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At least 19 records

Lunar sample electrical properties

Electrical conductivity and dielectric constant measurements have been performed in vacuum on solid and soil samples over a wide range of temperatures and frequencies. The temperature dependence and the frequency response of the dielectric properties together with the temperature dependence of the DC conductivity have permitted us to propose a mathematical model describing the mechanisms controlling the electrical properties. In general, each lunar sample has several distributed mechanisms, each mechanism dominant in a particular temperature range.

Olhoeft, G. R.↗

Cation uptake by fine aggregate in hardened cement mortar and its effect on electrical properties

Electrical resistivity tests can be used to evaluate the transport properties of concrete and provide a durability assessment. However, the electrical resistivity is largely dependent on the pore solution composition and recent work suggests that some aggregates have the capacity for cation uptake. This study first aims to provide further evidence for adsorption of cations on aggregate surfaces, without formation of reaction products (e.g. alkali-silica reaction). Secondly, hardened mortar samples were prepared using a fine aggregate with a high alkali affinity and a non-reactive fine aggregate as a control. The electrical resistivity of mortars was measured, and the pore solution of these mortars was obtained through high-pressure extraction. The effect of aggregate moisture dilution on the pore solution was decoupled by using a pore partitioning model. The results indicate that aggregate minerology can influence the pore solution composition through cation uptake. Specific minerals of minor quantity, like biotite, may be responsible for cation exchange. While adsorbed cations strongly affected pore solution and formation factor measurement, the bulk resistivity measurements on hardened mortar were only marginally influenced. Research on other implications of similar aggregate interactions with pore solutions are an intriguing area for future research.

Alkali-aggregate reaction↗

Thermal and Electrical Properties of Isocyanate Derived Organic Aerogels for Cryogenic Insulation Applications

The use and storage of cryogens such as liquefied nitrogen, helium, hydrogen among others requires reliable and efficient thermal insulation systems. Passive insulation from high performance materials that are well-known for their inherent low thermal conductivity would reduce the overall costs involved in design, manufacture and maintenance of such systems. One such class of materials are referred to as aerogels. These materials are known for their low density, high mesoporosity, high surface areas, low thermal conductivity and high acoustic impedance. Aerogels were invented by S.S. Kistler in 1931 and the most common type are those made of silica. However, the inherent fragility of silica aerogels makes them hard to mass produce, and therefore applications have been limited. A major breakthrough was introduced by our team almost 20 years ago with the invention of polymer crosslinked silica aerogels. Those materials shifted attention to all-polymer aerogels that have overcome all fragility issues associated with their inorganic counterparts. This study focuses on such polymeric aerogels that can be mass produced as large monoliths while maintaining the low thermal conductivity of traditional silica aerogels over a wide temperature range. Manufacturing flexibility of polymeric aerogels allows fabrication of blocks and sheets that can be applied in various configurations to insulate cryogenic and superconducting devices. The thermal conductivity with 80 K and room temperature boundary are reported as well as other properties (electrical), that need to be considered when designing devices for cryogenic applications.

Churu, Gitogo↗

Electrical properties of Apollo 17 rock and soil samples and a summary of the electrical properties of lunar material at 450 MHz frequency

The dielectric constant and the voltage absorption length was measured for four Apollo 17 soil samples (73241, 74220, 75061, 76501) and for two Apollo 17 rock samples (76315 and 79135) at 450 MHz frequency. The dielectric constant and absorption length measurements made on the lunar samples are reviewed and related to the transition element concentration in these samples. The significance of the laboratory measurements for radar observations is discussed.

Gold, T.↗

Thermal, mechanical, and electrical properties of LSCo/mullite composite contact materials for solid oxide fuel cells

Lanthanum strontium cobaltite (LSCo) is considered as a good candidate cathode contact material for solid oxide fuel cells, due to high electrical conductivity. However, LSCo has a very large coefficient of thermal expansion (CTE) than the cells and metallic interconnects. As a result, poor mechanical stability is expected during thermal cycling. To minimize the CTE mismatch, we investigate a composite approach involving mixing LSCo with an inert material of low CTE, such as mullite at volume fractions from 0.1 to 0.4. Composite’s CTE shows a decreasing trend with increasing mullite volume fractions, and is consistent with model predictions. X-ray powder diffraction analysis of sintered LSCo/mullite composites exhibits no presence of other phases for samples aged for 500h at 800oC, indicating chemical compatibility. Electrical conductivity by a 4-pt method shows a decreasing trend with increasing mullite content. Contact strength of as-sintered and thermally cycled samples show that only the composite with 0.4 volume fraction has a measurable strength; the other composites have no strength. Overall, the composite approach is demonstrated in the LSCo/mullite system to lower the CTE and hence achieve thermal cycle stability. The addition of the inert phase to the LSCo matrix; however, also reduces the electrical conductivity.

Contact materials, LSCo, mullite, CTE, electrical ↗

Surface electrical properties experiment

The surface electrical properties (SEP) experiment was used to explore the subsurface material of the Apollo 17 landing site by means of electromagnetic radiation. The experiment was designed to detect electrical layering, discrete scattering bodies, and the possible presence of water. From the analysis of the data, it was expected that values of the electrical properties (dielectric constant and loss tangent) of lunar material in situ would be obtained. The basic principle of the SEP experiment is interferometry. This principle involves only the interference of two or more waves to produce an interference pattern. The inversion of the interference pattern in terms of the spatial distribution of the electrical properties is the basic aim of the experiment (fig. 15-1). The experiment is most easily understood in terms of a single dipole antenna for radiating electromagnetic energy and a loop receiver for measuring the magnitudes of the fields.

Simmons, G.↗

The Apollo 17 Surface Electrical Properties Experiment antenna performance.

The electrical properties of the lunar surface in the area of the Apollo 17 landing site were recently studied by the use of electromagnetic sounding techniques. The Apollo 17 Surface Electrical Properties Experiment was different from most other electromagnetic investigations of the lunar surface in that both the transmitting and receiving equipment was located directly on the lunar surface. The use of such inplace measurements of the electrical properties of the lunar surface is significant in that the exact structure and density of the soil contributes largely to the total electrical model of the moon. This paper will be concerned with a discussion of the transmitter antenna design problems for the Surface Electrical Properties Experiment as well as what is indicated by the returned lunar data about the transmitter antenna performance during the Apollo 17 mission.

Cubley, H. D.↗

The low-temperature electrical properties of carbonaceous meteorites

Electrical conductivities and dielectric constants have been measured over the temperature range 90-300 K on several carbonaceous chondrites and some terrestrial analogues. The conductivities of meteorites of different petrologic subtypes range over many orders of magnitude and the low-temperature activation energies are typically much smaller than those observed in terrestrial materials at higher temperatures. The electrical properties of carbonaceous chondrites vary systematically with chemical-mineralogical characteristics in that: (1) activation energy at low temperature is greater in the more volatile-rich meteorites containing hydrated silicates, and (2) conductivity is greater in the more reduced meteorites of higher petrologic subtype. These new data on the electrical properties of chondrites hold important implications for both the thermal and magnetic histories of small bodies in the early solar system.

Brecher, A.↗

Surface electrical properties experiment

The Surface Electrical Properties Experiment (SEP) was flown to the moon in December 1972 on Apollo 17 and used to explore a portion of the Taurus-Littrow region. SEP used a relatively new technique, termed radio frequency interferometry (RFI). Electromagnetic waves were radiated from two orthogonal, horizontal electric dipole antennas on the surface of the moon at frequencies of 1, 2, 4, 8, 16, and 32 Mhz. The field strength of the EM waves was measured as a function of distance with a receiver mounted on the Lunar Roving Vehicle and using three orthogonal, electrically small, loops. The interference pattern produced by the waves that travelled above the moon's surface and those that travelled below the surface was recorded on magnetic tape. The tape was returned to earth for analysis and interpretation. Several reprints, preprints, and an initial draft of the first publication of the SEP results are included. These documents provide a rather complete account of the details of the theory of the RFI technique, of the terrestrial tests of the technique, and of the present state of our interpretation of the Apollo 17 data.

Simmons, G.↗

Results of investigating thermal and electrical properties of lunar surface material and its analogs

Thermal and electrical properties are reported of lunar surface material returned to Earth by the Luna 16 automatic station and its terrestrial analogs studied in a vacuum and in a helium atmosphere. Study of the lunar surface material and its analogs showed that their specific heat capacity and electrical properties are similar in value but the coefficients of thermal conductivity differ. The results are compared with data on thermal and electrical properties of the surficial layer of the Moon obtained by indirect radiometric methods, and with results obtained for samples of lunar surface material returned to Earth by the crew of the Apollo 11 spacecraft.

Golovkin, A. R.↗

Electrical properties of adhesives used in hybrid microelectronic applications

This paper describes a test program conducted to determine the electrical properties of adhesives used in hybrid microelectronic applications and to develop test methods for measuring these properties. The electrical properties of transistor chips mounted with conductive adhesives are also measured, and the effect of long term storage at high temperature on these devices is determined.

Sergent, J. E.↗

Off-stoichiometric semiconductors Cu 1.33+x Zn 1.33-x In 1.33 Se 4 (x = 0, 0.1, 0.2 and 0.3): Synthesis, structure, and thermal and electrical properties

The synthesis, structure, and temperature dependent thermal and electrical properties of off-stoichiometric polycrystalline modified zinc blende quaternary chalcogenides Cu 1.33+x Zn 1.33-x In 1.33 Se 4 , where x = 0, 0.1, 0.2 and 0.3, are investigated. Temperature-dependent electrical properties reveal these compositions to be semiconductors with alteration of the carrier concentration and electrical transport via stoichiometric variation. The thermal conductivity is low for all specimens and intrinsic to these materials. First principles calculations are also reported in establishing a fundamental investigation that illustrates the large variation in stoichiometry that is possible in these materials. This stoichiometric variation results in the observed variation of the transport properties. Overall, the results presented reveal fundamental structure-property relationships in these quaternary chalcogenides, and provides a basis for further research into the viability for large stoichiometric variation in other materials that are of interest for technological applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗