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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Ionic Liquids at Electrified Interfaces: From Double Layers to Decomposition

Ionic liquids are versatile electrolytes whose properties at electrified interfaces have the potential to enable technologies such as supercapacitors and Li-metal battery anodes. At electrified carbon surfaces, ionic liquids form an electric double layer that stores energy and provides the foundation for supercapacitors. At electrified lithium surfaces, ionic liquids decompose to form a solid electrolyte interphase that has the potential to stabilize Li-metal anodes in rechargable batteries. The behavior of two ionic liquids of technological importance, [pyr14][TFSI] and [EMIM][BF4], are examined at these electrified interfaces through molecular dynamics and ab initio techniques.

Haskins, Justin B.↗
NASA NTRS2018

Ionic Liquids at Electrified Interfaces: from Double Layers to Decomposition

Ionic liquids are versatile electrolytes whose properties at electrified interfaces have the potential to enable technologies such as supercapacitors and Li-metal battery anodes. At electrified carbon surfaces, ionic liquids form an electric double layer that stores energy and provides the foundation for supercapacitors. At electrified lithium surfaces, ionic liquids decompose to form a solid electrolyte interphase that has the potential to stabilize Li-metal anodes in rechargable batteries. The behavior of two ionic liquids of technological importance, [pyr14][TFSI] and [EMIM][BF4], are examined at these electrified interfaces through molecular dynamics and ab initio techniques.

Haskins, Justin B.↗
NASA NTRS2018

Ionic Liquids at Electrified Interfaces: from Double Layers to Decomposition

Ionic liquids are versatile electrolytes whose properties at electrified interfaces have the potential to enable technologies such as supercapacitors and Li-metal battery anodes. At electrified carbon surfaces, ionic liquids form an electric double layer that stores energy and provides the foundation for supercapacitors. At electrified lithium surfaces, ionic liquids decompose to form a solid electrolyte interphase that has the potential to stabilize Li-metal anodes in rechargable batteries. The behavior of two ionic liquids of technological importance, [pyr14][TFSI] and [EMIM][BF4], are examined at these electrified interfaces through molecular dynamics and ab initio techniques.

Haskins, Justin B.↗
NASA NTRS2016

Computational and Experimental Study of Li-doped Ionic Liquids at Electrified Interfaces

We evaluate the influence of Li-salt doping on the dynamics, capacitance, and structure of three ionic liquid electrolytes, [pyr14][TFSI], [pyr13][FSI], and [EMIM][BF4], using molecular dynamics and polarizable force fields. In this respect, our focus is on the properties of the electric double layer (EDL) formed by the electrolytes at the electrode surface as a function of surface potential (Psi). The rates of EDL formation are found to be on the order of hundreds of picoseconds and only slightly influenced by the addition of Li-salt. The EDLs of three electrolytes are shown to have different energy storage capacities, which we relate to the EDL formation free energy. The differential capacitance obtained from our computations exhibits asymmetry about the potential of zero charge and is consistent with the camel-like profiles noted from mean field theories and experiments on metallic electrodes. The introduction of Li-salt reduces the noted asymmetry in the differential capacitance profile. Complementary experimental capacitance measurements have been made on our three electrolytes in their neat forms and with Li-salt. The measurements, performed on glassy carbon electrodes, produce U-like profiles, and Li-salt doping is shown to strongly affect capacitance at high magnitudes of Psi. Differences in the theoretical and experimental shapes and magnitudes of capacitance are rationalized in terms of the electrode surface and pseudocapacitive effects. In both neat and Li-doped liquids, the details of the computational capacitance profile are well described by Psi-induced changes in the density and molecular orientation of ions in the molecular layer closest to the electrode. Our results suggest that the addition of Li+ induces disorder in the EDL, which originates from the strong binding of anions to Li+. An in-depth analysis of the distribution of Li+ in the EDL reveals that it does not readily enter the molecular layer at the electrode surface, preferring instead to be localized farther away from the surface in the second molecular layer. This behavior is validated through an analysis of the free energy of Li+ solvation as a function of distance from the electrode. Free energy wells are found to coincide with localized concentrations of Li+, the depths of which increase with Psi and suggest a source of impedance for Li+ to reach the electrode.

Haskins, Justin B.↗
NASA NTRS2016

Li-Doped Ionic Liquid Electrolytes: From Bulk Phase to Interfacial Behavior

Ionic liquids have been proposed as candidate electrolytes for high-energy density, rechargeable batteries. We present an extensive computational analysis supported by experimental comparisons of the bulk and interfacial properties of a representative set of these electrolytes as a function of Li-salt doping. We begin by investigating the bulk electrolyte using quantum chemistry and ab initio molecular dynamics to elucidate the solvation structure of Li(+). MD simulations using the polarizable force field of Borodin and coworkers were then performed, from which we obtain an array of thermodynamic and transport properties. Excellent agreement is found with experiments for diffusion, ionic conductivity, and viscosity. Combining MD simulations with electronic structure computations, we computed the electrochemical window of the electrolytes across a range of Li(+)-doping levels and comment on the role of the liquid environment. Finally, we performed a suite of simulations of these Li-doped electrolytes at ideal electrified interfaces to evaluate the differential capacitance and the equilibrium Li(+) distribution in the double layer. The magnitude of differential capacitance is in good agreement with our experiments and exhibits the characteristic camel-shaped profile. In addition, the simulations reveal Li(+) to be highly localized to the second molecular layer of the double layer, which is supported by additional computations that find this layer to be a free energy minimum with respect to Li(+) translation.

molecular dynamics↗
NASA NTRS2023

Transient Optimization for the Betterment of Turbine Electrified Energy Management

Gas turbine engine transients are associated with degraded compressor operability, which must be addressed by the engine control system and accounted for in the engine design. Failure to do so may result in events such as compressor stall/surge and combustor blow out. Transient operability concerns constrain the engine design and can result in sacrifices of efficiency and/or thrust responsiveness. The traditional approach to transient operability management is control logic that limits the fuel flow command. A companion paper presents a strategy for optimizing the transient fuel flow control logic taking into consideration transient operability and thrust responsiveness. The study covered here extends this idea to an electrified gas turbine engine that employs a power/energy management concept known as Turbine Electrified Energy Management (TEEM). TEEM uses an electric power system interfaced with the engine (hence the term ‘electrified gas turbine engine’) to further improve transient operability and alleviate associated design constraints. There can be costs associated with implementing TEEM in terms of power and energy requirements that impact the size of the electrical power system. However, the results of this study show that through optimization of the transient limit logic, power and energy requirements needed to implement TEEM can be significantly reduced. Among the conclusions that can be drawn from the results of the illustrative application covered herein are: (1) there is a reduction in the electric machine power requirement to manage operability during accelerations by 200 to 400 hp, and (2) power transfer from the low pressure spool (LPS) to the high pressure spool (HPS) is the most effective option for improving operability during decelerations, followed by the options of only injecting power on the HPS or only extracting power from the LPS.

Turbine Electrified Energy Management↗
NASA NTRSDate not supplied

Transient Optimization for the Betterment of Turbine Electrified Energy Management

Gas turbine engine transients are associated with degraded compressor operability, which must be addressed by the engine control system and accounted for in the engine design. Failure to do so may result in events such as compressor stall/surge and combustor blow out. Transient operability concerns constrain the engine design and can result in sacrifices of efficiency and/or thrust responsiveness. The traditional approach to transient operability management is control logic that limits the fuel flow command. A companion paper presents a strategy for optimizing the transient fuel flow control logic taking into consideration transient operability and thrust responsiveness. The study covered here extends this idea to an electrified gas turbine engine that employs a power/energy management concept known as Turbine Electrified Energy Management (TEEM). TEEM uses an electric power system interfaced with the engine (hence the term ‘electrified gas turbine engine’) to further improve transient operability and alleviate associated design constraints. There can be costs associated with implementing TEEM in terms of power and energy requirements that impact the size of the electrical power system. However, the results of this study show that through optimization of the transient limit logic, power and energy requirements needed to implement TEEM can be significantly reduced. Among the conclusions that can be drawn from the results of the illustrative application covered herein are: (1) there is a reduction in the electric machine power requirement to manage operability during accelerations by 200 to 400 hp, and (2) power transfer from the low pressure spool (LPS) to the high pressure spool (HPS) is the most effective option for improving operability during decelerations, followed by the options of only injecting power on the HPS or only extracting power from the LPS.

transient↗
NASA NTRSDate not supplied

Transient Optimization for the Betterment of Turbine Electrified Energy Management

Gas turbine engine transients are associated with degraded compressor operability, which must be addressed by the engine control system and accounted for in the engine design. Failure to do so may result in events such as compressor stall/surge and combustor blow out. Transient operability concerns constrain the engine design and can result in sacrifices of efficiency and/or thrust responsiveness. The traditional approach to transient operability management is control logic that limits the fuel flow command. A companion paper presents a strategy for optimizing the transient fuel flow control logic taking into consideration transient operability and thrust responsiveness. The study covered here extends this idea to an electrified gas turbine engine that employs a power/energy management concept known as Turbine Electrified Energy Management (TEEM). TEEM uses an electric power system interfaced with the engine (hence the term ‘electrified gas turbine engine’) to further improve transient operability and alleviate associated design constraints. There can be costs associated with implementing TEEM in terms of power and energy requirements that impact the size of the electrical power system. However, the results of this study show that through optimization of the transient limit logic, power and energy requirements needed to implement TEEM can be significantly reduced. Among the conclusions that can be drawn from the results of the illustrative application covered herein are: (1) there is a reduction in the electric machine power requirement to manage operability during accelerations by 200 to 400 hp, and (2) power transfer from the low pressure spool (LPS) to the high pressure spool (HPS) is the most effective option for improving operability during decelerations, followed by the options of only injecting power on the HPS or only extracting power from the LPS.

transient↗
NASA NTRSDate not supplied

Numerical Propulsion System Simulation (NPSS) Power Systems Library

This presentation covers the Numerical Propulsion System Simulation (NPSS) Power Systems Library being developed by NASA. This library is a set of components, models, and interfaces for the NPSS language to enable building electric power system models for electrified propulsion systems. The presentation is to be given at the 3rd annual RVLT Toolchain Workshop, where attendees from across the eVTOL industry will be informed of NASA’s tools for eVTOL conceptual design from the vehicle level down through subsystems including propulsion, noise, electrical power, and others. It covers where the NPSS Power System Library fits into NASA’s RVLT toolchain and RVLT work in general, and will inform the audience of how the tool can be useful in their own work.

Electric vertical takeoff and landing↗
NASA NTRSDate not supplied

Hybrid-Electric Aero-Propulsion Controls Testbed Results

NASA is supporting the development of Electrified Aircraft Propulsion (EAP) technology due to its potential to reduce aircraft fuel burn, emissions, and noise as well as improving safety and performance. One focus of this research is the electrification of conventional turbomachinery propulsion systems, which offers ways to improve the performance and operability of turbine-engine powered aircraft through the addition of electro-mechanical systems. These hybrid-electric turbine engines provide additional actuation and energy management control opportunities for improving stability and transient response behavior. This paper summarizes the results of a Hardware-in-the-Loop (HIL) test performed at the NASA Electric Aircraft Testbed (NEAT) during the summer of 2022. The test demonstrates the feasibility and performance of an advanced energy management control strategy by integrating a simulated turbofan engine with scaled electro-mechanical hardware. A full-scale real-time reference model of a geared turbofan was run alongside a scaled electro-mechanical system representing the electrified turbofan components operating at a megawatt-scale power level. The model was interfaced with the hardware through a novel closed-loop control and scaling algorithm that emulated the dynamic speed and torque response of the turbofan shafts. The control strategy was implemented on the electrical machines connected to the emulated turbomachinery shafts. The results from the testbed are compared against simulations that predict the testbed and geared turbofan model operation. The energy management control strategy successfully changed the operating point of the engine model and improved its stability during throttle transients. These results also demonstrate the success of the novel closed loop control and scaling approach for emulating turbomachinery and elevate the Technology Readiness Level (TRL) of the energy management control strategy.

Aeronautics↗
NASA NTRS2023

Hybrid-Electric Aero-Propulsion Controls Testbed Results

NASA is supporting the development of Electrified Aircraft Propulsion (EAP) technology due to its potential to reduce aircraft fuel burn, emissions, and noise as well as improving safety and performance. One focus of this research is the electrification of conventional turbomachinery propulsion systems, which offers ways to improve the performance and operability of turbine-engine powered aircraft through the addition of electro-mechanical systems. These hybrid-electric turbine engines provide additional actuation and energy management control opportunities for improving stability and transient response behavior. This paper summarizes the results of a Hardware-in-the-Loop (HIL) test performed at the NASA Electric Aircraft Testbed (NEAT) during the summer of 2022. The test demonstrates the feasibility and performance of an advanced energy management control strategy by integrating a simulated turbofan engine with scaled electro-mechanical hardware. A full-scale real-time reference model of a geared turbofan was run alongside a scaled electro-mechanical system representing the electrified turbofan components operating at a megawatt-scale power level. The model was interfaced with the hardware through a novel closed-loop control and scaling algorithm that emulated the dynamic speed and torque response of the turbofan shafts. The control strategy was implemented on the electrical machines connected to the emulated turbomachinery shafts. The results from the testbed are compared against simulations that predict the testbed and geared turbofan model operation. The energy management control strategy successfully changed the operating point of the engine model and improved its stability during throttle transients. These results also demonstrate the success of the novel closed loop control and scaling approach for emulating turbomachinery and elevate the Technology Readiness Level (TRL) of the energy management control strategy.

Aeronautics↗
NASA NTRSDate not supplied

Implementation Approach for an Electrified Aircraft Concept Vehicle in a Research Flight Simulator

A flight simulation test capability for the SUbsonic Single Aft eNgine (SUSAN) Electrofan is under development. SUSAN is a regional jet transport aircraft concept that utilizes electrified propulsion to gain benefits in fuel usage, emissions, and cost. The process, which involves the integration of independently developed models and their subsequent implementation in a flight simulator, is general and can be applied to a variety of aircraft types. However, the use of electrified propulsion adds complexity beyond that of a traditional aircraft, especially with regard to the pilot interface. The way the pilot interacts with the engines will differ from current practice, and the information displayed to the pilot will necessarily include additional variables beyond what is normally displayed in a traditional cockpit.

flight simulation↗
NASA NTRSDate not supplied

Hybrid-Electric Aero-Propulsion Controls Laboratory: Overview and Capability

A hardware-in-the-loop (HIL) laboratory is developed to investigate control technologies for electrified aircraft propulsion (EAP). The laboratory emulates a propulsion system by reproducing the mechanical shaft interface to the electrical power system in hardware. The experimental electric power system includes supercapacitor energy storage and a dynamically variable electrical load. A novel method of scaling power and inertia is provided in software to accurately reproduce the transient, off-design turbomachinery performance dynamics without including actual turbomachinery. An overview of how the HIL system can accommodate a broad range of EAP architectures, including power extraction and insertion, with capability for transient energy management is described. The real-time system operates in the 100kW power class and is instrumented to emulate turbomachinery – power system interactions. The platform is an agile, flexible laboratory for low-cost, risk-reduction development and testing of propulsion control, operability, and energy management technologies.

controls↗
NASA NTRSDate not supplied

Hybrid-Electric Aero-Propulsion Controls Laboratory: Overview and Capability

A hardware-in-the-loop (HIL) laboratory is developed to investigate control technologies for electrified aircraft propulsion (EAP). The laboratory emulates a propulsion system by reproducing the mechanical shaft interface to the electrical power system in hardware. The experimental electric power system includes supercapacitor energy storage and a dynamically variable electrical load. A novel method of scaling power and inertia is provided in software to accurately reproduce the transient, off-design turbomachinery performance dynamics without including actual turbomachinery. An overview of how the HIL system can accommodate a broad range of EAP architectures, including power extraction and insertion, with capability for transient energy management is described. The real-time system operates in the 100kW power class and is instrumented to emulate turbomachinery – power system interactions. The platform is an agile, flexible laboratory for low-cost, risk-reduction development and testing of propulsion control, operability, and energy management technologies.

Controls↗
NASA NTRS2021

Development and Characterization of Lightweight Durable Composite Conductor for Cables

Sustainable aviation in the form of electrified propulsion is likely to lead to an increase in the electrical assets contained within a single aircraft. As a result, it is desirable to design light weight conductor materials, thus reducing the payload of components like motor windings, low voltage signal cables, and transmission cables for data and power. One approach involves replacing pure Cu wiring with metalized CNT composites. This paper evaluates a framework for modeling overall conductivity and current sharing within such composites. Processing methods and parameters were refined. Select electroplated samples outperformed pure Cu in conductivity and had comparable ultimate tensile strengths. Tensile strengths are expected to improve with an additional densification step during processing. Acoustic emission data was used to predict the failure mechanism of the composite. Theories explaining improved intrinsic conductivity are discussed, with a focus on chemical and mechanical interactions at the Cu-CNT interface. These include Cu infiltration of CNT crevices, CNT oxidation, activity at defects in CNT walls, and the release of carbide-forming metals from CNT walls. Validating any or all these theories will require further work replicating data, collecting electron micrographs and conducting chemical analyses.

Metalized CNT↗
NASA NTRS2022

Novel Processing, Testing and Characterization of Copper/Carbon Nanotube (Cu/CNT) Yarn Composite Conductor

Sustainable electrified aircraft propulsion (EAP) is likely to lead to an increase in the electrical wiring contained within a single aircraft. Since the electrical resistance and mass of copper (Cu) conductors are associated with power losses, it is desirable to design high-conductivity lightweight conductor materials, thus reducing the mass of components like motor windings, low-voltage signal cables, and transmission cables for data and power to improve the overall energy efficiency. This paper describes a unique framework for manufacturing metalized carbon nanotube (CNT) composite conductors, measuring their electrical conductivity and strength, and modeling the overall conductivity and current sharing within such composites. Tensile testing was conducted on the processed composite conductor cables with the use of acoustic emission and electrical resistivity to determine stress-dependent-failure mechanisms while monitoring the electrical conductivity. The average of measured electrical conductivities of annealed Cu/CNT samples from batch 5 was greater than theoretical predictions by 9.8 percent and was also greater than the conductivity of pure annealed Cu by 4.8 percent and had comparable ultimate tensile strengths. Additionally, those Cu/CNT samples provide a 13.5% weight saving over current state of the art copper wires. Theories explaining improved intrinsic conductivity are discussed.

Metalized CNT↗
NASA NTRSDate not supplied

Implementation Approach for an Electrified Aircraft Concept Vehicle in a Research Flight Simulator

This paper describes a process to develop a flight simulation test capability for the SUbsonic Single Aft eNgine (SUSAN) Electrofan, a subsonic regional jet transport aircraft concept that utilizes electrified propulsion to gain benefits in fuel usage, emissions, and cost. The process, which involves the integration of independently developed models and their subsequent implementation in a flight simulator, is general and can be applied to a variety of aircraft types. However, the use of electrified propulsion architectures has the potential to add complexity beyond that of a traditional aircraft, especially with regard to the pilot interface. The way the pilot interacts with the thrust producing components could vary significantly between architectures, and the information displayed to the pilot will necessarily include additional variables beyond what is normally displayed in a traditional cockpit. This paper describes the integration process in general, as well as specific accommodations made for the architecture under consideration.

electrified aircraft propulsion↗
NASA NTRS2022

Implementation Approach for an Electrified Aircraft Concept Vehicle in a Research Flight Simulator

This paper describes a process to develop a flight simulation test capability for the SUbsonic Single Aft eNgine (SUSAN) Electrofan, a subsonic regional jet transport aircraft concept that utilizes electrified propulsion to gain benefits in fuel usage, emissions, and cost. The process, which involves the integration of independently developed models and their subsequent implementation in a flight simulator, is general and can be applied to a variety of aircraft types. However, the use of electrified propulsion architectures has the potential to add complexity beyond that of a traditional aircraft, especially with regard to the pilot interface. The way the pilot interacts with the thrust producing components could vary significantly between architectures, and the information displayed to the pilot will necessarily include additional variables beyond what is normally displayed in a traditional cockpit. This paper describes the integration process in general, as well as specific accommodations made for the architecture under consideration.

flight simulation↗