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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Surface-Enhanced Raman Scattering (SERS) Studies of Disc-on-Pillar (DOP) Arrays: Contrasting Enhancement Factor with Analytical Performance

The use of nanomachining methods capable of reproducible construction of nano-arrayed devices have revolutionized the field of plasmonic sensing by the introduction of a diversity of rationally engineered designs. Significant strides have been made to fabricate plasmonic platforms with tailored interparticle gaps to improve their performance for surface-enhanced Raman scattering (SERS) applications. Over time, a dichotomy has emerged in the implementation of SERS for analytical applications, the construction of substrates, optimization of interparticle spacing as a means to optimize electromagnetic field enhancement at the localized surface plasmon level, and the substrate sensitivity over extended areas to achieve quantitative performance. Here, we assessed the enhancement factor of plasmonic Ag/SiO 2 /Si disc-on-pillar (DOP) arrays of variable pitch with its analytical performance for quantitative applications. Experimental data were compared with those from finite-difference time-domain (FDTD) simulations used in the optimization of the array dimensions. A self-assembled monolayer (SAM) of benzenethiol rendered highly reproducible signals (RSD ~4–10%) and SERS substrate enhancement factor (SSEF) values in the orders of 10 6 –10 8 for all pitches. Furthermore, spectra corresponding to rhodamine 6G (R6G) and 4-aminobenzoic acid demonstrated the advantages of using the more densely packed DOP arrays with a 160 nm pitch (gap= 40 nm) for quantitation in spite of the strongest SSEF was attained for a pitch of 520 nm corresponding to a 400 nm gap.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Electrospun Nanofiber Dopped with TiO2 and Carbon Quantum Dots for the Photocatalytic Degradation of Antibiotics

Novel photocatalysts were synthesized through the association of carbon quantum dots (CQDs) with commercial (P25) titanium dioxide (TiO2) by sonication. The resulting TiO2/CQDs composite was then incorporated into the polyamide 66 (PA66) biopolymer nanofibers using the electrospinning technique, considering a composite nanoparticles-to-polymer ratio of 1:2 in the electrospinning precursor solution. The produced nanofibers presented suitable morphology and were tested for the photocatalytic degradation under simulated solar radiation of 10 mg L−1 of amoxicillin (AMX) and sulfadiazine (SDZ), in phosphate buffer solution (pH 8.06) and river water, using 1.5 g L−1 of photocatalyst. The presence of the photocatalyst increased the removal of AMX in phosphate buffer solution by 30 times, reducing the AMX degradation half-life time from 62 ± 1 h (without catalyst) to 1.98 ± 0.06 h. Moreover, SDZ degradation half-life time in phosphate buffer solution was reduced from 5.4 ± 0.1 h (without catalyst) to 1.87 ± 0.05 h in the presence of the photocatalyst. Furthermore, the PA66/TiO2/CQDs were also efficient in river water samples and maintained their performance in at least three cycles of SDZ photodegradation in river water. The presented results evidence that the produced photocatalyst can be a promising and sustainable solution for antibiotics’ efficient removal from water.

Silva, Valentina (ORCID:0000000285394787)↗
NASA NTRS2001

Flight Experiment to Study Double-Diffusive Instabilities in Silver-Dopped Lead Bromide Crystals

The main objective of the present program is to understand thermosolutal convection during crystal growth of PbBr2-AgBr alloys. This involves identification of the growth conditions for microgravity experiments delineating the microsegregation, observation of convecto-diffusive instabilities and comparison with theoretical models. The overall objectives can be summarized as follows: 1. Observe and study the double diffusive and morphological instabilities in controlled conditions and to compare with theoretically predicted convective and morphological instability curves. 2. Study the three-dimensional morphological instabilities and resulting cellular growth that occur near the onset of morphological instability in the bulk samples under purely diffusive conditions. 3. Understand the micro-and macro-segregation of silver dopant in lead bromide crystals in microgravity. 4. Provide basic data on convective behavior in alloy crystals grown by the commercially important Bridgman crystal growth process.

Singh, N. B.↗
NASA NTRS2006

Dilution of Precision-Based Lunar Navigation Assessment for Dynamic Position Fixing

The NASA Vision for Space Exploration is focused on the return of astronauts to the Moon. While navigation systems have already been proven in the Apollo missions to the moon, the current exploration campaign will involve more extensive and extended missions requiring new concepts for lunar navigation. In contrast to Apollo missions, which were limited to the near-side equatorial region of the moon, missions under the Exploration Systems Initiative will require navigation on the moon's limb and far-side. As these regions have poor Earth visibility, a navigation system comprised solely of Earth-based tracking stations will not provide adequate navigation solutions in these areas. In this paper, a Dilution of Precision (DoP) based analysis of the performance of a network of Moon orbiting satellites is provided. The analysis extends previous analysis of a Lunar Network (LN) of navigation satellites by providing an assessment of the capability associated with a variety of assumptions. These assumptions are with regard to the navigation receiver and satellite visibility. The assessment is accomplished by making appropriately formed estimates of DoP. Different adaptations of DoP (i.e. GDoP, PDoP, etc.) are associated with a different set of assumptions regarding augmentations to the navigation receiver or transceiver. A significant innovation described in this paper is the "Generalized" Dilution of Precision. In the same sense that the various versions of DoP can be represented as a functional of the observability grammian, Generalized DoP is defined as a functional of the sum of observability grammians associated with a batch of radiometric measurements. Generalized DoP extends the DoP concept to cases in which radiometric range and range-rate measurements are integrated over time to develop an estimate of user position (referred to here as a 'dynamic' solution.) Generalized DoP allows for the inclusion of cases in which the receiver location is underdetermined when assessed in the usual 'kinematic' sense. The Generalized DoP concept is thereby a method to assess the navigation capability associated with constellations with sparse coverage. This alleviates the burden of performing a full "covariance analysis" for each point on the surface of the Moon.

Sands, Obed S.↗
NASA NTRS2006

Dilution of precision-based lunar navigation assessment for dynamic position fixing

The NASA vision of exploration is focused on the return of astronauts to the Moon [1]. While navigation systems have already been proven in the Apollo missions to the moon, the current exploration campaign will involve more extensive and extended missions requiring new concepts for lunar navigation. In contrast to Apollo missions, which were limited to the near-side equatorial region of the moon, missions under the Exploration Systems Initiative will require navigation on the moon’s limb and far-side. As these regions have poor Earth visibility, a navigation system comprised solely of Earth-based tracking stations will not provide adequate navigation solutions in these areas. In this paper, a Dilution of Precision (DoP) based analysis of the performance of a network of Moon orbiting satellites is provided. The analysis extends previous analysis of a Lunar Network (LN) of navigation satellites by providing an assessment of the capability associated with a variety of assumptions regarding the navigation receiver and satellite visibility. The assessment is accomplished by making appropriately formed estimates of DoP, with different adaptations of DoP (i.e. GDoP, PDoP, etc.) being associated with a different set of assumptions regarding augmentations to the navigation receiver or transceiver A significant innovation described in this paper is the “Generalized” Dilution of Precision. In the same sense that the various versions of DoP can be represented as a functional of the observability grammian, Generalized DoP is defined as a functional of the sum of observability grammians associated with a batch of radiometric measurements. Generalized DoP extends the DoP concept to cases in which radiometric range and range-rate measurements are integrated over time to develop an estimate of user position (referred to here as a ‘dynamic’ solution.) Generalized DoP allows for the inclusion of cases in which the receiver location is underdetermined when assessed in the usual ‘kinematic’ sense. The Generalized DoP concept is thereby a method to assess the navigation capability associated with constellations with sparse coverage without the burden of performing a full “covariance analysis” for each point on the surface of the Moon.

Berry, Kevin↗
DOE OSTI2024

Response of Graphite to Dynamic Loading and Hypervelocity Jet Impacts

The compressive strengths of three varieties of high purity graphite, PCEA, NBG-18, and NBG-25, as well as the depth of penetration of small-scale charges into these materials was experimentally determined. These grades are similar in density, ranging from 1.80 – 1.85 g/cc, and nominal apparent porosity, ranging from 18% to 20%, but provide a wide range in maximum grain or particle size from 10s to 1000s of µm. Two very different manufacturing methods are also represented; PCEA is extruded while NBG-18 and NBG-25 are iso-molded. The quasistatic and dynamic strengths of each grade were determined on a load frame and split-Hopkinson pressure bar, respectively. The depth of penetration (DOP) of two small-scale shaped charges, the Teledyne RP-1 and RP-4, was determined against graphite. The global response of the RP-4 impacts was markedly different as the PCEA samples remained intact while all the NBG-25 samples split into 2 or 3 pieces after the jet penetration had completed. However, for all tests, the trusted DOPs fell within 2 cm. Preliminary hydrocode modeling of the penetration events used existing models that were not designed for graphite. The results can be tuned to reasonably reproduce the DOP, but the wound channel geometry is not reproduced well. A model designed for graphite would need to represent graphite’s non-linear and energy dissipation characteristics.

36 MATERIALS SCIENCE↗
DOE OSTI2024

A global database of dissolved organic matter (DOM) concentration measurements in coastal waters (CoastDOM v1)

Abstract. Measurements of dissolved organic carbon (DOC), nitrogen (DON), and phosphorus (DOP) concentrations are used to characterize the dissolved organic matter (DOM) pool and are important components of biogeochemical cycling in the coastal ocean. Here, we present the first edition of a global database (CoastDOM v1; available at https://doi.org/10.1594/PANGAEA.964012, Lønborg et al., 2023) compiling previously published and unpublished measurements of DOC, DON, and DOP in coastal waters. These data are complemented by hydrographic data such as temperature and salinity and, to the extent possible, other biogeochemical variables (e.g. chlorophyll a, inorganic nutrients) and the inorganic carbon system (e.g. dissolved inorganic carbon and total alkalinity). Overall, CoastDOM v1 includes observations of concentrations from all continents. However, most data were collected in the Northern Hemisphere, with a clear gap in DOM measurements from the Southern Hemisphere. The data included were collected from 1978 to 2022 and consist of 62 338 data points for DOC, 20 356 for DON, and 13 533 for DOP. The number of measurements decreases progressively in the sequence DOC > DON > DOP, reflecting both differences in the maturity of the analytical methods and the greater focus on carbon cycling by the aquatic science community. The global database shows that the average DOC concentration in coastal waters (average ± standard deviation (SD): 182±314 µmol C L−1; median: 103 µmol C L−1) is 13-fold higher than the average coastal DON concentration (13.6±30.4 µmol N L−1; median: 8.0 µmol N L−1), which is itself 39-fold higher than the average coastal DOP concentration (0.34±1.11 µmol P L−1; median: 0.18 µmol P L−1). This dataset will be useful for identifying global spatial and temporal patterns in DOM and will help facilitate the reuse of DOC, DON, and DOP data in studies aimed at better characterizing local biogeochemical processes; closing nutrient budgets; estimating carbon, nitrogen, and phosphorous pools; and establishing a baseline for modelling future changes in coastal waters.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2017

Quantifying Uncertainties in Navigation and Orbit Propagation Analyses

A tool used to calculate dilution of precision (DOP) was created in order to assist the Space Communications and Navigation (SCaN) program to analyze current and future user missions. The SCaN Center for Engineering, Networks, Integration, and Communication (SCENIC) is developing a new user interface (UI) to augment and replace the capabilities of currently used commercial software, such as Systems Tool Kit (STK). The DOP tool will be integrated in the SCENIC UI and will be used to analyze the accuracy of navigation solutions. This tool was developed using MATLAB and free and open-source tools to save cost and to use already existing orbital software libraries. GPS DOP data was collected and used for validation purposes. The similarities between the DOP tool results and GPS data show that the DOP tool is performing correctly. Additional improvements can be made in the DOP tool to improve its accuracy and performance in analyzing navigation solutions.

dilution of precision↗
NASA NTRS2007

Dilution-of-Precision-Based Lunar Surface Navigation System Analysis Utilizing Earth-Based Assets

The NASA Vision for Space Exploration is focused on the return of astronauts to the Moon. Although navigation systems have already been proven in the Apollo missions to the Moon, the current exploration campaign will involve more extensive and extended missions requiring new concepts for lunar navigation. In contrast to Apollo missions, which were limited to the near-side equatorial region of the Moon, those under the Exploration Systems Initiative will require navigation on the Moon's limb and far side. These regions are known to have poor Earth visibility, but unknown is the extent to which a navigation system comprised solely of Earth-based tracking stations will provide adequate navigation solutions in these areas. This report presents a dilution-of-precision (DoP)-based analysis of the performance of a network of Earth-based assets. This analysis extends a previous analysis of a lunar network (LN) of navigation satellites by providing an assessment of the capability associated with a variety of assumptions. These assumptions pertain to the minimum provider elevation angle, nadir and zenith beam widths, and a total single failure in one of the Earth-based assets. The assessment is accomplished by making appropriately formed estimates of DoP. Different adaptations of DoP, such as geometrical DoP and positional DoP (GDoP and PDoP), are associated with a different set of assumptions regarding augmentations to the navigation receiver or transceiver.

Welch, Bryan W.↗
NASA NTRS2007

Dilution-of-Precision-Based Lunar Surface Navigation System Analysis Utilizing Lunar Orbiters

The NASA Vision for Space Exploration is focused on the return of astronauts to the Moon. Although navigation systems have already been proven in the Apollo missions to the Moon, the current exploration campaign will involve more extensive and extended missions requiring new concepts for lunar navigation. In contrast to Apollo missions, which were limited to the near-side equatorial region of the Moon, those under the Exploration Systems Initiative will require navigation on the Moon's limb and far side. Since these regions have poor Earth visibility, a navigation system comprised solely of Earth-based tracking stations will not provide adequate navigation solutions in these areas. In this report, a dilution-of-precision (DoP)-based analysis of the performance of a network of Moon orbiting satellites is provided. This analysis extends a previous analysis of a lunar network (LN) of navigation satellites by providing an assessment of the capability associated with a variety of assumptions. These assumptions pertain to the minimum surface user elevation angle and a total single satellite failure in the lunar network. The assessment is accomplished by making appropriately formed estimates of DoP. Different adaptations of DoP, such as geometric DoP and positional DoP (GDoP and PDoP), are associated with a different set of assumptions regarding augmentations to the navigation receiver or transceiver.

Welch, Bryan W.↗
NASA NTRS2015

Characterization of the Scale Model Acoustic Test Overpressure Environment using Computational Fluid Dynamics

The Scale Model Acoustic Test (SMAT) is a 5% scale test of the Space Launch System (SLS), which is currently being designed at Marshall Space Flight Center (MSFC). The purpose of this test is to characterize and understand a variety of acoustic phenomena that occur during the early portions of lift off, one being the overpressure environment that develops shortly after booster ignition. The pressure waves that propagate from the mobile launcher (ML) exhaust hole are defined as the ignition overpressure (IOP), while the portion of the pressure waves that exit the duct or trench are the duct overpressure (DOP). Distinguishing the IOP and DOP in scale model test data has been difficult in past experiences and in early SMAT results, due to the effects of scaling the geometry. The speed of sound of the air and combustion gas constituents is not scaled, and therefore the SMAT pressure waves propagate at approximately the same speed as occurs in full scale. However, the SMAT geometry is twenty times smaller, allowing the pressure waves to move down the exhaust hole, through the trench and duct, and impact the vehicle model much faster than occurs at full scale. The DOP waves impact portions of the vehicle at the same time as the IOP waves, making it difficult to distinguish the different waves and fully understand the data. To better understand the SMAT data, a computational fluid dynamics (CFD) analysis was performed with a fictitious geometry that isolates the IOP and DOP. The upper and lower portions of the domain were segregated to accomplish the isolation in such a way that the flow physics were not significantly altered. The Loci/CHEM CFD software program was used to perform this analysis.

Nielsen, Tanner↗
NASA NTRS1985

Detector calibration of the Indian cosmic ray experiment (IONS) in Space-Shuttle Spacelab-13

In the Indian cosmic ray experiment (IONS) in Spacelab-3 the intention is to study nuclei up to iron in low energy cosmic rays, using CR-39 (DOP) detectors. CR-39 (DOP) was exposed to He4, C12, O16, Ne20, Si28, Ar40, Cr52 and Fe56 accelerated beams from various accelerator facilities available around the world. Different beam energies and exposure angles were used. From these exposures, the charge resolution and energy resolution for the detector in the region of interest were studied. The effect of pre-annealing and depth on the response of our detector was studied. For isotopic resolution, exposed the detector samples were exposed to Ne2O and Ne22 accelerated beams. Samples of CR-39 (DOP) exposed to different accelerated heavy ions were kept in the detector module to take into account the effect of ambient conditions on detector response during the flight.

Yadav, J. S.↗
NASA NTRS2006

Dilution of Precision-Based Lunar Navigation Assessment for Dynamic Position Fixing

The NASA Vision for Space Exploration is focused on the return of astronauts to the Moon. While navigation systems have already been proven in the Apollo missions to the moon, the current exploration campaign will involve more extensive and extended missions requiring new concepts for lunar navigation. In contrast to Apollo missions, which were limited to the near-side equatorial region of the moon, missions under the Exploration Systems Initiative will require navigation on the moon's limb and far-side. As these regions have poor Earth visibility, a navigation system comprised solely of Earth-based tracking stations will not provide adequate navigation solutions in these areas. In this paper, a Dilution of Precision (DoP) based analysis of the performance of a network of Moon orbiting satellites is provided. The analysis extends previous analysis of a Lunar Network (LN) of navigation satellites by providing an assessment of the capability associated with a variety of assumptions. These assumptions are with regard to the navigation receiver and satellite visibility. The assessment is accomplished by making appropriately formed estimates of DoP. Different adaptations of DoP (i.e., GDoP, PDoP, etc.) are associated with a different set of assumptions regarding augmentations to the navigation receiver or transceiver.

Sands, Obed S.↗
NASA NTRS2023

Evaluation of Systematic Errors on Polarization Parameters from POLDER Instrument Data for Use In CLARREO Pathfinder-VIIRS Intercalibration

One of the CLARREO Pathfinder (CPF) mission’s science objectives is to intercalibrate the reflective solar bands of the NOAA-20 VIIRS instrument against high-accuracy CPF measurements utilizing coincident, co-angled, and co-located footprints acquired over diverse Earth targets. To alleviate the effect of high polarization sensitivity of select VIIRS channels on intercalibration analysis, the CPF team will limit the intercalibration footprints over low-polarized scene types, which will be identified based on an empirical estimation of their degree and angle of polarization (DOP and AOP) using POLDER data. This paper describes the methodology for evaluating systematic errors in the estimation of DOP and AOP for Earth-reflected radiances using POLDER’s polarized bands and investigates their potential impact on CPF-VIIRS intercalibration uncertainty. The systematic errors were found to be less than 0.01 for DOP and less than 2.2 deg. for AOP, which will have a negligible impact on CPF-VIIRS intercalibration uncertainty.

polarization↗
NASA NTRSDate not supplied

Assessing Utility of Different Orbits for a Lunar PNT Constellation

"As the Artemis program establishes a long-term presence on the lunar surface, lunar surface users will need an accurate source of Position, Navigation, and Timing (PNT). Under the LunaNet framework, NASA has proposed the Lunar Navigation System (LNS), a constellation of satellites in lunar orbit which will broadcast LunaNet’s Augmented Forward Signal (AFS) [1] to the lunar surface. LNS will have the objective of providing user position accuracies of 10 m and timing accuracies of 10 microseconds on the lunar surface and up to 200 km above the surface. Several classes of orbits are possibilities for the LNS constellation, including circular orbits, eccentric orbits, and various families of 3-body orbits. Each of these orbit classes have both advantages and disadvantages in their utility as PNT constellations. In this study we examine a wide variety of potential LNS constellations and evaluate their performance against several metrics, including: a. Dilution of Precision (DOP) performance over the lunar service volume and the South Pole region, during both the constellation buildup and after the constellation is completed. b. Number of satellites required to achieve required DOP performance. c. Relative dynamics of LNS satellites with respect to surface users. d. Signal in space error (SISE) performance, assuming orbit determination that includes the Global Positioning System (GPS), crosslinks, and monitor sites on the surface of the moon. e. Constellation insertion, station keeping, and disposal costs. f. Specific Concept of Operations (CONOPS) and engineering challenges associated with establishing and operating the constellations. (E.g., frequent station keeping, variable signal strength, divergent CONOPS for different planes of the constellation.) The system’s performance is considered both independently and in combination with other proposed systems, such as NASA’s Lunar Communication Relay and Navigation System (LCRNS) and ESA’s Moonlight constellation. The study concludes that a 3-plane Walker constellation at 6 lunar radii (slightly higher than GPS’s 4.2 earth radii from a geometry perspective, but significantly closer in an absolute sense) is a good candidate for the LNS constellation, providing the user with good SISE and DOP performance, while not requiring excessive station keeping or complex CONOPS. However, other viable concepts exist and could be chosen if early South Pole coverage is a driving factor in the system design."

navigation↗
DOE OSTI2021

Tuning Conjugated Polymer Chain Packing for Stretchable Semiconductors

We report in order to apply polymer semiconductors to stretchable electronics, they need to be easily deformed under strain without being damaged. A small number of conjugated polymers, typically with semicrystalline packing structures, have been reported to exhibit mechanical stretchability. Herein, a method is reported to modify polymer semiconductor packing-structure using a molecular additive, dioctyl phthalate (DOP), which is found to act as a molecular spacer, to be inserted between the amorphous chain networks and disrupt the crystalline packing. As a result, large-crystal growth is suppressed while short-range aggregations of conjugated polymers are promoted, which leads to an improved mechanical stretchability without affecting charge-carrier transport. Due to the reduced conjugated polymer intermolecular interactions, strain-induced chain alignment and crystallization are observed. By adding DOP to a well-known conjugated polymer, poly[2,5-bis(4-decyltetradecyl)pyrrolo[3,4-c]pyrrole-1,4-(2H,5H)-dione-(E)-1,2-di(2,2 '-bithiophen-5-yl)ethene] (DPPTVT), stretchable transistors are obtained with anisotropic charge-carrier mobilities under strain, and stable current output under strain up to 100%.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Simulations of Cellulose Synthesis Initiation and Termination in Bacteria

The processivity of cellulose synthesis in bacterial cellulose synthase (CESA) was investigated using molecular dynamics simulations and the hybrid quantum mechanics and molecular mechanics approach. Our results suggested that cellulose synthesis in bacterial CESA can be initiated with H 2 O molecules. The chain length or degree of polymerization (DOP) of the product cellulose is related to the affinity of the cellulose chain to the transmembrane tunnel of the enzyme. This opens up the possibility of generating mutants that would produce cellulose chains with desired chain lengths that could have applications in the biofuel and textile fields that depend on the DOP of cellulose chains.

59 BASIC BIOLOGICAL SCIENCES↗