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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Modeling and analysis of synthetic liquid fuel production from CO 2 and nuclear energy using methanol-to-diesel process

Electrofuels (e-fuels) are synthetic fuels produced from carbon dioxide (CO 2 ) and electricity for blending with or replacing petroleum fuels. Nuclear energy is an attractive energy feedstock for e-fuel production because of its low environmental footprint and its ability to provide steady heat and power essential for e-fuels production. We modeled and evaluated the cost and environmental footprint of e-fuels production in the distillate range for three nuclear power scales, 100, 500, and 1000 MWe, through methanol and olefins intermediates leveraging commercial or high technology readiness level (TRL) processes. Compared to the commonly studied e-fuels from Fischer Tropsch process that has a distillate yield of <70% with the rest being low value naphtha, the proposed process via methanol intermediate increases the product selectivity with distillate yield of 96% and only 4% naphtha. The modeled process has a carbon conversion ratio of 98%, and a process energy efficiency of 56% relative to the total equivalent nuclear electricity input. The e-fuel plant economics and GHG emissions were estimated by considering CO 2 collected from ethanol plants adjacent to nuclear power plants. The estimated minimum fuel selling prices (MFSP) of e-fuel is in the range of $5.7-$9.1/gal depending on e-fuel plant scale, electricity cost, and CO 2 transportation distance. The corresponding e-fuels life cycle GHG emissions is estimated in the range of 5-6 gCO 2 e/MJ of liquid fuel using the R&D Greenhouse gases, Regulated Emissions, and Energy use in Technologies (R&D GREET) model.

10 SYNTHETIC FUELS↗

Assessing the Impacts of CO 2 Reduction and Utilization Technologies on Regional Freshwater Resources

This work, a product of the Bioenergy Technologies Office (BETO)-supported multi-lab CO 2 Reduction and Upgrading for e-Fuels Consortium (CO 2 RUe), focuses on advanced research and development and cross-cutting evaluation of environmental, economic, and social sustainability for CO 2 reduction and upgrading for fuels and chemicals. The Consortium develops and de-risks advanced technologies that use renewable electricity to convert CO 2 into e-fuels and commodity chemicals. One key aspect of environmental sustainability consideration is water resources. This report summarizes a three-year study that analyzed the impacts of water consumption in select CO 2 reduction and utilization technologies in two future scenarios using a pair of water indices—water availability index and water stress footprint. The analyses also account for projected electricity grid mixes and their water withdrawal and water consumption demand in grid regions. The work identifies drivers, challenges, and critical areas in water sustainability, along with valuable insights into technological and regional factors. The study also explores the potential of using non-traditional water resources to reduce water stress and increase availability. These findings are intended to support industry stakeholders and BETO with the knowledge needed for informed decision-making, contributing to strategies to mitigate risks associated with the implementation of CO 2 utilization technologies.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Assessing the Impacts of CO 2 Reduction and Utilization Technologies on Regional Freshwater Resources

This work, a product of the Bioenergy Technologies Office (BETO)-supported multi-lab CO 2 Reduction and Upgrading for e-Fuels Consortium (CO 2 RUe), focuses on advanced research and development and cross-cutting evaluation of environmental, economic, and social sustainability for CO 2 reduction and upgrading for fuels and chemicals. The Consortium develops and de-risks advanced technologies that use renewable electricity to convert CO 2 into e-fuels and commodity chemicals. One key aspect of environmental sustainability consideration is water resources. This report summarizes a three-year study that analyzed the impacts of water consumption in select CO 2 reduction and utilization technologies in two future scenarios using a pair of water indices—water availability index and water stress footprint. The analyses also account for projected electricity grid mixes and their water withdrawal and water consumption demand in grid regions. The work identifies drivers, challenges, and critical areas in water sustainability, along with valuable insights into technological and regional factors. The study also explores the potential of using non-traditional water resources to reduce water stress and increase availability. These findings are intended to support industry stakeholders and BETO with the knowledge needed for informed decision-making, contributing to strategies to mitigate risks associated with the implementation of CO 2 utilization technologies.

09 BIOMASS FUELS↗

LES and RANS Spray Combustion Analysis of OME 3-5 and n-Dodecane

Clean-burning oxygenated and synthetic fuels derived from renewable power, so-called e-fuels, are a promising pathway to decarbonize compression–ignition engines. Polyoxymethylene dimethyl ethers (PODEs or OMEs) are one candidate of such fuels with good prospects. Their lack of carbon-to-carbon bonds and high concentration of chemically bound oxygen effectively negate the emergence of polycyclic aromatic hydrocarbons (PAHs) and even their precursors like acetylene (C 2 H 2 ), enabling soot-free combustion without the soot-NO x trade-off common for diesel engines. The differences in the spray combustion process for OMEs and diesel-like reference fuels like n-dodecane and their potential implications on engine applications include discrepancies in the observed ignition delay, the stabilized flame lift-off location, and significant deviations in high-temperature flame morphology. For CFD simulations, the accurate modeling and prediction of these differences between OMEs and n-dodecane proved challenging. This study investigates the spray combustion process of an OME 3 − 5 mixture and n-dodecane with advanced optical diagnostics, Reynolds-Averaged Navier–Stokes (RANS), and Large-Eddy Simulations (LESs) within a constant-volume vessel. Cool-flame and high-temperature combustion were measured simultaneously via high-speed (50 kHz) imaging with formaldehyde (CH 2 O) planar laser-induced fluorescence (PLIF) representing the former and line-of-sight OH* chemiluminescence the latter. Both RANS and LES simulations accurately describe the cool-flame development process with the formation of CH 2 O. However, CH 2 O consumption and the onset of high-temperature reactions, signaled by the rise of OH* levels, show significant deviations between RANS, LES, and experiments as well as between n-dodecane and OME. A focus is set on the quality of the simulated results compared to the experimentally observed spatial distribution of OH*, especially in OME fuel-rich regions. The influence of the turbulence modeling is investigated for the two distinct ambient temperatures of 900 K and 1200 K within the Engine Combustion Network Spray A setup. The capabilities and limitations of the RANS simulations are demonstrated with the initial cool-flame propagation and periodic oscillations of CH 2 O formation/consumption during the quasi-steady combustion period captured by the LES.

CFD↗

Combining CO2 Electrolysis with Biological Upgrading to Fuels and Chemicals: Turning Waste into Fuels

The utilization of flue gas-derived CO2 presents an opportunity to enhance carbon utilization in the bioethanol industry, contributing to the production of valuable products. In the context of a 90 million-gallon-per-year corn ethanol plant generating approximately 30 tons per hour of 99% pure CO2, a collaborative effort involving six national laboratories has been established. This initiative, known as the CO2 Reduction and Upgrading for e-Fuels (CO2RUe) Consortium, is funded by the Department of Energy's BioEnergy Technologies Office (BETO). The primary objective of the CO2RUe Consortium is to explore innovative approaches to harness CO2 as a valuable feedstock. This interdisciplinary consortium integrates electrochemistry with biological upgrading techniques, aiming to yield sustainable, value-added products and aviation fuels. The presentation will delve into the recent advancements in the realms of electrochemistry and biological upgrading, with a specific focus on formic acid and CO. Additionally, the talk will include an analysis of future electricity grid scenarios, technoeconomic evaluations, and life-cycle assessments. These assessments aim to provide a comprehensive understanding of the impacts of various conversion pathways on both cost and carbon intensity. The CO2RUe Consortium is at the forefront of steering the development of economically favorable and sustainable processes for CO2 utilization. The presentation will showcase the consortium's progress in driving the advancement of technology and processes, emphasizing the economic viability and sustainability of CO2 utilization within the broader context of the bioethanol industry.

biological upgrading↗

Abatement cost curve analysis of freight rail decarbonization alternatives

This paper investigates decarbonization alternatives for the freight rail industry, considering economic, environmental, and operational aspects. The study compares battery-electric and hydrogen fuel cell locomotives, drop-in fuels including biofuels and e-fuels, and overhead catenary electrification through abatement cost analyses. Scenario analysis identifies the cost-effectiveness of each of the technologies at different stages of decarbonization in the US Class 1 freight railroad network. We show that though battery locomotives offer a lower-cost decarbonization option in the considered scenarios, green hydrogen fuel-powered locomotives become more attractive when battery charging delays are considered. We introduce the concept of the technology margin to cater for uncertainties in battery charging operations and hydrogen fuel production for cases where carbon taxes are imposed on railroad operations. In conclusion, the study provides valuable insights for policymakers and rail operators, contributing to sustainable freight rail operations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Reducing Economy-Wide Greenhouse Gas Emissions with Electrofuels and Biofuels as the Grid Decarbonizes

Biofuels and electrofuels have the potential to complement electrification in speeding greenhouse gas emissions reductions, especially in hard-to-decarbonize sectors. Concentrated waste CO 2 streams that can be used as a feedstock for electrofuels, however, may become less available as the share of renewable electricity increases and industries undergo decarbonization. Here, we conduct an analysis with detailed treatment of biofuels and electrofuels to probe their role in decarbonizing multiple industrial sectors and transportation. We examine how the changing availability of CO 2 could affect electrofuel production and the potential role of direct air capture in stabilizing the supply of CO 2 . The results indicate that biofuels could fulfill 12% of the total final energy demand across all U.S. sectors in 2050. Using seven industrial source points of CO 2 available in 2050, 15,388 PJ of electrofuels could be produced, which amounts to 25% of the total final energy demand. This result holds even upon decarbonization that requires direct air capture to boost the CO 2 supply. Biofuels and e-fuels have the potential to reduce economy-wide GHG emissions by 7 and 21% beyond electrification alone. However, electricity consumption and land use grow markedly with decarbonization at scale.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Technology Impact and Resource Assessment of Existing and Planned U.S. Biofuel Production: Life Cycle Water Consumption, Water Stress, Land Use, and Criteria Air Pollutants

Biofuels have the potential to strengthen the U.S. energy supply, enhance energy security, and promote economic development. As the United States continues to expand biofuel production, quantifying resource requirements and location-specific constraints is crucial for planning, siting, and technology development to support long-term viability. Accordingly, this work assesses the life cycle resource consumption (water consumption, and land use), water stress and criteria air pollutants associated with expanded U.S. biofuel production over the 2020–2035 period, based on producers’ plans. We perform a bottom-up technology impact assessment and resource assessment by integrating facility-level production statistics with Argonne’s Research and Development (R&D) GREET model and county-level water-stress characterization factors from Available Water Remaining for the United States (AWARE-US) model. Results suggest that by 2035, biofuels could meaningfully contribute to U.S. energy demand, driven primarily by first-generation and waste-based feedstocks with plans for substantial capacity expansion, although cellulosic and e-fuel technologies remain limited. However, growth must be managed to minimize impacts on water resources and land use. These impacts vary by fuel type and facility location, specifically, projected expansion increases water consumption and can elevate water-stress impacts in certain regions like Nebraska, Kansas, Colorado, Idaho, California and North Texas. Direct land use also increases overall, particularly for first-generation feedstocks such as corn and soybeans. These findings underscore the need for continued technological improvements and innovative strategies to manage resource demands as the industry scales and to support complementary deployment within the evolving U.S. energy system.

09 BIOMASS FUELS↗

Cradle-to-Grave Lifecycle Analysis of U.S. Medium- and Heavy-Duty Vehicle-Fuel Pathways: A Greenhouse Gas Emissions Assessment of Current (2021) and Future (2035) Technologies

This study presents a cradle-to-grave lifecycle analysis of energy use and greenhouse gas (GHG) emissions for U.S. medium- and heavy-duty vehicles across current (2021) and future (2035) technologies using the Greenhouse gas, Regulated Emissions, and Energy use in Technologies (GREET) model with industry-vetted assumptions. Results vary across vehicle classes but point to common trends: today, battery electric vehicles (BEVs) offer significant (10–60%) GHG emissions reduction compared to diesel internal combustion engine vehicles and are the lowest emissions option per ton-mile of cargo movement, followed by hydrogen fuel cell electric vehicles (FCEVs) (5–50% emissions reduction). Emissions savings depend largely on the duty cycle and fuel economy of the vehicle type. Future vehicle technology advancements result in comparable emission reductions associated with BEVs and hydrogen FCEVs. Weight-limited BEV trucks see less per-ton-mile emissions reduction due to the impact of battery weight on increased vehicle weight and reduced payload capacity. By 2035, improvements in vehicle efficiency can reduce emissions across all powertrains. However, very low levels of emissions require switching vehicles’ use-phase fuel/energy to low-carbon fuels and electricity. Renewable diesel, e-fuels, hydrogen produced from natural gas with carbon capture and storage or renewables, and use of low-carbon electricity can all achieve over 70% reduction in GHG emissions from the current day diesel-based internal combustion engine vehicle.

alternative fuels↗

Life cycle greenhouse gas emissions and carbon intensity of U.S. fuel use and projection for the next 10 years-based on built capacity and expansion plans

The U.S. Inflation Reduction Act of 2022 supports biofuel production expansion through the 45Z clean fuel production tax credit, replacing previous 40A and 40B credits. This follows on the Renewable Fuel Standard from the Energy Policy Act of 2005 and its expansion in 2007. States like California, Oregon, and Washington also offer clean fuel credits. Meanwhile, federal agencies, including the U.S. Department of Energy, have advanced alternative fuel technologies through research and development funding. The surging interest in the biofuel industry has spurred the demand for biofuel supplies in the markets, although achieving profitability for advanced biofuels and low-carbon e-fuels remains challenging. This study aims to track U.S. alternative fuel production capacity expansion plans over the next 10 years and estimate impacts on greenhouse gas (GHG) emissions. By tracking built capacity and industry announcements of planned expansion, this study complements other studies which use models to predict changes in energy technologies and the associated GHG implications. Modeled projections of future technologies are often criticized for over or underestimating the cost and potential role of new technologies. The study focuses on sustainable aviation fuel, renewable diesel, ethanol, biodiesel, and renewable natural gas. Using facility-level data, we conducted a bottom-up analysis linking biofuel production pathways with corresponding pathways and parameterizations in the Argonne R&D GREET model. Results indicate that biofuel capacity could reach 3.8 exajoules in 2035, potentially reducing U.S. GHG emissions by 179 million tonnes, including the full life cycle. This corresponds to a 20% reduction in transportation and 5% in industry sector emissions by 2035, or a 3.6% reduction in economy-wide emissions. Overall, this study shows that while biofuel production capacity in the U.S. is expanding, the capacities remain limited compared to fuel demand. Uncertainty regarding the durability and extension of incentives may be dampening the pace of growth. Meanwhile, demonstrating the commercial potential for alternative fuels and climbing the learning curve for new technologies could lead to an increased pace of expansion in later years. This study offers insights for bioenergy stakeholders, highlighting biofuel technologies' contribution to U.S. energy system and emissions reduction over time based on producers' plans.

Biofuel Producers↗

Hydrogen Considerations Tree: Executive Deck [Slides]

The Hydrogen Considerations Tree is designed to enhance the understanding and capabilities of U.S. Agency for International Development Missions and country partners, empowering them to make informed decisions regarding potential support for hydrogen and its derivatives, such as e-fuels, hydrogen carriers, or ammonia, within their respective nations. Moreover, the Considerations Tree is designed to provide fundamental and applied information for the identification of deployment, regulation, policy priorities for hydrogen technologies in the context of each country or region. Key topics are organized into a "considerations tree," enabling stakeholders to systematically and holistically address technical, regulatory, economic, environmental, social, and analytical questions.

08 HYDROGEN↗

Guiding Sustainable Hydrogen Integration: A Capacity Building Approach

The Hydrogen Considerations Tree is designed to empower institutions to explore and consider the costs, benefits, and tradeoffs of hydrogen and its derivatives (e.g. e-fuels and green ammonia) and inform hydrogen strategy, policy and investment decisions within unique contexts around the world. Key topics are organized into a "Considerations Tree," enabling stakeholders to explore technical, regulatory, economic, environmental, social, and other analysis questions systematically and holistically.

HYDROGEN↗

The Chemistry of CO 2 Conversion: A Review

For much of the past century, carbon dioxide (CO 2 ) has received little attention scientifically outside of its role as a byproduct in the industrialization of the global economy. This trend has recently been upended where, due to mounting environmental concerns, CO 2 has been brought squarely into the public consciousness. This surge in activity has contributed to a once unimaginable idea now pervading the scientific community: could CO 2 , a highly stable byproduct of hydrocarbon combustion, be recycled and converted back into useful chemicals and fuels? Owing to its ubiquitous nature and availability at truly massive quantities, it is thought that CO 2 -based products could offer a meaningful pathway toward lowering the environmental impact of many of the top industrial products while also enhancing supply chain diversification and resilience. In this manuscript we provide a holistic review of the pathways for CO 2 conversion, the underlying chemistry and challenges involved in the transformation to products, and considerations for commercialization.

09 BIOMASS FUELS↗

Techno-Economic Analysis and Life Cycle Assessment of Alternative Fuels for Locomotives in the U.S. Freight Rail Sector

Freight rail is more energy-efficient than truck transport over long-haul distances, offering a low-energy and emissions-intensive option for transporting freight. This study evaluates techno-economic analysis and life cycle assessment of seven alternative unblended fuels for freight locomotive engines─biodiesel, renewable diesel (RD), bio-oils, methanol, dimethyl ether (DME), ethanol, and ammonia─across 16 fuel pathways utilizing soybean, corn, woody biomass, renewable hydrogen, and waste sources, e.g., sludge, manure, and industrial CO 2 , and compares these to conventional diesel. The minimum fuel selling price (MFSP) ranged from $\$2.05$ to $\$8.27$ per diesel gallon equivalent (2020 US dollars), with biocrude and RDs produced from hydrothermal liquefaction (HTL) of sludge having the lowest MFSPs due to coproduct credits and avoided waste treatment cost. Life cycle GHG emissions ranged from −41 to 53 g of CO 2 e/MJ. RD from waste via HTL achieves negative emissions by diverting sludge/manure from GHG-intensive conventional management. Few pathways such as biocrude, methanol, and DME require additional control for SO X emissions in the refinery, while ethanol, FT-diesel, and bio-oil require additional control for particulate matter emissions. Bio-oil and RD from sludge have lower marginal abatement cost or MAC (–$\$38$/tonne CO 2 lowest) while methanol and ammonia with renewable hydrogen have higher MAC ($\$490$/tonne CO 2 maximum).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The Challenge Ahead: A Critical Perspective on Meeting U.S. Growth Targets for Sustainable Aviation Fuel

With demand for jet fuel expected to more than double by 2050 and triple by 2070, continued and accelerated efforts to decarbonize the global aviation sector are needed to curtail rising emissions and avert the worst outcomes of climate change. In response to this call-to-action, the United States has unveiled the Sustainable Aviation Fuel (SAF) Grand Challenge, which seeks to expedite the development of alternative fuel pathways that offer a minimum of a 50% reduction in life cycle greenhouse gas emissions compared to conventional jet fuel. However, there is growing concern on whether sufficient biomass will be readily available to satisfy the projected sharp rise in demand for SAF. Carbon dioxide point-source emissions combined with rising supply from direct air capture efforts have the potential to complement and offset any supply gaps for biomass-derived SAF and other use cases. Independent of the chosen feedstock and conversion technology, numerous challenges persist across SAF production in seeking to drive down fuel cost and carbon intensity. To hit the 2030 target of 3 billion gal/yr, this means about a 100% compound annual growth rate in volumetric SAF production (about 130 times scale-up) will need to be realized. To achieve the stretch goal of 35 billion gallons of SAF per year by 2050, volumetric production must increase by a factor of 12 from the 3-billion-gal/year 2030 target of SAF Grand Challenge. The comparatively longer runway for 2050 combined with significant production volume growth suggests a more inclusive "all-hands-on-deck"-style approach will likely play a role. A key component in success lies in the coordinated research, development, demonstration, and deployment efforts by multiple federal agencies and industry partnerships.

09 BIOMASS FUELS↗

Energy Clusters Offshore: A Technology Feasibility Review

Globally, governments, companies, and other organizations have committed to achieving net-zero emissions targets in the coming decades. To achieve decarbonization at the scale and pace required to meet these targets, future energy systems will need renewable energy to serve 100% of the existing direct electricity demand, support additional electrification, and decarbonize the wider economy. An energy cluster offshore (ECO) is a concept that seeks to meet this challenge by integrating and optimizing large-scale renewable electricity generation, storage, and fuel production technologies and pairing them with other complementary uses, such as carbon capture or water desalination. This research project explores the techno-economic feasibility of ECO concepts by taking a holistic view of complex, multidisciplinary hybrid plant designs while considering different configurations and objectives. We will outline the most promising technology combinations and configurations, their functional requirements, and opportunities for optimization.

14 SOLAR ENERGY↗

Launch Alaska Transportation and Energy Accelerator (LATEA)

The Launch Alaska Transportation and Energy Accelerator (LATEA), funded through the U.S. Department of Energy Office of Technology Commercialization’s Energy Program for Innovation Clusters (EPIC),advanced deployment of innovative and efficient transportation and energy technology in Alaska from October 2021 through June 2025. The project was designed to leverage Launch Alaska’s accelerator model to identify, recruit, and support transportation technology companies with novel solutions to market needs while building the stakeholder networks, demonstration opportunities, and institutional capacity necessary to accelerate commercialization in one of the most challenging operating environments in the United States.

08 HYDROGEN↗