit indicate that the principal quantum number decay exponent is closer to α = 4 at very high n. The brightness dependence on n below 16 is in excellent agreement with calculations from the flexible atomic code package.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

The Very High n Rydberg Series of Ar^16+ in Alcator C-Mod Tokamak Plasmas

X-ray transitions of the very high-n Rydberg series in Ar^16+ have been observed from Alcator C-Mod tokamak plasmas. Individual emission lines up to 1s16p - 1s^2 have been resolved and the central chord line brightnesses with principal quantum number n between 7 and 16 are generally found to decay as 1/n^alpha, with alpha slightly larger than 3. In the plasma periphery, emission from 1s9p - 1s^2 and 1s10p - 1s^2 are found to be significantly enhanced relative to this decrease, indicative of selected population of these levels through charge exchange between background neutral deuterium in the ground state and Ar^17+. An unresolved feature between the wavelengths of 1s27p - 1s^2 and 1s30p - 1s^2 is also present, which arises through charge exchange with neutral deuterium in the n^* = 3 excited state. The brightnesses of transitions populated by charge exchange are spatially up/down asymmetric, with an excess on the side of the magnetic surface X-point. The relative brightness of the unresolved very high-n feature compared to 1s7p - 1s^2 is found to increase with electron temperature and decrease with electron density. Simulations of line emission just on the long wavelength side of the Ar^16$ ionization limit indicate that the principal quantum number decay exponent is closer to alpha = 4 at very high n. The brightness dependence on n below 16 is in excellent agreement with calculations from the Flexible Atomic Code package.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

60 years of science in ICF: from conception to scientific breakeven on the National Ignition Facility

The recent achievements of a burning plasma, fusion ignition, and scientific energy gain with deuterium-tritium (DT) fuel at Lawrence Livermore National Laboratory’s National Ignition Facility (NIF) represents a major milestone in the development of inertial confinement fusion (ICF) and all of fusion research. In these experiments, fuel pressures well in excess of hundreds of GBars were achieved in the compressed fuel, and robust alpha heating of the fuel, far in excess of the energy provided by the implosion, were demonstrated for the first time. These achievements occurred 60 years after the inception of ICF and the first laser demonstration, and were made possible by more than five decades of research at laser facilities around the world. Advances in laser technology both in wavelength and precision, motivated by improved understanding of laser-plasma interaction physics and the demands of targets; improvements in target fabrication inspired by the need to control and minimize hydrodynamic instabilities in the implosion; and multi-dimensional simulations and diagnostics have been critical to this achievement. This paper will summarize the scientific and technical advances, the surprises, and the challenges that had to be overcome to achieve these goals.

fusion↗
DOE OSTI2021

Detrimental effects and mitigation of the joint feature in double shell implosion simulations

Double shell capsules provide an attractive option in inertial confinement fusion experiments due to their potential for achieving a low-convergence, robust burn. However, these designs suffer from symmetry degradation and accompanying reduced fuel confinement due to the currently necessary joint between the two hemispheres of the outer shell. Here, the gap widens as a result of the excess ablation pressure produced by x rays that penetrate the joint during the drive phase, and this perturbation grows and imprints onto the inner shell during the collision. xRAGE Eulerian radiation-hydrodynamic simulations predict significant reductions in deuterium–tritium fusion yields compared to joint-less simulations when the depth of the outer joint is increased, whereas the performance is less sensitive to the depth of the inner gap. Here we examine the technique of plating the insides of the outer gap with a high-Z material to mitigate the impact of this feature. Gold-plating in quantities comparable to or exceeding the “missing” outer shell mass shows promise toward restoring both implosion symmetry and yield closer to the joint-less levels, and synthetic diagnostics suggest that high-energy x-ray radiographs can capture this shape retention of the inner and outer shells in experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Isotope dependence of transport in ST40 hot ion mode plasmas

The ST40 compact, high-field spherical tokamak, operating at 2.1 T and with 1.8 MW of neutral beam heating, achieved central carbon impurity ion temperatures in excess of 10 keV, surpassing their business milestone of 100 M °C (8.6 keV). The high temperature discharges were in the hot ion mode, with $T_i \gg T_e$, and they were achieved in both hydrogen and deuterium plasmas with deuterium neutral beam injection. In order to achieve the high temperature scenarios, careful wall conditioning and scenario optimization was carried out in $H^0 \rightarrow H^+$, $D^0 \rightarrow H^+$, and finally in $D^0 \rightarrow D^+$ plasmas. The TRANSP transport code was employed to study the dependence of confinement and transport on isotopic mass, and the conditions that led to the high measured central ion temperatures in the $D^0 \rightarrow H^+$ and $D^0 \rightarrow D^+$ plasmas. The kinetic profiles input into TRANSP were inferred from line-of-sight and limited radial measurements as well as consistency with a number of other experimental constraints. The TRANSP results first showed that the main species central ion temperature was only 0.5–1 keV lower than the measured carbon impurity temperature, and thus in the high performance plasmas also surpassed the 100 M °C level. TRANSP also showed that while the electron thermal conduction loss was dominant, reductions in central ion transport, and an effective decoupling of the ions from the electrons, led to an increase in central ion temperatures with increasing plasma mass. In fact, the associated confinement times exhibited a strong dependence on the isotopic mass of the thermal plasma. These preliminary results are foundations for dedicated experiments with full kinetic profile measurements on ST40 in the next run campaign.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Investigation of boron powder flow rates on real-time wall

The limit of boron flow rates for real-time conditioning of the first walls has been systematically investigated in the Experimental Advanced Superconducting Tokamak (EAST) with a full metal wall. Initially, solid boron injection demonstrated effective control over carbon impurities and deuterium recycling on the basis of pre-discharge boronization. A minimum flow rate, identified between 1.0 mg/s and 2.0 mg/s, was necessary for actively improving wall conditions under specific plasma operating scenarios, with this effect progressively enhancing as boron flow rates increased. Additionally, a maximum flow rate, estimated between 3.5 mg/s and 8.0 mg/s, was identified for these plasma conditions. When boron flow rates exceeded this maximum, boron-induced fueling effects influenced the plasma line-averaged density, and at excessively high flow rates, plasma disruption was observed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Burning plasma achieved in inertial fusion

The achievement of obtaining a burning plasma is a critical step toward self-sustaining fusion energy. A burning plasma is a fusion plasma where the alpha-particles created by the deuterium-tritium (DT) fusion reactions are the primary source of heating in the plasma, which is necessary to sustain and propagate the fusion reaction to enable high energy gain. After decades of fusion research, a burning plasma state has finally been achieved. Herein, we report upon the first burning-plasma experiments; this state was achieved using a strategy to increase the capsule spatial scale via two different implosion concepts, on the US National Ignition Facility. These experiments show energies from self-heating in excess of the mechanical work injected into the implosions satisfying several burning plasma metrics, the last experiment additionally shows that the fusion self-heating is greater than losses from radiation and heat conduction. These experiments triple the fusion yield performance and show significantly higher yield amplification from self-heating than prior results; remaining degradations can be reduced for even higher fusion performance.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Disruption thermal load mitigation with shattered pellet injection on the Joint European Torus (JET)

Disruption mitigation remains a critical, unresolved challenge for ITER. To aid in addressing this challenge, a shattered pellet injection (SPI) system was installed on JET and experiments conducted at a range of thermal energy fractions and stored energies in excess of 7 MJ. The primary goals of these experiments were to investigate the efficacy of the SPI on JET and the ability of the plasma to assimilate multiple pellets. Single pellet injections produced a saturation in total radiated energy (Wrad) with increasing injected neon content, suggesting total radiation of stored thermal energy. Further increases in injected neon quantities resulted in reduced cooling times and current quench (CQ) durations, indicating higher impurity assimilation. No significant variation in CQ duration or W rad was observed when varying the deuterium content at fixed neon quantities. Additionally, higher assimilation, inferred by shorter CQ durations, was measured when a mechanical punch was used to launch the pellets and this was attributed to a lower pellet velocity leading to higher solid content in the pellet plume and larger fragments penetrating deeper into the plasma. Radiation asymmetries averaged over the cooling time were inferred from Emis3D and ranged from 1.6 to 1.9. Asymmetries averaged over the entire disruption sequence were found to increase at higher thermal energy fractions. The radiated energy fractions decreased with increasing thermal energy fractions but this trend was eliminated when toroidal asymmetries were accounted for with Emis3D. Pure deuterium pellets were able to produce cooling times of up to 75 ms with a gradual loss in thermal stored energy of up to 80%. Experiments with multiple pellet injection indicated W rad can be increased through pellet superposition and density can be increased with an additional D2 injection without a reduction in W rad . KPRAD modelling accurately reproduced the cooling times and the CQ duration at high thermal energies. Assimilation estimates from KPRAD indicated CQ rates scale strongly whilst W rad scales weakly and saturates with assimilated neon content. Comparable W rad can be achieved with lower assimilated neon quantities as longer cooling times are attained. Thus reduced neon content can be preferential in a thermal load mitigation scheme as it may reduce radiation asymmetries and prevent flash melting.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗