The electro-optic effect in barium titanate
Electro-optic effect in single crystal barium titanate
BARIUM TITANATE↗
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Determination of the low-frequency linear electro-optic effect in tetragonal batio sub 3.
LF linear electro-optic effect at 5461 angstroms in single crystal barium titanate in temperature range from 5 to 120 degrees C
ELECTRO-OPTICS↗
The strain-free electro-optic effect in single- crystal barium titanate.
Strain-free electro-optic effect in single crystal barium titanate as function of temperature between 10 and 120 degrees C
ELECTRO-OPTICS↗
Electro-optic sampling of classical and quantum light
Full characterization of electric-field waveforms in amplitude and phase is achieved across the terahertz to visible spectral range through interaction with an optical pulse shorter than a half-cycle period via the Pockels (linear electro-optic) effect. This technique of electro-optic sampling has become an indispensable tool in various areas, including ultrafast pump-probe, time-domain and frequency-comb spectroscopies, quantum optics, high-harmonic generation, and attosecond science, and holds great promise for further advances. Not only does it enable spectroscopic measurements with record dynamic range and temporal resolution, along with massively parallel real-time spectral data acquisition, but its remarkable sensitivity also allows the detection of vacuum fluctuations, i.e., “zero-point motion” of electric fields, profoundly impacting our understanding of the fundamental laws of nature.
Benea-Chelmus, Ileana-Cristina (ORCID:000000024814↗
Efficient on-chip terahertz generation and detection with GaN photoconductive emitters
Photoconductive emitters for terahertz generation hold promise for highly efficient down-conversion of optical photons because it is not constrained by the Manley-Rowe relation. Existing terahertz photoconductive devices, however, faces limits in efficiency due to the semiconductor properties of commonly used GaAs materials. Here, we demonstrate that large bandgap semiconductor GaN, characterized by its high breakdown electric field, facilitates the highly efficient generation of terahertz waves in a coplanar stripline waveguide. Towards this goal, we investigated the excitonic contribution to the electro-optic response of GaN under static electric field both through experiments and first-principles calculations, revealing a robust excitonic Stark shift. Using this electro-optic effect, we developed a novel ultraviolet pump-probe spectroscopy for in-situ characterization of the terahertz electric field strength generated by the GaN photoconductive emitter. Our findings show that terahertz power scales quadratically with optical excitation power and applied electric field over a broad parameter range. We achieved an optical-to-terahertz conversion efficiency approaching 100% within the 0.03–1 THz bandwidth at the highest bias field (116 kV/cm) in our experiment. Further optimization of GaN-based terahertz generation devices could achieve even greater optical-to-terahertz conversion efficiencies.
Uzundal, Can B↗
Colossal Cryogenic Electro‐Optic Response Through Metastability in Strained BaTiO 3 Thin Films
The search for thin film electro-optic materials that can retain superior performance under cryogenic conditions has become critical for quantum computing. Barium titanate thin films show large linear electro-optic coefficients in the tetragonal phase at room temperature, which is severely degraded down to ≈200 pm V −1 in the rhombohedral phase at cryogenic temperatures. There is immense interest in manipulating these phase transformations and retaining superior electro-optic properties down to liquid helium temperature. Utilizing the thermodynamic theory of optical properties, a large low-temperature electro-optic response is designed by engineering the energetic competition between different ferroelectric phases, leading to a low-symmetry monoclinic phase with a massive electro-optic response. The existence of this phase is demonstrated in a strain-tuned BaTiO 3 thin film that exhibits a linear electro-optic coefficient of 2516 ± 100 pm V −1 at 5 K, which is an order of magnitude higher than the best reported performance thus far. Importantly, the electro-optic coefficient increases by 100 × during cooling, unlike the conventional films, where it degrades. Further, at the lowest temperature, significant higher order electro-optic responses also emerge. These results represent a new framework for designing materials with property enhancements by stabilizing highly tunable metastable phases with strain.
barium titanate↗
Erbium quantum memory platform with long optical coherence via back-end-of-line deposition on foundry-fabricated photonics
Realizing scalable quantum interconnects necessitates the integration of solid-state quantum memories with foundry photonics processes. While prior photonic integration efforts have relied upon specialized, laboratory-scale fabrication techniques, this work demonstrates the monolithic integration of a quantum memory platform with low-loss foundry photonic circuits via back-end-of-line deposition. We deposited thin films of titanium dioxide (TiO 2 ) doped with erbium (Er) onto silicon nitride nanophotonic waveguides and studied Er optical coherence at subkelvin temperatures with photon echo techniques. Furthermore, we suppressed optical dephasing through ex-situ oxygen annealing and optimized measurement conditions, which yielded an optical coherence time of 64 μs (a 5-kHz homogeneous linewidth) and slow spectral diffusion of 27 kHz over 4 ms, results that are comparable to state-of-the-art Er nanophotonic devices. Combined with second-long electron spin lifetimes and demonstrated electrical control of Er emission, our findings establish Er:TiO 2 on foundry photonics as a manufacturable platform for ensemble and single-ion quantum memories.
Electro-optic effects↗
Electro-optic crystals and their use for light modulation
Several methods of modulating a beam of light, which have been described in the literature, utilizing the influence of an electrical signal on the birefringence of certain crystals, will be reviewed. These employ optics which respond to the state of polarization of a light beam, and include intensity modulation, position modulation, and the possibility of an electrically tuned optical filter. The influence of the piezo-optic, or strain contribution to the total electro-optic response in the design of an optoelectronic device will be discussed. Current experimental work in our laboratory in which the strain contribution is separated from the direct effect will be described. The strain-free effect is measured by applying a step voltage to the crystal, and observing the initial response. The electro-optical transient response can be observed with nanosecond time resolution. An electronic sampling technique is used to extract the desired response from photon noise. The stress-free or low-frequency effect is measured similarly but at low audio frequencies. Single crystal tetragonal BaT10 3 has been investigated in detail with the result that the strain-optic contribution to the low frequency effect r_(c) = r_(33)—r_(13) is about 80% of the total, where it is only 10% in KDP and 45% in ADP. The magnitudes of the electro-optic effect, dielectric constant, and other related properties are compared for several materials potentially useful as electro-optic modulators, and some comments are made about the practical problems of building a modulator.
ELECTRO-OPTICS↗
Effects of aerospace technology on civilian life through scientific instrumentation
Electro-optics contributions to optical astronomy, image transducers, and laser research and effect on civilian technology
IMAGE TRANSDUCER↗
Communication system uses modulated laser beam
Electro-optical system is placed on a satellite to effect communications between two remote stations. The system employs an essentially passive, retrodirective, laser beam modulator-reflector.
Minott, P. O.↗
Electronic Structures of Iron in Oxide Glasses via 1s3p Resonant Inelastic X-ray Scattering
Electronic structures of iron in glasses are essential for unraveling the effect of transition metals on amorphous networks and controlling the electro-optical and transport properties of advanced glasses and amorphous energy-storing materials. The electronic configurations around iron in glasses, however, remain not well understood due to the structural disorders arising from multiple iron species with distinct valence, coordination, and spin states. Here, the first 1s3p resonant inelastic X-ray scattering (RIXS) for oxide glasses identifies hidden electronic configurations for Fe 2+ and Fe 3+ in amorphous networks. The results allow us to quantify the composition-induced evolution of oxygen ligand–field interactions of high-spin Fe 3d states with varying valence and coordination environments in complex glasses. The distinct electronic structures account for the electronic origins of iron-induced changes in the glass properties. The results offer prospects for a simultaneous probing of valence, coordination, and spin states of transition metals in diverse multicomponent oxide glasses and functional amorphous solids via 1s3p RIXS.
Kim, Yong-Hyun [Seoul National Univ. (Korea, Repub↗
Dynamic Atomistic Polar Structure Underpins Ultrahigh Linear Electro-Optic Coefficient in Transparent Ferroelectric Ceramics
Transparent ferroelectrics with high linear electro-optic (EO) coefficients are critical for advanced electro-optical devices. However, achieving optical transparency in ferroelectric ceramics remains challenging due to visible light scattering caused by defects such as domain walls, grain boundaries, and pores. Here, we report the successful fabrication of transparent ferroelectric ceramics through innovative chemical composition design and an advanced two-step sintering process in the La-doped Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3 system. The optical transparency, which is near the theoretical upper limit, can be attributed to the wide band gap and the minimization of light scattering of defects. By minimizing porosity and engineering grain/domain sizes to differ significantly from the wavelengths of visible light, we suppress scattering, achieving optical transparency near the theoretical upper limit. Strikingly, these ceramics exhibit an ultrahigh linear EO coefficient of ∼1417 pm/V, over 65 times greater than that of LiNbO 3 single crystals, the current industry standard. We attribute this exceptional performance to dynamic atomistic polar structures within switchable, thermally stable domains, which enhance electronic polarization sensitivity. This mechanism is corroborated by dielectric spectroscopy, high-resolution transmission electron microscopy and simulation. Our findings offer insights into the design of cost-effective transparent materials with exceptional EO properties, paving the way for next-generation electro-optical devices.
36 MATERIALS SCIENCE↗
Fusion and fission of particle-like chiral nematic vortex knots
Vortex knots have been seen decaying in many physical systems. Here we describe topologically protected vortex knots, which remain stable and undergo fusion and fission and conserve a topological invariant. The host medium, a chiral nematic liquid crystal, exhibits intrinsic chirality of molecular alignment, whereas cores of the vortex lines are structurally achiral regions in which a molecular twist cannot be defined. We can reversibly switch between fusion and fission of these vortex knots by applying electric pulses. This reveals the physical embodiments of concepts in knot theory, such as connected sums of knots and band surgeries. Our findings demonstrate the interplay of chirality effects at hierarchical levels from constituent molecules to the host medium and the energetically stable chiral vortex knots. This emergent physical behaviour may enable applications in electro-optics and photonics in which such fusion and fission processes of vortex knots can be used for controlling light.
Applied mathematics↗
Roadmap for Photonics with 2D Materials
Triggered by advances in atomic-layer exfoliation and growth techniques, along with the identification of a wide range of extraordinary physical properties in self-standing films consisting of one or a few atomic layers, two-dimensional (2D) materials such as graphene, transition metal dichalcogenides (TMDs), and other van der Waals (vdW) crystals now constitute a broad research field expanding in multiple directions through the combination of layer stacking and twisting, nanofabrication, surface-science methods, and integration into nanostructured environments. Photonics encompasses a multidisciplinary subset of those directions, where 2D materials contribute remarkable nonlinearities, long-lived and ultraconfined polaritons, strong excitons, topological and chiral effects, susceptibility to external stimuli, accessibility, robustness, and a completely new range of photonic materials based on layer stacking, gating, and the formation of moiré patterns. These properties are being leveraged to develop applications in electro-optical modulation, light emission and detection, imaging and metasurfaces, integrated optics, sensing, and quantum physics across a broad spectral range extending from the far-infrared to the ultraviolet, as well as enabling hybridization with spin and momentum textures of electronic band structures and magnetic degrees of freedom. The rapid expansion of photonics with 2D materials as a dynamic research arena is yielding breakthroughs, which this Roadmap summarizes while identifying challenges and opportunities for future goals and how to meet them through a wide collection of topical sections prepared by leading practitioners.
2D materials↗
How Do You Hear a Quantum Computer Whisper?
Quantum transduction is the process of upconverting microwave quantum signals into optical signals to develop quantum networks through optical fibers outside the dilution refrigerator, enabling connections between quantum technologies on the quantum internet. In this project, upconversion is achieved by directing an optical laser and the microwave quantum signal into an electro-optic bulk crystal. The crystal is housed within a Superconducting Radio Frequency (SRF) cavity designed to maximize the overlap between the microwave field and the crystal volume. In the presence of microwaves, the refractive index of the crystal changes through the Pockels effect. This change in refractive index modifies the propagation of the optical field within the crystal, allowing the quantum information carried by the microwave field to be transferred to the optical field. This study focuses on coupling laser light from suspended waveguide chips into the whispering-gallery modes (WGMs) of the crystal to enable transduction. The coupling efficiency between the optical field in the suspended waveguide and the WGM depends on the position of the laser spot on the crystal. To address this challenge, a feedback-based algorithm is being developed to fine-tune the waveguide position so that the optical signal is coupled efficiently into the crystal. After passing through the crystal, the optical signal is detected by a photodiode connected to an oscilloscope. The algorithm evaluates the coupling quality and iteratively adjusts the waveguide position to maximize coupling efficiency. The expected outcome is an automated waveguide alignment method that improves optical coupling and enables more efficient microwave-to-optical quantum transduction.
Karanastasis, Mihael [Fermilab]↗
Giant Nonreciprocity and Gyration through Modulation-Induced Hatano-Nelson Coupling in Integrated Photonics
Asymmetric energy exchange interactions, also known as Hatano-Nelson type couplings, enable the study of non-Hermitian physics and associated phenomena like the non-Hermitian skin effect and exceptional points (EPs). Since these interactions are by definition nonreciprocal, there have been very few options for implementations in integrated photonics. Here, in this work, we show that asymmetric couplings are readily achievable in integrated photonic systems through time-domain dynamic modulation. We experimentally study this concept using a two-resonator photonic molecule produced in a lithium niobate on insulator platform that is electro-optically modulated by rf stimuli. We demonstrate the dynamic tuning of the Hatano-Nelson coupling between the resonators, surpassing the asymmetry that has been achieved in previous work, to reach an EP for the first time. We are additionally able to flip the relative sign of the couplings for opposite directions by going past the EP. Using this capability, we show that the through-chain transport can be configured to exhibit both giant (~60 dB) optical contrast as well as photonic gyration or nonreciprocal π phase contrast.
42 ENGINEERING↗
Quantum critical electro-optic and piezo-electric nonlinearities
Although electro-optic (EO) nonlinearities are essential for many quantum and classical photonics applications, a major challenge is inefficient modulation in cryogenic environments. Guided by the connection between phase transitions and nonlinearity, we identify the quantum paraelectric perovskite SrTiO 3 as a strong cryogenic EO [>500 picometers per volt (pm/V)] and piezo-electric material (>90 picocoulombs per newton) at T = 5 K, at frequencies to at least 1 megahertz. Furthermore, by tuning SrTiO 3 toward quantum criticality, we more than double the EO and piezo-electric effects, demonstrating a linear Pockels coefficient above 1000 pm/V. Furthermore, our results probe the link between quantum phase transitions, dielectric susceptibility, and nonlinearity, unlocking opportunities in cryogenic optical and mechanical systems and providing a framework for discovering new nonlinear materials.
Anderson, Christopher P. [Stanford University, CA ↗
Single-shot electro-optic sampling with arbitrary terahertz polarization
With the recent development of diversity electro-optic sampling (DEOS), significant progress has been made in the range of applicability of single-shot EOS measurements, allowing broadband THz waveforms to be captured in a single shot over large temporal windows. In addition to the decrease in acquisition time compared to standard multishot data acquisition, this technique allows measurements on systems far from equilibrium with large shot-to-shot noise or with irreversible or poorly repeatable dynamics. Although DEOS has been demonstrated and verified for linearly polarized THz waveforms, we investigate the effects resulting from the presence of a secondary polarization component. This imposes new challenges for accurate waveform reconstruction, and opens the opportunity to measure out complex polarization states such as arbitrary elliptically polarized THz field. We demonstrate a single-shot diversity-electro-optic-sampling-based approach to capture both x- and y-THz fields simultaneously with a single (110)-cut EO crystal for THz polarimetry and ellipsometry over a wide range of frequencies.
Lenz, Maximilian [University of California, Los An↗